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Carbon nanofiber catalysts containing high-entropy metal phosphides with low-content Ru for highly efficient hydrogen evolution reaction

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Rare Metals 2025年第1期44卷 324-335页

作者： Peng Wang Jie Zheng Xue-Hao Li Wen-Bo Cui Jin-Hua Liu Yong Wan Jun Zhang Yusuke Yamauchi Zhong-Li Wang Mang Niu Yun-Ze Long Shandong Key Laboratory of Medical and Health Textile Materials College of PhysicsQingdao UniversityQingdao 266071China Industrial Research Institute of Nonwovens and Technical Textiles Shandong Center for Engineered Nonwovens(SCEN)College of Textiles ClothingQingdao UniversityQingdao 266071China State Key Laboratory of Bio-Fibers and Eco-textiles Institute of Biochemical EngineeringCollege of Materials Science and EngineeringQingdao UniversityQingdao 266071China School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnology(AIBN) The University of QueenslandBrisbaneQLD 4072Australia Department of Chemical and Biomolecular Engineering Yonsei UniversitySeoul 03722Republic of Korea Department of Materials Process Engineering Graduate School of EngineeringNagoya UniversityNagoya 464-8603Japan Tianjin Key Laboratory of Applied Catalysis Science and Technology School of Chemical Engineering and TechnologyTianjin UniversityTianjin300072China

High-entropy metal phosphide(HEMP)has considerable potential as an electrocatalyst owing to its beneficial properties,including high-entropy alloy synergy as well as the controllable structure and high conductivity of ***,electrospinning and in situ phosphating were employed to prepare three-dimensional(3D)networks of self-supporting HEMP nanofibers with varying degrees of phosphate *** characterizations via X-ray diffraction and X-ray photoelectron spectroscopy,as well as density functional theory calculations,demonstrate that the introduction of phosphorus(P)atoms to HEMP carbon nanofibers mediates their electronic structure,leads to lattice expansion,which in turn enhances their catalytic performance in the hydrogen evolution reaction(HER).Moreover,the formation of metal-P bonds weakens metal-metal interaction and decreases the free energy of hydrogen adsorption,contributing to the exceptional activity observed in the HEMP *** measurements demonstrate that the HEMP-0.75 catalyst with an ultralow loading of 1.22 wt%ruthenium(Ru)exhibits the highest HER catalytic activity and stability in a 1 M KOH electrolyte,achieving a minimal overpotential of 26 mV at a current density of 10 mA·cm^(-2)and Tafel slope of 50.9 mV·dec^(-1).

关键词： High-entropy metal phosphide Electrospinning Hydrogen evolution reaction Self-supporting carbon nanofibers

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Enhancing photocatalytic CO_(2)reduction with TiO_(2)-based materials:Strategies,mechanisms,challenges,and perspectives

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Environmental Science and Ecotechnology 2024年第4期20卷 18-33页

作者： Zhimin Yuan Xianglin Zhu Xianqiang Gao Changhua An Zheng Wang Cheng Zuo Dionysios D.Dionysiou Hong He Zaiyong Jiang School of Chemistry&Chemical Engineering and Environmental Engineering Weifang UniversityWeifang261061PR China State Key Joint Laboratory of Environment Simulation and Pollution Control Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing100085PR China Institute for Energy Research School of Chemistry and Chemical EngineeringJiangsu UniversityZhenjiang212013PR China Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion School of Chemistry and Chemical EngineeringTianjin University of TechnologyTianjin300384PR China Environmental Engineering and Science Program Department of Chemical and Environmental Engineering(DChEE)University of CincinnatiCincinnatiOH45221-0012USA College of Forestry Shandong Agricultural UniversityTaian271018PR China

The concentration of atmospheric CO_(2)has exceeded 400 ppm,surpassing its natural variability and raising concerns about uncontrollable shifts in the carbon cycle,leading to significant climate and environmental impacts.A promising method to balance carbon levels and mitigate atmospheric CO_(2)rise is through photocatalytic CO_(2)*** dioxide(TiO_(2)),renowned for its affordability,stability,availability,and eco-friendliness,stands out as an exemplary catalyst in photocatalytic CO_(2)*** strategies have been proposed to modify TiO_(2)for photocatalytic CO_(2)reduction and improve catalytic activity and product ***,few studies have systematically summarized these strategies and analyzed their advantages,disadvantages,and current ***,we comprehensively review recent advancements in TiO_(2)engineering,focusing on crystal engineering,interface design,and reactive site construction to enhance photocatalytic efficiency and product *** discuss how modifications in TiO_(2)'s optical characteristics,carrier migration,and active site design have led to varied and selective CO_(2)reduction *** enhancements are thoroughly analyzed through experimental data and theoretical ***,we identify current challenges and suggest future research directions,emphasizing the role of TiO_(2)-based materials in understanding photocatalytic CO_(2)reduction mechanisms and in designing effective *** review is expected to contribute to the global pursuit of carbon neutrality by providing foundational insights into the mechanisms of photocatalytic CO_(2)reduction with TiO_(2)-based materials and guiding the development of efficient photocatalysts.

关键词： summarized dioxide neutral

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Surface hydrophobic modification of MXene to promote the electrochemical conversion of N_(2) to NH_(3)

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Journal of Energy Chemistry 2023年第12期87卷 439-449,I0011页

作者： Xu Wang Rui Zhang Chaoqun Ma Wei Yan Yanjiao Wei Jian Tian Min Ma Qing Li Minhua Shao School of Materials Science and Engineering Shandong University of Science and TechnologyQingdao 266590ShandongChina Department of Chemical and Biological Engineering The Hong Kong University of Science and TechnologyClear Water BayKowloonHong Kong 999077China Energy Institute and Chinese National Engineering Research Center for Control&Treatment of Heavy Metal PollutionThe Hong Kong University of Science and TechnologyClear Water BayKowloonHong Kong 999077China College of Chemistry and Chemical Engineering Xiamen UniversityXiamen 361005FujianChina College of Chemistry and Chemical Engineering Dezhou UniversityDezhou 253023ShandongChina

Hydrophobic treatment of the catalyst surfaces can suppress the competitive hydrogen evolution reaction(HER) during the nitrogen reduction reaction(NRR).In this work,the surface of Ti_(3)C_(2)Ti_(x) MXene is modified by cetyltrimethylammonium bromide(CTAB) and trimethoxy(3,3,4,4,5,5,6,6,7,7,8,8,8-trideca fluorooctyl) silane(FOTS) to increase the hydrophobicity of *** ammonia(NH_(3)) production rate and faradaic efficiency(FE) are improved from 37.62 to 54.01 μg h^(-1)mg_(cat)^(-1).and 5.5% to 18.1% at-0.7 V ***,respectively after surface modification.^(15)N isotopic labeling experiment confirms that nitrogen in produced ammonia originates from N_(2) in the *** excellent NRR activity of surface hydrophobic MXenes is mainly due to surfactant molecules,which inhibit the entry of water molecules and the competitive HER,which have been verified by in situ FT-IR,DFT and molecular dynamics *** strategy provides an ingenious method to design more active NRR electrocatalysts.

关键词： Electrocatalysis Nitrogen reduction reaction Surface hydrophobic modification MXene Ti_(3)C_(2)Ti_(x)

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Promoting catalysis activity with optimizable self-generated Co-Fe alloy nanoparticles for efficient CO_(2)electrolysis performance upgrade

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Nano research 2023年第8期16卷 10992-10999页

作者： Kun Zhang Dong Zhang Yao Wang Yihang Li Cong Ren Mingyue Ding Tong Liu Key Laboratory of Hydraulic Machinery Transients(Wuhan University) Ministry of EducationSchool of Power and Mechanical EngineeringThe Institute of Technological SciencesWuhan UniversityWuhan 430072China Key Laboratory of Green Chemical Process of Ministry of Education Hubei Key Laboratory of Novel Reactor and Green Chemical TechnologySchool of Chemical Engineering and PharmacyWuhan Institute of TechnologyWuhan 430205China Interdisciplinary Research Center of Smart Sensors Academy of Advanced Interdisciplinary ResearchXidian UniversityXi’an 710071China Department of Applied Chemistry School of Advanced Materials and NanotechnologyXidian UniversityXi’an 710071China

Stable and flexible metal nanoparticles(NPs)with regeneration ability are critical for long-term operation of solid oxide electrolysis cells(SOECs).Herein,a novel perovskite electrode with stoichiometric Pr_(0.4)Sr_(0.6)Co_(0.125)Fe_(0.75)Mo_(0.125)O_(3)−δ(PSFCM)is synthesized and studied,which undergoes multiple redox cycles to validate its structural stability and NPs *** Co-Fe alloy has exsolved from the parent bulk under reducing atmosphere,and is capable of reincorporation into the parent oxide after re-oxidation *** the redox process,we successfully manipulate the size and population density of the exsolved NPs,and find that the average particle size significantly reduces but the population density increases *** electrode polarization resistance of the symmetric cell remains stable for 450 h,and even activates after the redox cycling,which may be attributed to the higher quantity and larger specific surface area of the regenerated Co-Fe alloy ***,the electrochemical performance towards carbon dioxide reduction reaction(CO_(2)RR)is evaluated,and the CO_(2)electrolyzer consisting of CoFe@PSCFM-Ce_(0.8)Sm_(0.2)O_(1.9)(SDC)dual-phase electrode exhibits an excellent current density of 1.42 A·cm^(−2)at 1.6 V,which reaches 1.7 times higher than 0.83 A·cm^(−2)for the pristine PSCFM ***,with this flexible and reversible high-performance SOEC cathode material,new options and perspectives are provided for the efficient and durable CO_(2)electrolysis.

关键词： redox stability in situ exsolution regeneration carbon dioxide reduction reaction perovskite

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Influence of pH value and Zn/Ce cations ratio on the microstructures and corrosion resistance of LDH coating on AZ31

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Corrosion Communications 2022年第1期5卷 73-86页

作者： Vahdat Zahedi Asl Jingmao Zhao Yahya Palizdar Muhammad Junaid Anjum College of Material Science and Engineering Beijing University of Chemical Technology Beijing Key Laboratory of Electrochemical Process and Technology for Materials Nanotechnology and Advanced Materials Department Materials and Energy Research Center

To prepare a compact and anti-corrosion Zn-Ce LDH coating on AZ31 magnesium alloy,the various molar ratios of Zn/Ce cations,and different pH values were employed during preparation of the precursor *** composition,morphology,structure,and wettability of the deposited coatings were comprehensively characterized via scanning electronic microscopy （SEM）,energy-dispersive X-ray spectroscopy （EDS）,X-ray diffraction （XRD）,X-ray photoelectron spectroscopy （XPS）,Fourier transform infrared spectroscopy （FT-IR） and the static sessile drop ***,potentiodynamic polarization （PDP） and electrochemical impedance spectroscopy （EIS）measurements were conducted to evaluate the corrosion resistance of the coatings ***,the selfhealing ability of the coating was investigated by monitoring the scratched areas of the samples immersed in 3.5%NaCl solution for a long time up to 21 *** results reveal that the coated Mg alloy shows the lowest corrosion current density (icorr=1.29×10-8A/cm2) when the Zn/Ce ratio is 2,and the pH value of the precursor solution is approximately 11.

关键词： LDH coating Magnesium alloy Corrosion protection Self-healing Cerium XPS

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Electrocatalytic oxidation of gaseous toluene in an all-solid cell using a foam Ti/Sb-SnO2/β-PbO_(2) anode

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Journal of Environmental Sciences 2023年第12期134卷 77-85页

作者： Zhikun Liu Weiming Qian Min Chen Wenshuo Zhou Boying Song Bo Zhang Xiaolei Bao Qiong Tang Yongchun Liu Changbin Zhang Aerosol and Haze Laboratory Advanced Innovation Center for Soft Matter Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029China State Key Joint Laboratory of Environment Simulation and Pollution Control Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China Hebei Technological Innovation Center for Volatile Organic Compounds Detection and Treatment in Chemical Industry Department of quality inspection and managementHebei Chemical and Pharmaceutical CollegeShijiazhuang 050026China College of Energy materials and Chemicals Leshan Normal UniversityLeshan 614000China

Mineralization of benzene,toluene,and xylene (BTX) with high efficiency at room temperature is still a challenge for the purification of indoor *** this work,a foam Ti/Sb-Sn O2/β-Pb O_(2)anode catalyst was prepared for electrocatalytically oxidizing gaseous toluene in an all-solid cell at ambient *** complex Ti/Sb-Sn O_(2)/β-Pb O_(2)anode,which was prepared by sequentially deposing Sb-Sn O_(2)and β-Pb O_(2)on a foam Ti substrate,shows high electrocatalytic oxidation efficiency of toluene (80%) at 7 hr of reaction and high CO_(2)selectivity (94.9%) under an optimized condition,i.e.,a cell voltage of 2.0 V,relative humidity of60%and a flow rate of 100 m L/*** better catalytic performance can be ascribed to the high production rate of·OH radicals from discharging adsorbed water and the inhibition of oxygen evolution on the surface of foam Ti/Sb-Sn O_(2)/β-Pb O_(2)anode when compared with the foam Ti/Sb-Sn O_(2)*** results demonstrate that prepared complex electrodes can be potentially used for electrocatalytic removal of gaseous toluene at room temperature with a good performance.

关键词： Gaseous toluene Electrocatalytic oxidation Lead dioxide Indoor air purification Solid cell

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Highly active and durable core-shell electrocatalysts for proton exchange membrane fuel cells

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Nano research 2024年第10期17卷 8772-8784页

作者： Hsiwen Wu Fei Xiao Jing Wang Meng Gu Minhua Shao Department of Chemical and Biological Engineering The Hong Kong University of Science and TechnologyClear Water BayHong KongChina Department of Materials Science and Engineering Southern University of Science and TechnologyShenzhen 518055China Fok Ying Tung Research Institute The Hong Kong University of Science and TechnologyGuangzhou 511458China Energy Institute and Chinese National Engineering Research Center for Control&Treatment of Heavy Metal Pollution The Hong Kong University of Science and TechnologyClear Water BayHong KongChina

This work presents simple post-treatment methods to selectively and partially remove the Pd core of Pd-Pt core–shell(Pt@Pd/C)*** proton exchange membrane fuel cell with the post-treated Pt@Pd/C cathode(Pt loading:0.10 mg·cm^(-2))delivers an impressive peak power density of 1.2 W·cm^(-2).The partial removal of Pd core endows an ultrahigh oxygen reduction reaction(ORR)mass activity of 0.32 A·g_(PGM)-1 when normalized to the platinum group metal(PGM)mass,or equivalently 0.55 A·mg_(Pt)^(-1) at 0.9 V measured in a fuel *** post-treatment thickens the Pt shells and mitigates the Pd dissolution during potential *** a result,the post-treated core-shell catalyst demonstrates superior durability in ORR mass activity and polarization power density retention than untreated core-shell catalyst and benchmark Pt/***-situ inductively coupled plasmamass spectrometry(ICP-MS)results highlight that the amount of dissolved Pd in post-treated core–shell catalyst is 17-times lower than that of the untreated *** findings highlight the importance of structural tuning of catalysts in enhancing their mass activity and durability.

关键词： core-shell catalyst platinum monolayer proton exchange membrane fuel cell oxygen reduction reaction durability

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Self-healing of active site in Co(OH)_(2)/MXene electrocatalysts for hydrazine oxidation

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Journal of Materials Science & Technology 2024年第36期203卷 108-117页

作者： Kun Xiang Yongjing Wang Zechao Zhuang Jing Zou Neng Li Dingsheng Wang Tianyou Zhai Jizhou Jiang School of Environmental Ecology and Biological Engineering School of Chemistry and Environmental EngineeringKey Laboratory of Green Chemical Engineering Process of Ministry of EducationEngineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationNovel Catalytic Materials of Hubei Engineering Research CenterWuhan Institute of TechnologyWuhan 430205China Department of Chemistry Tsinghua UniversityBeijing 100084China State Key Laboratory of Silicate Materials for Architectures Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Material Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China

The development of efficient hydrazine oxidation reaction(HzOR)catalysts is important for the construc-tion of remarkable energy storage and conversion ***,after a period of electrochemical reaction,the active site of the catalyst will be irreversibly reduced or inactivated,and how to recover the active site is a major ***,we report 2D Co(OH)_(2)/Ti_(3)C_(2)(OH)_(x)MXene composites with rapid re-construction and self-healing behaviors as efficient and stable electrocatalysts during HzOR *** experimental and theoretical results indicate that the introduction of Ti_(3)C_(2)(OH)_(x)MXene can effectively reduce the dehydrogenation barrier of Co(OH)_(2),from 0.584 eV to 0.481 eV to form the real catalytic active center Co(OH)***,Co(OH)O/Ti_(3)C_(2)(OH)_(x)MXene composites with metal-like conductiv-ity not only present spontaneous adsorption capacity of N_(2)H_(4),but also can modulated rate-determining step of dehydrogenation of∗N_(2)H_(4)to∗N_(2)H_(3)(0.54 eV)compared with Co(OH)***,the electrophilic oxygen of Co(OH)O/Ti_(3)C_(2)(OH)_(x)can spontaneously obtain electrons and protons from N_(2)H_(4),achieving the oxidation of N_(2)H_(4)while reducing Co(OH)O to Co(OH)_(2),thus completing the self-healing of the efficient catalyst.

关键词： Hydrazine oxidation Self-healing Reconstruction Co(OH)_(2)/MXene Electrocatalysis

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A Composite Decomposition Method for Large-Scale Global Optimization

IEEE Transactions on Artificial Intelligence

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IEEE Transactions on Artificial Intelligence 2024年第12期5卷 6304-6319页

作者： Tian, Maojiang Chen, Minyang Du, Wei Tang, Yang Jin, Yaochu Yen, Gary G. Southern University of Science and Technology Department of Computer Science and Engineering Shenzhen518055 China East China University of Science and Technology Key Laboratory of Smart Manufacturing in Energy Chemical Process Ministry of Education Shanghai200237 China East China University of Science and Technology Engineering Research Center of Process System Engineering Ministry of Education Shanghai200237 China Westlake University School of Engineering Hangzhou310030 China Oklahoma State University School of Electrical and Computer Engineering StillwaterOK74048 United States

Cooperative coevolution (CC) algorithms, based on the divide-and-conquer strategy, have emerged as the predominant approach to solving large-scale global optimization (LSGO) problems. The efficiency and accuracy of the grouping stage significantly impact the performance of the optimization process. While the general separability grouping (GSG) method has overcome the limitation of previous differential grouping (DG) methods by enabling the decomposition of nonadditively separable functions, it suffers from high computational complexity. To address this challenge, this article proposes a composite separability grouping (CSG) method, seamlessly integrating DG and GSG into a problem decomposition framework to utilize the strengths of both approaches. CSG introduces a step-by-step decomposition framework that accurately decomposes various problem types using fewer computational resources. By sequentially identifying additively, multiplicatively and generally separable variables, CSG progressively groups nonseparable variables by recursively considering the interactions between each nonseparable variable and the formed nonseparable groups. Furthermore, to enhance the efficiency and accuracy of CSG, we introduce two innovative methods: a multiplicatively separable variable detection method and a nonseparable variable grouping method. These two methods are designed to effectively detect multiplicatively separable variables and efficiently group nonseparable variables, respectively. Extensive experimental results demonstrate that CSG achieves more accurate variable grouping with lower computational complexity compared to GSG and state-of-the-art DG-series designs. © 2024 IEEE.

关键词： Computational efficiency

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Reactant enrichment in hollow void of Pt NPs@MnOx nanoreactors for boosting hydrogenation performance

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National Science Review 2023年第10期10卷 114-122页

作者： Yanfu Ma Liwei Wang Wantong Zhao Tianyi Liu Haitao Li Wenhao Luo Qike Jiang Wei Liu Qihua Yang Jun Huang Riguang Zhang Jian Liu G.Q.Max Lu Can Li State Key Laboratory of Catalysis Dalian Institute of Chemical Physics (DICP)Chinese Academy of Sciences Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences State Key Laboratory of Clean and Efficient Coal Utilization Taiyuan University of Technology DICP-Surrey Joint Centre for Future Materials Department of Chemical and Process EngineeringUniversity of Surrey CAS Key Laboratory of Science and Technology on Applied Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences School of Chemistry and Chemical Engineering Inner Mongolia University Division of Energy Research Resources Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academyof Sciences Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces Institute of Physical ChemistryZhejiang Normal University Laboratory for Catalysis Engineering School of Chemical and Biomolecular Engineering Sydney Nano Institute The University of Sydney University of Surrey

In confined mesoscopic spaces,the unraveling of a catalytic mechanism with complex mass transfer and adsorption processes such as reactant enrichment is a great *** this study,a hollow nanoarchitecture of MnOx-encapsulated Pt nanoparticles was designed as a nanoreactor to investigate the reactant enrichment in a mesoscopic hollow *** employing advanced characterization techniques,we found that the reactant-enrichment behavior is derived from directional diffusion of the reactant driven through the local concentration gradient and this increased the amount of *** experimental results with density functional theory calculations,the superior cinnamyl alcohol（COL）selectivity originates from the selective adsorption of cinnamaldehyde（CAL） and the rapid formation and desorption of COL in the *** superb performance of 95% CAL conversion and 95% COL selectivity is obtained at only 0.5 MPa H2and 40 *** findings showcase that a rationally designed nanoreactor co uld boost catalytic performance in chemoselective hydrogenation,which can be of great aid and potential in various application scenarios.

关键词： reactant enrichment nanoreactor effect selective hydrogenation hollow nanostructure mesoporous materials

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