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Recyclable thiol-modified Zr-based MOFs/hydrogel composite beads for effective removal of Hg(Ⅱ)

Progress in Natural science:Materials International 2023年第5期33卷 644-651页

作者： Xuechun Wang Zeming Dai Xuan Zhou Hao Chen Yu Cao Jianhua Hou Xiaozhi Wang College of Environmental Science and Engineering Yangzhou University Jiangsu Collaborative Innovation Center for Solid Organic Waste Resource Utilization Institutes of Agricultural Science and Technology Development

In general, majority of MOFs are powder, which limit their applications. In this study, the highly stable Zr-based MOF-808 and its thiol-modified MOF-808-SH were selected as precursors, and then they were wrapped by sodium alginate hydrogel via a dripping strategy. Based on these, MOF/hydrogel composite beads（Alg-MOF-808, AlgMOF-808-SH） with 3D network structure were prepared successfully. Due to its excellent adsorption properties and easy recovery, they were employed as effective environmental functional materials for the adsorption of Hg（Ⅱ）. The adsorption capacities of Hg（Ⅱ） were 170.52 mg·g-1and 221.73 mg·g-1respectively and they can achieve adsorption equilibrium in a short time. The adsorption stability of Alg-MOF-808-SH was studied at different p H as well. In addition, the removal efficiency of composite beads for Hg（Ⅱ） was almost unaffected by other coexisting ions, displaying good adsorption selectivity. Furthermore, the removal efficiency only decreased by 10.4% after 5 cycles, indicating that the as-prepared materials have high recycling efficiency. The results demonstrated that the MOF/hydrogel composite beads have a certain application potential for mercury removal in actual wastewater.

关键词： Environmental functional material Hg (II) adsorption MOF-808 thiol groups Beads

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Characterization and comparison of organic functional groups effects on electrolyte performance for vanadium redox flow battery

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Frontiers of Chemical science and Engineering 2023年第9期17卷 1221-1230页

作者： Ling Ge Tao Liu Yimin Zhang Hong Liu School of Resource and Environmental Engineering Wuhan University of Science and TechnologyWuhan430081China State Environmental Protection Key Laboratory of Mineral Metallurgical Resources Utilization and Pollution Control Hubei Collaborative Innovation Center for High Efficient Utilization of Vanadium ResourcesWuhan University of Science and TechnologyWuhan430081China Collaborative Innovation Center of Strategic Vanadium Resources Utilization Wuhan University of Science and TechnologyWuhan430081China Hubei Provincial Engineering Technology Research Center of High Efficient Cleaning Utilization for Shale Vanadium Resource Wuhan University of Science and TechnologyWuhan430081China

The vanadium redox flow battery with a safe and capacity-controllable large-scale energy storage system offers a new method for the *** this case,acetic acid,methane sulfonic acid,sulfonic acid,amino methane sulfonic acid,and taurine are used to overcome the low electrolyte energy density and stability limitations,as well as to investigate the effects of various organic functional groups on the vanadium redox flow *** compared to the pristine electrolyte(0.22 Ah,5.0 Wh·L^(−1),85.0%),the results show that taurine has the advantage of maintaining vanadium ion concentrations,discharge capacity(1.43 Ah),energy density(33.9 Wh·L^(−1)),and energy efficiency(90.5%)even after several *** acetic acid electrolyte is more conducive to the low-temperature stability of the V(II)electrolyte(177 h at−25℃)than pristine(82 h at−2℃).The−SO_(3)H group,specifically the coaction of the−NH_(2)and−SO_(3)H groups,improves electrolyte ***−NH_(2)and−COOH additive groups improved conductivity and electrochemical activity.

关键词： vanadium redox flow battery functional groups organic additives energy density stability

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Optimized the vanadium electrolyte with sulfate-phosphoric mixed acids to enhance the stable operation at high-temperature

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Frontiers of Chemical science and Engineering 2024年第2期18卷 13-26页

作者： Ling Ge Tao Liu Yimin Zhang Hong Liu School of Resource and Environmental Engineering Wuhan University of Science and TechnologyWuhan 430081China State Environmental Protection Key Laboratory of Mineral Metallurgical Resources Utilization and Pollution Control Wuhan University of Science and TechnologyWuhan 430081China Hubei Collaborative Innovation Center for High Efficient Utilization of Vanadium Resources Wuhan University of Science and TechnologyWuhan 430081China Hubei Provincial Engineering Technology Research Center of High Efficient Cleaning Utilization for Shale Vanadium Resource Wuhan University of Science and TechnologyWuhan 430081China School of Resource and Environmental Engineering Wuhan University of TechnologyWuhan 430070China

Herein, the influence of the concentration design and comprehensive performance of the sulfate-phosphoric mixed acid system electrolyte is investigated to realize an electrolyte that maintains high energy density and stable operation at high temperatures. Static stability tests have shown that VOPO4 precipitation occurs only with vanadium(V) electrolyte. The concentration of vanadium ion of 2.0–2.2 mol·L^(–1), phosphoric acid of 0.10–0.15 mol·L^(–1), and sulfuric acid of 2.5–3.0 mol·L^(–1) are suitable for a vanadium redox flow battery in the temperature range from –20 to 50 ℃. The equations for predicting the viscosity and conductivity of electrolytes are obtained by the response surface method. The optimized electrolyte overcomes precipitation generation. It has 2.8 times higher energy density than the non-phosphate electrolyte, and a coulomb efficiency of 94.0% at 50 ℃. The sulfate-phosphoric mixed acid system electrolyte promotes the electrode reaction process, increases the current density, and reduces the resistance. This work systematically optimizes the concentrations of composition of positive and negative vanadium electrolytes with mixed sulfate-phosphoric acid. It provides a basis for the different valence states and comprehensive properties of sulfate-phosphoric mixed acid system vanadium electrolytes under extreme environments, guiding engineering applications.

关键词： all vanadium redox flow battery mixed-acid vanadium electrolyte concentration optimization response surface methodology high-temperature stability

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Extract lithium from clay-type lithium ore by mixed acid and its mechanism Author links open overlay panel

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Particuology 2024年第8期91卷 323-332页

作者： Wuchang Zhou Ruiqi Xie Xiong Tong Xian Xie Yang Liu Zhihui Zhao Faculty of Land Resource Engineering Kunming University of Science and TechnologyKunming650093China Technology Innovation Center for Comprehensive Utilization of Strategic Mineral Resources Ministry of Natural ResourcesChengdu610041China National&Regional Engineering Research Center for Green comprehensive Utilization of Tailing Resources from Metal Minerals Kunming650093China

A roasting-leaching test was carried out for the efficient utilization of clay-type lithium ore in the central region of Yunnan *** test used the mixed acid of sulfuric acid and phosphoric acid as the leaching *** the conditions of roasting temperature of 600℃,roasting time of 1 h,liquid-solid ratio of 5:1,volume ratio of H_(2)SO_(4)solution to H_(3)PO_(4)solution of 45:5,leaching time of 2 h and leaching temperature of 80℃,the leaching rate of lithium was as high as 97.83%.The leaching mechanism was studied by SEM,pore property analysis,XRD and *** was found that the morphology of the ore changed obviously after roasting and leaching,and a certain degree of collapse and fragmentation occurred,which provided favorable spatial conditions for the leaching of *** porosity,total intrusion volume and total pore area also increased after roasting and leaching,thus promoting the leaching of Li^(+).The results showed that chemical reaction taken placed during the roasting and *** phase of the sample changed from chlorite,kaolinite and diaspore(boehmite)mainly to corundum,hematite,periclase and quartz after ***,after leaching,no new phase was produced in the ore sample,and no S and P elements were found on the surface of the ore sample,indicating that the leaching mechanism of lithium might be the ion exchange between H^(+)and Li^(+).

关键词： Clay-type lithium ore Lithium extraction Roasting Leaching

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Harmless Impact of Electrolytic Manganese Residue by Low Temperature Thermochemical Method with Carbide Slag

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Journal of Wuhan University of technology(Materials science) 2025年第2期40卷 400-411页

作者： XIE Zhihan LIU Rongjin LU Fuhua JING Daiyan ZHAO Yanrong LIANG Jianbo HUANG Wanyu CHEN Tingchao College of Material Science and Engineering Guilin University of TechnologyGuilin 541004China Collaborative Innovation Center for Exploration of Nonferrous Metal Deposits and Efficient Utilization of Resources in Guangxi Guilin University of TechnologyGuilin 541004China Key Laboratory of New Processing Technology for Nonferrous Metal&Materials Ministry of EducationGuilin University of TechnologyGuilin 541004China Guangxi Engineering and Technology Center for Utilization of Industrial Waste Residue in Building Materials Guilin 541004China

This study introduced a low-temperature thermochemical method for the treatment of EMR in the presence of carbide slag(CS)to achieve an economical and efficient harmless *** experimental results indicate that,under suitable conditions,the NH_(4)^(+)and Mn^(2+)contents in EMR decrease notably with the increasing CS content,accompanied by an increase in pH ***,the concentration of NH_(4)^(+)in EMR considerably decreases with the increasing liquid-to-solid ratio,eventually ***,the pH value first increases and then decreases,ultimately *** a CS content of 12%and a liquid-to-solid ratio of 0.7,the leaching concentrations of NH_(4)^(+)and Mn^(2+)in EMR(127.7 mg/kg and 0.15 mg/L,respectively)fall below the standard detection limit(2 mg/L),with the pH measuring 8.26,meeting the conditions outlined in the GB ***_(4)^(+)is converted to NH_(3),while Mn^(2+)is transformed into solid precipitates such as Mn(OH)_(2),Mn_(2)O_(3),MnO_(2),Ca_(3)Mn_(2)O_(7),and Ca_(2)MnO_(4).The majority of manganese ions exist in trivalent or tetravalent states and remain stable over *** cost of using CS as a reagent for treating 1 ton of EMR is merely$*** high OH^(-)concentration provided by CS enables the effective removal of NH_(4)^(+)from EMR and the solidification of Mn^(2+)during thermal reactions.

关键词： low-temperature thermochemistry electrolytic manganese residue carbide slag harmless treatment soluble manganese ammonium ion

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Vanadium(Ⅳ)solvent extraction enhancement in high acidity using di-(2-ethylhexyl)phosphoric acid with[Cl^(-)]present:an experimental and theoretical study

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Frontiers of Chemical science and Engineering 2023年第1期17卷 56-67页

作者： Hong Liu Yi-Min Zhang Jing Huang Tao Liu School of Resource and Environmental Engineering Wuhan University of Science and TechnologyWuhan 430081China State Environmental Protection Key Laboratory of Mineral Metallurgical Resources Utilization and Pollution Control Wuhan University of Science and TechnologyWuhan 430081China Hubei Collaborative Innovation Center for High Efficient Utilization of Vanadium Resources Wuhan University of Science and TechnologyWuhan 430081China Hubei Provincial Engineering Technology Research Center of High Efficient Cleaning Utilization for Shale Vanadium Resource Wuhan University of Science and TechnologyWuhan 430081China

Separation of vanadium from black shale leaching solution at low pH is very meaningful,which can effectively avoid the generation of alkali neutralization slag and the resulting vanadium *** this study,coordination mechanism of vanadium in acid leaching solution at low pH was investigated with the intervention of chloride *** the conditions of pH 0.8,di-(2-ethylhexyl)phosphoric acid concentration of 20%,phase ratio of 1:2,and extraction time of 8 min,the vanadium extraction could reach 80.00%.The Fourier transform infrared and electrospray ionization results reveal that,despite the fact that the chloride ion in the leachate could significantly promote vanadium extraction,the chloride ion does not enter the organic phase,indicating an intriguing *** Cl^(-)-V,SO_(4)^(2-)-V,and H_(2)O-V,the V-Cl bond is longer and the potential difference between coordinate ions and vanadium is ***,Vo^(2+)gets easily desorbed with chloride ions and enter the organic *** the same time,the hydrogen ions of di-(2-ethylhexyl)phosphoric acid also enter the water phase more easily,which reduces the pH required for the extraction reaction.

关键词： vanadium black shale solvent extraction high acidity extraction

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Organic matter determines the exchange of nutrients at sediment-water interface in coastal bays

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Acta Oceanologica Sinica 2025年第1期44卷 72-85页

作者： Jiasen Zhong Ehui Tan Chunwei Fu Guiyi Ma Yongkai Chang Zhixiong Huang Jingchao Yin Fengying Li Jianzhong Su Min Xu Zhenzhen Zheng Jian’an Liu Yu Han Shuh-Ji Kao State Key Laboratory of Marine Resources Utilization in the South China Sea School of Ecology and Environment and School of Marine Science and EngineeringHainan UniversityHaikou 570228China Collaborative Innovation Center of Marine Science and Technology Hainan UniversityHaikou 570228China

The exchange of inorganic nutrients at the coastal sediment-water interface(SWI)plays a crucial role in regulating the nutrient budget in overlying *** related studies mainly focus on the mid-to high-latitude regions,leaving a significant gap in the quantitative assessment of nutrient exchange and environmental controls at the SWI in lowlatitude coastal *** quantitatively assess the exchange of inorganic nutrients at the SWI in three tropical bays(Dongzhai Harbor,Xiaohai Lagoon,Qinglan Harbor).Sediments act as a source of ammonium,phosphate,and silicate,but for nitrate,sediments can be both a source and sink,although with substantial spatial and temporal variations in their *** organic matter is a critical regulator for the fluxes of inorganic nutrients at the *** sedimentary nutrients input with high N/P molar ratio will alter the nutrient stoichiometry to mitigate the nitrogen limitation in coastal ***,the internal sediment release in these tropical bays plays a relative weak role in contributing to the nutrient addition in comparison with the other external nutrient sources including riverine input,submarine groundwater discharge,and atmospheric *** to the global compilation on SWI nutrient fluxes,we propose that water column primary production and external inputs to interpret the variation in exchange and fluxes of nutrients at the SWI in different *** a conceptual understanding of these chain biogeochemical processes involving external nutrient input,primary production,particulate organic matter settling,and the accumulation and release of inorganic nutrients in sediments will be helpful for the scientific-based pollution prevent and control in coastal waters.

关键词： tropical bay sediment-water interface nutrient exchange labile organic matter source/sink

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Donor-acceptor covalent organic frameworks-confined ultrafine bimetallic Pt-based nanoclusters for enhanced photocatalytic H_(2)generation

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Nano Research 2024年第7期17卷 5835-5844页

作者： Yu Liu Yawen Shi Hua Wang Shengbo Zhang Collaborative Innovation Center of Chemical Science and Engineering(Tianjin) Key Laboratory for Green Chemical Technology of the Ministry of EducationSchool of Chemical Engineering and TechnologyTianjin UniversityTianjin 300350China School of Environmental Science and Engineering Tianjin Key Laboratory of Biomass/Wastes UtilizationTianjin UniversityTianjin 300350China

Photocatalytic hydrogen generation from hydrogen storage media is an effective and promising approach for the green hydrogen industry as well as for achieving carbon neutrality ***,the lower photocatalytic efficiency due to the limited light trapping capacity,low electron transfer rate,and severe aggregation of nanoparticles caused by high surface energy seriously restricts their practical ***,we constructed a series of donor–acceptor(D–A)type covalent organic frameworks to confine ultrafine bimetallic Pt-based nanoclusters for photocatalytic hydrogen generation from ammonia borane(AB)*** visible light irradiation at 20℃,PtCo_(2)@covalent organic framework(COF)showed the highest photocatalytic activity with a turnover frequency(TOF)of 486 min−*** and density functional theory(DFT)calculations reveal that the high catalytic activity is mainly attributed to the strong electronic interactions between D–A type COF and ultrafine PtCo_(2)***,the D–A type COF can significantly enhance the light-trapping ability by fine-tuning the electron-acceptor type in the framework,and accelerate the photogenerated electron transfer from D–A type COF to PtCo_(2)nanocluster,which promotes the adsorption and activation of H_(2)O and AB molecules and accelerates hydrogen ***,PtCo_(2)@COF also exhibited ultra-high durability due to the significantly enhanced resistance to nanocluster aggregation caused by the nanopore confinement effect of D–A type *** believe that this work will provide a theoretical guide for the rational design of efficient D–A COFbased catalysts for photocatalysis.

关键词： light trapping electron transfer donor-acceptor covalent organic frameworks(D-A COFs) bimetallic nanoclusters photocatalysis

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Synthesis and characterization of superhydrophobic magnesium oxysulfate whiskers

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Particuology 2023年第7期78卷 111-121页

作者： Zhenying Yao Lu Gong Chunmei Zhu Xin Lian Bai He Shenghui Tian Bo Yui School of Chemistry and Chemical Engineering Chongqing University of Science and TechnologyChongqing401331China Provincial and Ministerial Co-Constructive of Collaborative Innovation Center for MSw Comprehensive Utilization School of Metallurgy and Materials EngineeringChongqing University of Science and TechnologyChongqing401331China

Superhydrophobic materials have attracted much attention for their special *** this *** oxysulfate(MOS)whiskers were surface modified by vinyltrimethoxysilane(VTMS)and prepared as superhydrophobic materials,which are expected to be widely used in self-cleaning,corro-sion prevention,and oil-water *** factors of silane concentration,hydrolysis time,reaction temperature,and reaction time were *** superhydrophobic Mos whiskers were *** and XRD turned out that there were no apparent changes in the morphology and crystalli-zation behavior of whiskers before and after modification,while the surface was uniformly coated with a layer of non-crystal material,and the surface of the whiskers employed a chemical bond Si-O-Mg covalently *** thermogravimetric analysis ultimately demonstrated that surface modification was beneficial to the improvement of the thermal stability of MoS *** MoS whiskers showed good compatibility with organic solvents through oil-water separation experiments,and demonstrated excellent self-cleaning *** methodology for the surface treatment of Mos whiskers to prepare superhydrophobic whiskers in this work may be extended for other whiskers or fillers,which may be promising for the preparation of superhydrophobic materials.

关键词： Magnesium oxysulfate whiskers Surface modification Vinyltrimethoxysilane Superhydrophobicity

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An insight on the mechanism of efficient leaching of vanadium from vanadium shale induced by microwave-generated hot spots

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International Journal of Minerals,Metallurgy and Materials 2023年第2期30卷 293-302页

作者： Sheng Li Yimin Zhang Yizhong Yuan Pengcheng Hu School of Resource and Environmental Engineering Wuhan University of Science and TechnologyWuhan 430081China State Environmental Protection Key Laboratory of Mineral Metallurgical Resources Utilization and Pollution Control Wuhan University of Science and TechnologyWuhan 430081China Collaborative Innovation Center of Strategic Vanadium Resources Utilization Wuhan 430081China Hubei Provincial Engineering Technology Research Center of High Efficient Cleaning Utilization for Shale Vanadium Resource Wuhan University of Science and TechnologyWuhan 430081China School of Resource and Environmental Engineering Wuhan University of TechnologyWuhan 430070China

Microwave heating can rapidly and uniformly raise the temperature and accelerate the reaction *** this paper,microwave heating was used to improve the acid leaching,and the mechanism was investigated via microscopic morphology analysis and numerical simulation by COMSOL Multiphysics *** effects of the microwave power,leaching temperature,CaF_(2) dosage,H_(2)SO_(4) concentration,and leaching time on the vanadium recovery were investigated.A vanadium recovery of 80.66%is obtained at a microwave power of 550 W,leaching temperature of 95℃,CaF_(2) dosage of 5wt%,H_(2)SO_(4) concentration of 20vol%,and leaching time of 2.5 *** with conventional leaching technology,the vanadium recovery increases by 6.18%,and the leaching time shortens by 79.17%.More obvious pulverization of shale particles and delamination of mica minerals happen in the microwave-assisted leaching *** simulation results show that the temperature of vanadium shales increases with an increase in electric field(E-field).The distributions of E-field and temperature among vanadium shale particles are relatively uniform,except for the higher content at the contact position of the *** analysis results of scaleup experiments and leaching experiments indicate high-temperature hot spots in the process of microwave-assisted leaching,and the local high temperature destroys the mineral structure and accelerates the reaction rate.

关键词： vanadium shale microwave-assisted leaching hot spots numerical simulation

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