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Environmentally friendly tailor-made oleo-dispersions of electrospun cellulose acetate propionate nanostructures in castor oil for lubricant applications

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Nano Materials Science 2025年第1期7卷 90-104页

作者： M.A.Martín-Alfonso J.F.Rubio-Valle J.P.Hinestroza J.E.Martín-Alfonso J.M.Franco Chemical Product and Process Technology Research Center(Pro2TecS) Department of Chemical Engineering and Materials ScienceETSIUniversity of Huelva21071HuelvaSpain Department of Fiber Science and Apparel Design Cornell UniversityIthacaNY14853USA

The aim of this work is to find an alternative lubricating grease formulation that can be produced from renewable and biodegradable sources with minimal risks to human health and the *** used a castor oil and electrospun cellulose acetate propionate(CAp)as raw *** hypothesized that the acetyl and propionyl groups could provide an adequate chemical compatibility with the castor oil and that the electrospun nanostructures could enable improved physical stability by creating a variety of morphologies allowing the tailoring of the rheological and tribological properties of the resulting *** experimental results show that the use of electrospun CAp nanostructures can indeed yield physically stable formulations,even when used at low concentrations(3 wt%).The resulting dispersions went through structural transitions due to changes in the thickener morphologies and/or concentration,as shown by oscillatory rheology,oil holding capacity,tackiness,and lubrication performance in metal–metal *** found that the formulations,containing smooth or porous CAp nanofibers,at 5 wt%as a thickener,possess suitable rheological and tribological properties with a performance comparable to that of traditional lithium lubricating greases.

关键词： Cleaner products Green lubricants Nanofibers Rheology Tribology

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Identifying the dynamic behaviors in complete reconstruction of Co-based complex precatalysts during electrocatalytic oxygen evolution

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Journal of Energy Chemistry 2025年第1期100卷 226-233页

作者： Jingfang Zhang Danyang Wu Linke Cai Youluan Lu Fanpeng Cheng Lijuan Shi Qun Yi Yao Liu Yi Huang Key Laboratory of Green Chemical Engineering Process of Ministry of Education Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationHubei Key Laboratory of Novel Reactor and Green Chemical TechnologySchool of Chemical Engineering&PharmacyWuhan Institute of TechnologyWuhan 430205HubeiChina Key Laboratory of Pesticide&Chemical Biology of Ministry of Education Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction of Ministry of EducationCollege of ChemistryCentral China Normal UniversityWuhan 430079HubeiChina College of Materials Science and Engineering Fuzhou UniversityFuzhou 350108FujianChina

Transition metal-based nanomaterials have emerged as promising electrocatalysts for oxygen evolution reaction(OER).Considerable research efforts have shown that self-reconstruction occurs on these nanomaterials under operating conditions of OER ***,most of them undergo incomplete reconstruction with limited thickness of reconstruction layer,leading to low component utilization and arduous exploration of real catalytic ***,we identify the dynamic behaviors in complete reconstruction of Co-based complexes during *** hollow phytic acid(PA)cross-linked CoFe-based complex nanoboxes with porous nanowalls are designed because of their good electrolyte penetration and mass transport ability,in favor of the fast and complete reconstruction.A series of experiment characterizations demonstrate that the reconstruction process includes the fast substitution of PA by OH-to form Co(Fe)(OH)xand subsequent potential-driven oxidation to Co(Fe)*** obtained CoFeOOH delivers a low overpotential of 290 mV at a current density of 10 mA cm^(-2)and a long-term *** experiment results together with theory calculations reveal that the Fe incorporation can result in the electron rearrangement of reconstructed CoFeOOH and optimization of their electronic structure,accounting for the enhanced OER *** work provides new insights into complete reconstruction of metal-based complexes during OER and offers guidelines for rational design of high-performance electrocatalysts.

关键词： Complete reconstruction Co-based complex Precatalysts Oxygen evolution reaction

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High concentration of Ti^(3+)in C-TiO_(x)nanosheets boosting efficient photodegradation

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Science China(Technological Sciences) 2025年第3期68卷 156-166页

作者： Chongbei WU Xuan LI Haibin WANG Jiaxin TANG Shuai WEI Yuanyuan WU Aobing WANG Jizhou JIANG Hebei Key Laboratory of Man-machine Environmental Thermal Control Technology and Equipment Hebei Vocational University of Technology and EngineeringXingtai054000China School of Materials Science and Engineering Key Laboratory of Green Chemical Engineering Process of Ministry of EducationEngineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationWuhan Institute of TechnologyWuhan430205China

Semiconductor photocatalysis holds significant promise for addressing dye-pollution in ***,the efficiency of photocatalytic water purification is constrained by the weak light absorption capacity and low active site distribution of *** a bottom-up approach,carbon-doped TiO_(x)(C-TiO_(x))nanosheets with high concentrations of Ti^(3+)active sites were fabricated by etching the Al element in Ti_(3)Ai C_(2)with H_(2)O_(2).Experimental evidence demonstrates that the optimal C-TiO_(x)nanosheets exhibit high activity for the photocatalytic degradation of methylene blue,achieving a degradation rate of 100%within 50 *** introduction of carbon into the C-TiO_(x)nanosheets induces a red shift in the absorption edge,boosting the migration of photo-generated charge ***,there is a significant correlation between the concentration of Ti^(3+)active sites and the density of oxygen vacancies in the C-TiO_(x)nanosheets,which synergistically influence the photocatalytic degradation performance of MB dye wastewater.

关键词： bottom-up strategies C-TiO_(x)nanosheets high-concentrations Ti^(3+) photocatalytic degradation

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Screening techniques as a preliminary diagnostic tool for advanced oxidative processes on a laboratory scale

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Frontiers of chemical Science and engineering 2025年第2期19卷 81-91页

作者： Larissa Pinheiro de Souza Flávio Olimpio Sanches-Neto Júlio César de Oliveira Ribeiro Bruno Ramos Valter H.Carvalho-Silva Antonio Carlos Silva Costa Teixeira Research Group in Advanced Oxidation Processes(AdOx) Department of Chemical EngineeringPolytechnic SchoolUniversity of São PauloSão Paulo 05508-010Brazil Modeling of Physical and Chemical Transformations Division Theoretical and Structural Chemistry GroupResearch and Postgraduate CenterGoiás State UniversityAnápolis 75132-903Brazil Federal Institute of Education Science and Technology of GoiásValparaíso de Goiás 72876-601Brazil Department of Chemical Engineering FEI UniversitySão Paulo 09850-901Brazil Chemistry Institute Federal University of GoiásGoiânia 74690-900Brazil

This study introduces an innovative screening approach to evaluate advanced oxidation processes (AOPs) as a preliminary diagnostic tool for degrading emerging contaminants (EC). It includes the design, prototyping, and cost-benefit analysis of circular photochemical reactors with flat and spiral internal geometries. Three-dimensional (3D) printing was used for reactor prototyping, providing flexibility and economy, and this stage was assisted by the hydrodynamic analysis of the prototypes based on residence time distribution (RTD) and macromixing models. The research evaluates the degradation of a model contaminant of emerging concern, fluoxetine (FLX) hydrochloride, using the solar/persulfate (PS) process in two water matrices (i.e., ultrapure water and sewage treatment plant effluent) to optimize reactor performance. The study also proposes primary theoretical pathways for fluoxetine degradation involving hydroxyl and sulfate radicals, as well as predicting the toxicity of the parent compound and its primary metabolites using quantitative structure-activity relationship (QSAR) models. The spiral reactor exhibits improved hydrodynamic behavior, closely resembling continuous stirred and plug flow reactors in series. Despite a slightly lower specific degradation rate in real wastewater, the solar/PS process remains effective for both matrices. By-products generated via the sulfate radical pathway are expected to be less toxic than those formed by hydroxyl radicals (HO·) attack.

关键词： emerging contaminants advanced oxidation process three-dimensional printed reactor quantum chemical calculations toxicity

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Green innovation unleashed:Harnessing tungsten-based nanomaterials for catalyzing solar-driven carbon dioxide conversion

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Chinese chemical Letters 2025年第2期36卷 108-117页

作者： Weidan Meng Yanbo Zhou Yi Zhou State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process East China University of Science and TechnologyShanghai 200237China National Engineering Research Center of Industrial Wastewater Detoxication and Resource Recovery East China University of Science and TechnologyShanghai 200237China Shanghai Engineering Research Center for Multi-media Environmental Catalysis and Resource Utilization East China University of Science and TechnologyShanghai 200237China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China

Carbon dioxide photocatalytic reduction (CO_(2)-PR) is an efficient method for controlling CO_(2)emissions and generating cleaner energy while mitigating global *** oxides (WxOy) have attracted considerable attention for CO_(2)-PR due to their excellent spectral ***,comprehensive reviews are lacking on the use of WxOyfor CO_(2)-***,this review provides a detailed summary of t research progress made with WxOy-based catalysts in CO_(2)-*** also explains the fundamental principles of CO_(2)-PR and evaluates key performance indicators that affect the activity of WxOy-based photocatalysts,including yield,selectivity,stability,and apparent quantum ***,this review explores opportunities for synthesizing high-performance WxOy-based photocatalysts and highlights their potential for the green preparation of C1/C2 products through CO_(2)-*** innovative strategies aim to address the challenges and pressures associated with energy and environmental issues,particularly by enhancing artificial photosynthesis efficiency.

关键词： Carbon dioxide photoreduction Tungsten-based nanocatalyst Mechanism Performance evaluation Selectivity

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Standalone polymer ‘litmus-paper’-like sensor for specific hydrogen detection: Integrating naked-eye and fluorescence techniques

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International Journal of Hydrogen Energy 2025年 137卷 397-405页

作者： Luzzatto, Yonatan Alatawna, Amr Sror, Gal Mendelson, Orit Pevzner, Svetlana Regev, Oren Department of Chemical Engineering Ben-Gurion University of the Negev Beer-Sheva8410500 Israel Department of Chemical Engineering and Blechner Center for Industrial Catalysis and Process Development Ben-Gurion University of the Negev Beer-Sheva8410500 Israel Department of Chemistry Nuclear Research Centre-Negev Beer-Sheva84190 Israel Ilse Katz Institute for Nanoscale Science and Technology Ben-Gurion University of the Negev Beer-Sheva8410500 Israel

Hydrogen is a promising renewable fuel with broad applications, but its flammability and tendency to leak through metals create safety challenges, necessitating reliable, standalone, and affordable sensing systems. Current hydrogen sensors are often costly, suffer from cross-sensitivity to gases, and are typically not standalone. Our sensing approach is based on the hydrogenation of the fluorophore 1,4-bisphenylethnylbenzene (PEB). This approach encompasses two levels of visual sensing: rapid detection via surface color change and quantitative "litmus paper"-like analysis and cross-section observation, which provides a hydrogen exposure history and other parameters such as hydrogen partial pressure and exposure time. The sensor detection limit is 1 mbar ( © 2025 Hydrogen Energy Publications LLC

关键词： Hydrogenolysis

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Oxidative torrefaction of woody biomass: introducing a modified severity factor

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Biomass Conversion and Biorefinery 2025年第6期15卷 9353-9366页

作者： Devaraja, Udya Madhavi Aravindi Dissanayake, Chamini Lakshika Wickramarathna Gunarathne, Duleeka Sandamali Chen, Wei-Hsin Department of Chemical and Process Engineering University of Moratuwa Moratuwa10400 Sri Lanka Department of Aeronautics and Astronautics National Cheng Kung University Tainan701 Taiwan Research Center for Smart Sustainable Circular Economy Tunghai University Taichung407 Taiwan Department of Mechanical Engineering National Chin-Yi University of Technology Taichung411 Taiwan

Torrefaction experiments of Rubberwood and Gliricidia were conducted at 250–300 °C for 30–60 min in a 3–9% oxygen environment to study the oxidative torrefaction behavior. The higher heating value of the torrefied Rubberwood increased from 18.9 to 24.68 MJ/kg and from 19.46 to 23.19 MJ/kg for Gliricidia under the most severe oxidative conditions. Effects of torrefaction conditions on the solid yield, VM removal, C enhancement, HHV enhancement, and energy yield were modeled using response surface methodology, and temperature and oxygen concentration mainly affected the torrefied biomass properties. Rubberwood recorded a significantly greater energy mass co-benefit index (EMCI) than Gliricidia. EMCI of oxidative torrefaction of Gliricidia showed no significant difference from that of inert conditions. A new severity factor was introduced for oxidative torrefaction, and the normalized severity factor showed a linear correlation with torrefied biomass properties, which could facilitate oxidative torrefaction modeling. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.

关键词： Biomass

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Very low Ru loadings boosting performance of Ni-based dual-function materials during the integrated CO_(2)capture and methanation process

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Journal of Energy Chemistry 2025年第3期102卷 309-328页

作者： Anastasios I.Tsiotsias Eleana Harkou Nikolaos D.Charisiou Victor Sebastian Dhanaji R.Naikwadi Bart van der Linden Atul Bansode Dragos Stoian George Manos Achilleas Constantinou Maria A.Goula Laboratory of Alternative Fuels and Environmental Catalysis(LAFEC) Department of Chemical EngineeringUniversity of Western MacedoniaKozani 50100Greece Department of Chemical Engineering Cyprus University of Technology57 Corner of Athinon and AnexartisiasLimassol 3036Cyprus Department of Chemical Engineering and Environmental Technology Universidad de ZaragozaCampus RióEbro-Edificio I+DZaragoza 50018Spain Instituto de Nanociencia y Materiales de Aragón(INMA) Universidad de ZaragozaCSICc/Mariáde Luna 3Zaragoza 50018Spain Networking Research Center on Bioengineering Biomaterials and NanomedicineCIBERBBN28029 MadridSpain Department of Chemical Engineering Delft University of TechnologyVan der Massweg 9Delft 2629 HZthe Netherlands The Swiss-Norwegian Beamlines(SNBL) European Synchrotron Radiation Facility(ESRF)Grenoble 38000France Department of Chemical Engineering University College LondonLondon WCIE7JEUnited Kingdom Centre for Research&Technology Hellas(CERTH) Chemical Process and Energy Resources Institute(CPERI)52 Egialias strMaroussiAthens 15125Greece School of Science and Technology Hellenic Open UniversityParodos Aristotelous 18Patras 26335Greece

Herein,the effect of the Ru:Ni bimetallic composition in dual-function materials(DFMs)for the integrated CO_(2)capture and methanation process(ICCU-Methanation)is systematically evaluated and combined with a thorough material characterization,as well as a mechanistic(in-situ diffuse reflectance infrared fourier-transform spectroscopy(in-situ DRIFTS))and computational(computational fluid dynamics(CFD)modelling)investigation,in order to improve the performance of Ni-based *** bimetallic DFMs are comprised of a main Ni active metallic phase(20 wt%)and are modified with low Ru loadings in the 0.1-1 wt%range(to keep the material cost low),supported on Na_(2)O/Al_(2)O_(3).It is shown that the addition of even a very low Ru loading(0.1-0.2 wt%)can drastically improve the material reducibility,exposing a significantly higher amount of surface-active metallic sites,with Ru being highly dispersed over the support and the Ni phase,while also forming some small Ru *** manifests in a significant enhancement in the CH_(4)yield and the CH_(4)production kinetics during ICCU-Methanation(which mainly proceeds via formate intermediates),with 0.2 wt%Ru addition leading to the best *** bimetallic DFM also shows high stability and a relatively good performance under an oxidizing CO_(2)capture *** formation rate of CH_(4)during hydrogenation is then further validated via CFD modelling and the developed model is subsequently applied in the prediction of the effect of other parameters,including the inlet H_(2)concentration,inlet flow rate,dual-fu nction material weight,and reactor internal diameter.

关键词： Dual-function materials Integrated CO_(2)capture and methanation Bimetallic materials Nickel-ruthenium Reducibility in-situ DRIFTS CFD modelling

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Time-Varying Formation Tracking control of Heterogeneous Multi-Agent Systems With Intermittent Communications and Directed Switching Networks

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IEEE/CAA Journal of Automatica Sinica 2025年第1期12卷 294-296页

作者： Yuhan Wang Zhuping Wang Hao Zhang Huaicheng Yan the Shanghai Research Institute for Intelligent Autonomous Systems Tongji University the National Key Laboratory of Autonomous Intelligent Unmanned Systems the Frontiers Science Center for Intelligent Autonomous System of Ministry of Education the College of Electronic and Information Engineering the Department of Control Science and Engineering Tongji University the Key Laboratory of Advanced Control and Optimization for Chemical Processes of Ministry of Education the School of Information Science and Engineering East China University of Science and Technology

Dear Editor,This letter is concerned with the problem of time-varying formation tracking for heterogeneous multi-agent systems(MASs) under directed switching networks. For this purpose, our first step is to present so... 详细信息

关键词： Switches Topology Observers Formation control Event detection Switched systems Multi-agent systems control theory Autonomous systems Stability

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Carbon nanofiber catalysts containing high-entropy metal phosphides with low-content Ru for highly efficient hydrogen evolution reaction

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Rare Metals 2025年第1期44卷 324-335页

作者： Peng Wang Jie Zheng Xue-Hao Li Wen-Bo Cui Jin-Hua Liu Yong Wan Jun Zhang Yusuke Yamauchi Zhong-Li Wang Mang Niu Yun-Ze Long Shandong Key Laboratory of Medical and Health Textile Materials College of PhysicsQingdao UniversityQingdao 266071China Industrial Research Institute of Nonwovens and Technical Textiles Shandong Center for Engineered Nonwovens(SCEN)College of Textiles ClothingQingdao UniversityQingdao 266071China State Key Laboratory of Bio-Fibers and Eco-textiles Institute of Biochemical EngineeringCollege of Materials Science and EngineeringQingdao UniversityQingdao 266071China School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnology(AIBN) The University of QueenslandBrisbaneQLD 4072Australia Department of Chemical and Biomolecular Engineering Yonsei UniversitySeoul 03722Republic of Korea Department of Materials Process Engineering Graduate School of EngineeringNagoya UniversityNagoya 464-8603Japan Tianjin Key Laboratory of Applied Catalysis Science and Technology School of Chemical Engineering and TechnologyTianjin UniversityTianjin300072China

High-entropy metal phosphide(HEMP)has considerable potential as an electrocatalyst owing to its beneficial properties,including high-entropy alloy synergy as well as the controllable structure and high conductivity of ***,electrospinning and in situ phosphating were employed to prepare three-dimensional(3D)networks of self-supporting HEMP nanofibers with varying degrees of phosphate *** characterizations via X-ray diffraction and X-ray photoelectron spectroscopy,as well as density functional theory calculations,demonstrate that the introduction of phosphorus(P)atoms to HEMP carbon nanofibers mediates their electronic structure,leads to lattice expansion,which in turn enhances their catalytic performance in the hydrogen evolution reaction(HER).Moreover,the formation of metal-P bonds weakens metal-metal interaction and decreases the free energy of hydrogen adsorption,contributing to the exceptional activity observed in the HEMP *** measurements demonstrate that the HEMP-0.75 catalyst with an ultralow loading of 1.22 wt%ruthenium(Ru)exhibits the highest HER catalytic activity and stability in a 1 M KOH electrolyte,achieving a minimal overpotential of 26 mV at a current density of 10 mA·cm^(-2)and Tafel slope of 50.9 mV·dec^(-1).

关键词： High-entropy metal phosphide Electrospinning Hydrogen evolution reaction Self-supporting carbon nanofibers

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