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science China materials 2024年第4期67卷 1292-1300页

作者：王榆惠郑天宇金昱丞孙婷婷丁旭王萧徐清梅李彤轩张少龙姜建壮 Beijing Advanced Innovation Center for Materials Genome Engineering Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline MaterialsDepartment of Chemistry and Chemical EngineeringSchool of Chemistry and Biological EngineeringUniversity of Science and Technology BeijingBeijing 100083China College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518060China

人工光合作用将二氧化碳转化为增值化学品和燃料,在克服全球环境能源危机方面具有巨大潜力.然而,由于CO_(2)的热力学稳定性和动力学滞后性,开发高效的CO_(2)RR光催化剂是一个巨大的挑战.本文在微介孔氮掺杂碳(0.8-Co-ISAS/MMNC-900)上... 详细信息

人工光合作用将二氧化碳转化为增值化学品和燃料,在克服全球环境能源危机方面具有巨大潜力.然而,由于CO_(2)的热力学稳定性和动力学滞后性,开发高效的CO_(2)RR光催化剂是一个巨大的挑战.本文在微介孔氮掺杂碳(0.8-Co-ISAS/MMNC-900)上制备了一种具有高度分散Co单原子位的分级多孔钴单原子光催化剂,该催化剂显著促进了CO_(2)-to-CO的光还原.0.8-Co-ISAS/MMNC-900催化剂的CO生成速率高达7261μmol g^(-1)h^(-1),CO选择性高达90.1%,并且在四次循环测试中表现出良好的稳定性.实验数据和理论结果表明,分层多孔结构可以促进电荷分离引起的外部局部电场的形成,Co隔离的单原子位和微介孔构型协同作用,促进光激发电子积累、CO_(2)吸附活化和*COOH中间体的形成.本研究通过多尺度多孔结构工程,提出了一种合成CO_(2)还原光催化剂的新策略.

关键词：单原子热力学稳定性激发电子光还原多尺度结构人工光合作用多孔结构电荷分离

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Determination of Local Structural and Dynamic Descriptors in Doped Oxides: The Case of Zr-Doped Ceria, a Non-Classical Electrostrictor

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Journal of the American chemical Society 2025年第22期147卷 18583-18593页

作者： Pechersky Savich, Tali Zheng, Kaifeng Shimogawa, Ryuichi Routh, Prahlad K. Varenik, Maxim Ehre, David Lubomirsky, Igor Frenkel, Anatoly I. Department of Molecular Chemistry and Materials Science Weizmann Institute of Science Rehovot 761001 Israel Department of Materials Science and Chemical Engineering Stony Brook University Stony Brook 11794 NY United States Mitsubishi Chemical Corporation Science & Innovation Center 1000 Kamoshida-cho Aobaku Yokohama 227-8502 Japan Division of Chemistry Brookhaven National Laboratory Upton 11973 NY United States

Non-classical electromechanical properties, such as large electrostriction stress coefficient and low dielectric constant in Zr-doped ceria and other doped cerium oxides, discovered in the last several years, are the focus of intense research as they indicate the existence of solids with unusually large anharmonicity of chemical bonds. Theoretical models of electrostriction mechanisms rely on the concept of elastic dipoles that are formed due to the local structural distortions around dopants. The structural, dynamic, and electronic descriptors of the pre-existing (at zero field) dipoles (as in aliovalent-doped ceria) and those dynamically formed under the electric field (as in isovalent-doped ceria) are unknown. Here, the characteristics of the local structure and dynamics of the dopant and host bonding environments were obtained by using the temperature-dependent X-ray absorption fine structure measurements. The candidate set of descriptors was identified in a quasiharmonic approximation for the nearest neighboring bonds between Zr (Ce) and the atoms in the first and second coordination shells. The descriptors included static bond length disorder, the anharmonicity of the effective pair potential, and effective force constants for the probed atomic pairs. The observation of significant Zr-O bond anharmonicity confirms previous first-principles calculations. The structural model, emerging from these simulations, emphasizes significant free volume around Zr in the oxygen cube, explaining both the mechanical anomaly (the decrease in Young’s modulus with Zr concentration) as well as correlating at least one descriptor (static disorder) to the measured electrostriction coefficient. This descriptor-based approach can be extended to studies under applied electric fields or stress in this and other materials. © 2025 American chemical Society.

关键词： Bond length

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Conductive hydrogels with photothermal effects: material design,mechanisms, and multifunctional applications

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science China Chemistry 2025年

作者： Mengchao Wang Ruizhuo Ouyang Yuqin Jiang Zhengang Liu Xun Zhou Yulong Shi Cheng He Liangliang Zhu Bingbing Yue School of Materials and Chemistry & Institute of Bismuth and Rhenium University of Shanghai for Science and Technology Collaborative Innovation Centre of Henan Province for Green Manufacturing of Fine Chemicals Key Laboratory of Green Chemical Media and Reactions Ministry of Education Henan Engineering Research Centre of Chiral Hydroxyl Pharmaceutical Henan Engineering Laboratory of Chemical Pharmaceutical and Biomedical Materials School of Chemistry and Chemical Engineering Henan Normal University State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular Science Fudan University

Conductive hydrogels with near-infrared(NIR) photothermal effects are a promising class of smart materials. They integrate the unique properties of hydrogels—such as flexibility and biocompatibility—with enhanced electrical conductivity and photothermal responsiveness. These materials use NIR light to induce localized heating through photothermal conversion, enabling precise control over physicochemical properties, including conductivity, mechanical strength, and antibacterial activity. However, comprehensive reviews in this field are limited. This article systematically classifies photothermal materials into four categories: conjugated polymers, carbon-based nanomaterials, inorganic nanomaterials, and metal-phenolic networks, and explains their mechanisms. We highlight recent advancements in applications such as smart wound dressings, soft actuators, and responsive sensors, while addressing challenges like optimizing photothermal efficiency, balancing biocompatibility with conductivity, and scaling up production. By providing a comprehensive analysis of material design strategies and applicationspecific innovations, this review aims to guide future research toward next-generation multifunctional hydrogels for advanced biomedical and technological applications.

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Correction: materials laboratories of the future for alloys, amorphous, and composite materials (MRS Bulletin, (2025), 50, 2, (190-207), 10.1557/s43577-024-00846-y)

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MRS Bulletin 2025年 1-2页

作者： Banerjee, Sarbajit Meng, Y. Shirley Minor, Andrew M. Zhang, Minghao Zaluzec, Nestor J. Chan, Maria K.Y. Seidler, Gerald McComb, David W. Agar, Joshua Mukherjee, Partha P. Melot, Brent Chapman, Karena Guiton, Beth S. Klie, Robert F. McCue, Ian D. Voyles, Paul M. Robertson, Ian Li, Ling Chi, Miaofang Destino, Joel F. Devaraj, Arun Marquis, Emmanuelle A. Segre, Carlo U. Liu, Huinan H. Yang, Judith C. Momeni, Kasra Misra, Amit Abdolrahim, Niaz Medvedeva, Julia E. Cai, Wenjun Sehirlioglu, Alp Dizbay-Onat, Melike Mehta, Apurva Graham-Brady, Lori Maruyama, Benji Rajan, Krishna Warner, Jamie H. Taheri, Mitra L. Kalinin, Sergei V. Reeja-Jayan, B. Schwarz, Udo D. Simon, Sindee L. Brown, Craig M. Department of Chemistry and Department of Materials Science & Engineering Texas A & M University College Station United States Pritzker School of Molecular Engineering The University of Chicago Chicago United States Department of Materials Science & Engineering University of California Berkeley Berkeley United States National Center for Electron Microscopy Molecular Foundry Lawrence Berkeley National Laboratory Berkeley United States Center for Nanoscale Materials Argonne National Laboratory Lemont United States Department of Physics University of Washington Seattle United States Department of Materials Science & Engineering The Ohio State University Columbus United States Department of Mechanical Engineering and Mechanics Drexel University Philadelphia United States School of Mechanical Engineering Purdue University West Lafayette United States Department of Chemistry University of Southern California Los Angeles United States Department of Chemistry Stony Brook University The State University of New York Stony Brook United States Department of Chemistry University of Kentucky Lexington United States Department of Physics University of Illinois at Chicago Chicago United States Department of Materials Science & Engineering Northwestern University Evanston Bangladesh Department of Materials Science & Engineering University of Wisconsin–Madison Madison United States Department of Materials Science and Engineering University of Pennsylvania Philadelphia United States Department of Mechanical Engineering and Materials Science Duke University Durham United States Department of Chemistry Creighton University Omaha United States Physical and Computational Sciences Directorate Pacific Northwest National Laboratory Richland United States Department of Materials Science & Engineering University of Michigan–Ann Arbor Ann Arbor United States Department of Physics Illinois Institute of Technology Chicago United States Department of Bioengineering and the Mater

This article was updated to correct Minghao Zhang’s affiliation from "Pritzker School of molecular engineering, The University of Chicago, Chicago, USA" to "Pritzker School of molecular engineering, The University of Chicago, Chicago, USA;Argonne National Laboratory, Lemont, USA." Argonne National Laboratory was left off the original publication. © The Author(s) 2025.

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Nucleic Acid-Backboned Chimeric Polymers with Designable Physics and Chemistry

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Chinese Journal of Chemistry 2023年第8期41卷 951-957页

作者： Jiangming Wang Yuanchen Dong Huajie Liu Dongsheng Liu School of Chemical Science and Engineering Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education and Shanghai Research Institute for Intelligent Autonomous SystemsTongji UniversityShanghai200092 China CAS Key Laboratory of Colloid Interface and Chemical ThermodynamicsBeijing National Laboratory for Molecular SciencesInstitute of ChemistryChinese Academy of SciencesBeijing100190 China Engineering Research Center of Advanced Rare Earth Materials(Ministry of Education) Department of ChemistryTsinghua UniversityBeijing100084 China

Comprehensive Summary The chain effect of polymer is the kernel of the precise synthesis of complex polymer compounds and the development of polymer *** acids,a special type of polyester,can form supramolecular polymers via hydrogen bonds among corresponding *** focused on the precise control of polymer chains and proposed the concept of“nucleic acid-backboned chimeric polymers”(NCPs).There are three important elements of NCPs,namely nucleic acid backbone,side group and intra-/inter-chain weak *** this review,we expound how to realize the construction of intelligent DNA structures through the regulation of these three elements and the applications of NCPs in various fields.

关键词： Chimeric polymers programmable polymers Kinetically interlocking Self-assembly DNA

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Ordered Mesoporous Magnetic Ceramics from Single-Source Self-Assembled Ferrocene-Functionalized Giant Molecules

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CCS Chemistry 2025年第2期7卷 460-469页

作者： Qing-Yun Guo Xing-Han Li Yuean Wu Xiao-Yun Yan Yuchu Liu Di Han Bo-xing Zhang Xian-You Liu Huanyu Lei Zebin Su Jiahao Huang Wei Zhang GengXin Liu Hao Liu Xueyan Feng Stephen Z.D.Cheng South China Advanced Institute of Soft Matter Science and Technology School of Emergent Soft MatterSouth China University of TechnologyGuangzhou 510640 Department of Polymer Science School of Polymer Science and Polymer EngineeringThe University of AkronAkronOhio 44325-3909 Guangdong Provincial Key Laboratory of Functional and Intelligent Hybrid Materials and Devices Guangdong Basic Research Center of Excellence for Energy and Information Polymer MaterialsSouth China University of TechnologyGuangzhou 510640 College of Polymer Science and Engineering State Key Laboratory of Polymer Materials and EngineeringSichuan UniversityChengdu 610065 Department of Pharmaceutical Science School of PharmacyUniversity of PittsburghPittsburghPennsyl-vania 15261 State Key Laboratory for Modification of Chemical Fibers and Polymer Materials Center for Advanced Low-dimensional MaterialsCollege of Materials Science and EngineeringDonghua UniversityShanghai 201620 State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular ScienceFudan UniversityShanghai 200438

Ordered mesoporous materials have demonstrated con-siderable potential in various fields,such as catalysis,separation,and biomedical *** such materials has garnered extensive ***-ever,current investigations of mesoporous materials predominantly focus on high porosity and related appli-cations,often neglecting the development of mesopor-ous materials possessing additional ***,we report the fabrication of ordered mesoporous magnetic ceramics by pyrolyzing single-source self-assembled giant molecules,constructed by dihydroxyl-functiona-lized polyhedral oligomeric silsequioxane,polystyrene,and *** ordered magnetic ceramics with high surface areas and uniform pore sizes were obtained after the *** measure-ments revealed the ferromagnetic nature of the ceramic *** magnetic ceramic monoliths and magnetic ceramic thin films can be fabricated by pro-cessing the precursor giant ***,the mesoporous magnetic ceramics exhibit exceptional adsorption capacity and facile separability,making them suitable for water pollutant removal applications.

关键词： mesoporous materials self-assembly giant molecules polyhedral oligomeric silsequioxane ferrocene

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Industrial and biomedical applications of slippery liquid-infused porous surfaces 4

Industrial and biomedical applications of slippery liquid-in...

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4th International Conference on materials Chemistry and Environmental engineering, CONF-MCEE 2024

作者： Cao, Zhilin Dong, Runjie Li, Jialu School of Materials Science and Engineering Beijing University of Chemical Technology Beijing10029 China Department of Chemistry University College London LondonWC1H 0AJ United Kingdom Department Chemical and Molecular Engineering Qingdao University of Science and Technology Qingdao266045 China

Slippery liquid-infused porous surfaces (SLIPS) are biomimetic interface materials that consist of a porous structure or polymer network substrate with a high specific surface area and a perfused liquid lubricant. This surface has an extremely low coefficient of friction and a high degree of antifouling property, which can effectively repel various liquids, oils, ice, biofilms, etc. The tunable performance of SLIPS endows it with promising application prospects in various fields, thus emphasizing the importance of designing diverse SLIPS materials tailored to specific application scenarios in the future. However, owing to the inherent fluid properties of lubricating oil, the surface may encounter challenges associated with lubricant depletion during practical utilization. This review paper focuses on elucidating the principles, design strategies, and fabrication techniques employed for developing SLIPS materials in anti-ice applications, drag reduction applications, and biomedicine. Furthermore, a comprehensive summary of challenges encountered by SLIPS in different domains is provided along with potential avenues for future research to improve the stability and durability of SLIPS. In conclusion, SLIPS shows significant potential for diverse applications, yet necessitates comprehensive research to address its inherent challenges and extend its versatility and functionality across various domains. © Published under licence by IOP Publishing Ltd.

关键词： Drag reduction

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Tuning Intermolecular Singlet Fission Efficiencies of Perylenediimide Derivatives through Bay Aromatic Substitution

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Chinese Journal of Chemistry 2023年第10期41卷 1170-1176页

作者： Chun-Lin Sun Xiao-Zhen Wang Hu-Hu Tian Qi-Wei Song Bo-Yang Zhang Xian Fei Cheng Zhang Jian-Rong Ma Juan Ye Hao-Li Zhang State Key Laboratory of Applied Organic Chemistry Key Laboratory of Special Function Materials and Structure DesignCollege of Chemistry and Chemical EngineeringFrontiers Science Center for Rare IsotopesLanzhou UniversityLanzhouGansu 730000China Tianjin Key Laboratory of Molecular Optoelectronic Sciences Department of ChemistryTianjin UniversityCollaborative Innovation Center of Chemical Science and Engineering(Tianjin)Tianjin 300072China

Singlet fission(SF)has potential applications in high-efficiency photo-energy harvesting applications,but its practical application is hindered by the limited number of *** this work,we explored the bay aromatic substitution strategy for the design of new perylenediimide(PDI)based SF materials.A series of PDI derivatives with biphenyl or naphthalene units substituted at the bay posi-tions were designed and synthesized to investigate the effects of aromatic substitutes on their photodynamic *** bay substitutions do not shift the energy level of the PDI core significantly but give rise to different intermolecular coupling strengths in the thin films and affect the intermolecular SF *** transient absorption(fsTA)spectroscopy reveals that appro-priate spacing configuration from the bay aromatic substitution groups enhances the SF yields by promoting the interaction of neighbouring PDI *** exciton yields of up to 183%have been obtained from these new PDI derivatives,making them po-tential candidates in future SF-based optoelectronics.

关键词： Singlet fission Perylenediimide Femtochemistry Thin films Density functional calculations

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Surface modification techniques of membranes to improve their antifouling characteristics:recent advancements and developments

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Frontiers of chemical science and engineering 2023年第12期17卷 1837-1865页

作者： Muhammad Tawalbeh Haya Aljaghoub Muhammad Qasim Amani Al-Othman Sustainable and Renewable Energy Engineering Department University of SharjahSharjah 27272United Arab Emirates Sustainable Energy&Power Systems Research Centre RISEUniversity of SharjahSharjah 27272United Arab Emirates Industrial Engineering and Engineering Management Department University of SharjahSharjah 27272United Arab Emirates Department of Chemical and Biological Engineering American University of SharjahSharjah 26666United Arab Emirates Materials Science and Engineering Program College of Arts and SciencesAmerican University of SharjahSharjah 26666United Arab Emirates

Extensive research efforts are currently devoted to developing and improving conventional technologies for water treatment. Membrane-based water treatment technologies are among the most preferred options due to their commercial success, simple operation, low energy and space requirements, and high separation efficiency. Despite the advances made in membrane-based technologies, fouling remains a critical challenge. Fouling occurs upon the accumulation of unwanted impurities on the membrane surface and within the membrane pores which results in a significant decline in the membrane permeate flux. To alleviate the operational challenges from fouling, surface modification to develop antifouling membranes appears to be an effective technique. A comprehensive review of the surface modification techniques for the development of antifouling membranes is provided in this paper. chemical surface modification techniques (grafting and plasma treatment), physical modification techniques (blending, coating, adsorption, and thermal treatment), and combined physical and chemical modification techniques have been discussed. Moreover, the challenges related to surface modification and the future research directions are addressed.

关键词： fouling antifouling membrane surface modification membrane pretreatment

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What Can Topology Bring to Chemistry?

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CCS Chemistry 2024年第9期6卷 2084-2109页

作者： Wei Wang Songtao Zhou Xiujun Yu Qing-Hui Guo Yanhang Ma Jie Song Liang Zhang Xuzhou Yan Lu Han Qing Liao Xiaopeng Li Wen-Bin Zhang Yiyong Mai Shaodong Zhang Shunai Che Hai-Bo Yang Xuefeng Fu Mei-Xiang Wang School of Chemistry and Molecular Engineering East China Normal UniversityShanghai 200062 Hangzhou Institute of Medicine Chinese Academy of SciencesHangzhou 310022Zhejiang College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518060Guangdong MOE Key Laboratory of Bioorganic Phosphorous and Chemical Biology Department of ChemistryTsinghua UniversityBeijing 100084 School of Physical Science and Technology and Shanghai Key Laboratory of High-Resolution Electron Microscopy ShanghaiTech UniversityShanghai 201210 School of Chemistry and Chemical Engineering Frontiers Science Center for Transformative MoleculesState Key Laboratory of Composite MaterialsShanghai Key Laboratory for Molecular Engineering of Chiral DrugsShanghai Jiao Tong UniversityShanghai 200240 School of Chemical Science and Engineering Tongji UniversityShanghai 200092 Beijing Key Laboratory for Optical Materials and Photonic Devices Department of ChemistryCapital Normal UniversityBeijing 100048 Beijing National Laboratory for Molecular Sciences Key Laboratory of Polymer Chemistry and Physics of Ministry of EducationCenter for Soft Matter Science and EngineeringCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871 Department of Chemical Sciences National Natural Science Foundation of ChinaBeijing 10085

The unique mathematical perspectives and principal concepts of topology have not only promoted the development of other branches of mathematics but have also deeply influenced other subjects,particularly physics and *** minireview aims to elucidate the substantial influence of topology on chemistry by critically examining both the contributions of topology to current chemical science and its potential future *** will discuss the topology of molecular structures and assemblies across various scales—from small molecules and mechanically interlocked molecules to polymers,biomacromolecules,and supramolecular *** discussion will include an exploration of cutting-edge techniques for characterizing topological features,underscoring the role of topology as a novel paradigm for the design and synthesis of new molecular ***,a critical analysis of topology’s role in the development of functional materials—such as photonic materials,polymers,biomacromolecules,and chiral materials—will demonstrate its emerging significance as a crucial parameter in unveiling novel properties and *** topology’s formidable potential,it is anticipated to be used increasingly to address pivotal challenges within chemistry and adjacent disciplines.

关键词： chemical topology topological invariants molecular graphs links and knots structureproperty relationship

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