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Synthesis of chitosan-based grafting magnetic flocculants for flocculation of kaolin suspensions

Journal of Environmental Sciences 2024年第5期139卷 193-205页

作者： Chuang Liu Xiaoyu Wang Sicong Du Wenyan Liang Beijing Key Lab for Source Control Technology of Water Pollution/Engineering Research Center for Water Pollution Source Control&Eco-remediation/College of Environmental Science and Engineering Beijing Forestry UniversityBeijing 100083China

A series of novel chitosan-based magnetic flocculants FS@CTS-P(AM-DMC)was prepared by molecular structure *** characterization results showed that FS@CTS-P(AM-DMC)had a uniform size of about 21.46 nm,featuring a typical core-shell structure,and the average coating layer thickness of CTS-P(AM-DMC)was about 5.03 ***@CTS-P(AM-DMC)exhibited excellent flocculation performance for kaolin suspension,achieved 92.54% turbidity removal efficiency under dosage of 150 mg/L,pH 7.0,even at high turbidity(2000 NTU)with a removal efficiency of 96.96%.The flocculation mechanism was revealed to be dominated by charge neutralization under acidic and neutral conditions,while adsorption and bridging effects play an important role in alkaline *** properties of magnetic aggregates during flocculation,breakage,and regeneration were studied at different pH levels and *** the process of magnetophoretic,magnetic particles collide and adsorb with kaolin particles continuously due to magnetic and electrostatic attraction,transform into magnetic chain clusters,and then further form three-dimensional network magnetic aggregates that can capture free kaolin particles and other chain *** image velocimetry confirmed the formation of eddy current of magnetic flocs and experienced three stages:acceleration,stabilization,and deceleration.

关键词： Magnetic flocculation Chitosan Fe_(3)O_(4) Graft copolymerization PIV

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Catalytic applications of amorphous alloys in wastewater treatment: A review on mechanisms, recent trends, challenges and future directions

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Chinese Chemical Letters 2024年第10期35卷 73-81页

作者： Yulong Liu Haoran Lu Tong Yang Peng Cheng Xu Han Wenyan Liang Engineering Research Center for Water Pollution Source Control&Eco-remediation Beijing Key Lab for Source Control Technology of Water PollutionCollege of Environmental Science and EngineeringBejing Forestry UniversityBeijing 100083China

Amorphous alloys,with unique atomic structures and metastable nature,are treated as superior candi-dates for environmental wastewater remediation due to their superior catalytic *** the strong demand for environmental protection,the field of amorphous alloys in wastewater treatment has great development prospects,and numerous research results have been published in recent *** a promising catalyst,it was demonstrated that amorphous alloys could exhibit many excellent proper-ties in wastewater treatment,such as high catalytic efficiency,easily adjustable parameters and reliable *** paper aims to summarize recent research trends regarding amorphous alloys in the field of catalysis,focusing on the preparation methods,physical performance,catalytic mechanisms and environmental ***,this review also investigates the challenges encountered and fu-ture perspectives of amorphous alloys,offering new research opportunities to enlarge their applicability spectra.

关键词： Amorphous alloys Wastewater treatment Advanced oxidation processes Catalyst Catalytic mechanism

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Boosting oxygen vacancies by modulating the morphology of Au decorated In_(2)O_(3)with enhanced CO_(2)hydrogenation activity to CH_(3)OH

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Journal of Environmental Sciences 2024年第6期140卷 91-102页

作者： Ruxian Hou Jiewen Xiao Qian Wu Tianyu Zhang Qiang Wang Beijing Key Lab for Source Control Technology of Water Pollution College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China Engineering Research Center for Water Pollution Source Control&Eco-remediation College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China

CO_(2)hydrogenation to methanol has become one of the most promising ways for CO_(2)utilization,however,the CO_(2)conversion rate and methanol selectivity of this reaction still need to be improved for industrial *** we investigated the structure-activity relationship for CO_(2)conversion to methanol of In_(2)O_(3)-based catalysts by modulating morphology and decorating *** different Au/In_(2)O_(3)catalysts were prepared,their activity follow the sequence of Au/In_(2)O_(3)-nanosphere(Au/In_(2)O_(3)-NS)>Au/In_(2)O_(3)-nanoplate(Au/In_(2)O_(3)-NP)>Au/In_(2)O_(3)-hollow microsphere(Au/In_(2)O_(3)-HM).Au/In_(2)O_(3)-NS exhibited the best performance with good CO_(2)conversion of 12.7%,high methanol selectivity of 59.8%,and large space time yield of 0.32 g CH_(3)OH/(hr·gcat)at 300℃.The high performance of Au/In_(2)O_(3)-NS was considered as the presence of *** contributes to the creation of more surface oxygen vacancies,which further promoted the CO_(2)adsorption and facilitated CO_(2)activation to form the formate intermediates towards *** work clearly suggests that the activity of In_(2)O_(3)catalyst can be effective enhanced by structure engineering and Au decorating.

关键词： CO_(2)hydrogenation Methanol Au/In_(2)O_(3) Morphology Oxygen vacancies

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Enhanced hydrolytic removal of tylosin in wastewater using polymer-based solid acid catalysts converted from polystyrene

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Journal of Environmental Sciences 2023年第4期126卷 287-296页

作者： Shiling Li Shuhan Sun Fei Qi Xiaomin Dou Beijing Key Lab for Source Control Technology of Water Pollution College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China Engineering Research Center for Water Pollution Source Control and Eco-remediation College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China

Antibiotic production wastewater usually contains high concentrations of antibiotic residues,which can cause instability and deterioration of biological wastewater treatment units and also domestication and proliferation of antibiotic-resistance *** effective pretreatment on antibiotics production wastewater is expected to selectively reduce the concentration of antibiotics and decrease the toxicity,rather than mitigate organic and other contaminants before further *** this work,two polymer-based solid acids,PS-S and CPS-S bearing high concentrations of-SOH_(3)groups (up to 4.57 mmol/g),were prepared and successfully used for hydrolytic mitigation of 100 mg/L tylosin within 20 *** co-existence of high concentrations of COD and humic substances did not affect the mitigation of tylosin obviously,while more than 500 mg/L of nitrogenous compounds suppressed the hydrolytic *** and reuse experiments showed that the solid acids performed well in five cycles after *** transformation products (P1,P2 and P3)were identified using UPLC-QTOF-MS/*** moieties including mycarse,mycaminose,and mycinose detached and released simultaneously or in order from the 16-member lactone ring through desugarization,which led to a dramatic decrease in antibacterial activity as revealed by cytotoxicity evaluations using *** estimation indicated the acute toxicities of the hydrolyzed products to model species (e.g.,fish,daphnid and green algae) were classified as“not harmful”.This work suggested an effective and selective method to pretreat tylosin-contained production wastewater by using polymer-based solid *** results will shed light on effective elimination of antibiotics pollution from pharmaceutical industries through strengthening the pretreatments.

关键词： Polymer Sulfonation Solid acid catalysts Tylosin hydrolysis Antibiotic

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Surface modification of Cu_(2)O with stabilized Cu^(+) for highly efficient and stable CO_(2) electroreduction to C_(2+) chemicals

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Journal of Energy Chemistry 2023年第9期84卷 277-285页

作者： Ziyu Zhou Shuyu Liang Jiewen Xiao Tianyu Zhang Min Li Wenfu Xie Qiang Wang Beijing Key Lab for Source Control Technology of Water Pollution College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China Engineering Research Center for Water Pollution Source Control&Eco-remediation College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China

Copper(Cu)-based materials are known as the most attractive catalysts for electrochemical carbon dioxide reduction reaction(CO_(2)RR),especially the Cu^(+) species(e.g.,Cu_(2)O),which show excellent capability for catalyzing CO_(2) to C_(2+) chemicals because of their unique electronic ***,the active Cu^(+) species are prone to be reduced to metallic Cu under an electroreduction environment,thus resulting in fast deactivation and poor ***,we developed an advanced surface modification strategy to maintain the active Cu^(+) species via assembling a protective layer of metal-organic framework(copper benzenetricarboxylate,CuBTC) on the surface of Cu_(2)O octahedron(Cu_(2)O@CuBTC).It's encouraging to see that the Cu_(2)O@CuBTC heterostructure outperforms the bare Cu_(2)O octahedron in catalyzing CO_(2) to C_(2+) chemicals and dramatically enhances the ratio of C_(2)H_(4)/CH_(4) products.A systematic study reveals that the introduced CuBTC shell plays a critical role in maintaining the active Cu^(+) species in Cu_(2)O@CuBTC heterostructure under reductive *** work offers a practical strategy for improving the catalytic performance of CO_(2)RR over copper oxides and also establishes a route to maintain the state of valence-sensitive catalysts.

关键词： CO_(2)RR Copper Oxide Metal-organic Framework Core-shell Structure C_(2+)Chemicals

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Dimension-controlled synthesis of BiOI for efficient visible light photodegradation of tetracycline: role of pore structure

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Environmental Science and pollution Research 2024年第20期31卷 29101-29112页

作者： Gao, Peng Qiu, Nanting Feng, Li Zhang, Liqiu Beijing Key Lab for Source Control Technology of Water Pollution College of Environmental Science and Engineering Beijing Forestry University Beijing100083 China Engineering Research Center for Water Pollution Source Control & amp Eco-Remediation College of Environmental Science and Engineering Beijing Forestry University Beijing100083 China

The transformation of photogenerated charge carriers (PC) in variable dimensional photocatalyst plays a pivotal role in unraveling the generation of reactive species (RS). However, the dimensional structure–activity relationship in photocatalysis remains elusive, with limited insights into its intricacies. Herein, we report a controlled synthesis strategy by using polyvinyl pyrrolidone (PVP)-assisted precipitation method for BiOI photocatalyst. Due to the steric hindrance of PVP, the 3D microsphere (3D-PVP0.5) and porous structure (3D-PVP1) of BiOI catalysts have been successfully prepared at room temperature. The 3D-PVP1 photocatalyst contains abundant mesopores and larger pores, which significantly shorten the diffusion distance of PC. Also, these PC in porous structure is beneficial for transferring from the inner phase to the surface of materials. Combined with optical property and radicals trapping experiments, the recombination rate of PC in porous structure performs a significant decrease, leading to the generation of more dominated ROS (•O2− and h+). The •O2− played a dominated role (86.98% of contribution rate) in photodegradation of tetracycline (TC) in 3D-PVP1 photocatalytic process. Compared with 2D nanosheet of BiOI (16.7% removal rate of TC), the as-prepared 3D porous structure of BiOI catalyst exhibits unique stable and high removal capacities (90.5%) for TC photodegradation under visible light irradiation. The kobs of 3D-PVP1 photocatalyst increased by 5.1 times than that of 2D nanosheet. To investigate its practical application, the effects of inorganic anions and pH have been systematically studied. This work sheds light on the design of variable dimension BiOI catalyst and provides more insight into the transfer mechanism of PC. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.

关键词： Bismuth compounds

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A novel electro-Fenton hybrid system for enhancing the interception of volatile organic compounds in membrane distillation desalination

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Journal of Environmental Sciences 2024年第4期138卷 189-199页

作者： Hongxin Liu Kuiling Li Kunpeng Wang Zhiyong Wang Zimou Liu Sichao Zhu Dan Qu Yu Zhang Jun Wang State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China University of Chinese Academy of Sciences Beijing 100049China State Key Laboratory of Environment Simulation and Pollution Control School of Environment Tsinghua UniversityBeijing 100084China School of Chemical and Environmental Engineering Beijing CampusChina University of Mining and TechnologyBeijing 100083China Beijing Key Lab for Source Control Technology of Water Pollution College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China

Membrane distillation(MD)is a promising alternative desalination technology,but the hydrophobic membrane cannot intercept volatile organic compounds(VOCs),resulting in aggravation in the quality of *** term of this,electro-Fenton(EF)was coupled with sweeping gas membrane distillation(SGMD)in a more efficient way to construct an advanced oxidation barrier at the gas-liquid interface,so that the VOCs could be trapped in this layer to guarantee the water quality of the *** the so-called EF-MD process,an interfacial interception barrier containing hydroxyl radical formed on the hydrophobic membrane *** contributed to the high phenol rejection of 90.2% with the permeate phenol concentration lower than 1.50 mg/*** interceptions can be achieved in a wide temperature range,even though the permeate flux of phenol was also *** EF-MD system was robust to high salinity and could electrochemically regenerate ferrous ions,which endowed the long-term stability of the *** novel EF-MD configuration proposed a valuable strategy to intercept VOCs in MD and will broaden the application of MD in hypersaline wastewater treatment.

关键词： Membrane distillation VOC interception Interfacial oxidation Electro-Fenton Hypersaline wastewater

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New insights into membrane fouling in coagulation-ultrafiltration by cake characteristics analysis:A case study with PACl-Al_(13)and PACl

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Journal of Environmental Sciences 2024年第12期146卷 217-225页

作者： Mingyao Xu Wei Ju Zhenbei Wang Jun Nan Fei Qi Chen Li Yatao Liu Wei Li Dezhi Sun Beijing Key Lab for Source Control Technology of Water Pollution College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China Beijing Forestry University Science Co. Ltd.Beijing 100085China Skate Key Laboratory of Urban Water Resource and Environment School of EnvironmentHarbin Institute of TechnologyHarbin 150090China Research Center for Eco-environmental Engineering Dongguan University of TechnologyDongguan 523106China

Membrane fouling is a bottleneck issue that hindered the further application of ultrafiltration *** alleviate membrane fouling,coagulation-ultrafiltration(C-UF)process using polyaluminum chloride(PACl)and PACl-Al_(13)with high proportion of Al_(13)O_(4)(OH)_(24)^(7+)as coagulants,respectively,were investigated at various pH *** indicated that an increase in solution pH contributed to larger floc size and looser floc structure for both PACl and PACl-Al_(13).It was conducive to the formation of more porous cake,as evidenced by mean pore area and pore area distribution of cake,leading to lower reversible ***,humic acid(HA)removal presented a trend of first increasing and then decreasing with the increase of *** optimal HA removal was achieved at pH 6 regardless of coagulant type,suggesting that the slightest irreversible fouling should be occurred at this ***,the irreversible fouling with PACl coagulant achieved a minimum value at pH 9,while the minimal irreversible fouling with PACl-Al_(13)was observed at pH *** speculated that the cake formed by PACl could further intercept HA prior to UF process at alkaline ***,compared with PACl,PACl-Al_(13)had a stronger charge neutralization ability,thus contributing to more compact floc structure and higher HA removal at various pH *** UF fractionation measurement,higher HA removal for PACl-Al_(13)was due to higher removal of HA with molecular weight less than 50 kDa.

关键词： Coagultion-ultrafiltration Floc properties Cake characteristics Molecular weight of HA Membrane fouling

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controllable synthesis of MnO_(2)/iron mesh monolithic catalyst and its significant enhancement for toluene oxidation

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Chinese Chemical Letters 2023年第2期34卷 338-341页

作者： Meijuan Qi Zhe Li Zhang Zhang Yanshan Gao Qiang Wang Beijing Key Lab for Source Control Technology of Water Pollution College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China Engineering Research Center for Water Pollution Source Control&Eco-remediation College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China Beijing Municipal Ecological and Environmental Monitoring Center Beijing 100048China

A series of monolithic MnO_(2)/iron mesh (IM) catalysts for oxidation of toluene were successfully prepared by using in situ hydrothermal ***_(2)can grow firmly on the IM substrates surface with a shedding rate of only 0.14%.Due to the highest O_(ads) and high-valent Mn^(4+) and Fe^(3+) elements,the temperature at 50% and 90% toluene conversion (T_(50%) and T_(90%)) was 252 and 265℃,respectively for the best performance catalyst (hydrothermal temperature of 80℃,hydrothermal time of 12 h,and precursor manganese ion concentration of 0.03 mol/L).The catalysts also presented good water resistance and cycle ***-situ DRIFTS results suggesting that toluene was first rapid transformed into the reaction intermediate species (benzoate species) and then converted to CO_(2)and H_(2)***,this work provides a new direction for the research and application of IM-based monolithic catalysts.

关键词： Toluene oxidation Iron mesh monoliths catalysts MnO_(2) Resistance properties Reaction mechanism

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Pre-combustion mercury removal with co-production of hydrogen via coal electrolysis

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Journal of Environmental Sciences 2024年第2期136卷 382-389页

作者： Xiang Lyu Runming Tao Tianyu Zhang Chemical and Biomolecular Engineering Department Ohio University165 Stocker CenterAthensOH45701USA Electrification and Energy Infrastructures Division Oak Ridge National LaboratoryOak RidgeTN37831USA Beijing Key Lab for Source Control Technology of Water Pollution College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China Engineering Research Center for Water Pollution Source Control&Eco-remediation College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China

Pre-combustion mercury removal via coal electrolysis was performed and investigated on a bench-scale coal electrolytic cell(CEC)systemically,and factorial design was used to determine the effect of different operating conditions(coal particle size,operating temperature,operating cell voltage,and flow rate of slurry)on the percentage of mercury removal,percentage of ash removal,and dry heating value *** results showed that the operating cell voltage,as well as the interaction between operating cell voltage and coal particle size,are significant factors in the percentage of mercury *** is no significant factor in the percentage of ash removal and the dry heating value change,but the coal could be purified while keeping the dry heating value almost constant after electrolysis.A co-product of hydrogen could be produced during coal electrolysis with 50%lower energy consumption compared with water ***,a mechanism for mercury removal in coal was *** facts indicate that coal electrolysis is a promising method for precombustion mercury removal.

关键词： Pre-combustion mercury removal Coal electrolysis Ash removal Dry heating value Hydrogen production

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