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Exotic surface magnetotransport phenomena in the antiferromagnetic Mott insulator NiS2

Physical Review materials 2023年第10期7卷 104401-104401页

作者： Sami El-Khatib Faisal Mustafa Mehmet Egilmez Bhaskar Das Yu Tao Moumita Maiti Yeon Lee Chris Leighton Department of Physics American University of Sharjah Sharjah PO Box 26666 United Arab Emirates Materials Science and Engineering Program American University of Sharjah Sharjah PO Box 26666 United Arab Emirates Department of Chemical Engineering and Materials Science University of Minnesota Minneapolis Minnesota 55455 USA

The pyrite-structure transition-metal disulfide NiS2 is in principle a model cubic antiferromagnetic Mott insulator that can be doped through insulator-metal transitions with both electrons and holes (in Ni1–xCuxS2 and Ni1–xCoxS2), eventually inducing superconductivity and ferromagnetism, respectively. Magnetism and transport have proven challenging to understand in NiS2, however. The antiferromagnetic spin structure below ∼39K is complex due to frustration, while unexplained weak ferromagnetism emerges below ∼30K. Surface conduction is also now understood to dominate in NiS2 at low temperatures, raising questions about the interpretation of decades of prior data. Here, we present a complete study of the surface magnetotransport phenomena that emerge at low temperatures in high-quality single-crystal NiS2, which turn out to be strikingly rich. On cooling, isotropic magnetoresistance due to a field-induced shift of the first-order weak ferromagnetic ordering transition is first uncovered, i.e., metamagnetic magnetoresistance. At lower temperatures, larger, anisotropic magnetoresistance effects arise due to distinct switching events associated with the weak ferromagnetism. Strong evidence is presented that this is due to a field-driven in-plane to out-of-plane reorientation of surface spins, likely correlated with surface steps and terraces. In-plane exchange bias accompanies these effects, further supporting this interpretation. At the lowest temperatures, the spin reorientation field eventually exceeds the 9-T measurement window, generating strongly field-asymmetric magnetoresistance. Some of these unusual phenomena also manifest in the Hall channel, culminating in a sizable anomalous Hall effect at low temperatures. These results significantly demystify recent magnetoresistance and magnetic microscopy observations in NiS2 crystals and nanoflakes, and constitute an important step in elucidating the complex electronic and magnetic properties of this pivotal antiferro

关键词： Electrical properties Electronic structure Magnetism Antiferromagnets Ferromagnets Mott insulators Magnetic techniques Transport techniques

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Brownian motion of poly(divinylbenzene) nanoparticles in water

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Journal of Applied Physics 2023年第11期133卷 114303-114303页

作者： Lin, Ching-Bin Lee, Chia-Wei Ouyang, Hao Yang, Fuqian Lee, Sanboh Mechanical and Electro-Mechanical Engineering Tamkang University New Taipei City251301 Taiwan Department of Materials Science and Engineering National Tsing Hua University Hsinchu300 Taiwan Materials Program Department of Chemical and Materials Engineering University of Kentucky LexingtonKY40506 United States

Understanding the motion of nanoparticles in liquid is of practical importance for drug delivery and fluid flow in nanofluidic systems. In this work, we use a nanoparticle tracking analyzer to investigate the Brownian motion of polydivinylbenzene (PDVB) nanoparticles in water and a video camera to record the aggregation of PDVB aggregates on the water surface. Using water as the liquid medium precludes the possible complex interaction between the liquid medium and the PDVB nanoparticles, which can possibly alter the random characteristics of the motion of the PDVB nanoparticles. The diffusivity of the PDVB nanoparticles determined from the mean square displacements of the PDVB nanoparticles has the same activation energy as that for the intrinsic viscosity of the corresponding aqueous suspension of the PDVB nanoparticles. The correlation between the diffusivity for the motion of the PDVB nanoparticles in water and the intrinsic viscosity of the corresponding aqueous suspension follows the Stokes-Einstein relation. The capillary effect and the interaction between PDVB aggregates and the liquid media enable the aggregation of the PDVB aggregates on the water surface, which follows the first-order reaction with activation energy larger than that for the random motion of the PDVB nanoparticles in water. © 2023 Author(s).

关键词： Nanoparticles

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Enhanced subacute ischemic stroke treatment via multistage drug delivery system design for combination therapy

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science China Chemistry 2025年

作者： Xihan Xu Juan-Juan Li Jiamin Li Hui-Yan Zhang Yilin Qi Bing-Sen Shi Tianqi Li Shan-Shan Su Weitao Zhao Chang Chen Zhongying Gong Huiyu Liu Ke-Rang Wang Dong-Sheng Guo Xue Xue State Key Laboratory of Medicinal Chemical Biology College of Pharmacy Nankai University College of Chemistry State Key Laboratory of Elemento-Organic Chemistry Key Laboratory of Functional Polymer Materials (Ministry of Education) Frontiers Science Center for New Organic Matter Collaborative Innovation Center of Chemical Science and EngineeringNankai University College of Chemistry and Materials Science State Key Laboratory of New Pharmaceutical Preparations and Excipients Key Laboratory of Medicinal Chemistry and Molecular Diagnosis (Ministry of Education) Key Laboratory of Chemical Biology of Hebei Province Hebei Research Center of the Basic Discipline of Synthetic Chemistry Hebei University Department of Neurology Tianjin First Central Hospital School of Medicine Nankai University Beijing Advanced Innovation Center for Soft Matter Science and Engineering State Key Laboratory of Organic-Inorganic Composites Beijing Laboratory of Biomedical Materials Bionanomaterials & Translational Engineering Laboratory Beijing Key Laboratory of BioprocessBeijing University of Chemical Technology

The management of acute ischemic stroke remains challenging due to its abrupt onset and the narrow treatment window,resulting in high rates of disability and *** therapy for neuroprotection and neurorepair strategies provided new hopes for subacute stroke *** we designed a multistage nanodelivery system that matches the unique microenvironment of the subacute phase of stroke,which utilizes calixarene as a building block to effectively load the neuroprotective drug *** calixarene is designed with glycosidic linkages targeting the glucose transporter 1 (GLUT1)on the blood-brain barrier (BBB) and azo bonds that are responsive to hypoxic ***,the decomposed calixarene molecules themselves possess intrinsic bio-activation to modulate inflammatory responses,achieving a multistage therapeutic approach that transitions from targeting to release and finally to *** approach combines anti-inflammation and neuroprotection,providing a multi-level treatment *** system was validated in a rat model of permanent middle cerebral artery occlusion (pMCAO),demonstrating that intravenous administration of the nanodelivery system repairs brain damage and improves motor function 24 h post-pMCAO *** work offers a precise and integrative strategy for stroke patients missing the acute therapy window to improve functional recovery and enhance the effect of comprehensive treatment.

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High Performance Electrospun Polynaphthalimide Nanofibrous Membranes with Excellent Resistance to chemically Harsh Conditions

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Chinese Journal of Polymer science 2021年第12期39卷 1634-1644页

作者： Meng-Jie Yuan Zhao-Yu Hu Hong Fang Shu-Jing Li Hong-Tao Guo Ru-Bei Hu Shao-Hua Jiang Kun-Ming Liu Hao-Qing Hou Department of Chemistry and Chemical Engineering Jiangxi Normal UniversityNanchang 330022China Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources International Innovation Center for Forest Chemicals and MaterialsCollege of Materials Science and EngineeringNanjing Forestry UniversityNanjing 210037China Shandong Key Laboratory of Biochemical Analysis College of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042China Faculty of Materials Metallurgy and Chemistry Jiangxi University of Science and TechnologyGanzhou 341000China

Polynaphthalimide(PNI)with six-membered imide ring(_(6-)PI)has better chemical resistance than five-membered imide ring(_(5-)PI),but is difficult to be processed into nano fibers due to the poor *** this work,we proposed a template strategy to fabricate nanofiber _(6-)PI membranes and their composite *** _(6-)PI and _(6-)PI composite fibrous membranes were prepared using high-molecular-weight polymers _(5-)PAA and PVP as templates by ***,DMA,TGA and tensile tests were used to characterize their chemical structures,thermal stability and mechanical *** eye-observation,micro-morphology investigation and tensile tests were applied to evaluate the chemical resistance of nanofibrous membranes in strong acid,strong alkaline,and concentrated *** results demonstrated that 6-PI nano fibrous membra nes possessed the best thermal stability,best acid,alkaline,and salt resista nee with the highest mecha nical rete *** study will provide basic information for high-performance electrospun 6-PI nanofiber membranes and provide opportunities for applications of Pls in different chemically harsh environments.

关键词： Polynaphthalimide Nanofibrous membrane Strong acid Strong base Salt

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Biomedical polymers: synthesis, properties, and applications

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science China Chemistry 2022年第6期65卷 1010-1075页

作者： Wei-Hai Chen Qi-Wen Chen Qian Chen Chunyan Cui Shun Duan Yongyuan Kang Yang Liu Yun Liu Wali Muhammad Shiqun Shao Chengqiang Tang Jinqiang Wang Lei Wang Meng-Hua Xiong Lichen Yin Kuo Zhang Zhanzhan Zhang Xu Zhen Jun Feng Changyou Gao Zhen Gu Chaoliang He Jian Ji Xiqun Jiang Wenguang Liu Zhuang Liu Huisheng Peng Youqing Shen Linqi Shi Xuemei Sun Hao Wang Jun Wang Haihua Xiao Fu-Jian Xu Zhiyuan Zhong Xian-Zheng Zhang Xuesi Chen Key Laboratory of Biomedical Polymers of Ministry of Education&Department of Chemistry Wuhan UniversityWuhan430072China Institute of Functional Nano&Soft Materials(FUNSOM) Jiangsu Key Laboratory for Carbon-Based Functional Materials&DevicesSoochow UniversitySuzhou215123China School of Materials Science and Engineering Tianjin Key Laboratory of Composite and Functional MaterialsTianjin UniversityTianjin300350China Key Laboratory of Biomedical Materials of Natural Macromolecules(Beijing University of Chemical Technology) Ministry of EducationBeijing Laboratory of Biomedical MaterialsCollege of Materials Science and EngineeringBeijing University of Chemical TechnologyBeijing100029China MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and EngineeringZhejiang UniversityHangzhou310027China State Key Laboratory of Medicinal Chemical Biology Key Laboratory of Functional Polymer Materials of Ministry of EducationCollege of ChemistryNankai UniversityTianjin300071China Key Laboratory of Advanced Drug Delivery Systems of Zhejiang Province College of Pharmaceutical SciencesZhejiang UniversityHangzhou310058China Jinhua Institute of Zhejiang University Jinhua321299China Zhejiang Key Laboratory of Smart BioMaterials and Center for Bionanoengineering College of Chemical and Biological EngineeringZhejiang UniversityHangzhou310027China ZJU-Hangzhou Global Scientific and Technological Innovation Center Hangzhou311215China State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular Science and Laboratory of Advanced MaterialsFudan UniversityShanghai200438China CAS Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety CAS Center for Excellence in Nano-scienceNational Center for Nanoscience and Technology(NCNST)Beijing100190China School of Biomedical Sciences and Engineering Guangzhou International CampusSouth China University of TechnologyGuangzhou510006China Institute of Functional Nano and So

Biomedical polymers have been extensively developed for promising applications in a lot of biomedical fields, such as therapeutic medicine delivery, disease detection and diagnosis, biosensing, regenerative medicine, and disease treatment. In this review, we summarize the most recent advances in the synthesis and application of biomedical polymers, and discuss the comprehensive understanding of their property-function relationship for corresponding biomedical applications. In particular, a few burgeoning bioactive polymers, such as peptide/biomembrane/microorganism/cell-based biomedical polymers, are also introduced and highlighted as the emerging biomaterials for cancer precision therapy. Furthermore, the foreseeable challenges and outlook of the development of more efficient, healthier and safer biomedical polymers are discussed. We wish this systemic and comprehensive review on highlighting frontier progress of biomedical polymers could inspire and promote new breakthrough in fundamental research and clinical translation.

关键词： biomedical polymer nanomedicine cancer therapy drug delivery bioimaging and biosensing tissue engineering regenerative medicine cytotoxicity biocompatibility

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Dipole moment regulation for enhancing internal electric field in covalent organic frameworks photocatalysts

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Chemosphere 2024年 356卷 141947页

作者： Zhao, Xiaoying Shang, Shuaishuai Liu, Honglai Peng, Changjun Hu, Jun Key Laboratory for Advanced Materials and Joint International Research Laboratory for Precision Chemistry and Molecular Engineering School of Chemistry and Molecular Engineering East China University of Science and Technology 130 Meilong Road Shanghai200237 China State Key Laboratory of Chemical Engineering and Department of Chemistry East China University of Science and Technology Shanghai200237 China

Covalent organic frameworks (COFs) have recently emerged as a kind of promising photocatalytic platform in addressing the growing threat of trace pollutants in aquatic environments. Along this, we propose a strategy of constructing internal electric field (IEF) in COFs through the dipole moment regulation, which intrinsically facilitates the separation and transfer of photogenerated excitons. Two COFs of BTT-TZ-COF and BTT-TB-COF are developed by linking the electron-donor of benzotrithiophene (BTT) block and the electron-acceptor of triazine (TZ) or tribenzene (TB) block, respectively. DFT calculations demonstrate TZ block with larger dipole moment can achieve more efficient IEF due to the stronger electron-attractive force and hence narrower bandgap. Moreover, featuring the highly-order crystalline structure for accelerating photo-excitons transfer and rich porosity for facilitating the adsorption, BTT-TZ-COF exhibited an excellent universal performance of photocatalytic degradations of various dyes. Specifically, a superior photodegradation efficiency of 99% Rhodamine B (RhB) is achieved within 20 min under the simulated sunlight. Therefore, this convenient construction approach of enhanced IEF in COFs through rational regulation of the dipole moment can be a promising way to realize high photocatalytic activity. © 2024 Elsevier Ltd

关键词： Excitons

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Recent Progress in Metal-Organic Frameworks@Cellulose Hybrids and Their Applications

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Chinese Journal of Chemistry 2021年第12期39卷 3462-3480页

作者： Xiongli Liu Yun Xiao Zhiyuan Zhang Zifeng You Jinli Li Dingxuan Ma Baiyan Li School of Materials Science and Engineering National institute for Advanced MaterialsTKL of Metal and Molecule-Based Material ChemistryNankai UniversityTianjin 300350China College of Chemistry and Molecular Engineering Laboratory of Eco-chemical EngineeringMinistry of EducationQingdao University of Science and TechnologyQingdao 266042China General English Department College of Foreign LanguagesNankai UniversityTianjin 300071China

In recent years,metal-organic frameworks(MOFs)are attracting increasing attention due to their charming ***,the intrinsic fragility,powdered crystalline state,and poor processibility of MOFs hinder their further *** this,the designs of MOF-based aerogels,hydrogels,membranes are effective ways to solve this ***,silica,synthetic polymer and cellulose are the commonly used raw materials for fabricating MOF-based aerogels,hydrogels,and *** them,cellulose and its derivatives are the best candidates to support the powdered MOFs from the perspectives of economy,environmental protection and *** review focuses on discussing the advantages of MOF@cellulose hybrids in applications such as water treatment,antibacterial,gas separation and adsorption,energy storage,drug delivery,catalysis,and other smart ***@cellulose-based aerogels,hydrogels and membranes can provide valuable guidance for investigating the practical application of MOFs in terms of processability,reusability,stability and easiness in handling.

关键词： Metal-organic frameworks Cellulose Membranes Organic-inorganic hybrid composites Application

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Growth of Wafer-Scale Single-Crystal 2D Semiconducting Transition Metal Dichalcogenide Monolayers

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Advanced science 2024年第11期11卷 e2307839页

作者： Singh, Jitendra Astarini, Nadiya Ayu Tsai, Meng-Lin Venkatesan, Manikandan Kuo, Chi-Ching Yang, Chan-Shan Yen, Hung-Wei Department of Materials Science and Engineering National Taiwan University of Science and Technology Taipei City106335 Taiwan Department of Physics Udit Narayan Post Graduate College Padrauna Uttar Pradesh Kushinagar274304 India Department of Molecular Science and Engineering Institute of Organic and Polymeric Materials National Taipei University of Technology Taipei City106344 Taiwan Institute and Undergraduate Program of Electro-Optical Engineering National Taiwan Normal University Taipei City11677 Taiwan Department of Materials Science and Engineering National Taiwan University Taipei City106319 Taiwan

Due to extraordinary electronic and optoelectronic properties, large-scale single-crystal two-dimensional (2D) semiconducting transition metal dichalcogenide (TMD) monolayers have gained significant interest in the development of profit-making cutting-edge nano and atomic-scale devices. To explore the remarkable properties of single-crystal 2D monolayers, many strategies are proposed to achieve ultra-thin functional devices. Despite substantial attempts, the controllable growth of high-quality single-crystal 2D monolayer still needs to be improved. The quality of the 2D monolayer strongly depends on the underlying substrates primarily responsible for the formation of grain boundaries during the growth process. To restrain the grain boundaries, the epitaxial growth process plays a crucial role and becomes ideal if an appropriate single crystal substrate is selected. Therefore, this perspective focuses on the latest advances in the growth of large-scale single-crystal 2D TMD monolayers in the light of enhancing their industrial applicability. In the end, recent progress and challenges of 2D TMD materials for various potential applications are highlighted. © 2023 The Authors. Advanced science published by Wiley-VCH GmbH.

关键词： Single crystals

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Soft-lock drawing of super-aligned carbon nanotube bundles for nanometre electrical contacts (vol 17, pg 278, 2022)

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NATURE NANOTECHNOLOGY 2022年第3期17卷 331-331页

作者： Guo, Yunfan Shi, Enzheng Zhu, Jiadi Shen, Pin-Chun Wang, Jiangtao Lin, Yuxuan Mao, Yunwei Deng, Shibin Li, Baini Park, Ji-Hoon Lu, Ang-Yu Zhang, Shuchen Ji, Qingqing Li, Zhe Qiu, Chenguang Qiu, Song Li, Qingwen Dou, Letian Wu, Yue Zhang, Jin Palacios, Tomas Cao, Anyuan Kong, Jing Department of Electrical Engineering and Computer Science Massachusetts Institute of Technology Cambridge MA USA Research Institute of Frontier Technology College of Micro-Nano Electronics Zhejiang University Hangzhou China Key Laboratory of 3D Micro/Nano Fabrication and Characterization of Zhejiang Province School of Engineering Westlake University Hangzhou China School of Materials Science and Engineering Peking University Beijing China Davidson School of Chemical Engineering Purdue University West Lafayette IN USA Taiwan Semiconductor Manufacturing Company (TSMC) Hsinchu Taiwan Department of Mechanical Engineering Massachusetts Institute of Technology Cambridge MA USA Department of Chemistry Purdue University West Lafayette IN USA College of Chemistry and Molecular Engineering Peking University Beijing China Department of Chemical and Biological Engineering Iowa State University Ames IA USA Key Laboratory for the Physics and Chemistry of Nanodevices and Department of Electronics Peking University Beijing China Division of Advanced Nano-Materials Suzhou Institute of Nano-Tech and Nano-Bionics Chinese Academy of Sciences Suzhou China

The assembly of single-walled carbon nanotubes (CNTs) into high-density horizontal arrays is strongly desired for practical applications, but challenges remain despite myriads of research efforts. Herein, we developed a non-destructive soft-lock drawing method to achieve ultraclean single-walled CNT arrays with a very high degree of alignment (angle standard deviation of ~0.03°). These arrays contained a large portion of nanometre-sized CNT bundles, yielding a high packing density (~400 µm−1) and high current carrying capacity (∼1.8 × 108 A cm−2). This alignment strategy can be generally extended to diverse substrates or sources of raw single-walled CNTs. Significantly, the assembled CNT bundles were used as nanometre electrical contacts of high-density monolayer molybdenum disulfide (MoS2) transistors, exhibiting high current density (~38 µA µm−1), low contact resistance (~1.6 kΩ µm), excellent device-to-device uniformity and highly reduced device areas (0.06 µm2 per device), demonstrating their potential for future electronic devices and advanced integration technologies.

关键词： Carbon nanotubes and fullerenes materials science general Nanotechnology Nanotechnology and Microengineering

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Z-Laminating Assembly of Graphene Nanoflakes for Super-Strong Membranes and Functional Coatings

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ACS Applied Nano materials 2024年第13期7卷 14957-14963页

作者： Santos, Ian Daniell Tjarks, Patrick Muthu, Jeyavelan Lin, You-Chen Yen, Zhi-Long Chand, Pradyumna Kumar Raman, Radha Nguyen, Dinh Tuan Rouhani, Mehdi Jeng, Yeau-Ren Hsieh, Ya-Ping Hofmann, Mario Department of Physics National Taiwan University Taipei 106 Taiwan Nano Science and Technology Program Taiwan International Graduate Program Academia Sinica and National Taiwan University Taipei 106 Taiwan J. Heyrovsky Institute of Physical Chemistry of the Czech Academy of Sciences Prague 18200 Czech Republic Institute of Atomic and Molecular Sciences Academia Sinica Taipei 106 Taiwan Department of Chemistry National Taiwan University Taipei 106 Taiwan Department of Physics National Central University Taoyuan 320 Taiwan Molecular Science and Technology Program Taiwan International Graduate Program Academia Sinica and National Central University Taipei 106 Taiwan Department of Biomedical Engineering National Cheng Kung University 1 University Road Tainan 70101 Taiwan Department of Materials Science and Engineering National Cheng Kung University Tainan 70101 Taiwan Academy of Innovative Semiconductor and Sustainable Manufacturing National Cheng-Kung University (NCKU) Tainan 70101 Taiwan

We demonstrate the strengthening of graphene, an atomically thin carbon allotrope, by out-of-plane folding. Through lateral confinement of graphene at the water-air interface, nanoscale buckling was induced in suspended flakes, leading to an unexpected folding transition beyond a critical surface pressure. The emergence of folding was confirmed by in situ Brewster angle reflectivity and ex situ microscopy, showing a unique “z-laminated” nanostructure. molecular dynamics simulations indicate that z-lamination yields an enhanced adhesion between neighboring flakes compared to lateral sliding, which was confirmed by a surface pressure hysteresis during the folding process. Mechanical testing reveals superior Young’s modulus and yield strength when compared to conventional graphene assemblies and even compared to composites. We demonstrate the potential of the z-lamination approach for applications in graphene-based structural materials, tribological layers, and functional electrochemical coatings. Finally, the complete recyclability of z-laminated graphene opens up new routes toward sustainable nanostructured materials. © 2024 The Authors. Published by American chemical Society

关键词： 2D materials composites laminated graphene membranes recyclable

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