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Accurate identification and formation mechanism unraveling of radicals in UV-induced peracetic acid activation system using in-situ electron paramagnetic resonance

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Science Bulletin 2025年第10期70卷 1581-1585页

作者： Chen, Long Zhang, Ruohan Liu, Zhaoli Li, Fan Huang, Boyu Liu, Wen College of Environmental Sciences and Engineering The Key Laboratory of Water and Sediment Sciences Peking University Beijing100871 China Beijing Key Lab for Source Control Technology of Water Pollution College of Environmental Science and Engineering Beijing Forestry University Beijing100083 China Molecular Sciences National Laboratory for Molecular Sciences Peking University Beijing100871 China

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Peracetic acid catalytic activation using Co_(3)O_(4) nanocluster decorated graphitic carbon nitride for cefapirin degradation in water

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Science China(Technological Sciences) 2024年第10期67卷 3103-3115页

作者： YIN ShiMei GAO YiXuan CHEN Long LI Fan LIU XiaoNa QI Fei LIU Wen Beijing Key Lab for Source Control Technology of Water Pollution College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China Key Laboratory of Water and Sediment Sciences(Ministry of Education) College of Environmental Sciences and EngineeringPeking UniversityBeijing 100871China School of Environmental Science and Engineering Taiyuan University of TechnologyTaiyuan 030024China State Environmental Protection Key Laboratory of All Material Fluxes in River Ecosystems Peking UniversityBeijing 100871China Beijing National Laboratory for Molecular Sciences Peking UniversityBeijing 100871China

This study innovated cobalt-based catalytic nanocomposites(CCNs)for the heterogeneous activation of peracetic acid(PAA),a green and efficient advanced oxidation process for removing antibiotics from *** Co_(3)O_(4) catalysts exhibit limited activity due to stable electronic *** overcome this,CCNs were synthesized using a one-step condensation method,incorporating a size control strategy that anchors Co_(3)O_(4) nanoclusters within 4‒5 nm onto six-fold cavity of g-C3N4,simultaneously modifying the coordination environment of *** alteration significantly enhances the adsorption energy of PAA and catalytic activity compared to commercial Co_(3)O_(4).The improved performance of CCN2,in particular,is attributed to a shift in the cobalt d band center towards the Fermi level,facilitating electron delocalization and transfer,enhancing Co‒O bonding,and accelerating PAA ***2’s superior activity,with a cefapirin(CFP)degradation kinetic rate constant(k1=0.760 min^(−1))~11 times that of PAA direct oxidation(k1=0.070 min^(−1))and~5 times that of commercial Co_(3)O_(4)/PAA system(k1=0.164 min^(−1)),is due to its ability to generate dominant reactive species for antibiotic degradation,including alkoxy radicals(CH3C(=O)OO•),high valence metal(Co^(Ⅳ)(=O)^(2+)),and singlet oxygen(^(1)O_(2)),with the latter two being crucial for the degradation *** degradation of CFP involved three mechanisms,including direct oxidation by PAA,decarboxylation,and open-ring reactions at nitrogen *** research provides insights into developing high-activity catalysts for efficient PAA activation and antibiotic removal,leveraging the strategy of shifting the transition metal d band center.

关键词： peracetic acid Co_(3)O_(4)nanocluster high valence metal singlet oxygen cefapirin

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Highly efficient P uptake by Fe3O4 loaded amorphous Zr-La (carbonate) oxides: Electrostatic attraction, inner-sphere complexation and oxygen vacancies acceleration effect

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Journal of Environmental Sciences 2022年第10期34卷 18-29页

作者： Chenyang Liu Yili Wang Xiaolin Li Junyi Li Shuoxun Dong Haotian Hao Yao Tong Yanqing Zhou College of Environmental Science and Engineering Beijing Key Lab for Source Control Technology of Water PollutionBeijing Forestry UniversityBeijing 100083China Center for Water and Ecology State Key Joint Laboratory of Environment Simulation and Pollution ControlSchool of EnvironmentTsinghua UniversityBeijing 100084China Research Center for Eco-Environmental Sciences Chinese Academy of SciencesBeijing 100085China

Bimetallic oxides composites have received an increasing attention as promising adsorbents for aqueous phosphate (P) removal in recent years. In this study, a novel magnetic composite MZLCO was prepared by hybridizing amorphous Zr-La (carbonate) oxides (ZLCO) with nano-FeOthrough a one-pot solvothermal method for efficient phosphate adsorption. Our optimum sample of MZLCO-45 exhibited a high Langmuir maximum adsorption capacity of 96.16 mg P/g and performed well even at low phosphate concentration. The phosphate adsorption kinetics by MZLCO-45 fitted well with the pseudo-second-order model, and the adsorption capacity could reach 79% of the ultimate value within the first 60 min. The phosphate adsorption process was highly p H-dependent, and MZLCO-45 performed well over a wide p H range of 2.0-8.0. Moreover, MZLCO-45 showed a strong selectivity to phosphate in the presence of competing ions (Cl^(-), NO_(3)^(-), SO_(4)^(2-), HCO_(3)^(-), Ca^(2+), and Mg^(2+)) and a good reusability using the eluent of Na OH/Na Cl mixture, then 64% adsorption capacity remained after ten recycles. The initial 2.0 mg P/L in municipal wastewater and surface water could be efficiently reduced to below 0.1mg P/L by 0.07 g/L MZLCO-45, and the phosphate removal efficiencies were 95.7% and 96.21%, respectively. Phosphate adsorption mechanisms by MZLCO-45 could be attributed to electrostatic attraction and the inner-sphere complexation via ligand exchange forming Zr/La-O-P, -OH and CO_(3)^(2-)groups on MZLCO-45 surface played important roles in the ligand exchange process. The existence of oxygen vacancies could accelerate the phosphate absorption rate of the MZLCO-45 composites.

关键词： Fe3O4 loaded amorphous Zr-La(carbonate)oxides Phosphate adsorption performance Regeneration Mechanism Real water treatment

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Phosphate removal by a La(OH)_(3) loaded magnetic MAPTAC-based cationic hydrogel:Enhanced surface charge density and Donnan membrane effect

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Journal of Environmental Sciences 2022年第3期34卷 26-39页

作者： Yanqing Zhou Yili Wang Shuoxun Dong Haotian Hao Junyi Li Chenyang Liu Xiaolin Li Yao Tong College of Environmental Science and Engineering Beijing Key Lab for Source Control Technology of Water PollutionBeijing Forestry UniversityBeijing 100083China Center for Water and Ecology State Key Joint Laboratory of Environment Simulation and Pollution ControlSchool of EnvironmentTsinghua UniversityBeijing 100083China State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China

Cationic hydrogels have received great attention to control eutrophication and recycle *** this study,a type of La(OH)_(3) loaded magnetic MAPTAC-based cationic hydrogel(La(OH)_(3)@MMCH)was developed as a potential adsorbent for enhanced phosphate removal from aqueous ***(OH)_(3)@MMCH exhibited high adsorption capacity of 105.72±5.99 mg P/g,and reached equilibrium within 2 ***(OH)_(3)@MMCH could perform effectively in a wide pH range from 3.0 to 9.0 and in the presence of coexisting ions(including SO_(4)^(2-),Cl^(-),NO_(3)^(-),HCO_(3)^(-),SiO_(4)^(4-) and HA).The adsorption-desorption experiment indicated that La(OH)_(3)@MMCH could be easily regenerated by using NaOH-NaCl as the desorption agent,and 73.3%adsorption capacity remained after five ***,La(OH)_(3)@MMCH was employed to treat surface water with phosphate concentration of 1.90 mg/L and showed great removal efficiency of 95.21%.Actually,MMCH showed high surface charge density of 34.38-59.38 meq/kg in the pH range from 3.0 to 11.0 and great swelling ratio of 3014.57%within 24 h,indicating that MMCH could produce the enhanced Donnan membrane effect to pre-permeate ***,the bifunctional structure of La(OH)_(3)@MMCH enabled it to capture phosphate through electrostatic attraction and ligand *** the results prove that La(OH)_(3)@MMCH is a promising adsorbent for eutrophication control and phosphate recovery.

关键词： Cationic hydrogel La(0H)_(3) Phosphate adsorption Enhanced Donnan membrane effect

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Low-condensation diesel use contributes to winter haze in cold regions of China

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Environmental Science and Ecotechnology 2024年第6期22卷 226-232页

作者： Weiwei Song Mengying Wang Yixuan Zhao Yu Bo Wanying Yao Ruihan Chen Xianshi Wang Xiaoyan Wang Chunhui Li Kebin He State Key Laboratory of Urban Water Resource and Environment School of EnvironmentHarbin Institute of TechnologyHarbin150090China State Key Joint Laboratory of Environment Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing100084China Institute of Atmospheric Physics Chinese Academy of SciencesBeijing100029China Harbin Ecological and Environmental Monitoring Center Harbin150076China Collaborative Innovation Center for Regional Environmental Quality Beijing100084China State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex Beijing100084China

The application of low-condensation diesel in cold regions with extremely low ambient temperatures(−14 to−29℃)has enabled the operation of diesel ***,it may contribute to heavy haze pollution in cold regions during *** we examine pollutant emissions from low-condensation diesel in *** measure the emissions of elemental carbon(EC),organic carbon(OC),and elements,including heavy metals such as arsenic(As).Our results show that low-condensation diesel increased EC and OC emissions by 2.5 and 2.6 times compared to normal diesel fuel,*** of vehicular sources,including EC,As,lead(Pb),cadmium(Cd),chromium(Cr),nickel(Ni),and manganese(Mn),increased by approximately 20.2-162.5%when using low-condensation *** variation of vehicular source indicators,observed at road site ambient environments revealed the enhancement of PM2.5 pollution by the application of low-condensation diesel in *** findings suggest that−35#diesel,a low-cetane index diesel,may enhance air pollution in winter,according to a dynamometer test conducted in *** raises questions about whether higher emissions are released if−35#diesel is applied to running vehicles in real-world cold ambient environments.

关键词： Low condensation diesel Carbonaceous matterHeavy metal Dynamometer Cold regions

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Modeling the dynamic impacts of maritime network blockage on global supply chains

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The Innovation 2024年第4期5卷 103-109,102页

作者： Shen Qu Yunlei She Qi Zhou Jasper Verschuur Lu-Tao Zhao Huan Liu Ming Xu Yi-Ming Wei Center for Energy and Environmental Policy Research Beijing Institute of TechnologyBeijing 100081China School of Management Beijing Institute of TechnologyBeijing 100081China Beijing Key Lab of Energy Economics and Environmental Management Beijing 100081China Oxford Programme for Sustainable Infrastructure Systems(OPSIS) Environmental Change InstituteUniversity of OxfordOX12JD OxfordUK State Key Joint Laboratory of Environment Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing 100084China State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex Beijing 100084China School of Environment Tsinghua UniversityBeijing 100084China

Recent phenomena such as pandemics,geopolitical tensions,and climate change-induced extreme weather events have caused transportation network interruptions,revealing vulnerabilities in the global supply chain.A salient example is the March 2021 Suez Canal blockage,which delayed 432 vessels carrying cargo valued at$92.7 billion,triggering widespread supply chain *** ability to model the spatiotemporal ramifications of such incidents remains *** fill this gap,we develop an agent-based complex network model integrated with frequently updated maritime *** Suez Canal blockage is taken as a case *** results indicate that the effects of such blockages go beyond the directly affected countries and *** Suez Canal blockage led to global losses of about$136.9($127.5–$147.3)billion,with India suffering 75%of these *** losses show a nonlinear relationship with the duration of blockage and exhibit intricate trends post *** proposed model can be applied to diverse blockage scenarios,potentially acting as an earlyalert system for the ensuing supply chain ***,high-resolution daily data post blockage offer valuable insights that can help nations and industries enhance their resilience against similar future events.

关键词： chains valued extreme

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Transcriptomic analysis reveals hub genes and pathways in response to acetic acid stress in Kluyveromyces marxianus during high-temperature ethanol fermentation

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Stress Biology 2023年第1期3卷 288-299页

作者： Yumeng Li Shiqi Hou Ziwei Ren Shaojie Fu Sunhaoyu Wang Mingpeng Chen Yan Dang Hongshen Li Shizhong Li Pengsong Li Beijing Key Lab for Source Control Technology of Water Pollution College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China Engineering Research Center for Water Pollution Source Control&Eco-Remediation College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China Institute of New Energy Technology Tsinghua UniversityBeijing 100084China

The thermotolerant yeast Kluyveromyces marxianus is known for its potential in high-temperature ethanol fermentation,yet it suffers from excess acetic acid production at elevated temperatures,which hinders ethanol *** better understand how the yeast responds to acetic acid stress during high-temperature ethanol fermentation,this study investigated its transcriptomic changes under this *** sequencing(RNA-seq)was used to identify differentially expressed genes(DEGs)and enriched gene ontology(GO)terms and pathways under acetic acid *** results showed that 611 genes were differentially expressed,and GO and pathway enrichment analysis revealed that acetic acid stress promoted protein catabolism but repressed protein synthesis during high-temperature ***-protein interaction(PPI)networks were also constructed based on the interactions between proteins coded by the *** genes and key modules in the PPI networks were identified,providing insight into the mechanisms of this yeast’s response to acetic acid *** findings suggest that the decrease in ethanol production is caused by the imbalance between protein catabolism and protein ***,this study provides valuable insights into the mechanisms of ***’s response to acetic acid stress and highlights the importance of maintaining a proper balance between protein catabolism and protein synthesis for high-temperature ethanol fermentation.

关键词： Kluyveromyces marxianus Acetic acid Transcriptomics Protein-protein interaction network

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water-soluble chitosan promotes remediation of Pb-contaminated soil by Hylotelephium spectabile

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Frontiers of Environmental Science & Engineering 2024年第7期18卷 109-122页

作者： Bingxin Guo Yiwei Zhang Junxing Yang Tianwei Qian Junmei Guo Xiaona Liu Yuan Jiao Tongbin Chen Guodi Zheng Wenjun Li Fei Qi College of Environmental Science and Engineering Taiyuan University of TechnologyShanxi Key Laboratory of Earth Surface Processes and Resource Ecological Security in Fenhe River BasinShanxi Engineering Research Center of Low Carbon Remediation for Water and Soil Pollution in Yellow River BasinJinzhong 030600China Center for Environmental Remediation Institute of Geographic Sciences and Natural Resources ResearchChinese Academy of SciencesBeijing 100101China University of Chinese Academy of Sciences Beijing 100049China Shanxi Transportation Holding Ecological Environment Co. Ltd.Shanxi 030000China Beijing Key Lab for Source Control Technology of Water Pollution College of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China

water-soluble chitosan(WSC)has been studied for its ability to mobilize soil Pb and promote the phytoremediation by Hylotelephium spectabile in Pb-contaminated *** aimed to clarify the internal mechanism by which wSC impacts phytoremediation by examining plant growth and Pb accumulation performance of *** as well as the Pb form,functional groups,and mineral phases of Pb-contaminated *** effectively decreased soil pH and activated Pb migration in rhizosphere soils,with a considerable increase in water-soluble and acid-extractable Pb by 29%-102%and 9%-65%,respectively,and a clear decreasing trend in reducible and oxidizable ***-transform infrared spectroscopy revealed a significant increase in amino and hydroxyl groups in the soil generated by *** coordination of Pb with amino and hydroxyl groups may play an important role in the formation of Pb complexes and activation of Pb in *** field trials,the application of WSC significantly increased Pb accumulation in *** by 125.44%,reaching 92 g/hm^(2).Moreover,the organic matter and nitrogen in the soils were increased by WSc,which improved the growth conditions of *** obvious growth inhibition was observed in either the pot or field ***,WSC is a promising chelating agent for mobilizing Pb in ***,WSC can be potentially used to boost ***-mediated phytoremediation of Pb-contaminatedfarmland.

关键词： Phytoremediation Pb-contaminated soil water-soluble chitosan Hylotelephium spectabile Fourier transform infrared spectroscopy

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Energy-efficient removal of carbamazepine in solution by electrocoagulation-electrofenton using a novel P-rGO cathode

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Journal of Environmental Sciences 2022年第5期34卷 88-102页

作者： Zhihui Xiao Tingyu Cui Zhenbei Wang Yan Dang Meijie Zheng Yixinfei Lin Zilong Song YipingWang Chao Liu Bingbing Xu Amir Ikhlaq Jolanta Kumirska Ewa Maria Siedlecka Fei Qi Beijing Key Lab for Source Control Technology of Water Pollution School of Environmental Science and EngineeringBeijing Forestry UniversityBeijing 100083China Jiangsu Key Lab of Industrial Pollution Control and Resource Reuse School of Environmental EngineeringXuzhou University of TechnologyXuzhou 221018China State Key Lab of Environmental Criteria and Risk Assessment Chinese Research Academy of Environmental SciencesBeijing 100012China Institute of Environment Engineering and Research University of Engineering and TechnologyGT Road54890LahorePunjabPakistan Faculty of Chemistry University of GdanskWita Stwosza 6380-308 GdanskPoland

In this study,carbamazepine(CBZ)decay in solution has been studied by coupling electro-coagulation with electro-Fenton(EC-EF)with a novel P-rGO/carbon felt(CF)cathode,aiming to accelerate the in-situ generation of·OH,instead of adding Fe2+and ***,the fabri-cated P-rGO and its derived cathode were characterized by XRD,SEM,AFM,XPS and electro-chemical test(EIS,CV and LSV).Secondly,it was confirmed that the performance in removal efficiency and electric energy consumption(EEC)by EC-EF(kobs=0.124 min^(-1),EEC=43.98 kWh/kg CBZ)was better than EF(kobs=0.069 min^(-1),EEC=61.04 kWh/kg CBZ).Then,P-rGO/CF(kobs=0.248 min^(-1),EEC=29.47 kWh/kg CBZ,CE=61.04%)showed the best performance in EC-EF,among all studied heteroatom-doped graphene/*** superior performance may be associated with its largest layer spacing and richest C=C,which can promote the electron transfer rate and conductivity of the ***,more H2O2 and·OH could be produced to degrade CBZ,and almost 100%CBZ was removed with kobs being 0.337 min^(-1) and the EEC was only 24.18 kWh/kg CBZ,under the optimal conditions(P-rGO loading was 6.0 mg/cm^(2),the current density was 10.0 mA/cm^(2),the gap between electrode was 2.0 cm).Additionally,no matter the influent is acidic,neutral or alkaline,no additional pH adjustment is required for the effluent of *** last,an inconsecutive empirical kinetic model was firstly estab-lished to predict the effect of operating parameters on CBZ removal.

关键词： Carbamazepine Electro-fenton Electrocoagulation Empirical kinetic model P-rGO

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Separation of nutrients from SCFAs with a dynamic membrane in a sludge anaerobic fermenter

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Chemosphere 2024年 355卷 141824页

作者： Yang, Lisha Chen, Kai Chen, Long Zhai, Shixin Li, Zhuo Zhu, Hongtao Beijing Key Lab for Source Control Technology of Water Pollution Beijing Forestry University Beijing100083 China Engineering Research Center for Water Pollution Source Control & Eco-Remediation College of Environmental Science and Engineering Beijing Forestry University Beijing100083 China

The complexity and high cost to separate and recover short chain fatty acids (SCFAs), ammonium ions, and phosphates in the sludge fermentation liquid hinder the application of sludge anaerobic fermentation. In this study, an interesting phenomenon was found in a sludge anaerobic fermenter with a dynamic membrane (DM) which could not only enhance SCFAs production but also retain most SCFAs in fermenter. The separation factor of DM for NH3-N/SCFAs and PO43−/SCFAs throughout the DM development were about 40 and 80, respectively. Analysis reveals that rejection of SCFAs by DM could not be simply correlated to molecular weight or membrane pore size. The rejection mechanisms might be dominated by Donnan rejection. In addition, biodegradation in the DM may also have contribution. Findings of this study suggest the potential of DM as an economical technology for nutrients and SCFAs recover. © 2024 Elsevier Ltd

关键词： Nutrients

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