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ACS electrochemistry 2025年第2期1卷 239-248页

作者： Emily K Volk Arielle L Clauser Melissa E Kreider Diego D Soetrisno Sunilkumar Khandavalli Joshua D Sugar Stephanie Kwon Shaun M Alia Advanced Energy Systems Graduate Program Colorado School of Mines Golden Colorado 80401 United States. Sandia National Laboratories Livermore California 94550 United States. Chemistry and Nanoscience Center National Renewable Energy Laboratory Golden Colorado 80401 United States. Materials Science Center National Renewable Energy Laboratory Golden Colorado 80401 United States. Department of Chemical and Biological Engineering Colorado School of Mines Golden Colorado 80401 United States.

While anion exchange membrane water electrolyzers (AEMWEs) have achieved significant performance advances in recent decades, overpotentials remain high relative to their proton exchange membrane water electrolyzer (PEMWE) counterparts, requiring AEMWE-specific catalyst layer design strategies to further advance this technology. In this work, the role of the ionomer in catalyst layer structure and quality, catalyst layer stability, and ion conduction for supporting electrolyte-fed AEMWEs is assessed for catalyst layers composed of NiFeO and PiperION TP85 from Versogen at variable ionomer contents (0-30 wt %) for tests up to 200 h. The results reveal that, for supporting electrolyte-fed AEM devices, the ionomer is not required for ion conduction through the catalyst layer. Instead, the ionomer is found to play a critical role in catalyst layer structure and stability, where intermediate ionomer contents lead to the lowest overpotentials, highest effective surface areas, and lowest catalyst layer resistances. Catalyst layer stability is found to be a function of both catalyst adhesion and ionomer loss. These results show that an ionomer may be selected which is not of the same chemistry as the anion exchange membrane, mitigating ionomer stability concerns throughout the catalyst layer and offering a pathway towards highly active and stable AEMWEs.

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Metal ratio and bimetal nanoarchitectonics of ammonia-based fluoride complex induced nickel hydroxide and manganese oxide composites as active materials of an energy storage device

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Journal of Energy Storage 2024年 80卷

作者： Hsu, Chuan-Chih Yu, You Zher Wu, Chung-Hsien Lee, Pin-Yan Chen, Hung-Ming Husain, Sadang Kongvarhodom, Chutima Hsiao, Yu-Cheng Lin, Lu-Yin Division of Cardiovascular Surgery Department of Surgery School of Medicine College of Medicine Taipei Medical University Taiwan Division of Cardiovascular Surgery Department of Surgery Taipei Medical University Hospital Taiwan Department of Chemical Engineering and Biotechnology National Taipei University of Technology Taipei Taiwan Gingen Technology Co. LTD. Rm. 7 10F. No.189 Sec. 2 Keelung Rd. Xinyi Dist. Taipei11054 Taiwan Department of Physics Faculty of Mathematics and Natural Science Lambung Mangkurat University Banjarmasin70124 Indonesia Department of Chemical Engineering King Mongkut's University of Technology Thonburi 126 Pracha-u-thit Toong-kru Bangkok10140 Thailand Department of Chemical Engineering Ming Chi University of Technology New Taipei City24301 Taiwan Cell Physiology and Molecular Image Research Center Wan Fang Hospital Taipei Medical University Taipei11696 Taiwan International PhD Program in Biomedical Engineering College of Biomedical Engineering Taipei Medical University Taipei11031 Taiwan Stanford Byers Center for Biodesign Stanford University CA94305-5428 United States Graduate Institute of Biomedical Optomechatronics College of Biomedical Engineering Taipei Medical University Taipei11031 Taiwan

Nickel and manganese compounds are widely applied as efficient battery-type active materials for energy storage devices, due to high theoretical capacities and abundant redox states for generating redox reactions to store charges. Morphology plays significant roles on energy storage ability. Structure directing agent (SDA) is widely reported to have ability for modulating configurations of active materials and to achieve excellent surface properties. In this work, it is the first time to use NH4BF4 and NH4HF2 as structure directing agents for synthesizing nickel manganese compounds derived from ZIF67 as active materials of energy storage devices. Bimetallic compounds are composed of nickel hydroxide and manganese oxide, which presents the favorable two-dimensional flower-like structure with high surface area and abundant redox states. The largest specific capacitance (CF) of 1358.2 F/g corresponding to the capacity of 226.4 mAh/g are achieved for the bimetallic compound synthesized using the Ni to Mn precursor ratio of 1 to 1 (NiMn11). The energy storage device assembled using NiMn11 and reduced graphene oxide on Ni foams presents a maximum energy density of 11.45 Wh/kg at the power density of 0.35 kW/kg, and excellent long-term stability with the CF retention of 85.6% and Coulombic efficiency of 87.5% after 10,000 cycles. © 2023

关键词： Fluorine compounds

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Shape Anisotropy-Governed High-Performance Nanomagnetosol for In Vivo Magnetic Particle Imaging of Lungs

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Small 2024年第5期20卷 2305300-2305300页

作者： Nigam, Saumya Mohapatra, Jeotikanta Makela, Ashley V. Hayat, Hanaan Rodriguez, Jessi Mercedes Sun, Aixia Kenyon, Elizabeth Redman, Nathan A. Spence, Dana Jabin, George Gu, Bin Ashry, Mohamed Sempere, Lorenzo F. Mitra, Arijit Li, Jinxing Chen, Jiahui Wei, Guo-Wei Bolin, Steven Etchebarne, Brett Liu, J. Ping Contag, Christopher H. Wang, Ping Precision Health Program Michigan State University East LansingMI48824 United States Department of Radiology College of Human Medicine Michigan State University East LansingMI48824 United States Department of Physics The University of Texas at Arlington ArlingtonTX76019 United States Michigan State University East LansingMI48824 United States Department of Biomedical Engineering College of Engineering Michigan State University East LansingMI48824 United States Human Biology Program College of Natural Science Michigan State University East LansingMI48824 United States Department of Obstetrics Gynecology and Reproductive Sciences College of Human Medicine Michigan State University East LansingMI48824 United States Department of Materials Science and Engineering National Cheng Kung University Tainan City701 Taiwan Department of Mathematics College of Natural Science Michigan State U niversity East LansingMI48824 United States Department of Electrical and Computer Engineering College of Engineering Michigan State University East LansingMI48824 United States Department of Biochemistry and Molecular Biology College of Natural Science Michigan State University East LansingMI48824 United States Department of Pathobiology and Diagnostic Investigation College of Veterinary Medicine Michigan State University East LansingMI48824 United States Osteopathic Medical Specialties College of Osteopathic Medicine Michigan State University East LansingMI48824 United States Department of Microbiology and Molecular Genetics Michigan State University East LansingMI48824 United States

Caused by severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2), coronavirus disease 2019 (COVID-19) has shown extensive lung manifestations in vulnerable individuals, putting lung imaging and monitoring at the forefront of early detection and treatment. Magnetic particle imaging (MPI) is an imaging modality, which can bring excellent contrast, sensitivity, and signal-to-noise ratios to lung imaging for the development of new theranostic approaches for respiratory diseases. Advances in MPI tracers would offer additional improvements and increase the potential for clinical translation of MPI. Here, a high-performance nanotracer based on shape anisotropy of magnetic nanoparticles is developed and its use in MPI imaging of the lung is demonstrated. Shape anisotropy proves to be a critical parameter for increasing signal intensity and resolution and exceeding those properties of conventional spherical nanoparticles. The 0D nanoparticles exhibit a 2-fold increase, while the 1D nanorods have a > 5-fold increase in signal intensity when compared to VivoTrax. Newly designed 1D nanorods displayed high signal intensities and excellent resolution in lung images. A spatiotemporal lung imaging study in mice revealed that this tracer offers new opportunities for monitoring disease and guiding intervention. © 2023 The Authors. Small published by Wiley-VCH GmbH.

关键词： Nanorods

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Effect of dual modification on structural, functional and dielectric properties of cassava starch

Food Physics

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Food Physics 2025年 2卷

作者： Cremasco, Paula Figueiredo M. Siqueira, Karine Mayuri Pistoni Sobral, Paulo José do Amaral Velloso, Walter Ferreira de Lima, César Gonçalves Gut, Jorge Andrey Wilhelms Moraes, Izabel Cristina Freitas Postgraduate Program in Materials Science and Engineering Faculty of Animal Science and Food Engineering University of São Paulo Avenue Duque de Caxias Norte São Paulo Pirassununga 13635900 Brazil Department of Biossistems Engineering Faculty of Animal Science and Food Engineering University of São Paulo Avenue Duque de Caxias Norte São Paulo Pirassununga 13635900 Brazil Department of Food Engineering Faculty of Animal Science and Food Engineering University of São Paulo Avenue Duque de Caxias Norte São Paulo Pirassununga 13635900 Brazil Food Research Center (FoRC) University of São Paulo Lake Street São Paulo São Paulo 05508-080 Brazil Departament of Basic Sciences Faculty of Animal Science and Food Engineering University of São Paulo Avenue Duque de Caxias Norte São Paulo Pirassununga 13635900 Brazil Department of Chemical Engineering Polytechnic School University of São Paulo Lake Street São Paulo São Paulo 05508-080 Brazil

The combined effect of hydrocolloid addition and microwave heating on the structural, physical and functional properties of cassava starch remains underexplored, despite individual studies on these modification methods. The dielectric properties, important for the microwave treatment of starch, have received little attention in recent studies. Cassava starch with and without addition of hydrocolloids (guar and xanthan gums) was modified by microwave heating for two different exposure times, and its structural, functional, and dielectric properties were studied. The dual modification enhanced the swelling power and oil holding capacity of the starch, reduced its gelatinization temperature, and did not alter its crystallinity. Notably, xanthan-modified starch microwaved for 6 min exhibited higher color variation (ΔE*) and increased granules agglomeration, while the microwave treatment alone roughened the surface of the starch granules. The mean diameters D[4,3] of starch increased with xanthan gum addition, microwave treatment (6 min), and their combination. The relative permittivity (ε’), loss factor (ε”) and penetration depth (D_p) were lower for samples modified by the combined method. Considering the type of hydrocolloid and the microwave exposure time, the combined modification significantly influenced the properties of starch, offering a promising approach to producing starch with enhanced functional properties. © 2024 KeAi Communications Co., Ltd

关键词： Biopolymers Cassava starch Guar Microwave Xanthan

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Efficient removal for multiple pollutants via Ag_(2)O/BiOBr heterojunction:A promoted photocatalytic process by valid electron transfer pathway

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Chinese chemical Letters 2020年第10期31卷 2698-2704页

作者： Zhiruo Zhou Yanan Li Mingmei Li Yi Li Sihui Zhan College of Environmental Science and Engineering Key Laboratory of Pollution Processes and Environmental CriteriaTianjin Key Laboratory of Environmental Remediation and Pollution ControlNankai UniversityTianjin 300071China Tianjin Key Laboratory of Molecular Optoelectronic Sciences Department of ChemistrySchool of ScienceTianjin University&Collaborative Innovation Center of Chemical Science and Engineering(Tianjin)Tianjin 300072China Tianjin Key Lab for Rare Earth Materials and Applications Tianjin 300072China

Multiple pollutants including pathogenic microorganism contaminations and emerging organic contaminations(EOCs)have shown a growing threat to the environment,especially the natural ***,the control and removal of pathogenic microorganism contaminations and EOCs have been greatly limited since limited knowledge of their environmental ***,a novel and efficient photocatalyst Ag_(2)O/BiOBr heterojunction was synthesized and used for removal of multiple pollutants including Escherichia coli(***),Staphylococcus aureus(***),tetracycline and acetaminophen under visible *** results showed that there were valid electron transfer pathways between BiOBr and Ag_(2)O,the main electron transfer direction was the BiOBr to Ag_(2)***-generated electrons were stored in Ag_(2)O and thus separation efficiency between holes and photo-generated electrons was obviously *** oxygen species were highly produced and eventually end up with the high efficiency of removal of multiple *** Ag_(2)O/BiOBr with Ag_(2)O content at 3%(the best performance)under visible light,log decrease of *** was 7.16(removal efficiency was 100%)in 120 min,log decrease of *** was 7.23(removal efficiency was 100%)in 160 min,C/C0 of tetracycline was 0.06 in 180 min,C/C0 of acetaminophen was 0.17 in 180 *** work could provide a promising candidate in the actual contaminated natural waters for cleaning multiple pollutants.

关键词： Water pollution Photocatalysis Multiple pollutants Electrons transfer channels

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Generative chemical Transformer: Neural Machine Learning of molecular Geometric Structures from chemical Language via Attention

arXiv

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arXiv 2021年

作者： Kim, Hyunseung Na, Jonggeol Lee, Won Bo School of Chemical and Biological Engineering Seoul National University Gwanak-ro 1 Gwanak-gu Seoul08826 Korea Republic of Department of Chemical Engineering and Materials Science Graduate Program in System Health Science and Engineering Ewha Womans University Seoul03760 Korea Republic of

Discovering new materials better suited to specific purposes is an important issue in improving the quality of human life. Here, a neural network that creates molecules that meet some desired conditions based on a deep understanding of chemical language is proposed (Generative chemical Transformer, GCT). The attention mechanism in GCT allows a deeper understanding of molecular structures beyond the limitations of chemical language itself which cause semantic discontinuity by paying attention to characters sparsely. It is investigated that the significance of language models for inverse molecular design problems by quantitatively evaluating the quality of the generated molecules. GCT generates highly realistic chemical strings that satisfy both chemical and linguistic grammar rules. Molecules parsed from generated strings simultaneously satisfy the multiple target properties and vary for a single condition set. These advances will contribute to improving the quality of human life by accelerating the process of desired material discovery. Copyright © 2021, The Authors. All rights reserved.

关键词： Molecules

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Red AIE conjugated polyelectrolytes for long-term tracing and image-guided photodynamic therapy of tumors

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science China Chemistry 2020年第12期63卷 1815-1824页

作者： Hongming Yao Jun Dai Zeyan Zhuang Jinya Yao Zixuan Wu Shixuan Wang Fan Xia Jian Zhou Xiaoding Lou Zujin Zhao College of Material Chemistry and Chemical EngineeringHangzhou Normal UniversityHangzhou 311121China State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular AggregatesSouth China University of TechnologyGuangzhou 510640China Department of Obstetrics and Gynecology Tongji HospitalTongji Medical CollegeHuazhong University of Science and TechnologyWuhan 430074China Engineering Research Center of Nano-Geomaterials of Ministry of Education Faculty of Materials Science and ChemistryChina University of GeosciencesWuhan 430074China

Robust photosensitizers with strong red/NIR fluorescence, efficient reactive oxygen species(ROS) generation and high photostability are highly desired for photodynamic therapy(PDT). Herein, three novel red conjugated polyelectrolytes(CPEs) with tetraphenylethene and 2,1,3-benzothiadiazole on the main chains and triphenylphosphonium on the side chains are *** CPEs display apparent aggregation-induced emission feature and high fluorescence quantum yields in the aggregated state. They can target lysosome in He La cells for fluorescence bioimaging. By virtue of the good retention effect and high photostability, these CPEs show ultralong-term tracing performance of subcutaneous tumors, and the tumor site can still be visualized for 20 days after injection. Owing to their good biocompatibility and strong ROS generation ability, the image-guided PDT based on these CPEs can effectively inhibit the growth of subcutaneous tumor and significantly prolong the survival of tumor bearing mice. The H&E and IHC staining reveal that the PDT of these CPEs depress the proliferation of tumor cells, and promote apoptosis and necrosis process. These new CPEs may be employed both as fluorescent probes for in vitro and in vivo long-term tracing and as photosensitizers for image-guided PDT of tumors.

关键词： conjugated polyelectrolytes aggregation-induced emission long-term tracing fluorescence imaging photodynamic therapy

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Synergistic Antifouling Behaviors between Zwitterions and Zno Nanoparticles in Moisture-Curable Polyacrylate Coatings

SSRN

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SSRN 2023年

作者： Tan, Jinyan Wang, Jinsong Yang, Jinlong Wang, Jie Gui, Taijiang Wu, Limin Zhou, Shuxue Department of Materials Science State Key Laboratory of Molecular Engineering of Polymers Advanced Coatings Research Center of Ministry of Education of China Fudan University Shanghai200433 China International Research Center for Marine Biosciences Ministry of Science and Technology Shanghai Ocean University Shanghai201306 China Marine Chemical Research Institute Co. Ltd. Qingdao266071 China

The current zwitterionic antifouling (AF) coatings generally have limited broad-spectrum AF ability, poor compatibility with coating matrixes and weak mechanical properties due to high water adsorption. In this work, we tried to incorporate zwitterionic component, namely, (N-methoxyacylethyl)-3-aminopropyltriethoxysilane (MAPS) and ZnO nanoparticles into a moisture-curable polyacrylate (MCP) to fabricate marine AF coatings. AF behaviors were examined by laboratory and field assays towards different target foulants. Laboratory anti-protein ability towards bovine serum albumin promoted with the increase of MAPS and/or ZnO content, verifying their synergistic AF effect towards the earliest pollutant in biofouling process. Laboratory AF test towards bacterium Pseudoalteromonas marina and diatom Cylindrotheca closterium also exhibited the synergistic AF effect between zwitterions and ZnO nanoparticles. But at high content of MAPS (i.e., 30%) or ZnO nanoparticles (i.e., 50%), their synergistic AF effect was not obvious. As for the marine field AF performance, the ZnO nanoparticles content had a significant effect on improving the field antibacterial ability, while the effect of MAPS was not obvious. But for the field anti-diatom assay, MAPS and ZnO nanoparticles depicted synergistic effect on diatom resistance. After field exposure for 52 d, the highest field bacteria and diatom reduction were 85.5% and 95.9%, respectively. In addition to the AF performance, the coatings also possessed good mechanical properties, which provided a basis for their applications in underwater robot-cleaning techniques. © 2023, The Authors. All rights reserved.

关键词： ZnO nanoparticles

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Pd Ensemble Sites Tuned Local Environment of Cu Catalysts for Matching Propyne Semi-Hydrogenation

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Angewandte Chemie 2025年

作者： Kelin Yan Dr. Xiaohu Ge Dr. Yueqiang Cao Qiang Yuwen Prof. Jing Zhang Prof. Sheng Dai Prof. Gang Qian Prof. De Chen Prof. Xinggui Zhou Prof. Weikang Yuan Prof. Xuezhi Duan State Key Laboratory of Chemical Engineering School of Chemical Engineering East China University of Science and Technology Shanghai 200237 China Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering Feringa Nobel Prize Scientist Joint Research Centre School of Chemistry and Molecular Engineering East China University of Science and Technology Shanghai 200237 China Department of Chemical Engineering Norwegian University of Science and Technology Trondheim 7491 Norway

Tailoring local environments of active sites to match targeted configuration of key species is significant for controlling reaction pathways in selective hydrogenations. Herein, differently typed Pd sites are introduced onto Cu catalysts to tune the local environment of Cu sites for controlling the configuration of semi-hydrogenation pathway of propyne hydrogenation used in production of polymer-grade propylene. Detailed structure characterizations demonstrate the controllable construction of Pd single-atom and Pd ensemble sites modified Cu surfaces and PdCu alloy via fine tuning the Pd/Cu ratios. Catalytic tests, kinetics analysis, and temperature-programmed experiments demonstrate that the presence of Pd ensemble sites on Cu surface directly catalyzes the hydrogenation of propyne that occurs on the Cu sites in other cases, and enables a facile activation for hydrogen and simultaneously promotes the desorption of propylene against its hydrogenation. Accordingly, the selectivity to target propylene is up to 95.3% at the full conversion of propyne on the corresponding Pd 0.1 Cu catalyst. In contrast, the C─C coupling pathway is quite facile on the Cu surface tuned by single-atom Pd sites, which is similar to that on the pristine Cu sites on the Cu catalyst, and the well-defined Pd─Cu coordination on PdCu alloy catalyst leads to facile over-hydrogenation process.

关键词： Configuration Ensemble sites Local environment Propyne semi-hydrogenation Reaction pathway

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Novel Biodegradable Ca–P/Ti–F Composite Conversion Coatings for Improving the Corrosion Resistance of Medical Magnesium materials

SSRN

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SSRN 2024年

作者： Sun, Ying-Sui Chu, Peng-Wei Cheng, An-Yu You, Jhu-Lin Chang, Tsung-Ming Jian, Shun-Yi Chi, Chun-Shang Liu, Yu-Cheng Chang, Chin-Jou School of Dental Technology College of Oral Medicine Taipei Medical University Taipei Taiwan Department of Engineering and System Science National Tsing Hua University Hsinchu300044 Taiwan Department of Chemical & Materials Engineering Chung Cheng Institute of Technology National Defense University Taoyuan335 Taiwan System Engineering and Technology Program National Chiao Tung University Hsinchu300 Taiwan Department of Material Engineering Ming Chi University of Technology New Taipei City24301 Taiwan Center for Plasma and Thin Film Technology Ming Chi University of Technology New Taipei243303 Taiwan Combination Medical Device Technology Division Medical Devices R&D Service Department Metal Industries Research & Development Centre Kaohsiung802 Taiwan

Mg and its alloys are characterized by favorable biocompatibility and nontoxicity, and these properties have stimulated considerable research interest in their application as degradable biomaterials for medical implants. However, the clinical application of these materials is restricted by their rapid degradation. Therefore, this study designed a surface modification method for Mg and Mg alloys to enable them to satisfy clinical requirements. A two-step conversion coating method was applied to pure Mg. Pure Mg samples were first coated with calcium phosphate (Ca–P), following which they were coated with titanium fluoride (Ti–F), resulting in the production of Mg samples coated with a bioactive Ca–P/Ti–F composite. The composition of the coated samples was investigated through energy-dispersive X-ray spectroscopy with transmission electron microscopy, and their morphology was characterized through scanning electron microscopy. Moreover, hydrogen evolution measurements in simulated body fluid (SBF), electrochemical impedance spectroscopy, and polarization curves were employed to evaluate the samples’ corrosion resistance. The prepared composite conversion coatings had an average thickness of approximately 350 nm, and their corroded area was less than 5% of their total area following their immersion in SBF for 72 h. Thus, the prepared Ca–P/Ti–F composite conversion coatings effectively inhibited Mg corrosion in SBF. Moreover, the attachment and differentiation of MG-63 cells on the prepared coatings were observed. © 2024, The Authors. All rights reserved.

关键词： Energy dispersive spectroscopy

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