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Room-temperature sputtered-SnO_(2) modified anode toward efficient TiO_(2)-based planar perovskite solar cells

science China(Technological sciences) 2021年第9期64卷 1995-2002页

作者： LI Dan LI Yong LIU ZhiKe WANG DaPeng LIU ShengZhong(Frank) Key Laboratory of Applied Surface and Colloid Chemistry Ministry of EducationShaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringShaanxi Normal UniversityXi’an 710119China

It is of the utmost importance to promote the charge transport and retard the heterojunction barrier in the functional layers and at their adjacent interfaces to pursuit excellent photovoltaic characteristics of the perovskite solar cells(PSCs). Here, roomtemperature sputtered-SnO_(2) films are introduced to modify FTO anode for improving carrier extraction and aligning energy band in the TiO_(2)-based planar PSCs. For the SnO_(2)-modified substrate with suitable sputtering duration, the following TiO_(2) film exhibits smoother surface roughness, less surface defects, and lower the trap-assisted interfacial recombination than that directly on the FTO, further facilitating the growth of perovskite grain size and promoting the extraction efficiency of charge carriers. On the basis of the optimized SnO_(2)(6 nm)/TiO_(2) stack layer as electron transport layer(ETL), the PSC exhibits an outstanding power conversion efficiency of 21.45%, which is much better than that of the single TiO_(2)-based device(19.68%). More importantly, the cell with the bilayer ETL shows a long-term stability against air, maintaining over 76% of its initial efficiency after 40 d. These achievements suggest that this study provides a feasible path to design energy level alignment and low temperature ETL for highly efficient and stable PSCs.

关键词： sputtered-SnO_(2) anode modification bilayer ETL TiO_(2) PSC device

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Plating Al Coating on High-Strength Steel in Chloroaluminate Ionic Liquid Under Pulse Current Modes

SSRN

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SSRN 2024年

作者： Nan, Yang Li, Wen Li, Shaojie Wei, Qi Li, Weiping Aviation Key Laboratory of Science and Technology on Advanced Surface Engineering AVIC Manufacturing Technology Institute Beijing100024 China School of Materials Science and Engineering Beihang University Beijing100191 China

Aluminum coating is a potential candidate for cadmium coating replacement due to its excellent corrosion resistance and nontoxicity. Among the fabrication methods of Al coating, plating Al via ionic liquids has drawn major attention of researchers because of the superiority of controllability, stability and low energy consumption. However, the evolution rules of plating aluminum on high-strength steel via pulse current modes at room temperature requires deeper investigation. In this work, pulse current density and pulse duty factor are regulated to reveal the plating patterns of Al on 300M high-strength steel in AlCl3-EMIC (2:1 in mole) ionic liquid. It is found that higher current density can significantly facilitate the nucleation of Al grains and the compactness of morphology, while an enlarged pulse duty factor tends to result in more regular Al crystals. When the current density and the pulse duty factor are fixed at 20 mA cm−2 and 80%, the densest and most uniform aluminum coating is obtained. The component of Al coating is verified to be pure Al crystals with good adhesion and the plating process achieves a high current efficiency of 97.27%. Under the protection of Al coating, the impedance and galvanic corrosion current density of 300M steel substrate are optimized by two orders of magnitude, while the corrosion current density is markedly decreased from 5.58 μA cm−2 to 0.77 μA cm−2. © 2024, The Authors. All rights reserved.

关键词： Morphology

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Study on Microstructure and Corrosion Behavior of Welded Joints of 2a12 and 2a97 Aluminum Alloys by Fsw

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SSRN 2024年

作者： Li, Wen Li, Shaojie Nan, Yang Bai, Xuepiao Li, Weiping School of Materials Science and Engineering Beihang University Beijing100191 China Aviation Key Laboratory of Science and Technology on Advanced Surface Engineering AVIC Manufacturing Technology Institute Beijing100024 China

T-shaped joints of high-strength aluminum alloy welded by friction stir welding (FSW) are expected to replace the traditional riveting structures. However, the corrosion of T-joint still hinder the popularization of FSW in aerospace industry. Herein, T-joints of 2A12 and 2A97 aluminum alloys are prepared and studied via structural characterization and corrosion tests. The microstructures and constituents of different micro zones in T-joints before and after corrosion tests are characterized and analyzed particularly. The internal relationship between different micro zones in T-joints and their corrosion behaviors are clarified, which provides theoretical basis for improving welding process and surface protection after welding. © 2024, The Authors. All rights reserved.

关键词： Friction stir welding

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Low Trap Density Para-F Substituted 2D PEA_(2)PbI_(4)(X=Cl,Br,I)Single Crystals with Tunable Optoelectrical Properties and High Sensitive X-Ray Detector Performance

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Research 2023年第1期2022卷 273-283页

作者： Jiayu Di Haojin Li Li Chen Siyu Zhang Yinhui Hu Kai Sun Bo Peng Jie Su Xue Zhao Yuqi Fan Zhenhua Lin Yue Hao Peng Gao Kui Zhao Jingjing Chang State Key Discipline Laboratory of Wide Band Gap Semiconductor Technology School of MicroelectronicsXidian University710071 XianChina Advanced Interdisciplinary Research Center for Flexible Electronics Academy of Advanced Interdisciplinary ResearchXidian University710071 Xi'anChina Key Laboratory of Applied Surface and Collid Chemistry National Ministry of EducationSchool of Materials Science and EngineeringShaanxi Normal University710119 Xi'anChina CAS Key Laboratory of Design and Assembly of Functional Nanostructures Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China

Exploring halogen engineering is of great significance for reducing the density of defect states in crystals of organic-inorganic hybrid perovskites and hence improving the crystal ***,high-quality single crystals of PEA_(2)PbI_(4)(X=CI,Br,I)and their para-F(p-F)substitution analogs are prepared using the facile solution method to study the effects of both p-F substitution and halogen anion *** p-F substitution,the triclinic PEA_(2)PbX_(4)(X=Cl,Br)and cubic PEA_(2)PbX_(4)(X=I)crystals unifies to monoclinic crystal structure for p-F-PEA_(2)PbX_(4)(X=Cl,Br,I)*** p-F substitution and halogen engineering,together with crystal structure variation,enable the tunability of optoelectrical ***,after the p-F substitution,the energy levels are lowered with increased Fermi levels,and the bandgaps of p-F-PEA_(2)PbX_(4)(X=Cl,Br,I)are slightly *** from the enhancement of the charge transfer and the reduced trap density by p-F substitution and halogen anion engineering,the average carrier lifetime of the p-F-PEA_(2)PbI_(4)is obviously *** with PEA_(2)PbI_(4)the X-ray detector based on p-F-PEA_(2)PbI_(4)single crystals exhibits higher radiation stability under high-dose X-ray irradiation,implying long-term operando stability.

关键词： properties stability substitution

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Simultaneously achieving high energy density and responsivity in submicron BaTiO_(3) film capacitors integrated on Si

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Journal of advanced Ceramics 2024年第2期13卷 198-206页

作者： Jun Ouyang Yinxiu Xue Chuanqi Song Meiling Yuan Kun Wang Yuyao Zhao Hongbo Cheng Hanfei Zhu Chao Liu Institute of Advanced Energy Materials and Chemistry School of Chemistry and Chemical EngineeringQilu University of Technology(Shandong Academy of Sciences)Jinan 250353China Key Laboratory of Key Film Materials&Application for Equipment School of Material Sciences and EngineeringXiangtan UniversityXiangtan 411105China School of Materials Science and Engineering Shandong UniversityJinan 250061China Academic Affairs Office Civil Aviation University of ChinaTianjin 300300China China Tobacco Shandong Industrial Co. Ltd.Jinan 250014China

In the research field of energy storage dielectrics,the“responsivity”parameter,defined as the recyclable/recoverable energy density per unit electric field,has become critically important for a comprehensive evaluation of the energy storage capability of a *** this work,high recyclable energy density and responsivity,i.e.,W_(rec)=161.1 J·cm^(-3) and ξ=373.8 J·(kV·m^(2))^(-1),have been simultaneously achieved in a prototype perovskite dielectric,BaTiO_(3),which is integrated on Si at 500℃ in the form of a submicron thick *** ferroelectric film features a multi-scale polar structure consisting of ferroelectric grains with different orientations and inner-grain ferroelastic domains.A LaNiO_(3) buffer layer is used to induce a{001}textured,columnar nanograin microstructure,while an elevated deposition temperature promotes lateral growth of the nanograins(in-plane diameter increases from~10-20 nm at lower temperatures to~30 nm).These preferably oriented and periodically regulated nanograins have resulted in a small remnant polarization and a delayed polarization saturation in the film’s P-E behavior,leading to a high recyclable energy ***,an improved polarizability/dielectric constant of the BaTiO_(3) film has produced a much larger maximum polarization than those deposited at lower temperatures at the same electric field,leading to a record-breaking responsivity for this simple perovskite.

关键词： energy storage energy density responsivity BaTiO_(3) dielectric capacitor Si

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Study on coal pyrolysis characteristics by combining different pyrolysis reactors

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Chinese Journal of Chemical engineering 2024年第12期76卷 1-9页

作者： Xiaoping Su Zhao Wang Ning Li Longjian Li Ping Zhang Ming Sun Xiaoxun Ma School of Chemical Engineering Northwest Minzu UniversityKey Laboratory of Environment-Friendly Composites of the State Ethnic Affairs CommissionGansu Provincial Biomass Function Composites Engineering Research CenterKey Laboratory for Utility of Environment-Friendly Composites and Biomass in Universities of Gansu ProvinceGansu Province Research Center for Basic Sciences of Surface and Interface ChemistryLanzhou 730030China School of Chemical Engineering Northwest UniversityInternational Science&Technology Cooperation Base of MOST for Clean Utilization of Hydrocarbon ResourcesChemical Engineering Research Center of the Ministry of Education for Advanced Use Technology of Shanbei EnergyShaanxi Research Center of Engineering Technology for Clean Coal ConversionCollaborative Innovation Center for Development of Energy and Chemical Industry in Northern ShaanxiXi'an 710069China

The pyrolysis process of Shendong coal(SD)was first studied by combining the characteristics of thermal gravimetric(TG),pyrolysis-gas chromatography/mass spectrometry(Py-GC/MS)and Gray-King assay(GK).The results show that the order of coke yields is G-K(76.35%(mass))>TG(73.11%(mass))>Py(70.03%(mass)).G-K coke yield caused by condensation reaction and secondary reaction accounts for 3.08%(mass)and 3.24%(mass),*** with slow pyrolysis,fast pyrolysis has stronger fracture ability to coal molecules and can obtain more O-compounds,mono-ring aromatics and ***,the content of phenolics increases significantly from 15.49%to 35.17%,but the content of multi-ring aromatics decreases from 23.13%to 2.36%.By comparing the compositions of Py primary tar and G-K final tar,it is found that secondary reactions occurred during G-K pyrolysis process include the cleavage of alkane and esters,condensation of mono-ring aromatics with low carbon alkene,ring opening,isomerization of tri-ring aromatics,hydrogenation of aromatics and acids.

关键词： Shendong coal Different pyrolysis reactors Pyrolysis process

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Structural parameters and molecular model of Shendong subbituminous coal

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Chinese Journal of Chemical engineering 2024年第12期76卷 124-134页

作者： Xiaoping Su Ning Li Longjian Li Reyila Tuerhong Yongchong Yu Ping Zhang Qiong Su Tao Shen Ming Sun Xiaoxun Ma Key Laboratory of Environment-Friendly Composite Materials of the State Ethnic Affairs Commission Gansu Provincial Biomass Function Composites Engineering Research CenterKey Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in University of Gansu ProvinceGansu Province Research Center for Basic Sciences of Surface and Interface ChemistryCollege of Chemical EngineeringNorthwest Minzu UniversityLanzhou 730124China School of Chemical Engineering Northwest UniversityInternational Science&Technology Cooperation Base of MOST for Clean Utilization of Hydrocarbon ResourcesChemical Engineering Research Center of the Ministry of Education for Advanced Use Technology of Shanbei EnergyShaanxi Research Center of Engineering Technology for Clean Coal ConversionCollaborative Innovation Center for Development of Energy and Chemical Industry in Northern ShaanxiXi'an 710069China

Coal has a highly complex chemical structure,similar to polymers,coal is a macromolecular structure composed of a large number of“similar compounds”,which is called the basic structural *** coal structure is the basis of its transformation and ***(SD)coal was analyzed by FTIR,XRD,XPS,and *** results show that SD coal normalized structure formula is C_(100)H_(68.5)O_(35.7)N_(1.2)S_(0.2)and the average number of aromatic rings is 1.98.-CH_(2)-content accounts for about 82%in aliphatic CeH region,and the ratio of ether bond CeO,aromatic ether C-O and C=O is about 2:1:11 in oxygen-containing functional group *** d_(002),L_(C),L_(a)and N_(C)of S_(D)coal microcrystalline structure parameters are 0.1832 nm,1.4688 nm,2.0852 nm and 9.017,*** carbon and aliphatic carbon ratios of SD coal are 55.67%and 29.97%,aromatic cluster size and average methylene chain length are 0.224 and *** on these structural parameters,molecular model of SD coal was constructed with^(13)C SSNMR experimental spectra as a *** model was constructed with an atom composition of C_(214)H_(214)O_(49)N_(2)S.

关键词： Subbituminous coal Structural parameters ^(13)C CP/MAS SSNMR Molecular model

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Graded 2D/3D(CF_(3)-PEA)_(2)FA_(0.85)MA_(0.15)Pb_(2)I_(7)/FA_(0.85)MA_(0.15)PbI_(3) heterojunction for stable perovskite solar cell with an efficiency over 23.0%

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Journal of Energy Chemistry 2022年第2期31卷 480-489页

作者： Yuan Cai Jialun Wen Zhike Liu Fang Qian Chenyang Duan Kun He Wenjing Zhao Sheng Zhan Shaomin Yang Jian Cui Shengzhong(Frank)Liu Key Laboratory of Applied Surface and Colloid Chemistry Ministry of EducationShaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringShaanxi Normal UniversityXi’an 710119ShaanxiChina iChEM Dalian Institute of Chemical PhysicsUniversity of Chinese Academy of SciencesDalian National Laboratory for Clean EnergyChinese Academy of SciencesDalian 116023LiaoningChina

The replacement of small cations with bulkier organic cations containing long alkyl chains or benzene rings to form a thin two-dimensional(2D)perovskite passivation layer on three-dimensional(3D)perovskite(2D/3D)has become a promising strategy for improving both the efficiency and stability of perovskite solar cells(PSCs).The 2 D layer defines the interfacial chemistry and physics at the 2D/3D bilayer and endows the 2D/3D structure with better chemical and thermal ***,2D/3D(CF_(3)-PEA)_(2) FA_(0.85)MA_(0.15)Pb_(2)I_(7)/FA_(0.85)MA_(0.15)PbI_(3) planar heterojunction perovskite was produced using a facile interfacial ion exchange *** 2 D(CF_(3)-PEA)_(2) FA_(0.85)MA_(0.15)Pb_(2)I_(7) capping layer can not only passivate the FA_(0.85)MA_(0.15)PbI_(3) film but also act as super-hydrophobic layer to inhibit water diffusion and significantly enhance the *** 2D capping layer can also establish a unique graded band structure at the perovskite/Spiro-OMeTAD interface and lead to p-type doping for Spiro-OMeTAD layer which is beneficial for efficient charge *** PSCs based on this 2D/3D heterojunction yield a champion power conversion efficiency(PCE)of 23.1%and improved *** device maintains 84%output for 2400 h aging under ambient environmental conditions without encapsulation,and maintains 81%for 200 h under illumination with *** work will inspire the design of more fluorinated 2D perovskite interfaces for advanced photovoltaics and beyond.

关键词： Perovskite solar cells Heterojunction Two-dimensional FA_(0.85)MA_(0.15)PbI_(3) High efficiency

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Double Side Interfacial Optimization for Low-Temperature Stable CsPbI_(2)Br Perovskite Solar Cells with High Efficiency Beyond 16%

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Energy & Environmental Materials 2022年第2期5卷 637-644页

作者： Jing Ma Jie Su Zhenhua Lin Jian He Long Zhou Tao Li Jincheng Zhang Shengzhong Liu Jingjing Chang Yue Hao State Key Discipline Laboratory of Wide Band Gap Semiconductor Technology Shaanxi Joint Key Laboratory of GrapheneSchool of MicroelectronicsXidian UniversityXi’an 710071China Advanced Interdisciplinary Research Center for Flexible Electronics Xidian UniversityXi’an 710071China Centre for Spintronics and Quantum System State Key Laboratory for Mechanical Behavior of MaterialsSchool of Materials Science and EngineeringXi’an Jiaotong UniversityXi’an 710049China Key Laboratory of Applied Surface and Colloid Chemistry National Ministry of Education Shaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringShaanxi Normal UniversityXi’an 710119China

CsPbI_(2)Br perovskite solar cells have achieved rapid development owing to their exceptional optoelectronic properties and relatively outstanding ***,open-circuit voltage(Voc)loss caused by band mismatch and charge recombination between perovskite and charge transporting layer is one of the crucial obstacles to further improve the device ***,we proposed a bilayer electron transport layer ZnO(bottom)/SnO_(2)(top)to reduce the Voc loss(Eloss)and promote device Voc by ZnO insert layer thickness modulation,which could improve the efficiency of charge carrier extraction/transfer and suppress the charge carrier *** addition,guanidinium iodide top surface treatment is used to further reduce the trap density,stabilize the perovskite film and align the energy levels,which promotes the fill factor,short-circuit current density(Jsc),and stability of the *** a result,the champion cell of double-side optimized CsPbI_(2)Br perovskite solar cells exhibits an extraordinary efficiency of 16.25%with the best Voc as high as 1.27 V and excellent thermal and storage stability.

关键词： CsPbI_(2)Br dual interfacial optimization high performance low temperature perovskite solar cells

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Decorating hole transport material with −CF_(3) groups for highly efficient and stable perovskite solar cells

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Journal of Energy Chemistry 2021年第11期30卷 523-531,I0012页

作者： Bin Li Yuan Cai Xia Tian Xiaozhong Liang Da Li Zheng Zhang Sijing Wang Kunpeng Guo Zhike Liu Ministry of Education Key Laboratory of Interface Science and Engineering in Advanced Materials Taiyuan University of TechnologyTaiyuanShanxi 030024China Key Laboratory of Applied Surface and Colloid Chemistry Ministry of EducationShaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringShaanxi Normal UniversityXi’anShaanxi 710119China

The hole transport material (HTM) plays an extremely important role to determine the power conversion efficiency (PCE) and the stability of perovskite solar cells (PSCs). Herein, we report an effective strategy to improve the performance of HTMs by introducing −CF_(3) groups via the rational decorative mode. Upon direct attachment or nonconjugated alkoxyl bridging of −CF_(3) groups on the terminal diphenylamines, the resulting molecular HTMs, i.e., 2,7-BCzA4CF_(3) and 2,7-BCzA4OCCF_(3), show distinct properties. Compared with 2,7-BCzA4CF_(3), the nonconjugated alkoxyl bridging −CF_(3) group-based 2,7-BCzA4OCCF_(3) exhibits better thermal stability, hydrophobicity, and a dramatically upgraded hole mobility by 135.7-fold of magnitude to 1.71 × 10^(−4) cm^(2) V^(−1) S^(−1). The PSCs with 2,7-BCzA4OCCF_(3) as HTM exhibit an PCE of up to 20.53% and excellent long-term stability, maintaining 92.57% of their performance for 30 days in air with humidity of 30% without encapsulation. This work provides beneficial guidelines for the design of new HTMs for efficient and stable PSCs.

关键词： Perovskite solar cell Hole transport material Decorating group Trifluoromethyl group Nonconjugated alkoxyl bridging

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