While reliance on renewable energy resources has become a reality, there is still a need to deploy greener and more sustainable methods in order to achieve sustainable development goals. Indeed, green hydrogen is curr...
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While reliance on renewable energy resources has become a reality, there is still a need to deploy greener and more sustainable methods in order to achieve sustainable development goals. Indeed, green hydrogen is currently believed to be a reliable solution for global warming and the pollution challenges arising from fossil fuels, making it the resilient fuel of the future. However, the sustainability of green hydrogen technologies is yet to be achieved. In this context, generation of green hydrogen with the aid of deep eutectic solvents(DESs) as green mixtures has been demonstrated as a promising research area. This systematic review article covers green hydrogen generation through water splitting and biomass fermentation when DESs are utilized within the generation process. It also discusses the incorporation of DESs in fuel cell technologies. DESs can play a variety of roles such as solvent, electrolyte, or precursor;colloidal suspension and reaction medium;galvanic replacement, shape-controlling, decoration, or extractive agent;finally oxidant. These roles are relevant to several methods of green hydrogen generation, including electrocatalysis, photocatalysis, and fermentation. As such, it is of utmost importance to screen potential DES formulations and determine how they can function in and contribute throughout the green hydrogen mobility stages. The realization of super green hydrogen generation stands out as a pivotal milestone in our journey towards achieving a more sustainable form of development;DESs have great potential in making this milestone achievable. Overall, incorporating DESs in hydrogen generation constitutes a promising research area and offers potential scalability for green hydrogen production, storage,transport, and utilization.
Novel advanced nanocomposites formed by associating graphene oxide(GO)nanosheets with other nanomaterials such as titanium dioxide nanoparticles,cellulose nanofibers,cellulose nanocrystals,and carbon nanotubes were in...
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Novel advanced nanocomposites formed by associating graphene oxide(GO)nanosheets with other nanomaterials such as titanium dioxide nanoparticles,cellulose nanofibers,cellulose nanocrystals,and carbon nanotubes were incorporated in nanofiltration(NF)and reverse osmosis(RO)membranes for wastewater treatment and ***-based nanocomposite has promising potential in membrane technology due to its high hydrophilicity,absorption capacity,good dispersibility in water and organic solvents,anti-biofouling properties,and negative ***,additional properties can be obtained depending on the nanohybrid *** review paper highlights the recent breakthrough in membranes functionalized with GO-based nanohybrids,focusing on membrane performance in terms of permeability,selectivity,and antifouling *** GO-based nanohybrids have made significant progress in membrane technology,improvements are still needed,especially regarding trade-off ***,the studies presented here are limited to laboratory scale,which leads to suggestions for new studies evaluating the possibility of commercial application and the potential environmental impact caused by nanocomposites.
Bubble point oil formation volume factor (Bob) and solution gas–oil ratio (Rs) are two crucial PVT parameters used for modeling and volumetric calculations in petroleum industry. They are usually determined in labora...
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Green enhanced oil recovery (GEOR) has emerged as an eco-friendly alternative to conventional oil recovery techniques, offering a more sustainable way to increase oil extraction while minimizing environmental harm. Th...
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Downhole drilling dynamic data has proven to be valuable operational information for vibration mitigation and drilling optimization. Yet, the downhole dynamic behavior of the BHA is often misinterpreted. Most downscal...
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ISBN:
(纸本)9781959025108
Downhole drilling dynamic data has proven to be valuable operational information for vibration mitigation and drilling optimization. Yet, the downhole dynamic behavior of the BHA is often misinterpreted. Most downscaled experimental investigations neglect the changes in dynamic field conditions due to fluid flow. The objective of this work is to establish a visual understanding of downhole vibration data analysis in the presence of fully circulated fluid flow and to investigate the effect of flow rate on the BHA lateral trajectory, using a scaled laboratory BHA. A mechanically downscaled test assembly adhering to the geometric and material property relations of a field-size BHA section was designed and manufactured to investigate the nature of lateral vibration under field-like fluid flow conditions. Axial excitation and rotation were induced respectively using an electromagnetic shaker and an electrical motor. Fluid was pumped through the BHA using an electric pump and an in-house designed swivel. The BHA trajectory was mapped using inductive displacement sensors mounted outside the transparent wellbore structure for direct visual correlation between the BHA movement and the vibration data. Real-time induced bit vibration was observed and recorded using a high-frequency tri-axial accelerometer. The results from this experiment provide precise and insightful visual information for BHA trajectory correlation with the acceleration data acquired under field-like fluid flow conditions. The BHA vibration behavior of high-frequency accelerations (shock and vibration), critical lateral vibration phenomena such as whirling, and shift in dominant vibration frequencies were characterized based on both the nature of dynamic forces at the bit and fluid flow rates. Instead of a general observation of the vibration-damping effect in the presence of circulating fluid, the experiment also presents correlations between vibration characteristic changes at different frequencies for di
Carbon dioxide (CO2) storage serves as a greenhouse gas mitigation strategy employed by numerous nations. This study aims to explore the feasibility of CO2 storage in the Rio del Rey Basin (RDR), Gulf of Guinea region...
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The treatment of heavy metals in water is of high importance worldwide,and different treatment types have been *** use of plant material is becoming more and more important,and oilseed crops biomass have been investig...
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The treatment of heavy metals in water is of high importance worldwide,and different treatment types have been *** use of plant material is becoming more and more important,and oilseed crops biomass have been investigated in terms of phytoremediation and biosorption *** article is a review of the literature reporting the applications in 10 different plants and evaluating the removal efficiencies for 12 metals,including the findings of 81 *** olifera and Helianthus annuus are the most studied plants,whereas Cu(21.9%),Cd(18.5%),and Pb(19.9%)are the most studied *** a result,it was found that more than 90%of Pb,Cu,Cd,Fe,Zn,Ni,Cr,Sr and Mn showed removals in their *** the same time,the variables most related to the efficiency of metal removal are pH,temperature,and contact *** article includes a review of the biosorption isotherms used in the different studies.
The phenomenon of oxygen adsorption induced surface restructuring is widespread across various metal-oxygen systems, yet its impact on initiating bulk oxide formation remains largely unexplored. Through in situ atomic...
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The phenomenon of oxygen adsorption induced surface restructuring is widespread across various metal-oxygen systems, yet its impact on initiating bulk oxide formation remains largely unexplored. Through in situ atomic-resolution electron microscopy observations of surface oxidation of Cu(110) and Cu85Au15(110), we unveil intermittent oxide-film growth modulated by oxygen-induced surface restructuring. This modulation is evidenced by repeated pinning of the Cu2O growth front at isolated Cu columns of the c(6×2)-O reconstruction, owing to required long-range diffusion of Cu and O atoms to the Cu2O growth front. We reveal that Cu vacancies, generated at the Cu2O growth front, are injected into the Cu2O/Cu interface, inducing hill and valley undulation of the Cu2O film. In contrast, atomic vacancies produced during the Cu85Au15(110) oxidation preferentially migrate into interfaces between Au-rich and Au-poor regions in the bulk, resulting in a flat and adherent Cu2O film. These findings demonstrate the critical role of oxygen-induced surface restructuring in modulating oxide film growth kinetics and the manipulability of the fate of injected vacancies by alloying, thereby offering insights applicable to a broader range of metal-oxygen systems for fine-tuning oxidation kinetics and enhancing oxide/metal interfacial adhesion.
Transition metal phosphides(TMPs)have been regarded as alternative hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)catalysts owing to their comparable activity to those of noble metal-based *** have ...
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Transition metal phosphides(TMPs)have been regarded as alternative hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)catalysts owing to their comparable activity to those of noble metal-based *** have been produced in various morphologies,including hollow and porous nanostructures,which are features deemed desirable for electrocatalytic *** synthesis routes are often responsible for such *** paper reviews the latest advances and existing challenges in the synthesis of TMP-based OER and HER catalysts through templated methods.A comprehensive review of the structure-property-performance of TMP-based HER and OER catalysts prepared using different templates is *** discussion proceeds according to application,first by HER and further divided among the types of templates used-from hard templates,sacrificial templates,and soft templates to the emerging dynamic hydrogen bubble *** catalysts are then reviewed and grouped according to their ***,prospective research directions for the synthesis of hollow and porous TMP-based catalysts,such as improvements on both activity and stability of TMPs,design of environmentally benign templates and processes,and analysis of the reaction mechanism through advanced material characterization techniques and theoretical calculations,are suggested.
Confronting the severe health threats and environmental impacts of Cr(Ⅵ) in aquatic environments demands innovative and effective remediation approaches. In this study, Graphene oxide(GO)-decorated poly(dimethyl amin...
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Confronting the severe health threats and environmental impacts of Cr(Ⅵ) in aquatic environments demands innovative and effective remediation approaches. In this study, Graphene oxide(GO)-decorated poly(dimethyl amino ethyl methacrylate)(PDMAEMA) brush nanocomposites(GOP1, GOP2, GOP3, and GOP4) were fabricated using atom transfer radical polymerization(ATRP) by the “graft from” *** resulting nanocomposites were utilized for removing Cr(Ⅵ) with good adsorption performance due to the electrostatic interaction of protonated nitrogen groups in the brush chains with negatively charged particles in the solution. The kinetic model of pseudo-second-order best represented the contaminants' adsorption characteristics. The Weber-Morris model further indicated that surface adsorption and intraparticle diffusion mechanisms primarily controlled the adsorption procedure. Additionally, the Langmuir and Temkin isotherm models were found to most accurately represent the adsorption characteristics of the pollutants on the nanocomposites, and GOP4 can achieve the maximum adsorption capacity of 164.4 mg·g^(-1). The adsorbents' capacity maintains above 85% after five cycles of adsorption-desorption. The nanocomposites in this study demonstrate promising potential for eliminating Cr(Ⅵ) from aqueous solutions.
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