Development of advanced high-voltage electrolytes is key to achieving high-energy-density lithium metal batteries(LMBs).Weakly solvating electrolytes(WSE)can produce unique anion-driven interphasial chemistry via alte...
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Development of advanced high-voltage electrolytes is key to achieving high-energy-density lithium metal batteries(LMBs).Weakly solvating electrolytes(WSE)can produce unique anion-driven interphasial chemistry via altering the solvating power of the solvent,but it is difficult to dissolve the majority of Li salts and fail to cycle at a cut-off voltage above 4.5 ***,we present a new-type WSE that is regulated by the anion rather than the solvent,and the first realize stable cycling of dimethoxyethane(DME)at 4.6 V without the use of the“solvent-in-salt”*** relationships between the degree of dissociation of salts,the solvation structure of electrolytes,and the electrochemical performance of LMBs were systematically *** found that LiBF_(4),which has the lowest degree of dissociation,can construct an anion-rich inner solvation shell,resulting in anion-derived anode/cathode *** to such unusual solvation structure and interphasial chemistry,the Li-LiCoO_(2)full cell with LiBF_(4)-based WSE could deliver excellent rate performance(115 mAh g^(-1)at 10 C)and outstanding cycling stability even under practical conditions,including high loading(10.7 mg cm^(-2)),thin Li(50μm),and limited electrolyte(1.2μL mg^(-1)).
Laser powder bed fusion(LPBF)technology offers a promising solution to the fabricability challenges of titanium alloys;however,it introduces defects such as porosity and ***,we evaluated the effectiveness of hot isost...
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Laser powder bed fusion(LPBF)technology offers a promising solution to the fabricability challenges of titanium alloys;however,it introduces defects such as porosity and ***,we evaluated the effectiveness of hot isostatic pressing(HIP)in eliminating defects and enhancing the overall properties of LPBF Ti-6Al-4V *** findings indicated that LPBF Ti-6Al-4V alloy after HIP established better corrosion resistance and *** improvements could be related to the decomposition ofαʹphase and the elimination of internal defects within alloy ***,the application prospect of LPBF Ti-6Al-4V alloy in spent fuel reprocessing environment was expounded.
Sluggish storage kinetics is considered as the main bottleneck of cathode materials for fast-charging aqueous zinc-ion batteries(AZIBs).In this report,we propose a novel in-situ self-etching strategy to unlock the Pal...
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Sluggish storage kinetics is considered as the main bottleneck of cathode materials for fast-charging aqueous zinc-ion batteries(AZIBs).In this report,we propose a novel in-situ self-etching strategy to unlock the Palm tree-like vanadium oxide/carbon nanofiber membrane(P-VO/C)as a robust freestanding *** investigations including the finite element simulation,in-situ X-ray diffraction,and in-situ electrochemical impedance spectroscopy disclosed it an electrochemically induced phase transformation mechanism from VO to layered Zn_(x)V_(2)O_5·nH_(2)O,as well as superior storage kinetics with ultrahigh pseudocapacitive *** demonstrated,such electrode can remain a specific capacity of 285 mA h g^(-1)after 100 cycles at 1 A g^(-1),144.4 mA h g^(-1)after 1500 cycles at 30 A g^(-1),and even 97 mA h g^(-1)after 3000 cycles at 60 A g^(-1),***,an impressive power density of 78.9 kW kg^(-1)at the super-high current density of 100 A g^(-1)also can be *** design concept of in-situ self-etching free-standing electrode can provide a brand-new insight into extending the pseudocapacitive storage limit,so as to promote the development of high-power energy storage devices including but not limited to AZIBs.
作者:
Shuangtai LiuLei HeQiuxiang YaoXi LiLinyang WangJing WangMing SunXiaoxun MaSchool of Chemical Engineering
Northwest UniversityInternational Science&Technology Cooperation Base of MOST for Clean Utilization of Hydrocarbon ResourcesChemical Engineering Research Center of the Ministry of Education for Advanced Use Technology of Shanbei EnergyShaanxi Research Center of Engineering Technology for CleanSchool of Chemical EngineeringNorthwest UniversityInternational Science&Technology Cooperation Base of MOST for Clean Utiliza School of Electronic Information
Xijing UniversityXi’an Key Laboratory of Advanced Photo-electronics Materials and Energy Conversion DeviceXi’an 710123China
The low temperature coal tar(CT)is taken as the raw material,and the extraction and column chromatography are used for detailed and accurate characterization in this *** n-heptane soluble fraction(CT-HS)and insoluble ...
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The low temperature coal tar(CT)is taken as the raw material,and the extraction and column chromatography are used for detailed and accurate characterization in this *** n-heptane soluble fraction(CT-HS)and insoluble fraction(CT-HI)were obtained by n-heptane Soxhlet *** extraction rate of CT-HS reached 92.79%(mass),which indicated that there are few heavy compounds in ***,different solvents(methylbenzene,benzene,ethyl acetate,methylbenzene-ethanol)were used to elute CT-HS by chromatographic column to obtain five fractions(saturates,aromatics,heteroatoms,phenolics and resins,named CT-SA,CT-AR,CT-HE,CT-PH,CT-RE,respectively).The yields of CTSA,CT-AR,CT-HE,CT-PH,CT-RE are 42.12%,10.43%,2.19%,9.50%and 6.63%(mass),*** chromatography-mass spectrometry analysis of eluting components show that alkanes are the main components in CT,followed by polycyclic aromatics,and the corresponding fractions are CT-SA and CT-AR,*** relative content of aliphatics in CT-SA is 76.93%,and the relative content of aromatics in CT-AR is 75.05%.This separation technology effectively separates and enriches different components in CT,and the activation energy required for the pyrolysis process of a single eluting fraction is lower than that of CT,which is expected to provide an important reference for the separation,analysis and conversion of complex oil products such as coal-oil co-processing products,coal tar and other complex heavy carbon oil products.
As smart applications mature, the application of machine learning technologies in photonics has become a prospective research area. Thus, the present study investigated various patents identified and cited by examiner...
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In this paper,we study scene image recognition with knowledge transfer for drone *** divide navigation scenes into three macro-classes,namely outdoor special scenes(OSSs),the space from indoors to outdoors or from out...
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In this paper,we study scene image recognition with knowledge transfer for drone *** divide navigation scenes into three macro-classes,namely outdoor special scenes(OSSs),the space from indoors to outdoors or from outdoors to indoors transitional scenes(TSs),and ***,there are difficulties in how to recognize the TSs,to this end,we employ deep convolutional neural network(CNN)based on knowledge transfer,techniques for image augmentation,and fine tuning to solve the ***,there is still a novelty detection prob-lem in the classifier,and we use global navigation satellite sys-tems(GNSS)to solve it in the prediction *** results show our method,with a pre-trained model and fine tun-ing,can achieve 91.3196%top-1 accuracy on Scenes21 dataset,paving the way for drones to learn to understand the scenes around them autonomously.
Handedness-selective chiral transport is an intriguing phenomenon that not only holds signifcant importance for fundamental research but also carries application prospects in fields such as optical communications and ...
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Handedness-selective chiral transport is an intriguing phenomenon that not only holds signifcant importance for fundamental research but also carries application prospects in fields such as optical communications and ***,on-chip chiral transport devices are static,unable to modulate the output modes based on the input *** limits both device functionality reconfiguration and information transmission ***,we propose to use the incident polarization diversity to control the Hamiltonian evolution path,achieving polarization-dependent chiral *** mapping the evolution path of TE and TM polarizations onto elaborately engineered double-coupled waveguides,we experimentally demonstrate that different polarizations yield controllable modal *** work combines Multiple-lnput,Multiple-Output,and polarization diversity concepts with chiral transport and challenges the prevailing notion that the modal outputs are fixed to specific modes in chiral transport,thereby opening pathways for the development of on-chip reconfigurable and high-capacity handedness-selective devices.
In this paper, we study autonomous landing scene recognition with knowledge transfer for drones. Considering the difficulties in aerial remote sensing, especially that some scenes are extremely similar, or the same sc...
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In this paper, we study autonomous landing scene recognition with knowledge transfer for drones. Considering the difficulties in aerial remote sensing, especially that some scenes are extremely similar, or the same scene has different representations in different altitudes, we employ a deep convolutional neural network(CNN) based on knowledge transfer and fine-tuning to solve the problem. Then, LandingScenes-7 dataset is established and divided into seven classes. Moreover, there is still a novelty detection problem in the classifier, and we address this by excluding other landing scenes using the approach of thresholding in the prediction stage. We employ the transfer learning method based on ResNeXt-50 backbone with the adaptive momentum(ADAM) optimization algorithm. We also compare ResNet-50 backbone and the momentum stochastic gradient descent(SGD) optimizer. Experiment results show that ResNeXt-50 based on the ADAM optimization algorithm has better performance. With a pre-trained model and fine-tuning, it can achieve 97.845 0% top-1 accuracy on the LandingScenes-7dataset, paving the way for drones to autonomously learn landing scenes.
In this study,ultrafine/nano W-Y_(2)O_(3)composite powders were synthesized by spray drying,roasting and two-step hydrogen reduction using ammonium metatungstate and yttrium nitrate as raw *** mechanism of the influen...
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In this study,ultrafine/nano W-Y_(2)O_(3)composite powders were synthesized by spray drying,roasting and two-step hydrogen reduction using ammonium metatungstate and yttrium nitrate as raw *** mechanism of the influence of Y_(2)O_(3)on the growth of WO_(2.72)and the particle refinement of tungsten powder is *** effect of Y_(2)O_(3)particles on the reduction behavior of tungsten powder was investigated using scanning electron microscopy to study the near surface morphology and X-ray diffraction for phase ID(composition)and crystal structural changes for the reduced powders at each *** results show that the doping of 0.3 wt.%Y_(2)O_(3)can significantly increase the aspect ratio of WO_(2.72)in the first step of hydrogen ***,Y_(2)O_(3)can effectively inhibit the growth of tungsten particles in the hydrogen reduction ***,The Y_(2)O_(3)-doped tungsten powders have finer particles and a narrower particle size distribution range than the undoped *** average particle diameter of 0.3 wt.%Y_(2)O_(3)doping tungsten powder was in the range of 90-120 nm.
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