检索结果-内蒙古大学图书馆

Ethylene Glycol-Manipulated Syntheses of Calcium Carbonate Particles and DNA Capsules toward Efficient ATP-Responsive Cargo Release

引用

ACS Applied Bio materials 2023年第8期6卷 3351-3360页

作者： Lin, Yu-Hsuan Singuru, Murali Mohana Rao Marpaung, David Septian Sumanto Liao, Wei-Ching Chuang, Min-Chieh Department of Chemistry Tunghai University Taichung407224 Taiwan International Ph.D. Program in Biomedical and Materials Science Tunghai University Taichung407224 Taiwan Department of Biosystems Engineering Institut Teknologi Sumatera Lampung Selatan35365 Indonesia Institute of Biochemistry and Molecular Biology National Yang Ming Chiao Tung University Taipei112304 Taiwan

Cargo molecule-encapsulated DNA capsules synthesized with a solid sacrificial template have elicited significant interest in the last decade and have been used for active materials in applications ranging from biosensors to drug delivery. However, the correlation between template properties and the subsequent assembly and triggered release behavior of the resultant carriers remain uninvestigated. In this study, ethylene glycol (EG) was added during the CaCO3 precipitation synthesis to yield particles of various sizes and surface properties, and the adenosine triphosphate (ATP)-responsive release characteristics of the fabricated DNA capsules affected by these particle properties were investigated. The geometry, crystallization, and surface morphology of the CaCO3 particles co-precipitated at various EG concentrations were characterized. We discuss the integrity of cross-linking hybridization, fluorescent molecule internalization, degree of leakage, and release efficiency of the resulting DNA capsules and their relevance brought by particle properties. To achieve efficient encapsulation and cargo release, the surface roughness of the CaCO3 particles was explored and was deemed a key determinant of the compactness of the DNA shell after template removal. This effect was particularly strong in CaCO3 particles in connection with high EG concentrations. The DNA capsules fabricated using 83% EG exhibited low leakage, high loading, and moderate release efficiencies as well as a greater apparent association constant with ATP due to their small particle size and the high-integrity DNA shells. © 2023 American chemical Society.

关键词： Ethylene glycol

来源：评论

学校读者我要写书评

暂无评论

Enhanced Photocatalytic Properties of Tio2/Rgo Nanocomposites Doped with CDS

SSRN

引用

SSRN 2024年

作者： Seliverstova, Evgeniya Serikov, Timur Sadykova, Aigul Ibrayev, Niyazbek Nuraje, Nurxat Institute of Molecular Nanophotonics Buketov Karaganda University Karaganda100024 Kazakhstan Department of Chemical and Materials Engineering School of Engineering and Digital Science Nazarbayev University Astana010000 Kazakhstan

To increase the photocatalytic activity of nanocomposite material based on TiO2 and rGO (NC) and improve its photosensitivity in the visible region of the spectrum, the influence of CdS concentration on its physicochemical and photocatalytic properties was studied. The concentration of CdS was varied in the range of 1 to 10 wt% with respect to NC. The measurements showed that the addition of CdS to NC leads to a significant increase in the photocatalytic activity. An almost fivefold increase in photocurrent compared to pure NC was registered for NC/CdS_5%. Data on Methylene blue photodegradation showed that after 210 min of irradiation, only 5% of dye molecules remained in solution. This value is 14.4 and 11.6 times higher than that of pure NC or CdS, respectively. The observed improvements in photocatalytic activity are related both to the improvement of NC absorption in the region of 400 – 800 nm and the decrease of the band gap width of NC upon addition of CdS, as well as the significant change in the electrophysical characteristics of the nanocomposite. © 2024, The Authors. All rights reserved.

关键词： Cadmium sulfide

来源：评论

学校读者我要写书评

暂无评论

Selective Pb^(2+) removal and electrochemical regeneration of fresh and recycled FeOOH

引用

Nano Research 2023年第7期16卷 9352-9363页

作者： Lei Wang Lexane Deligniere Samantha Husmann Regina Leiner Carsten Bahr Shengjie Zhang Chaochao Dun Matthew M.Montemore Markus Gallei Jeffrey J.Urban Choonsoo Kim Volker Presser INM—Leibniz Institute for New Materials Campus D22Saarbrücken 66123Germany Department of Materials Science and Engineering Saarland UniversityCampus D22Saarbrücken 66123Germany Polymer Chemistry Saarland UniversityCampus C42Saarbrücken 66123Germany 4 GEH Wasserchemie GmbH&Co.KGAdolf-Köhne-Straße Osnabrück 49090 Germany Department of Chemical and Biomolecular Engineering Tulane UniversityNew OrleansLA 70118USA The Molecular Foundry Lawrence Berkeley National Laboratory BerkeleyBerkeleyCA 94720USA Saarene-Saarland Center for Energy Materials and Sustainability Campus C42Saarbrücken 66123Germany Department of Environmental Engineering with Institute of Energy/Environment Convergence Technologies Kongju National University1223-24 Cheonan-daeroCheonan-si 31080Republic of Korea Department of Future Convergence Engineering Kongju National University1223-24 Cheonan-daeroCheonan-si 31080Republic of Korea

Heavy metal pollution is a key environmental *** extracting heavy metals could accomplish water purification and resource recycling *** is a promising approach with a facile process,adaptability for the broad concentration of feed water,and high ***,the adsorption method faces challenges in synthesizing highperformance sorbents and regenerating adsorbents *** is an environmentally friendly sorbent with low-cost production on a large ***,the selectivity behavior and regeneration of FeOOH are seldom ***,we investigated the selectivity of FeOOH in a mixed solution of Co^(2+),Ni^(2+),and Pb^(2+)and proposed to enhance the capacity of FeOOH and regenerate it by using external *** charge,the FeOOH electrode shows a Pb^(2+)uptake capacity of 20 mg/*** applying a voltage of-0.2/+0.8 V,the uptake capacity increases to a maximum of 42 mg/g and the desorption ratio is 70%-80%.In 35 cycles,FeOOH shows a superior selectivity towards Pb^(2+)compared with Co^(2+)and Ni^(2+),with a purity of 97%±3%in the *** high selectivity is attributed to the lower activation energy for Pb^(2+)*** capacity retentions at the 5^(th)and the 35^(th)cycles are ca.80%and ca.50%,respectively,comparable to the chemical regeneration *** industrially exhausted granular ferric hydroxide as the electrode material,the system exhibits a Pb^(2+)uptake capacity of 37.4 mg/g with high *** work demonstrates the feasibility of regenerating FeOOH by charge and provides a new approach for recycling and upcycling FeOOH sorbent.

关键词： FeOOH electrochemical regeneration selective separation heavy metal ions

来源：评论

学校读者我要写书评

暂无评论

Columnar Liquid Crystalline Corannulenes: Synthesis, Assembly and Charge-Carrier Transport Properties

引用

Chinese Journal of Chemistry 2021年第9期39卷 2354-2358页

作者： Yang Li Zunzhi Wang Mengwei Li Feiyi Chen Yang Zhao Qi Wang Fanli Lu Yi Liu Xiang-Kui Ren Long Chen Tianjin Key Laboratory of Molecular Optoelectronic Science Department of ChemistryTianjin UniversityTianjin 300072China School of Chemical Engineering and Technology Tianjin UniversityTianjin 300072China Shenzhen Key Laboratory of Polymer Science and Technology Guangdong Research Center for Interfacial Engineering of Functional MaterialsCollege of Materials Science and EngineeringShenzhen UniversityShenzhenGuangdong 518060China School of Materials Science and Engineering Tianjin UniversityTianjin 300072China

Two discotic liquid crystalline(LC)molecules consisting of a bowl-shaped corannulene core and five-fold photoactive azobenzene branches with differe nt pa raff i nk side chai ns were *** self-assembly,photo-resp on sive behavior and charge-carrier tran sport properties were investigated in detail.A wider mesophase temperature range was achieved when utilizi ng Ion ger and furcal flexible side chai n substituti on.2D XRD measureme nts revealed the n-packed cora nnulen e-ce ntered lb(i.e.,with furcal side alkoxy I chains)exhibited helical columnar LC *** packing structure also led to a higher hole charge carrier mobility of 7.07 ×1O^(-2) cm^(2)-V^(-1)s^(-1) compared to that of the counterpart la with linear side chain substitutions.

关键词： Corannulene Azo compounds Self-assembly Liquid crystals Organic electronics

来源：评论

学校读者我要写书评

暂无评论

Prediction of Potential-Dependent Kinetics for the Electrocatalytic Reduction of CO2to CO over Ti@4N-Gr

ACS Electrochemistry

引用

ACS Electrochemistry 2024年第3期1卷 328-337页

作者： Yousef A. Alsunni Abdulaziz W. Alherz Charles B. Musgrave Chemical Engineering Department King Fahd University of Petroleum and Minerals Dhahran 31261 Saudi Arabia；Department of Chemical and Biological Engineering University of Colorado Boulder Colorado 80309 United States Department of Chemical Engineering College of Engineering and Petroleum Kuwait University Safat 13060 Kuwait Department of Chemical and Biological Engineering University of Colorado Boulder Colorado 80309 United States；Renewable and Sustainable Energy Institute University of Colorado Boulder Colorado 80309 United States；Materials Science and Engineering Program University of Colorado Boulder Colorado 80309 United States

Grand canonical density functional theory (GC-DFT) was employed to model the electrocatalytic reduction of CO2(CO2R) to CO by single titanium atom nitrogen-doped graphene, referred to as Ti@4N-Gr. Previous GC-DFT thermodynamic investigations have identified Ti@4N-Gr as a promising CO2R catalyst; however, no in-depth studies have examined it. In this study, we analyze activation energies of the elementary steps at various applied potentials in addition to thermodynamics of CO2R to CO catalyzed by Ti@xN-Gr defects. Reaction intermediates are predicted to be destabilized when Ti is coordinated to fewer N atoms. Based on reaction thermodynamics, Ti@4N-Gr and all defect configurations are predicted to be potentially promising catalysts for CO2R to CO at an applied potential of −0.7 VSHEwhile at −0.3 and −1.2 VSHEthe reaction is predicted to be hindered by relatively large grand free energy differences between intermediates. We propose a criterion to identify optimum applied potentials for CO2R to CO based on the potential of zero charge (PZC) of the reaction intermediates and the contention that the optimum applied potential for CO2R to CO lies in the rangePZC*CO

关键词：

来源：评论

学校读者我要写书评

暂无评论

Pt_(1)/Ni_(6)Co_(1)layered double hydroxides/N-doped graphene for electrochemical non-enzymatic glucose sensing by synergistic enhancement of single atoms and doping

引用

Nano Research 2023年第1期16卷 318-324页

作者： Baojun Long Peiyu Cao Yuanmeng Zhao Qianqian Fu Yan Mo Yueming Zhai Juejing Liu Xingyi Lyu Tao Li Xiaofeng Guo Changsheng Shan Minghua Zeng Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules College of Chemistry and Chemical EngineeringHubei UniversityWuhan 430062China Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources School of Chemistry and Pharmaceutical SciencesGuangxi Normal UniversityGuilin 541004China The Institute for Advanced Studies(IAS) Wuhan UniversityWuhan 430072China Material Science and Engineering Program Washington State UniversityPullmanWA 99164USA Department of Chemistry and Alexandra Navrotsky Institute for Experimental Thermodynamics Washington State UniversityPullmanWA 99164USA X-ray Science Division Argonne National LaboratoryArgonneIL 60439USA Department of Chemistry and Biochemistry Northern Illinois UniversityDeKalbIL 60115USA

The development of novel single-atom catalysts is important for highly efficient electrochemical catalysis and *** this work,a novel Pt single atoms(SAs)supported on Ni_(6)Co_(1)layered double hydroxides/nitrogen-doped graphene(Pt_(1)/Ni_(6)Co_(1)LDHs/NG)was constructed for electrochemical enzyme-free catalysis and sensing towards *** loading of Pt single atoms increases with doping of Co atoms that generate more anchoring sites for Pt *** resulting Pt_(1)/Ni_(6)Co_(1)LDHs/NG exhibits low oxidative potential of 0.440 V with high sensitivity of 273.78μA·mM^(−1)·cm^(−2)toward glucose,which are 85 mV lower and 15 times higher than those of Ni(OH)_(2),***_(1)/Ni_(6)Co_(1)LDHs/NG also shows excellent selectivity and great stability during 5-week *** and experimental results show that the boosted performance of Pt_(1)/Ni_(6)Co_(1)LDHs/NG originates from its stronger binding energy with glucose and the synergistic effect of Pt SAs,Co doping,and *** work provides a general strategy of designing highly active SACs for extending their application in electrochemical sensing.

关键词： single-atom catalysts electrochemical sensor layered double hydroxides nitrogen-doped graphene synergistic effect

来源：评论

学校读者我要写书评

暂无评论

Observation of oxygen evolution over a {Ni12}-cluster-based metal-organic framework

引用

science China Chemistry 2022年第6期65卷 1088-1093页

作者： Zongsu Han Zheng Yan Kunyu Wang Xinchen Kang Kai Lv Xiaoping Zhang Zhen Zhou Sihai Yang Wei Shi Peng Cheng Department of Chemistry Key Laboratory of Advanced Energy Materials Chemistry(MOE)Renewable Energy Conversion and Storage Center(RECAST)College of ChemistryNankai UniversityTianjin300071China College of Biological Chemical Sciences and EngineeringJiaxing UniversityJiaxing314001China Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of ColloidInterface and Chemical ThermodynamicsCAS Research/Education Center for Excellence in Molecular SciencesInstitute of ChemistryChinese Academy of SciencesBeijing100190China Department of Chemistry University of ManchesterManchesterM139PLUK School of Materials Science and Engineering Institute of New Energy Material ChemistryNankai UniversityTianjin300350China

The development of efficient electrocatalysts based on non-noble metals for oxygen evolution reaction(OER) remains an important and challenging task. Multinuclear transition-metal clusters with high structural stability are promising OER catalysts but their catalytic role is poorly understood. Here we report the crystallographic observation of OER activity over robust {Ni12}-clusters immobilised in a porous metal-organic framework, NKU-100, by single-crystal X-ray diffraction as a function of external applied potential. We observed the aggregation of confined oxygen species around the {Ni12}-cluster as a function of applied potential during the electrocatalytic process. The refined occupancy of these oxygen species shows a strong correlation with the variation of current density. This study demonstrates that the enrichment of oxygen species in the secondary coordination sphere of multinuclear transition-metal clusters can promote the OER activity.

关键词： metal-organic framework oxygen evolution reaction secondary coordination sphere X-ray diffraction binding site

来源：评论

学校读者我要写书评

暂无评论

Thermodynamic and Transport Properties of Binary Mixtures of Polyethylene and Higher n-Alkanes from Physics-Informed and Machine-Learned Models

arXiv

引用

arXiv 2024年

作者： Ley-Flores, Maria Alessandri, Riccardo Najmi, Sean Valsecchi, Michele Jackson, George Galindo, Amparo Korley, LaShanda Vlachos, Dionisios G. de Pablo, Juan J. Pritzker School of Molecular Engineering University of Chicago United States Department of Chemical and Biomolecular Engineering University of Delaware United States Institute for Molecular Science and Engineering Imperial College London United Kingdom Materials Science Division Argonne National Lab United States

The thermodynamics and transport properties of polymeric materials are essential for design of reactors and for development of polymer deconstruction processes. Existing property prediction tools such as correlations based on entropy scaling, kinetic gas theory, and free-volume model are inadequate for polymers. In this paper, we introduce a data-driven model for polyolefins based on data from molecular dynamics simulations that can accurately predict the transport properties of polyethylenes and their binary mixtures with higher n-alkanes across a range of temperatures, pressures, concentrations, and oligomer molecular weights. © 2024, CC BY.

关键词： Polyethylenes

来源：评论

学校读者我要写书评

暂无评论

Palladium-free chemoselective probe for in vivo fluorescence imaging of carbon monoxide

引用

Chinese chemical Letters 2024年第9期35卷 223-226页

作者： Gongcheng Ma Qihang Ding Yuding Zhang Yue Wang Jingjing Xiang Mingle Li Qi Zhao Saipeng Huang Ping Gong Jong Seung Kim Guangdong Key Laboratory of Nanomedicine Shenzhen Engineering Laboratory of Nanomedicine and NanoformulationsCAS-HK Joint Lab for BiomaterialsResearch Laboratory for Biomedical Optics and Molecular ImagingShenzhen Key Laboratory for Molecular ImagingCAS Key Lab for Health InformaticsShenzhen Institutes of Advanced TechnologyChinese Academy of SciencesShenzhen 518055China University of Chinese Academy of Sciences Beijing 100049China Department of Chemistry Korea UniversitySeoul 02841South Korea School of Chemical Engineering Northwest UniversityXi’an 710069China Cancer Center Institute of Translational MedicineFaculty of Health SciencesUniversity of MacaoMacao 999078China State Key Laboratory of Fine Chemicals College of Materials Science and EngineeringShenzhen UniversityShenzhen 518060China

Carbon monoxide(CO)is a vital intracellular gas messenger known for its cytoprotective and homeostatic *** plays a pivotal role in a myriad of biological ***,the precise detection of CO is of paramount importance in unraveling the intricacies of pathological mechanisms and advancing the development of disease *** herein introduce NFCOP,a state-of-the-art near-infrared(NIR)turn-on fluorescence(FL)probe that has been meticulously designed for highly sensitive,swift and selective imaging of *** NFCOP response occurred rapidly with CO,within just 10 s,and the calculated detection limit for CO was determined to be 0.32μmol/*** investigations conducted at the cellular level and in vivo demonstrated that NFCOP possesses high sensitivity and selectivity for imaging CO.

关键词： Palladium-free Chemoselective probe Fluorescence imaging Carbon monoxide Near-infrared

来源：评论

学校读者我要写书评

暂无评论

放射敏感的纳米调节剂重新编程肿瘤-免疫细胞通讯用于免疫治疗

引用

science China materials 2023年第1期66卷 352-362页

作者：陈园园刘淑杰高鹏潘伟石明婉王建波李娜唐波 College of Chemistry Chemical Engineering and Materials ScienceKey Laboratory of Molecular and Nano ProbesMinistry of EducationCollaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of ShandongInstitute of Molecular and Nano ScienceShandong Normal UniversityJinan 250014China Department of Radiation Oncology Qilu HospitalCheeloo College of MedicineShandong UniversityJinan 250012China

目前,将肿瘤相关巨噬细胞从促肿瘤生长的M2表型调节为抑制肿瘤生长的M1表型已成为一种有前途的肿瘤免疫治疗策略,但仍然具有挑战性,而且以可控的方式实现显得尤为困难.在此,我们报道了一种用于可时空激活免疫反应的放射敏感型纳米调节剂... 详细信息

目前,将肿瘤相关巨噬细胞从促肿瘤生长的M2表型调节为抑制肿瘤生长的M1表型已成为一种有前途的肿瘤免疫治疗策略,但仍然具有挑战性,而且以可控的方式实现显得尤为困难.在此,我们报道了一种用于可时空激活免疫反应的放射敏感型纳米调节剂(AuDAP).AuDAP可通过多价相互作用同时识别和结合M2巨噬细胞与肿瘤细胞.在低剂量医用X射线照射下,纳米调节剂可介导产生大量活性氧(ROS),激活NF-κB信号通路,使M2型巨噬细胞复极化为M1型,从而原位激活巨噬细胞的免疫功能.一系列体外和体内实验结果表明,纳米调节剂可以有效重塑肿瘤细胞和巨噬细胞之间的通讯,并特异性地激活抗肿瘤免疫治疗.通过长时间观察发现,治疗组小鼠的原位肿瘤被明显抑制且未观察到肺部转移瘤的形成.该纳米调节剂可作为一种有潜力的纳米药物用于精确的肿瘤治疗,并能为可控的免疫治疗提供新的见解.

关键词：肿瘤免疫治疗 M2型巨噬细胞肿瘤相关巨噬细胞复极化免疫细胞肿瘤治疗纳米药物体内实验

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：