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Fabrication of graphene oxide decorated with poly(dimethyl amino ethyl methacrylate) brush for efficient Cr(Ⅵ) adsorption from aqueous solution

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Chinese Journal of chemical engineering 2024年第9期73卷 51-61页

作者： Alireza Nouri Siew Fen Chua Ebrahim Mahmoudi Abdul Wahab Mohammad Wei Lun Ang Department of Chemical and Process Engineering Faculty of Engineering and Built EnvironmentUniversiti Kebangsaan MalaysiaBangi 43600Malaysia Centre for Sustainable Process Technology(CESPRO) Faculty of Engineering and Built EnvironmentUniversiti Kebangsaan MalaysiaBangi 43600Malaysia Chemical and Water Desalination Engineering Program College of EngineeringUniversity of SharjahSharjah 27272United Arab Emirates

Confronting the severe health threats and environmental impacts of Cr(Ⅵ) in aquatic environments demands innovative and effective remediation approaches. In this study, Graphene oxide(GO)-decorated poly(dimethyl amino ethyl methacrylate)(PDMAEMA) brush nanocomposites(GOP1, GOP2, GOP3, and GOP4) were fabricated using atom transfer radical polymerization(ATRP) by the “graft from” *** resulting nanocomposites were utilized for removing Cr(Ⅵ) with good adsorption performance due to the electrostatic interaction of protonated nitrogen groups in the brush chains with negatively charged particles in the solution. The kinetic model of pseudo-second-order best represented the contaminants' adsorption characteristics. The Weber-Morris model further indicated that surface adsorption and intraparticle diffusion mechanisms primarily controlled the adsorption procedure. Additionally, the Langmuir and Temkin isotherm models were found to most accurately represent the adsorption characteristics of the pollutants on the nanocomposites, and GOP4 can achieve the maximum adsorption capacity of 164.4 mg·g^(-1). The adsorbents' capacity maintains above 85% after five cycles of adsorption-desorption. The nanocomposites in this study demonstrate promising potential for eliminating Cr(Ⅵ) from aqueous solutions.

关键词： Graphene oxide PDMAEMA brush Polymerization Nanoparticles Adsorption Chromium

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Improving the Thermo-Physical Properties of Plam Oil with Zeolite Nanoparticles

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Defect and Diffusion Forum 2024年 432卷 115-120页

作者： Assawasaengrat, Pornsawan Limsakul, Thanasuta Bunprasert, Penpichcha Chokelarb, Wasan Sriprom, Pongsert Department of Chemical Engineering School of Engineering King Mongkut's Institute of Technology Ladkrabang Bangkok Thailand Program of Food Process Engineering School of Food Industry King Mongkut's Institute of Technology Ladkrabang Bangkok Thailand

This research aimed to improve the thermo-physical properties of plam oil with NaA zeolite. Palm oil was selected for heating oil due to its high flash point and environmental friendliness compared to synthetic or mineral oil. The effect of NaA zeolite concentration suspended in palm oil was investigated in terms of the specific heat capacity (Cp), viscosity (μ), viscosity index (VI), thermal analysis (TGA) and density (ρ) of palm oil. The NaA zeolite was synthesized by crystallization technique, and X-ray diffraction analysis was performed to determine NaA zeolite crystallinity. The size of NaA zeolite was measured using a particle size analyzer. The average size of the synthesized NaA zeolite was 4767 nm. After grinding process for 180 min, the average size of zeolite decreased to 632 nm. An average 632 nm NaA zeolite particle size was added to palm oil at 0.25, 0.5, 0.75 and 1 wt%. The results showed that when the NaA zeolite concentration increased, the nanofluid’s viscosity at 40 °C and 100 °C was increased. The addition of 1 wt% NaA zeolite resulted in the nanofluid having a maximum viscosity of 41.31 and 8.47 cSt at 40 °C and 100 °C, respectively. The highest viscosity index was 195 cSt when added with 0.5 wt% NaA zeolite. The density of palm oil slightly increased with increasing NaA zeolite concentrations. The specific heat capacity of palm oil increased when NaA zeolite was added. The results showed that NaA zeolite allowed palm oil to store heat energy better than palm oil, enabling it to release and absorb more heat during heat transfer. Thermogravimetric analysis, palm oil initiated to degrade at 263 °C, while the addition NaA zeolite in palm oil indicated that palm oil initiated to degrade at 350 °C. The shift in the degradation curve demonstrated that the nanofluid could withstand high temperatures. Adding NaA zeolite to palm oil showed that palm oil could endure more heat and has a long service life. © 2024 Trans Tech Publications Ltd, Switzerland.

关键词： Palm oil

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Enhanced peroxi-coagulation process for the treatment of anaerobically-treated palm oil mill effluent (POME)

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Journal of Industrial and engineering Chemistry 2025年 149卷 859-874页

作者： Ismail, Saiyidah Anisah Ang, Wei Lun Mahmoudi, Ebrahim Mohammad, Abdul Wahab Wong, Wai Yin Department of Chemical and Process Engineering Faculty of Engineering and Built Environment Universiti Kebangsaan Malaysia Selangor Bangi43600 Malaysia Chemical and Water Desalination Engineering Program College of Engineering University of Sharjah Sharjah27272 United Arab Emirates Fuel Cell Institute Universiti Kebangsaan Malaysia Selangor Bangi43600 Malaysia

This study investigated the effectiveness of the peroxi-coagulation (PC) process in removing dissolved organic impurities from palm oil mill effluent (POME). Key experimental parameters assessed in this study included wastewater pH, electrolysis duration, and the dosage of H2O2. After a five-hour treatment period, maximum breakdown of organic contaminants and removal of suspended particles were achieved, with around 86 % of soluble COD (SCOD), 91 % of total COD (TCOD), 99 % of true colour, and 84 % of turbidity were removed under optimal operating conditions (pH 3 and external dosing of 31.09 mM H2O2). These outcomes can be attributed to two removal mechanisms: the predominant Fenton oxidation reaction at low pH which promoted effective •OH generation from the dosed H2O2, and the simultaneous coagulation activity by the electrochemically produced Fe(OH)3 coagulant. This PC process was governed by the pseudo-first-order kinetic model, which achieved a maximum kinetic rate of 0.5321 min−1 under ideal operating conditions. The estimated energy consumption for POME degradation ranged from 0.461 to 1.874 kWh per kg of COD reduced, indicating low electrical energy intake. These findings demonstrate the potential of the PC process as a pre- or post- treatment step that can enhance the removal of COD and pigmentation in integrated POME treatment systems. © 2025 The Korean Society of Industrial and engineering Chemistry

关键词： Coagulation

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Production and characterization of polymeric nanocomposite foams based on starch and cellulose nanofibers from oil palm mesocarp fiber

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Applied Nanoscience (Switzerland) 2025年第2期15卷 1-11页

作者： Souza, Mariana Costa Gonçalves, Ana Paula Bispo da Silva Oliveira, Emanoel Igor dos Santos, Juscivaldo Passos Lazzari, Lídia Kunz Zattera, Ademir José José, Nadia Mamede Chemical Engineering Graduate Program Polytechnic School Federal University of Bahia Bahia Salvador Brazil Department of Education Federal Institute of Education Science and Technology Feira de Santana Bahia Brazil Postgraduate Program in Process Engineering and Technologies University of Caxias Do Sul Rio Grande Do Sul Caxias Do Sul Brazil

The demand for sustainable and eco-friendly materials has promoted studies over the years to explore different polymeric materials that meet requirements such as biodegradability and sustainability. In this context, biopolymer materials based on cellulose nanoparticles and starch from different botanical sources have been investigated, aiming to achieve satisfactory performance. The present study aims to develop and characterize cassava starch foams based on density, scanning electron microscopy (SEM), and three-point flexure tests, and to evaluate the effect of cellulose nanofibers obtained from palm mesocarp fibers using the ultrafine friction grinding method after different processing times, characterized by X-ray diffractometry (XRD), microscopy, and chemical composition, as a reinforcing filler. The chemical composition and scanning electron microscopy revealed the effectiveness of the cellulose isolation process, with the analysis of the chemical composition revealing a cellulose content of 55.70% in the fibers after pulping and bleaching, in addition to changes in the visual characteristics of the material after the process aimed at isolating the cellulose. After grinding, XRD showed an increase in crystallinity (76.1% at the maximum grinding time), along with typical microscopy images of cellulose nanofibers. The analysis of the obtained nanocomposites provided insights into the role of these nanostructures in the thermo-expanded starch matrix, indicating that the nanofibers promoted changes such as an increase in mechanical properties and crystallinity, which contributed to improving overall mechanical performance. A 67.48% increase in flexural strength was achieved for the formulation with cellulose nanofibers that underwent 150 min of grinding, without causing major variations in density. © King Abdulaziz City for Science and Technology 2025.

关键词： Starch

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MXene:From synthesis to environment remediation

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Chinese Journal of chemical engineering 2023年第9期61卷 260-280页

作者： Ali Nikkhah Hasan Nikkhah Hadis langari Alireza Nouri Abdul Wahab Mohammad Ang Wei Lun Ng law Yong Rosiah Rohani Ebrahim Mahmoudi Department of Chemical and Process Engineering Faculty of Engineering and Built EnvironmentUniversiti Kebangsaan MalaysiaBangi 43600Malaysia Department of Mechanical and Aerospace Engineering University at BuffaloBuffaloUSA Department of Chemical and Biomolecular Engineering University of ConnecticutStorrsUSA Department of Chemistry and Medicinal Chemistry University at BuffaloBuffaloUSA Chemical and Water Desalination Engineering Program College of EngineeringUniversity of SharjahSharjah 27272United Arab Emirates Lee Kong Chian Faculty of Engineering and Science Universiti Tunku Abdul RahmanJalan Sungai LongBandar Sungai LongKajangSelangorMalaysia

A new burgeoning family of two-dimensional(2D)transition metal carbides/nitrides,better known as MXenes,have received extensive attention because of their distinct properties,such as metallic conductivity,good hydrophilicity,large surface area,good mechanical stability,and *** 40 different MXenes have been synthesized,and dozens more structures and properties have been theoretically ***,the recent progress in MXenes development is not well covered in chronological order based on different *** review article focuses on emerging synthesis methods,the properties of MXenes,and mainly the applications of MXenes and MXene-based material family in environmental remediation,a comprehensive review of gaseous and aqueous pollutants treatment.

关键词： MXene 2D materials Wastewater treatment CO_(2)capture Adsorption Photodegradation

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Transient CFD Simulation of Vortex Formation in a Stirred Multiphase Flow 6th

Transient CFD Simulation of Vortex Formation in a Stirred Mu...

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6th Multiphase Flow Journey, JEM 2021

作者： Nogueira, André Lourenço Department of Chemical Engineering and Post-Graduation Program in Process Engineering University of the Region of Joinville UNIVILLE Joinville89219-710 Brazil

ISBN: (纸本)9783030934552

The present study simulated the dynamic behavior of the water–air interface in a cylindrical tank stirred mechanically. CFD techniques were applied using the software ANSYS-Fluent. The Volume of Fluid (VOF) model with explicit formulation coupled to the κ - ω SST turbulence model was employed to numerically represent the transient displacement of the water–air interface starting from a situation of stagnated flow. An isothermal operation was considered for the case studied. A simple experimental apparatus composed of a glass vessel filled with dyed water and a mechanical stirrer with a pitched-bladed impeller was used to generate the experimental data of the interface position along the time. The model accuracy was evaluated at stirring rates of 300 and 400 RPM. According to the results, the geometric shape profile of the vortex at the pseudo-stationary state could be reasonably well reproduced by the model. However, the model could not generate accurate results regarding the transient behavior of the vortex formation. Additional strategies should be tested to enhance the model capability to reproduce the transient displacement of the water–air interface due to the rotational flow. © 2022, The Author(s), under exclusive license to Springer Nature Switzerland AG.

关键词： Computational fluid dynamics Stirred tank Two-phase interface

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Investigating CO_(2) electro-reduction mechanisms:DFT insight into earth-abundant Mn diimine catalysts for CO_(2) conversions over hydrogen evolution reaction,feasibility,and selectivity considerations

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Frontiers of chemical Science and engineering 2024年第12期18卷 117-129页

作者： Murugesan Panneerselvam Marcelo Albuquerque Iuri Soter Viana Segtovich Frederico W.Tavares Luciano T.Costa MolMod-CS-Institute of Chemistry Fluminense Federal UniversityValonginho CampusCentroNiteroi 24020-14Rio de JaneiroBrazil Chemical Engineering Program(PEQ/COPPE) Federal University of Rio de Janeiro(UFRJ)Moniz AragaoRio de Janeiro21941-594RJBrazil Institute of Physics Fluminense Federal UniversityPraia Vermelha CampusGragoataNiteroiRio de JaneiroBrazil Chemical and Biochemical Process Engineering School of ChemistryFederal University of Rio de JaneiroRio de Janeiro 21941Brazil

This study investigates the detailed mechanism of CO_(2) conversion to CO using the manganese(I) diimine electrocatalyst [Mn(pyrox)(CO)3Br], synthesized by Christoph Steinlechner and coworkers. Employing density functional theory calculations, we thoroughly explore the electrocatalytic pathway of CO_(2) reduction alongside the competing hydrogen evolution reaction. Our analysis reveals the significant role of diimine nitrogen coordination in enhancing the electron density of the Mn center, thereby favoring both CO_(2) reduction and hydrogen evolution reaction thermodynamically. Furthermore, we observe that triethanolamine (TEOA) stabilizes transition states, aiding in CO_(2) fixation and reduction. The critical steps influencing the reaction rate involve breaking the MnC(O)–OH bond during CO_(2) reduction and cleaving the MnH–H–TEOA bond in the hydrogen evolution reaction. We explain the preference for CO_(2) conversion to CO over H_(2) evolution due to the higher energy barrier in forming the Mn-H_(2) species during H_(2) production. Our findings suggest the potential for tuning the electron density of the Mn center to enhance reactivity and selectivity in CO_(2) reduction. Additionally, we analyze potential competing reactions, focusing on electrocatalytic processes for CO_(2) reduction and evaluating “protonation-first” and “reduction-first” pathways through density functional theory calculations of redox potentials and Gibbs free energies. This analysis indicates the predominance of the “reduction-first” pathway in CO production, especially under high applied potential conditions. Moreover, our research highlights the selectivity of [Mn(pyrox)(CO)3Br] toward CO production over HCOO– and H_(2) formation, proposing avenues for future research to expand upon these findings by using larger basis sets and exploring additional functionalized ligands.

关键词： manganese carbonyl complex CO_(2)reduction reaction hydrogen evolution reaction selectivity density functional theory studies

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Influence of dope composition of polyethersulfone membrane blend with cellulose nanocrystal and carboxylated multi-walled carbon nanotube on humic acid rejection

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Materials Today: Proceedings 2024年 107卷 53-58页

作者： Nor Azura C. Mahmud Mazrul Nizam Abu Seman Mohd Sobri Takriff Wei Lun Ang Syed M. Saufi Faculty of Chemical and Process Engineering Technology Universiti Malaysia Pahang Lebuhraya Persiaran Tun Khalil Yaakob 26300 Gambang Kuantan Pahang Malaysia Chemical and Water Desalination Engineering Program College of Engineering University of Sharjah United Arab Emirates Department of Chemical & Process Engineering Faculty of Engineering & Built Environment Universiti Kebangsaan Malaysia 43600 Bangi Selangor Malaysia

A full factorial experimental design was employed to investigate the dope composition of a membrane made of cellulose nanocrystal (CNC), multi-walled carbon nanotube (MWCNT), and polyethersulfone (PES) for its ability to reject humic acid (HA). Four factors were screened, including PES composition, polyvinylpyrrolidone content, CNC content, and carboxylated MWCNT content. The membranes were tested for HA rejection using a 10-ppm aqueous feed solution. The results indicated that the percentage of MWCNT had the most significant impact, contributing 72.31% to the overall contribution. The fabricated membranes exhibited high HA removal capacity of up to 90% for the membrane embedded with MWCNT. The model's predicted values agreed reasonably with the experimental data, indicating the model's validity. This study provides insights into the development of CNC/MWCNT/PES membranes for efficient HA rejection in water treatment applications.

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Influence of dope composition of polyethersulfone membrane blend with cellulose nanocrystal and carboxylated multi-walled carbon nanotube on humic acid rejection 6

Influence of dope composition of polyethersulfone membrane b...

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6th National Conference on Postgraduate Research, NCON-PGR 2022

作者： Mahmud, Nor Azura C. Abu Seman, Mazrul Nizam Takriff, Mohd Sobri Ang, Wei Lun Saufi, Syed M. Faculty of Chemical and Process Engineering Technology Universiti Malaysia Pahang Lebuhraya Persiaran Tun Khalil Yaakob Gambang Kuantan Pahang26300 Malaysia Chemical and Water Desalination Engineering Program College of Engineering United Arab Emirates Department of Chemical & Process Engineering Faculty of Engineering & Built Environment Universiti Kebangsaan Malaysia Selangor Bangi43600 Malaysia

关键词： Nanoclay

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Development of Supported Catalyst for Hydrogen Production from Sodium Borohydride

Development of Supported Catalyst for Hydrogen Production fr...

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2024 IEEE Global Energy Conference, GEC 2024

作者： Sayilgan, Ahmet Onat, Erhan Ekinci, Selma Izgi, Mehmet Sait Tatvan Vocational School Electricity and Energy Program Bitlis Eren University Bitlis Turkey Organized Industrial Zone Vocational School Electricity and Energy Program Bitlis Eren University Bitlis Turkey Vocational School of Technical Sciences Department of Chemistry and Chemical Process Technology Batman University Batman Turkey Faculty of Engineering Architecture Siirt University Siirt Turkey

ISBN: (纸本)9798331532611

The best solution to the problems caused by fossil fuels and the limitations of renewable energy sources is the conversion of hydrogen into energy in fuel cells. The transportation and storage problems, which are the main obstacles to the conversion of hydrogen into energy in fuel cells, can be overcome by storing hydrogen in boron compounds. The recovery of hydrogen stored in boron compounds when needed is carried out through catalytic processes. In this study, a supported catalyst was synthesized for use in hydrogen production from sodium borohydride (SBH), which is one of the main boron compounds used in the solid storage of hydrogen, and the dehydrogenation parameters of the synthesized catalyst were investigated. In this context, chenopodium botrys plant extract was used as a support material for nickel (Ni) metal atoms. At the end of the extraction carried out through a hydrothermal process, Ni atoms were decorated using the impregnation method in the extract, and the Ni@KBHE catalyst was produced via reduction under SBH. After the washing, filtration, and drying processes were carried out under a nitrogen atmosphere, the solution medium, catalyst amount, SBH concentration, and temperature parameters of SBH hydrolysis with the crumbled catalyst were optimized. Optimum values for hydrogen production were obtained using 5% NaOH, 60 mg of catalyst, and 2% SBH. The hydrogen production rate (HGR) at these values was 4664 mL/g min. As a result of the catalytic reaction kinetic calculations, it was determined that the reaction was nth order, and the reaction activation energy was 49.4 kJ/mol. ©2024 IEEE.

关键词： Activation energy

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