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Corrosion behavior of Gd_(2)Zr_(2)O_(7)thermal barrier coatings under Fe-containing environmental sediment attack

Journal of advanced Ceramics 2024年第4期13卷 447-462页

作者： Lei Guo Yanyan Li Kai Yan School of Materials Science and Engineering Tianjin UniversityTianjin 300072China Tianjin Key Laboratory of Advanced Joining Technology Key Lab of Advanced Ceramics and Machining Technology of Ministry of EducationTianjin 300072China Key Laboratory of Special Equipment Safety and Energy-saving for State Market Regulation China Special Equipment Inspection&Research InstituteBeijing 100029China

Environmental sediments mainly consisting of CaO–MgO–Al_(2)O_(3)–SiO_(2)(CMAS)corrosion are a serious threat to thermal barrier coatings(TBCs),in which Fe element is usually ***_(2)Zr_(2)O_(7)TBCs are famous for their excellent CMAS *** this study,the characteristics of Fe-containing environmental sediments(CMAS-Fe)and their corrosiveness to Gd_(2)Zr_(2)O_(7)coatings were *** types of CMAS-Fe glass with different Fe contents were *** melting points were measured to be 1322–1344℃,and the high-temperature viscosity showed a decreasing trend with increasing Fe *** corrosion behavior of four types of CMAS-Fe to Gd_(2)Zr_(2)O_(7)coatings at 1350℃was *** the initial corrosion stage(0.1 h),anorthite was precipitated in CMAS-Fe with a high Ca:Si ratio,while Fe-garnet was formed in the melt with the highest Fe *** the corrosion time resulted in the formation of a reaction layer,which exhibited an interpenetrating network composed of Gd-oxyapatite,ZrO_(2),and residual *** spinel was precipitated within the reaction *** 1 h or even longer time,the reaction layers tended to be stable and compact,which had comparable hardness and fracture toughness to those of Gd_(2)Zr_(2)O_(7)*** the cyclic CMAS-Fe attack,the residual CMAS-Fe in the interpenetrating network provided a pathway for the redeposited CMAS-Fe infiltration,resulting in the continuous growth of the reaction *** a result,the Gd_(2)Zr_(2)O_(7)coatings had a large consumption in the thickness,degrading the coating ***,the Gd_(2)Zr_(2)O_(7)coatings exhibit unsatisfactory corrosion resistance to CMAS-Fe attack.

关键词： thermal barrier coatings(TBCs) Gd_(2)Zr_(2)O_(7) Fe-containing CaO-MgO-Al2O3-SiO_(2)(CMAS) corrosion resistance reaction layer

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Coordinated Optimization of Multi-energy Generation Systems Considering the Health Damages of Coal-fired Pollutant Dispersion

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CSEE Journal of Power and Energy Systems 2022年第6期8卷 1613-1622页

作者： Suhua Lou Yinhao Yang Yanjie Liang Yaowu Wu State Key Laboratory of Advanced Electromagnetic Engineering and Technology Huazhong University of Science and TechnologyWuhan 430074China Power Dispatch and Control Center of China Southern Power Grid Guangzhou 510623China

Pollutants emitted from coal-fired power plants lead to the deterioration of air quality in developing countries,and contribute to both mortality and *** improve air quality from power generation,new dispatch strategies incorporated with air pollution dispersion models should be *** paper takes into account the impact of meteorological variations on spatio-temporal dispersion of *** on the coal-fired pollutant concentration estimated by the Gaussian plume dispersion model,exposure-response functions are used to quantify the resulting health ***,the corresponding economic costs of health damages are incorporated to penalize the power *** generation costs and economic costs of health damages,this paper formulates a twostage stochastic optimization model of a multi-energy generation system including coal units,gas units,and photovoltaic ***,numerical studies based on a modified IEEE 14-node system are performed for illustration and validation.

关键词： Coal-fired pollutant dispersion exposure-response functions Gaussian plume model meteorological variations multi-energy generation system

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Research on an Optimal Design of DSOGI-PLL Based on Complex Power Grid 2

Research on an Optimal Design of DSOGI-PLL Based on Complex ...

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2nd Power Electronics and Power System Conference, PEPSC 2024

作者： Ye, Zhengyang Dai, Yufeng Cao, Tiantian Xu, Jiaxin Wu, Qiong Li, Dayi State Key Laboratory of Advance Electromagnetic Engineering and Technology Huazhong University of Science and Technology Wuhan China

ISBN: (纸本)9798350390193

The complexity of modern power systems, attributed to electronic integration and nonlinear loads, intensifies harmonic pollution and power quality problems. Effective management necessitates real-time detection of the grid phase and frequency utilizing PLLs. The dual second-order generalized integrator phase-locked loop (DSOGI-PLL), renowned for its minimal overshoot and delay, lacks adequate filtering capacity in complex grids and is sensitive to DC components. This paper optimizes the SOGI within the traditional DSOGI-PLL, enhancing its resistance to high and low frequency interference. Additionally, a Double Cascade Optimized Sliding Average Filter (DCO-MAF) based on the Moving Average Filter (MAF) is introduced to eliminate grid harmonics with minimal delay, enabling swift and accurate PLL synchronization. Simulation results employing MATLAB/Simulink demonstrate that the optimized design significantly outperforms the traditional DSOGI-PLL in conditions with DC offsets or harmonics, showcasing its robustness and effectiveness. © 2024 IEEE.

关键词： Phase locked loops

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Relationships of Internal Voltage Dependence on Power Imbalance Illustrating Characteristics and Roles in System Dynamics of Inertial-Controlled DFIG-based Wind Turbines

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CSEE Journal of Power and Energy Systems 2022年第3期11卷 1107-1117页

作者： Wan, Minhui Yuan, Xiaoming Hu, Jiabing The State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic Engineering Huazhong University of Science and Technology Wuhan430074 China

Frequency and voltage dynamics, as the focus of power systems, depends more and more on the frequency and amplitude response characteristics of renewable energy devices being subjected to power imbalance. Doubly-fed induction generator (DFIG)-based wind turbine (WT) is representative of renewable energy devices and shows different characteristics from those of conventional synchronous generator (SG). Unfortunately, the individual characteristics ofWT during system frequency and voltage dynamics are not intuitively illustrated by the existing structure-oriented models. Therefore, this paper aims to propose a function-oriented modeling methodology by representing inertia-controlled DFIG-based WT as internal voltage frequency and amplitude solely stimulated by active and reactive power imbalance. The individuality of characteristics is demonstrated that with grid voltage detection-based controls the internal voltage depends yet solely on power imbalance of WT, just like the case of SG. Through the infinity gain equivalence of the fast-electromagnetic loops, a simplified analytical model illustrating the electromechanical characteristics ofWT is further proposed. Based on the model, the similarities and differences between the characteristics of WT and SG are recognized. Simulation results for verification are also presented. © 2022 china Electric Power Research Institute. All rights reserved.

关键词： Wind turbines

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Three-dimensional fracture of UO_(2)ceramic pellets by phase field modeling

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Science china(Physics,Mechanics & Astronomy) 2025年第1期68卷 165-176页

作者： Wei Xiong Xuan Ye Hongzhang Cheng Xiaoming Liu Institute of Nuclear and New Energy Technology Collaborative Innovation Center of Advanced Nuclear Energy TechnologyKey Laboratory of Advanced Reactor Engineering and Safety of Ministry of EducationTsinghua UniversityBeijing 100084China State Key Laboratory of Nonlinear Mechanics Institute of MechanicsChinese Academy of SciencesBeijing 100190China School of Engineering Science University of Chinese Academy of SciencesBeijing 100049China

Fracture is the primary failure type for the UO_(2)ceramic pellets,which are operated under irradiation and thermal processes,and physically confined by the *** this work,by combining closely coupled physical processes of heat conduction,heat transfer,and mechanical deformation with the cohesive phase field framework,we proposed a high-precision modeling of quasistatic cracking of three-dimensional(3D)UO_(2)ceramic fuel pellets under high temperature and *** simulation results agree well with the experimental results,indicating that the proposed method has the potential to capture 3D crack modes in the interested time ***,we studied the relation of the 3D fracture patterns of fuel pellets with the peak power *** was found that the power level plays a critical role in determining the competition between radial and circumferential cracks,as well as transverse penetrating cracks.

关键词： phase field method nuclear fuel pellet coupled thermo-mechanical model thermal fracture

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In situ construction of Cu(Ⅰ)-Cu(Ⅱ) pairs for efficient electrocatalytic nitrate reduction reaction to ammonia

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Journal of Energy Chemistry 2025年第1期100卷 106-113页

作者： Muyun Zheng Yuchi Wan Leping Yang Shen Ao Wangyang Fu Zhengjun Zhang Zheng-Hong Huang Tao Ling Feiyu Kang Ruitao Lv State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China Institute of New Energy Materials and Engineering School of Materials Science and EngineeringFuzhou UniversityFuzhou 350108FujianChina Key Laboratory of Advanced Materials(MOE) School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education Tianjin Key Laboratory of Composite and Functional MaterialsSchool of Materials Science and EngineeringTianjin UniversityTianjin 300072China

Electrocatalytic nitrate reduction reaction (NO_(3)-RR) to ammonia under ambient conditions is expected to be a green process for ammonia synthesis and alleviate water pollution *** report a CuO nanoparticles incorporated on nitrogen-doped porous carbon (CuO@NC) catalyst for NO_(3)-*** of Cu(Ⅱ) is reduced to Cu(Ⅰ) during the NO_(3)-RR process to construct Cu(Ⅰ)-Cu(Ⅱ) pairs,confirmed by in situ X-ray photoelectron spectroscopy (XPS) and Raman *** functional theory (DFT) calculations indicated that the formation of Cu(Ⅰ) could provide a reaction path with smaller energy barrier for NO_(3)-RR,while Cu(Ⅱ) effectively suppressed the competition of hydrogen evolution reaction (HER).As a result,CuO@NC catalyst achieved a Faradaic efficiency of 84.2% at -0.49 V versus reversible hydrogen electrode (RHE),and a NH_(3)yield rate of 17.2 mg h^(-1)mg^(-1)*** -0.79 V ***,higher than the HaberBosch process (<3.4 g h^(-1)g^(-1)cat.).This work may open a new avenue for effective NO_(3)-RR by modulating oxidation states.

关键词： Ammonia synthesis Cu oxidation state Electrochemistry Nitrate reduction In situ XPS

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Charge regulation by ferromagnetic metal/LiF spin-polarized interface for high-performance Li metal anodes

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Rare Metals 2024年第3期43卷 995-1005页

作者： Ming-Yang Feng Shuang Zhou Yi-Fang Zhang Ya-Ping Wang Chun-Yan Fu Jian-Wen Li Yuan-Lang Wan Zhi-Jia Zhang Yong Jiang An-Qiang Pan State Key Laboratory of Powder Metallurgy School of Materials Science and EngineeringCentral South UniversityChangsha410083China State Key Laboratory of Separation Membranes and Membrane Processes Tianjin Key Laboratory of Advanced Fibers and Energy StorageSchool of Material Science and EngineeringTiangong UniversityTianjin300387China School of Materials Science and Engineering Hebei University of TechnologyTianjin300130China

The interfacial characteristics of the Li metal anode(LMA)play a crucial role in its overall *** various materials being applied to modify the interface,a comprehensive understanding of their specific mechanisms remains to be ***,we have prepared carbon cloth(CC)frameworks with their surfaces modified using ferromagnetic metal/LiF heterogeneous films(T^(M)-LiF-CC)as the substrate for LMA,which exhibit superior electrochemical *** ferromagnetic Co as a representative example,our study demonstrates that the enhanced performance of Co-LiF-CC,compared to bare CC,is attributed to the spinpolarized interface contributed by the Co/LiF *** and LiF play individual roles in redistributing electrons and Li^(+)to promote homogeneous Li *** nanoparticles play a crucial role in generating strong surface capacitance by storing electrons in spin-split bands,while LiF,with low surface diffusion barriers,ensures fast transportation of Li^(+).The Co-LiF-CC@Li electrodes deliver long lives of 7400 and 3600 h at 1 and 2 mA·cm^(-2)in symmetric cells,respectively;moreover,they enable full batteries with high and durable capacities,particularly when the N/P ratios are low(3.3 or even 1.7).

关键词： Lithium metal anode Interfacial charge Ferromagnetic metal Lithium fluoride Spin polarization

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The impact of the coupling relationship between projectile size and yarn dimension on the ballistic performance of plain weave fabric

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Defence technology(防务技术) 2025年第1期43卷 288-303页

作者： Kaiying Wang Xuan Zhou Wenke Ren Yiding Wu Yilei Yu Yi Zhou Lizhi Xu Guangfa Gao School of Mechanical Engineering Nanjing University of Science and TechnologyNanjing210094China State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan430079China

Aramid fibers,due to their relatively high inter-yarn friction,high strength,high modulus,and other characteristics,have become a typical representative of flexible anti-ballistic materials in modern *** research on the anti-penetration of aramid fabrics mostly focuses unilaterally on the structure and performance of aramid fabrics or the shape and size of projectiles,with fewer studies on the coupled effect of both on ballistic *** study analyzes how the coupling relationship(or size effect)between the projectile and fiber bundle dimensions affects the fabric ballistic performance from a mesoscopic scale *** plain weave aramid fabric as the research object,considering different diameter projectiles,through a large number of ballistic impact tests and numerical simulations,parameters such as ballistic limit velocity,average energy absorption of fabric,and specific energy absorption ratio(average energy absorption of fabric divided by projectile cross-sectional area)are obtained for ballistic performance *** influence law of projectile size on the ballistic performance of high-performance fabrics is as follows:The relative range of fitted ballistic limit velocity at different target positions gradually decreases and then stabilizes as the projectile diameter increases,indicating that the fabric structure effect gradually disappears at a projectile diameter of 12 mm;The average ballistic limit velocity at three impact positions,P1,P2,and P3,provides the corresponding ballistic limit velocity for 1000D aramid fabric,which increases with projectile diameter but the rate of increase slows down at an inflection point,which in this study occurs where the fabric structure effect nearly disappears at a projectile diameter of 12 mm;The energy absorption ratio increases and then decreases as the projectile diameter increases from 4 mm to 20 mm,reaching a peak at the diameter of 12 mm due to the gradual disappearance of the fabri

关键词： Plain weave fabric Ballistic performance Aramid fiber Projectile size Ballistic experiment

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The Effect of Nano-Cu Interconnection Materials on the Thermomechanical Properties of SiC Double-Sided Power Modules

The Effect of Nano-Cu Interconnection Materials on the Therm...

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2024 International Exhibition and Conference for Power Electronics, Intelligent Motion, Renewable Energy and Energy Management, PCIM Europe 2024

作者： Wei, Suhang Liu, Jiaxin Lv, Weishan Chen, Cai Kang, Yong Wu, Yue He, Zhipeng State Key Laboratory of Advanced Electromagnetic Technology Huazhong University of Science and Technology China School of Mechanical Science and Engineering Huazhong University of Science and Technology China State Key Laboratory of HVDC Electric Power Research Institute CSG China

ISBN: (纸本)9783800762620

The high porosity and high coefficient of thermal expansion (CTE) of nano-silver limit its application in SiC double-sided power modules, and the easy electromigration of nano-silver reduces its reliability. Stress fluctuations and residual stress during the sintering process directly affect the yield limit and fatigue strength of the power module and determine the reliability of solder interconnection. Therefore, this paper uses nano-copper slurry with lower cost and better CTE matching as the interconnect material for SiC double-sided power modules to solve these problems. Through finite element simulation, we conducted thermo-mechanical stress simulations on three SiC double-sided power modules whose interconnect layer materials are nano-copper, nano-silver, and SAC305. The results show that during the sintering process, compared with nano-silver, the stress fluctuation of the three layers of nano-copper slurry is greatly reduced, and the average residual stress is reduced by 33.58%, 14.79%, and 37.22% respectively. The thin interconnect layer thickness of 50um makes the steady-state junction temperature of the nano-copper module lower and has a heat dissipation capability comparable to that of nano-silver. During the sintering heating and cooling processes, the overall average stress of the nano-copper module was 11.76% and 4.98% lower than that of the nano-silver module respectively, proving that nano-copper has an excellent ability to alleviate stress concentration and improve the reliability of SiC double-sided power modules. © VDE VERLAG GMBH · Berlin · Offenbach.

关键词： Sintering

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Effect of Particle Size on Silicon Nitride Ceramic Slurry by Stereolithography

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Journal of Wuhan University of technology(Materials Science) 2023年第3期38卷 514-519页

作者：汪春柳 ZHANG Jinyong 雷丽文 School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan 430070China

The effects of particle size,gradation and solid loading of silicon nitride (Si_(3)N_(4)) on the rheological behavior and curing properties of ceramic slurry are studied by stereolithography (SLA).The results show that the particle size of Si_(3)N_(4) powder has a signif icant influence on the rheological properties and stability of the *** m_(D50=1.3μm):m_(D50=2.3μm)=3:7,the slurry viscosity is low and the sedimentation is *** most important thing is that with the increase of the solid loading of the slurry,the viscosity of the slurry increases,the stability becomes higher,and the curing thickness *** curing thickness of Si_(3)N_(4) ceramic slurry with solid loading of 50 vol% can reach nearly 50μ*** above results finally show that the process optimizes the formulation of the slurry in rheological and curing properties.

关键词： silicon nitride stereolithography dispersion stability

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