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New strategy for boosting cathodic performance of low temperature solid oxide fuel cells via chlorine doping

Nano Research 2024年第9期17卷 8086-8094页

作者： ShaoHua Xu Hao Qiu Shanshan Jiang Jingjing Jiang Wei Wang Xiaomin Xu Wei Kong Tanaka Dennis Chivurugwi Arkadii Proskurin Daifen Chen Chao Su School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang 212100China Institute of Analysis and Testing Beijing Academy of Science and TechnologyBeijing 100089China State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical EngineeringNanjing Tech UniversityNanjing 211816China WA School of Mines:Minerals Energy and Chemical EngineeringCurtin UniversityPerthWA6102Australia Admiral Makarov National University of Shipbuilding Heroiv Ukrainy av.9Mykolaiv54025Ukraine

To enhance the performance and widespread use of solid oxide fuel cells(SOFCs),addressing the low-temperature(<650℃)electrochemical performance and operational stability issues of cathode materials is ***,we propose an innovative approach to enhance oxygen ion mobility and electrochemical performance of perovskite oxide by substituting some oxygen sites with chlorine *** designed SrTa_(0.1)Fe_(0.9)O_(3-δ-x)Clx(x=0.05 and 0.10)exhibits improved performance compared to SrTa_(0.1)Fe_(0.9)O_(3-δ)(STF).SrTa_(0.1)Fe_(0.9)O_(2.95-δ)Cl_(0.05)(STFCl0.05)shows the lowest area-specific resistance(ASR)value on Sm0.2Ce0.8O1.9(SDC)*** 600℃,STFCl0.05 achieves an ASR value of 0.084Ω·cm^(2),and a single cell with STFCl0.05 reaches a higher peak power density(PPD)value(1143 mW·cm^(-2))than that with STF(672 mW·cm^(-2)).Additionally,besides exhibiting excellent oxygen reduction reaction(ORR)activity at lower temperatures,the STFCl0.05 cathode demonstrates good CO_(2)tolerance and operational *** cell operation lasts for 150 h,and single cell operation endures for 720 h without significant performance *** chlorine doping approach effectively enhances ORR activity and stability,making STFCl0.05 a promising cathode material for low-temperature SOFCs.

关键词： low-temperature solid oxide fuel cells(LT-SOFCs) oxygen reduction reaction(ORR) CO_(2)tolerance chlorine doping

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Attenuation of Richtmyer-Meshkov instability growth of fluid layer via double shock

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science China(Physics,Mechanics & Astronomy) 2025年第4期68卷 144-151页

作者： Chenren Chen Jiaxuan Li He Wang Zhigang Zhai Xisheng Luo Advanced Propulsion Laboratory Department of Modern MechanicsUniversity of Science and Technology of ChinaHefei230026China State Key Laboratory of High-Temperature Gas Dynamics Institute of MechanicsChinese Academy of SciencesBeijing100190China

Suppression of the hydrodynamic instabilities involved in the inertial confinement fusion has attracted much attention but remains a *** this work,we report the first theoretical analysis and experimental validation on attenuating the instability growth of a shock-accelerated fluid layer through a second shock *** analytical model is established to predict linear growth rates of the perturbations at two interfaces of the layer by considering both the effects of interface coupling and reverberating ***,there are nine possibilities for simultaneously attenuating the instability growths of perturbations at the two ***,shock-tube experiments are specially designed and conducted,and nine possibilities are all realized by experiments,which verifies the reliability of the analytical model and also demonstrates the feasibility of attenuating the instability growth of a fluid layer via double shock.

关键词： shock waves Richtmyer-Meshkv instability fluid layer

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Efects of Defect,Mean Stress and Lower Loading on High Cycle and Very High Cycle Fatigue Behavior of Ti‑6Al‑4V Alloy

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Acta Metallurgica Sinica(English Letters) 2025年第3期38卷 435-448页

作者： Yiyun Guo Lei Wu Yibo Shang Chengqi Sun State Key Laboratory of Nonlinear Mechanics Institute of MechanicsChinese Academy of SciencesBeijing 100190China School of Engineering Science University of Chinese Academy of SciencesBeijing 100049China Guobiao(Beijing)Testing&Certifcation Co. Ltd.Beijing 101400China Fundamentals Department Air Force Engineering UniversityXi’an 710051China National Key Lab of Aerospace Power System and Plasma Technology Air Force Engineering UniversityXi’an 710038China

In this study,the efects of defect,mean stress and lower loading are investigated for high cycle(HCF)and very high cycle fatigue(VHCF)behavior of Ti-6Al-4V *** indicates that the S-N curve of Ti-6Al-4V alloy exhibits a linear decreasing trend or a plateau characteristic in HCF and VHCF regimes,which depends on the defect size and stress *** strength decreases with increasing the defect size,and it is irrespective of stress *** fatigue crack initiates from specimen surface at R=−1 in both HCF and VHCF *** the fatigue crack initiates from the subsurface or the interior of the specimen at R=0.1 in VHCF regime.A sequence of lower stress amplitude below the fatigue strength at 10^(9) cyc has no or negligible infuence on the fatigue life of 10^(5)-10^(9) *** lower stress amplitude in variable amplitude loadings does not afect the failure *** residual compressive stress relaxation is not observed after a large number of lower loadings under ultrasonic frequency fatigue *** formula and Goodman formula give dangerous predictions of VHCF strength for both smooth specimens and specimens with defects.

关键词： Ti-6Al-4V titanium alloy Very high cycle fatigue Defect Stress ratio Lower stress amplitude

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Calibration of the Solar X-ray Detector on-board the Macao science Satellite-1B for Soft X-ray Detection

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science China Earth sciences 2025年第1期68卷 11-26页

作者： Man-Hei NG Xiaoping ZHANG Jianwu CHEN Yongqiang SHI Fuchang ZUO Wenxi PENG Weichun FU Liansheng LI Pengwei LUO Chi-Long TANG Guozheng ZHANG Zhiwu MEI Li WANG Cunhui LI Jiaming OU Yanyan Xu State Key Laboratory of Lunar and Planetary Sciences Macao University of Science and TechnologyMacao999078China Space Optoelectronic Measurement and Perception Laboratory Beijing Institute of Control EngineeringBeijing100190China Institute of High Energy Physics Chinese Academy of SciencesBeijing100049China Science and Technology on Vacuum Technology and Physics Laboratory Lanzhou Institute of PhysicsLanzhou730000China China National Space Administration(CNSA) Macao Center for Space Exploration and ScienceMacao999078China

The Solar X-ray Detector(SXD)on-board the Macao science Satellite-1B(MSS-1B)was successfully launched via the Chinese Long March-2C rocket on 21 May 2023,and commenced operations in early June of the same *** MSS-1B/Soft X-ray Detection Units(SXDUs)employ two silicon drift detectors(SDDs),providing a wide range of energy spectra spanning from 0.7 to 24 ***,the SXDUs deliver a high-resolution capability of 0.14 keV@5.9 keV and operate with a time cadence of 1 ***,we perform thorough calibrations of the MSS-1B/SXDUs,employing a combination of ground experiments and *** addition,quantitative analysis comparing the flux measurements obtained by the MSS-1B/SXDUs to the data collected by the Geostationary Operational Environmental Satellite(GOES),provides compelling evidence of their ***,the preliminary spectral analysis results showcase the robustness and expected performance of the MSS-1B/SXDUs,unlocking their potential for facilitating the study of dynamic evolution of solar ***,the innovative MSS-1B/Solar X-ray Detector facilitates concurrent observations of solar soft and hard X-rays,thereby making valuable contributions to the advancements in solar research.

关键词： Macao science Satellite-1B(MSS-1B) Calibration Solar X-Ray Detector Spectrometer Soft X-rays Solar flares Solar abundances

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Balloon-based exposed payload designed for astrobiological research in Earth’s near space

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Earth and Planetary Physics 2024年第6期8卷 878-889页

作者： YanQiu Wang JianXun Shen Chao Wang WeiNing Li GaoHong Wang Wei Lin YuanDa Jiang Key Laboratory of Electronics and Information Technology for Space Systems National Space Science CenterChinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China Key Laboratory of Earth and Planetary Physics Institute of Geology and GeophysicsChinese Academy of SciencesBeijing 100029China Key Laboratory of Algal Biology Institute of HydrobiologyChinese Academy of SciencesWuhan 430072China

Earth’s near space,located in the region between 20 and 100 km above sea level,is characterized by extreme conditions,such as low temperature,low atmospheric pressure,harsh radiation,and extreme *** conditions are analogous to those found on the surface of Mars and in the atmosphere of Venus,making Earth’s near space a unique natural laboratory for astrobiological *** address essential astrobiological questions,teams from the Chinese academy of sciences(CAS)have developed a scientific balloon platform,the CAS Balloon-Borne Astrobiology Platform(CAS-BAP),to study the effects of near space environmental conditions on the biology and survival strategies of representative organisms in this terrestrial ***,we describe the versatile Biological Samples Exposure Payload(BIOSEP)loaded on the CAS-BAP with respect to its structure and *** primary function of BIOSEP is to expose appropriate biological specimens to the harsh conditions of near space and subsequently return the exposed samples to laboratories for further *** successful flight missions in near space from 2019 to 2021 have demonstrated the high reliability and efficiency of the payload in communicating between hardware and software units,recording environmental data,exposing sample containers,protecting samples from external contamination,and recovering *** the effects of Earth’s near space conditions on biological specimens will provide valuable insights into the survival strategies of organisms in extreme environments and the search for life beyond *** development of BIOSEP and associated biological exposure experiments will enhance our understanding of the potential for life on Mars and the habitability of the atmospheric regions of other planets in the solar system and beyond.

关键词： Earth’s near space biological sample exposure payload performance testing Mars analog astrobiology

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Jetting of a near-wall cavitation bubble induced by another tandem bubble

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Journal of Hydrodynamics 2024年第3期36卷 444-456页

作者： Hui Han Jing-zhu Wang Jian-lin Huang Peng-bo Bai Yong-gang Chen Yi-wei Wang Key Laboratory for Mechanics in Fluid Solid Coupling Systems Institute of MechanicsChinese Academy of SciencesBeijing100190China School of Engineering Science University of Chinese Academy of SciencesBeijing100049China Guangdong Aerospace Research Academy Guangzhou511458China School of Future Technology University of Chinese Academy of SciencesBeijing100049China Jianghuai Advance Technology Center Hefei230088China

Double bubbles near a rigid wall surface collapse to produce a significant jet impact,with potential applications in surface cleaning and ultrasonic ***,the dynamic behaviors of near-wall bubbles remain *** this study,we investigate the jetting of a near-wall bubble induced by another tandem *** define two dimensionless standoff distances,γ_(1),γ_(2),to represent the distances from the center of the near-wall bubble to the rigid wall and the center of controlling bubble to the center of the near-wall bubble,*** observations reveal three distinct jetting regimes for the near-wall bubble:transferred jetting,double jetting,and directed *** further investigate the jetting mechanism,numerical simulations are conducted using the compressibleInterFoam solver in the open-source framework of OpenFOAM.A detailed analysis shows that the transferred jet flow is caused by the pinch-off resulting from the axial contraction velocity at the lower end of the near-wall bubble being greater than the vertical contraction velocity,leading to a maximum jet velocity of 682.58 m/*** the case of double jetting,intense stretching between the controlling bubble and the wall leads to a pinch-off and a double jetting with a maximum velocity of 1096.29 m/*** directed jet flow is caused by the downward movement of the high-pressure region generated by the premature collapse of the controlling bubble,with the maximum jet velocity reaching 444.62 m/s.

关键词： Jetting of near-wall bubble controlling bubble impact velocity

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Protective performance of shear stiffening gel-modified foam against ballistic impact:Experimental and numerical study

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Defence technology（防务技术） 2024年第2期32卷 510-520页

作者： Huan Tu Haowei Yang Pengzhao Xu Zhe Yang Fan Tang Cheng Dong Yuchao Chen Lei Ren Wenjian Cao Chenguang Huang Yacong Guo Yanpeng Wei Key Laboratory for Mechanics in Fluid Solid Coupling Systems Institute of MechanicsChinese Academy of SciencesBeijing 100190China School of Mechanical Engineering Northwestern Polytechnical UniversityXi'an 710072China Xi'an Institute of Electromechanical Information Technology Xi'an 710065China Science and Technology on Transient Impact Laboratory Beijing 102202China School of Engineering Science University of Chinese Academy of SciencesBeijing 100049China

As one of the most widely used personal protective equipment(PPE),body armors play an important role in protecting the human body from the high-velocity impact of bullets or *** body torso and critical organs of the wear may suffer severe behind-armor blunt trauma(BABT)even though the impactor is stopped by the body armor.A type of novel composite material through incorporating shear stiffening gel(STG)into ethylene-vinyl acetate(EVA)foam is developed and used as buffer layers to reduce *** this paper,the protective performance of body armors composed of fabric bulletproof layers and a buffer layer made of foam material is investigated both experimentally and *** effectiveness of STG-modified EVA in damage relief is verified by ballistic *** parallel with the experimental study,numerical simulations are conducted by LS-DYNA®to investigate the dynamic response of each component and capture the key mechanical parameters,which are hardly obtained from field *** fully describe the material behavior under the transient impact,the selected constitutive models take the failure and strain rate effect into consideration.A good agreement between the experimental observations and numerical results is achieved to prove the validity of the modelling *** tests and simulations show that the impact-induced deformation on the human body is significantly reduced by using STG-modified EVA as the buffering *** improvement of protective performance is attributed to better dynamic properties and more outstanding energy absorption capability of the composite foam.

关键词： Ballistic behavior Composite foam Shear stiffening gel Finite element analysis Protective mechanism

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Growth,characterization,and transport calculation of Ge/SiGe heterojunction:strategy for the growth of undoped Ge quantum wells

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Journal of Semiconductors 2024年第12期45卷 62-70页

作者： Yiwen Zhang Jun Deng Zonghu Li Xinyou Liu Haiou Li Baochuan Wang Jun Luo Zhenzhen Kong Gang Cao Guoping Guo Chao Zhao Guilei Wang Laboratory of Fabrication Technologies for Integrated Circuits Chinese Academy of SciencesBeijing 100029China Institute of Microelectronics Chinese Academy of SciencesBeijing 100029China School of Electronic Electrical and Communication Engineering University of Chinese Academy of SciencesBeijing 100049China Hefei National Laboratory University of Science and Technology of ChinaHefei 230088China CAS Key Laboratory of Quantum Information University of Science and Technology of ChinaHefei 230026China

Ge/SiGe heterostructure quantum wells play a pivotal role in the pursuit of scalable silicon-based *** varying compressive strains within these quantum wells profoundly influence the physical characteristics of the qubits,yet this factor remains largely unexplored,driving our research *** this study,we utilized RP-CVD(Reduced Pressure Chemical Vapor Deposition)to grow Ge quantum wells with varied compressive strain,proposing growth schemes for lightly-strained(ε∥=-0.43%)QW(quantum well),standard-strained(ε∥=-0.61%)QW,and heavily-strained(ε∥=-1.19%)*** comprehensive material characterization,particularly employing the low-temperature magneto-transport measurements,we derived the percolation densities ranging from 4.7×10^(10) to 14.2×10^(10) cm^(-2) and mobilities from 3.382×10^(5) to 7.301×10^(5) cm^(2)∙V^(-1)∙s^(-1).Combined with the first-principles calculations,our analysis delves into the trends in effective mass and percolation density at low temperatures,shedding light on the impact of quantum effects on band structures and the interplay between structural components and wave *** research offers a comprehensive investigation into the intrinsic mechanisms governing complex multi-strained quantum wells,spanning growth,characterization,and computational perspectives,thereby establishing a strategy for the growth of high-quality strained quantum wells.

关键词： germanium quantum wells RP-CVD multi-strained quantum wells magneto-transport hetero-structure

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Adsorption and membrane separation for removal and recovery of volatile organic compounds

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Journal of Environmental sciences 2023年第1期123卷 96-115页

作者： Guoqiang Gan Shiying Fan Xinyong Li Zhongshen Zhang Zhengping Hao State Key Laboratory of Fine Chemicals Key Laboratory of Industrial Ecology and Environmental Engineering(MOE)School of Environmental Science and TechnologyDalian University of TechnologyDalian 116024China National Engineering Laboratory for VOCs Pollution Control Material and Technology University of Chinese Academy of SciencesBeijing 101408China

Volatile organic compounds(VOCs)are a crucial kind of pollutants in the environment due to their obvious features of severe toxicity,high volatility,and poor *** is particularly urgent to control the emission of VOCs due to the persistent increase of concentration and the stringent *** China,clear directions and requirements for reduction of VOCs have been given in the“national plan on environmental improvement for the 13th Five-Year Plan period”.Therefore,the development of efficient technologies for removal and recovery of VOCs is of great *** technologies are favored by researchers due to their advantages in both recycling VOCs and reducing carbon *** them,adsorption and membrane separation processes have been extensively studied due to their remarkable industrial *** overview was to provide an up-to-date progress of adsorption and membrane separation for removal and recovery of ***,adsorption and membrane separation were found to be the research hotspots through bibliometric ***,a comprehensive understanding of their mechanisms,factors,and current application statuses was ***,the challenges and perspectives in this emerging field were briefly highlighted.

关键词： Volatile organic compounds(VOCs) Removal and recovery technology Adsorption Membrane separation Bibliometric analysis

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Quantitative study of high-frequency fatigue hole-edge stresses in nickel-based single-crystal superalloy 2

Quantitative study of high-frequency fatigue hole-edge stres...

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2nd International Conference on Frontier Materials, ICFM 2023

作者： Li, Leyu Li, Zheng Liu, Jiabin Zhang, Jingang Deng, Zhiwei Li, Quanwei Liu, Xinling AECC Beijing Institute of Aeronautical Materials China AVIC Failure Analysis Center China Beijing Key Laboratory of Aeronautical Materials Testing and Evaluation China Key Laboratory of Aeronautical Materials Testing and Evaluation Aero Engine Corporation of China China Aviation Key Laboratory of Science and Technology on Materials Testing and Evaluation China

In this paper, the influence of air film holes on the stress distribution of nickel-based single-crystal superalloy blades is investigated, a simulated test piece is designed for the analysis and test of the stress distribution of air film holes, and a method of quantitative inverse inference of the stress at the edge of the air film holes is proposed. Finite element simulation of high circumferential vibration fatigue of the simulated test piece was carried out by ANSYS to obtain the gradient of stress distribution at the hole edge. The EBSD technique was used to measure the dimensions of the plastic zone in the region near the fracture, and the quantitative fatigue stresses were extrapolated using a crack tip plastic zone model with Tresca yield criterion. The compressive stress exerted by the femtosecond laser perforation method on the air film aperture wall was detected by the nanoindentation technique, and the residual stress was analysed using the S. Suresh computational model. The results of this study show that based solely on finite element simulation, it is not possible to completely simulate the effect of residual stresses caused by machining on fatigue fracture, which in turn leads to a lack of conformity between the results of finite element simulation and the results of the inverse plastic zone size extrapolation;however, the stress magnitude at the edge of the hole can be well computed by combining the stress concentration coefficients from finite element simulation with the stresses from the inverse plastic zone size extrapolation after taking into account the residual stresses from machining. The quantitative analysis results of this method have an error within 1.3 times the dispersion band compared to the test data. © 2023 Published under licence by IOP Publishing Ltd.

关键词： Nickel

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