Highly efficient inorganic phosphors are desirable for lighting-emitting diode light sources,and increasing the doping concentration of activators is a common approach for enhancing the photoluminescence quantum yield...
详细信息
Highly efficient inorganic phosphors are desirable for lighting-emitting diode light sources,and increasing the doping concentration of activators is a common approach for enhancing the photoluminescence quantum yield(PLQY).However,the constraint of concentration quenching poses a great challenge for improving the ***,we propose a fundamental design principle by separating activators and prolonging their distance in Eu^(2+)-activated Rb_(3)Y(PO_(4))_(2)phosphors to inhibit concentration quenching,in which different quenching rates are controlled by the Eu distribution at various crystallographic *** blue-violet-emitting Rb_(3)Y(PO_(4))2:xEu(x=0.1%–15%)phosphors,with the occupation of Rb1,Rb2 and Y sites by Eu^(2+),exhibit rapid luminescence quenching with optimum external PLQY of 10%due to multi-channel energy ***,as the Eu concentration increases above 20%,Eu^(2+)prefer to occupy the Rb1 and Y sites with separated polyhedra and large interionic distances,resulting in green emission with suppressed concentration quenching,achieving an improved external PLQY of 41%.Our study provides a unique design perspective for elevating the efficiency of Eu^(2+)-activated phosphors toward high-performance inorganic luminescent materials for full-spectrum lighting.
Artificial Intelligence of Things (AIoT) systems are widely utilized in various domains such as smart logistics and smart health. In AIoT systems, computational tasks earmarked for offloading by IoT devices often have...
详细信息
Current aqueous battery electrolytes,including conve ntional hydrogel electrolytes,exhibit unsatisfactory water retention *** sustained water loss will lead to subsequent polarization and increased internal resistance...
详细信息
Current aqueous battery electrolytes,including conve ntional hydrogel electrolytes,exhibit unsatisfactory water retention *** sustained water loss will lead to subsequent polarization and increased internal resistance,ultimately resulting in battery ***,a double network(DN) orga no hydrogel electrolyte based on dimethyl sulfoxide(DMSO)/H_(2)O binary solvent was *** directionally reconstructing hydrogen bonds and reducing active H_(2)O molecules,the water retention ability and cathode/anode interfaces were synergistic *** a result,the synthesized DN organohydrogel demonstrates exceptional water retention capabilities,retaining approximately 75% of its original weight even after the exposure to air for 20 *** Zn MnO_(2) battery delivers an outstanding specific capacity of275 mA h g^(-1) at 1 C,impressive rate performance with 85 mA h g^(-1) at 30 C,and excellent cyclic stability(95% retention after 6000 cycles at 5 C).Zn‖Zn symmetric battery can cycle more than 5000 h at 1 mA cm^(-2) and 1 mA h cm^(-2) without short *** study will encourage the further development of functional organohydrogel electrolytes for advanced energy storage devices.
Lithium-metal anodes(LMAs)have been recognized as the ultimate anodes for next-generation batteries with high energy density,but stringent assembly-environment conditions derived from the poor moisture stability drama...
详细信息
Lithium-metal anodes(LMAs)have been recognized as the ultimate anodes for next-generation batteries with high energy density,but stringent assembly-environment conditions derived from the poor moisture stability dramatically hinder the transformation of LMAs from laboratory to ***,an in situ formed cross-linked polymer layer on LMAs is designed and constructed by a facile thiol-acrylate click chemistry reaction between poly(ethylene glycol)diacrylate(PEGDA)and the crosslinker containing multi thiol groups under UV *** to the hydrophobic nature of the layer,the treated LMAs demonstrate remarkable humid stability for more than 3 h in ambient air(70%relative humidity).The coating humid-resistant protective layer also possesses a dual-functional characterization as solid polymer electrolytes by introducing lithium bis(trifluoromethanesulfonyl)imide in the system in *** intimate contact between the polymer layer and LMAs reduces interfacial resistance in the assembled Li/LiFePO_(4)or Li/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)full cell effectively,and endows the cell with an outstanding cycle performance.
The steep temperature gradient near the bottom of the mantle is known to generate a negative correlation between the shear wave velocity(VS)and the depth in most regions of the D00 layer,as detected by seismological *...
详细信息
The steep temperature gradient near the bottom of the mantle is known to generate a negative correlation between the shear wave velocity(VS)and the depth in most regions of the D00 layer,as detected by seismological ***,increasing VSwith depth is observed at the D00 layer beneath Central America,where the Farallon slab sinks,and the origin of this anomaly has not beenwell ***,we calculate the thermoelastic constants and obtain the elastic wave velocities of hydrous phase H with various Al contents and cation configurations,which may act as a water carrier to the D00 *** find its VS to be substantially lower than the post-perovskite-type *** dehydration of Al-enriched phase H and the redistribution of Al from the hydrous component to dry silicates would gradually raise the VS below the top of the D00 *** presence of 3.5 wt%water is sufficient to compensate for the thermal effects to match the seismic anomaly at the bottomof themantle beneath Central *** positive slope of VS versus depth in the D00 layer may fingerprint deep water recycling.
Covalent organic frameworks(COFs)have been well developed in electrocatalytic systems owing to their controllable skeletons,porosities,and ***,the catalytic process in COFs remains underexplored,hindering an in-depth ...
详细信息
Covalent organic frameworks(COFs)have been well developed in electrocatalytic systems owing to their controllable skeletons,porosities,and ***,the catalytic process in COFs remains underexplored,hindering an in-depth understanding of the catalytic *** this work,uniform Pt-N_(1)O_(1)Cl_(4)sites chelated via C-N and C=O bonds along the one-dimensional and open channels of TP-TTA-COF were *** from conventional single-metal sites constructed for the near-free platinum for hydrogen evolution,the as-constructed PtCl-COF showed 2e−oxygen reduction for H_(2)O_(2)*** tracked the dynamic evolution process of atomic Pt sites in which Pt-N_(1)O_(1)Cl_(4)was transformed into Pt-N_(1)O_(1)(OH)_(2)using in situ X-ray *** theoretical calculations revealed that the strong Pt-support interaction in Pt-N_(1)O_(1)(OH)_(2)facilitated*OOH formation and thus led to higher selectivity and activity for the oxygen reduction reaction in the 2e−*** work can expand the applications of COFs through the regulation of their local electronic states for the manipulation of the metal center.
A microdisk resona tor ba sed on monocrysta lline yttrium iron ga rnet is reported. The 100-μm-dia meter microdisk in a 300-nm-thick ga rnet film a llows tight spa tia l confinement to enha nce ma gneto-optica l inte...
详细信息
In the present study,graphite/alumina composites are fabricated via reductive sintering of gel-casted green bodies with structurally controlled cross-linked epoxy polymers for the first *** cross-linking degrees of po...
详细信息
In the present study,graphite/alumina composites are fabricated via reductive sintering of gel-casted green bodies with structurally controlled cross-linked epoxy polymers for the first *** cross-linking degrees of polymers are tuned by the amount ratio of epoxy monomer/polyvinyl alcohol cross-linker utilized in gel-casting *** electrical properties with respect to 5-fold enhanced electrical conductivity and 2-fold higher carrier mobility are successfully achieved in graphite/alumina composite fabricated from cross-linked epoxy polymer,whose phenomenon is attributed to the excellent conductive path in ceramic matrix established by highly uniform network with improved graphitization degree.
Profile requirements of silicon steel strip are extremely high and the thickness difference of cold-rolled products is usually less than 7μm,and the profile quality of hot-rolled strip is the key to ensure the thickn...
详细信息
Profile requirements of silicon steel strip are extremely high and the thickness difference of cold-rolled products is usually less than 7μm,and the profile quality of hot-rolled strip is the key to ensure the thickness difference of cold-rolled *** order to produce the silicon steel strip with high-precision shape,the concept of quasi-rectangular rolling during hot continuous rolling was put forward;the equipment configuration and technical method of approximate rectangular section control were *** the roughing multi-target load distribution technology and the roll configuration technology for uniform wear of a 4-high rolling mill,the strip crown of transfer bar was reduced and the profile control stability was *** variable contact back-up roll technology on all stands in the finishing rolling process,equipped with symmetry variable taper work roll and long-stroke intelligent shifting strategy in the downstream stands,and using side rolling lubrication technology can make the roll wear more uniform,reduce the edge drop of silicon steel strip,improve the profile quality,and make the strip section of finishing exit"quasi-rectangular".In addition,induction furnace and side heater were also equipped to guarantee the temperature uniformity of the strip,so as to improve the stability of profile *** whole control technology is based on the 1580-mm hot continuous rolling production line,designed,and developed according to the characteristics of equipment and products,and has been successfully applied,which can obtain the approximate rectangular strip section satisfying the flatness quality,and improve the strip section precision of silicon steel and other products.
暂无评论