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Synthesis and optical properties of highly efficient Na_(3)KMg_(7)(PO_(4))_(6):Eu^(2+)blue phosphor for full-spectrum white-light-emitting diodes:The role of Li_(2)CO_(3)flux

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Journal of Rare Earths 2024年第7期42卷 1217-1223,I0001页

作者： Zihao Wang Sisi Liang Chenyang Zhan Kunyuan Xu Jie Hu Dejian Chen Liping Song Haomiao Zhu School of Physics and Materials Science Nanchang UniversityNanchang330000China Ganjiang Innovation Academy Chinese Academy of SciencesGanzhou341000China CAS Key Laboratory of Design and Assembly of Functional Nanostructures and Fujian Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou350002China Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials Xiamen Research Center of Rare Earth MaterialsHaixi InstituteChinese Academy of SciencesXiamen361021China

Full-spectrum phosphor-converted white-light-emitting diodes(pc-WLED)are emerging as a mainstream technology in semiconductor ***,high-performance blue phosphor which can be excited efficiently by a 400 nm NUV diode chip is still ***,we present a blue-emitting Na_(3)KMg_(7)(PO_(4))6:Eu^(2+)phosphor synthesized by the solid-reaction ***,we find that the using of Li_(2)CO_(3)as flux can significantly improve the crystal quality and thus the emission efficiency of the ***,the excitation peak of the phosphor shifts from 365 to 400 nm,which is pivotal for efficient NUV(400 nm)diode chip *** practical Eu^(2+)concentration is also enhanced by using Li_(2)CO_(3)as flux,and the absorption efficiency is greatly *** phosphor exhibits superior PL thermal stability,namely retains 94%integrated photoluminescence intensity at 150℃of that at 25℃.As a result,the optimized phosphor shows an emission band peaked at 437 nm with a bandwidth of 40 nm and a high external photoluminescence quantum yield of 51.7%.Finally,a pc-WLED was fabricated by using NKMPO:Eu^(2+)blue,Sr_(2)SiO_(4):Eu^(2+)green,CaAlSiN_(3):Eu^(2+)red phosphors,and a 400 nm NUV diode *** shows a high color rendering index of R_(a)=96.4 and a correlated color temperature of 4358 *** results prove that NKMPO:Eu^(2+)is a promising blue phosphor for full-spectrum WLED based on NUV diode chips.

关键词： Eu^(2+) Blue phosphor Na_(3)KMg_(7)(PO_(4))_(6) Full-spectrum white LEDs Rare earths

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Oxygen self-doping pyrolyzed polyacrylic acid as sulfur host with physical/chemical adsorption dual function for lithium-sulfur batteries

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Chinese Chemical Letters 2024年第7期35卷 473-479页

作者： Yan Wang Huixin Chen Fuda Yu Shanyue Wei Jinhui Song Qianfeng He Yiming Xie Miaoliang Huang Canzhong Lu Engineering Research Center of Environment-Friendly Functional Materials Ministry of EducationInstitute of Materials Physical ChemistryHuaqiao UniversityXiamen 361021China CAS Key Laboratory of Design and Assembly of Functional Nanostructures and Fujian Provincial Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials Xiamen Institute of Rare Earth MaterialsHaixi InstitutesChinese Academy of SciencesXiamen 361021China

Lithium-sulfur(Li-S)batteries with high theoretical capacity and energy density need to solve problems such as the high decomposition energy barrier of Li_(2)S and large volume change of sulfur in the charging process caused by the shuttle effect before practical ***,a green synthesis method is used to prepare polyacrylic acid(PAA)superabsorbent material,and then the pyrolyzed PAA(P/PAA)material is obtained as the positive electrode of Li-S *** functional calculation reveals that the oxygen self-doping pyrolyzed polyacrylic acid(P/PAA)delivered stronger binding energy toward Li2S species in carbonyl C=O than that of graphite powder(GP)which are-1.58 eV and-1.02 eV,*** with the distribution of relaxation time analysis and the in-situ electrochemical impedance approach,it is further demonstrated that the designed P/PAA as sulfur host plays a physical/chemical adsorption dual function in maintaining the stability and rate performance of *** an initial discharge capacity of 1258 mAh/g at 0.1 C and a minimal capacity decline of 0.05%per cycle even after 800 cycles at 0.5 C,the produced cathode demonstrated outstanding electrochemical *** average Coulombic efficiency is nearly 100%.The P/PAA electrodes may typically retain 96%of their capacity while declining on average only 0.033%per cycle after 130 cycles at 3 *** effort provides a new method for the future development of heteroatomic self-doping superabsorbent with promising adsorption properties for polysulfides as cathode materials of Li-S batteries.

关键词： Polyacrylic acid Oxygen self-doping Green synthetic Pore mesh polymer cathodes Lithium-sulfur batteries

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Room-temperature synthesis of layered open framework cathode for sodium-ion batteries

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Chinese Chemical Letters 2023年第5期34卷 576-579页

作者： Ruding Zhang Huixin Chen Hongjun Yue CAS Key Laboratory of Design and Assembly of Functional Nanostructures and Fujian Provincial Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials Xiamen Institute of Rare Earth MaterialsHaixi InstitutesChinese Academy of SciencesXiamen 361021China

The synthesis of active electrode materials at room temperature is one of the effective strategies to reduce the fabrication cost of sodium ion batteries(SIBs).Herein,a layered material(Na_(2)[(VO)_(2)(HPO_(4))_(2)C_(2)O_(4)]·2H_(2)O,abbreviated as NVPC followingly)with open-framework structures has been successfully prepared at room temperature under ambient conditions and is evaluated as a cathode for *** is revealed that NVPC cathode can deliver a maximum reversible capacity of ca.70 mAh/g at 10 mA/g,and exhibit superior rate capability and cycling performance:at 50 mA/g,maximum reversible capacity ca.50 m Ah/g with capacity retention of 88.4%over 250 cycles corresponds to only 0.046%capacity decay per cycle;at 100 mA/g,a maximum reversible capacity of 35 mAh/g with capacity retention of60.9%over 500 *** study demonstrates a practical example of a low-cost synthesis of the cathode materials for *** the same time,the systematic electrochemical research results also show promising prospects for long lifespan low-cost SIBs.

关键词： Room temperature solution synthesis Open framework structure Cathode materials Sodium-ion batteries Full cell

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Advanced dielectrics for 2D devices

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Science Bulletin 2025年第3期70卷 295-296页

作者： Hao Zhang Zhiwen Lu Zhenhai Wen Department of Chemical Engineering Massachusetts Institute of TechnologyCambridgeMA 02139USA Department of Chemistry University of OxfordOxford OX13TAUK CAS Key Laboratory of Design and Assembly of Functional Nanostructures Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen EnergyFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China

As the application potential of two-dimensional(2D)materials in fields such as nanoelectronics,optoelectronics,and quantum computing continues to grow,the challenge of fabricating high-quality dielectric layers has be... 详细信息

关键词： computing continue devices

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A MOF-to-MOF conversion assisted formation of hierarchical hollow Zn-Co_(1-x)S/C@C composite for efficient potassium-ion storage

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Chinese Journal of Structural Chemistry 2023年第6期42卷 47-54页

作者： Qixin Zhang Lizhong Liu Lulu Song Chuxin Wu Yi Zhao Lunhui Guan The Straits Institute of Flexible Electronics(SIFE Future Technologies)Fujian Normal UniversityFuzhou350117China CAS Key Laboratory of Design and Assembly of Functional Nanostructures Fujian Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou350108China

Hollow structured composite can enhance the structural stability of metal sulfide anode by accommodating its volume variation,while the performance is still hindered by its poor electron/ion ***,we develop a hier-archical hollow structure to achieve superior electrochemical performance,from which a MOF-to-MOF conversion is utilized to generate hollow Zn-Co_(1-x)S/C composite followed with additional carbon coating *** potassium storage,as-prepared hollow ***/C@C composite displays high capacities of 375 mA h g^(-1)after 100 cycles at 0.2 A g^(-1)and 201 mA h g^(-1)after 500 cycles at 1 A g^(-1).Moreover,it also manifests outstanding rate capability of 200 mA h g^(-1)at 10 A g^(-1),outperforming hollow Co_(1-x)S@C and majority of the reported cobalt-based *** illustration by kinetics analysis and theoretical calculation,both of Zn doping and internal carbon matrix are conductive to promote the charge transportation ability of Co_(1-x)S,thus accounting for the good cycling behavior and excellent rate capacity of hierarchical hollow ***/C@C composite.

关键词： MOF conversion Hollow structure Cobalt sulfide Element doping Potassium-ion batteries

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Fluorinated N,P co-doped biomass carbon with high-rate performance as cathode material for lithium/fluorinated carbon battery

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Rare Metals 2025年第1期44卷 110-120页

作者： Ke Yan Yan Zou Liang-Xue Bao Qi Xia Ling-Yi Meng Hai-Chen Lin Hui-Xin Chen Hong-Jun Yue College of Chemistry Fuzhou UniversityFuzhou 350108China CAS Key Laboratory of Design and Assembly of Functional Nanostructures and Fujian Provincial Key Laboratory of NanomaterialsFujian Institute of Research On the Structure of MatterChinese Academy of SciencesFuzhou 350002China Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials Xiamen Institute of Rare Earth MaterialsHaixi InstitutesChinese Academy of SciencesXiamen 361021China Sustainable Power and Energy Center Nano Engineering DepartmentUniversity of California San DiegoLa JollaSan DiegoCA 92093USA

Lithium/fluorinated carbon(Li/CF_(x))batteries are greatly limited in their applications mostly due to poor rate *** this study,N,P co-doped biomass carbon was synthesized using melamine and phytic acid as doping sources,and the resulting product was then utilized as a precursor for CF_(x).The resulting fluorinated biomass carbon has a high degree of fluorination,exceeding the specific capacity of commercial fluorinated graphite while also demonstrating exceptional performance at high discharge *** the fluorination process,N,P-containing functional groups were removed from the crystalline lattice in the basal *** facilitates the formation of a defect-rich carbon matrix,enhancing the F/C ratio by improving the fluorinated active sites and obtaining more highly active semi-ionic ***,the abundant defects and porous structure promote Li^(+)*** functional theory calculations indicated that doping modification effectively reduces the energy barrier for Li+migration,enhancing Li+transport *** prepared CF_(x)delivers material with a maximum specific capacity of 919 mAh·g^(-1),while maintaining a specific capacity of 702 mAh·g^(-1)at a high discharge current density of 20C(with a capacity retention rate of 76.4%).In this study,fluorinated N,P co-doped biomass carbon,exhibiting ultrahigh capacity and high-rate performance,was prepared for the first time,which can potentially advance the commercialization of CF_(x).

关键词： Li/CF_(x)primary batteries Biomass carbon Heteroatom doping High performance

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Precursor chemistry towards highly efficient and phase-stable red emitting CsPbI_(3) perovskite nanocrystals

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Nano Research 2022年第1期15卷 644-652页

作者： Dejian Chen Decai Huang Mingwei Yang Kunyuan Xu Jie Hu Sisi Liang Haomiao Zhu CAS Key Laboratory of Design and Assembly of Functional Nanostructures and Fujian Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials Xiamen Institute of Rare Earth MaterialsHaixi InstituteChinese Academy of SciencesXiamen 361021China

All-inorganic cesium lead halide perovskite nanocrystals(CsPbX_(3),X=Cl,Br,I)have attracted considerable scientific and technological interest due to their precise bandgap tunability,high color purity and efficient ***,their poor stability in harsh conditions such as moisture,ultraviolet(UV)light irradiation and high temperature,is a major obstacle for their further commercial ***,by simply using a new type of precursor,namely“HPbX_(3)”(X=Cl,Br,I),we can achieve the coordination equilibrium for Pb precursors during reaction and obtain high-quality perovskite nanocrystals with tremendously enhanced luminous efficiency and chemical stability based on hot-injection *** prepared a-CsPbb nanocrystals exhibit an extremely high photoluminescence quantum yield of 96%and keep stable in air for more than two months without any post-synthesis ***,stability evaluations under UV light irradiation,water or thermal impact are also performed and the results show substantially improved stability of these nanocrystals as compared with the samples prepared using traditional Pbl_(2) as *** temperature-dependent(10-300 K)steady and transient spectral analysis combined with compositional measurements,it is revealed that the lower structural defect density,which is guaranteed by abundant halogen when using HPbX3 as precursor,is the most important reason for such performance enhancement.

关键词： perovskite nanocrystals CsPbX_(3) precursor stability vacancy defect

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Novel 2D bifunctional layered rare-earth hydroxides@GO catalyst as a functional interlayer for improved liquid-solid conversion of polysulfides in lithium-sulfur batteries

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Chinese Chemical Letters 2024年第5期35卷 434-440页

作者： Haodong Wang Xiaoxu Lai Chi Chen Pei Shi Houzhao Wan Hao Wang Xingguang Chen Dan Sun CAS Key Laboratory of Design and Assembly of Functional Nanostructures and Fujian Provincial Key Laboratory of Nanomaterials Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China College of Chemistry and Materials Fujian Normal UniversityFuzhou 350007China Xiamen Institute of Rare Earth Materials Haixi InstitutesChinese Academy of SciencesXiamen 361021China School of Microelectronics Hubei UniversityWuhan 430062China Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials Xiamen 361021China

The detrimental“shuttle effect”of lithium polysulfides(LiPSs)together with sluggish multi-order reaction kinetics are the main drawbacks hindering lithium-sulfur(Li-S)batteries from commercial ***,we first propose the implementability of layered rare-earth hydroxides(LREHs)in Li-S batteries to optimize electrochemical *** this work,a two-dimensional(2D)rare-earth-based composite constructed by the layered gadolinium hydroxy chloride[Gd_(2)(OH)_(5)(H_(2)O)_(n)]Cl nanoplates(LGdH NPs)and graphene oxide(GO)was designed as a sulfur immobilizer for Li-S *** the experimental results and density functional theory(DFT)calculations,it is revealed that the LGdH@GO composite not only provides a strong anchoring of the intermediates during cycling,but also acts as an effective catalyst to accelerate the liquid-solid conversion of *** Li-S batteries assembled by LGdH@GO modified separators delivered a superior rate performance with a specific capacity of 605.34 mAh/g at 5 C,as well as excellent cycle stability with a decay rate of 0.087%over 500 cycles at 2 *** study provided a deep understanding of the mechanism to suppress the“shuttle effect”by the LREHs,and a guide to design effective functional interlayers for high-performance Li-S batteries with excellent electrocatalytic activity.

关键词： Lithium-sulfur batteries functional separator Layered rare-earth hydroxides Shuttle effect Adsorption Catalysis

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Anionic covalent organic framework electrolyte with tailored ion channels for high-areal-capacity solid-state lithium metal battery

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Science China Chemistry 2025年第4期68卷 1533-1540页

作者： Xu Zhuang Yangdan Hui Yangyang Feng Jiajie Chen Junlan Chen Yaobing Wang College of Chemistry Institute of Molecular Engineering PlusFuzhou UniversityFuzhou 350116China CAS Key Laboratory of Design and Assembly of Functional Nanostructures and Fujian Provincial Key Laboratory of NanomaterialsState Key Laboratory of Structural ChemistryFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China Fuzhou 350108China University of Chinese Academy of Sciences Beijing 100049China Fujian College University of Chinese Academy of SciencesFuzhou 350002China

Covalent organic frameworks(COFs)are an emerging class for solid-state electrolytes due to their ordered and customizable ion transport *** high ionic conductivity(σ_(Li+))and Li^(+) transference number(t_(Li+))are achieved;the high-arealcapacity solid-state lithium metal battery(LMB)still encountered challenges;which is mainly determined by homogeneous Li^(+) flux through channels and ***;we design a COF coupling anionic skeletons with branched ion-conductive chains(COF-S)as tailored fast ion-transport channels to achieve high-areal-capacity solid-state *** the dispersed COF-S-based electrolyte is further obtained by incorporating ethoxylated trimethylolpropane triacrylate(ETPTA)and Li FSI(ETPTA-COF-S)via in situ light *** this way;the abundant SO_(3)-groups promote Li+adsorption and facilitate axial transport via 1D channels;thus enabling highσLi+of 1.29 m S cm^(-1)and tLi+of *** branched chains can tailor ion channels to suppress largesize anions transport;disperse and uniform Li+flux;thus leading to high average Coulombic efficiency(CE)up to 98.43%for 100 cycles(~800 h)at 0.5 m A cm^(-2)under the high areal capacity of 2 mAh cm^(-2).When paired with 2 m Ah cm^(-2)LiFePO_(4)(LFP)cathode and thin Li anode of 20μm;Li||ETPTA-COF-S||LFP exhibits superior cyclic stability for 80 cycles.

关键词： covalent organic framework ion channel sulfonic acid group gel electrolyte lithium metal battery high areal capacity

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ZnMn_(3)O_(7):A New Layered Cathode Material for Fast-Charging Zinc-Ion Batteries

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Chinese Journal of Structural Chemistry 2022年第5期41卷 85-92页

作者： Ruitao Sun Qin Liu Wenzhuo Deng CAS Key Laboratory of Design and Assembly of Functional Nanostructures and Fujian Key Laboratory of NanomaterialsState Key Laboratory of Structural ChemistryFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China University of Chinese Academy of Sciences Beijing 100039China

Low-cost and high-energy-density manganese-based compounds are promising cathode materials for rechargeable aqueous zinc-ion batteries(AZIBs),however,they often experience cycling instability issues and inferior rate ***,we report a new layered manganese-based cathode material,ZnMn_(3)O_(7)(ZMO),which possesses a large interlayer spacing of 4.8Åand allows the intercalation of~1.23 Zn-ions per formula unit(corresponding to a capacity of~170 mAh/g).Importantly,ZMO exhibits good cycling stability(72.9%capacity retention over 400 cycles),ultrafast-charging capability(73%state of charge in 1.5 min),and an ultrahigh power density(3510 W/kg at 88 Wh/kg).Through kinetic characterization,the favorable diffusion of ions and the dominant capacitor contribution are found to be conducive to the achievement of superior fast charging ***,the charge storage mechanism is revealed by ex-situ XRD and ex-situ *** work may shed light on the design of high-performance electrode materials for AZIBs.

关键词： layered structure zinc-manganese oxide cathode zinc-ion battery

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