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SSRN 2023年

作者： Santos, Diego Haltiery Rosa, Laura Pereira Alves, Cleidson Rosa Simão, Lisandro Arcaro, Sabrina Klegues Montedo, Oscar Rubem Raupp-Pereira, Fabiano Graduate Program in Materials Science and Engineering University of the Extreme South of Santa Catarina Criciúma88806-000 Brazil Department of Civil Engineering Federal Institute of Santa Catarina Criciúma88813-600 Brazil Research Group on Sustainability and Waste Management Postgraduate Program in Environmental Technology University of Ribeirão Preto Ribeirão Preto14096-900 Brazil Brazil

The growing disparity between the high extraction of natural resources and low use of waste as alternative mineral resources will aggravate the scarcity of natural reserves. Therefore, the current linear economy model must be converted to sustainable economic models, such as the circular economy. To achieve this transition, it is important that waste recovery strategies are implemented with a continuous search for solutions for these materials. Thus, this study investigates the waste from the processing of nepheline syenite stone, to promote its valorization as an alternative mineral resource. The classification, potentiality, quantity/viability and applicability (CPQvA) criteria are used as tools to aid decision-making for the waste valorization. The environmental, physical, chemical, morphological, and durability characteristics of nepheline syenite waste (NSW) are analyzed. The results showed evidence for the substitution of NSW for up to 100% of fine aggregates and 25% of Portland cement in civil construction. Furthermore, NSW yields recoveries of more than 90% of potassium for use in agriculture, and up to 70% of iron ore for use in steelworks. Therefore, the results indicate that NSW is viable for different applications, contributing to industrial symbiosis and a strategy for advancing the circular economy. © 2023, The Authors. All rights reserved.

关键词： Sustainable development

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Directional Sewage Sludge Transformation Using Acidic Hydrothermal Carbonization for Enhanced Alkaline Extraction of Phosphorus

SSRN

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SSRN 2024年

作者： Tiwari, Satya Brat Veksha, Andrei Chan, Wei Ping Fei, Xunchang Liu, Wen Lisak, Grzegorz Lim, Teik-Thye School of Civil and Environmental Engineering Nanyang Technological University 50 Nanyang Avenue 639798 Singapore Nanyang Environment and Water Research Institute Nanyang Technological University 1 Cleantech Loop CleanTech One 637141 Singapore Interdisciplinary Graduate Program Nanyang Technological University Singapore School of Chemistry Chemical Engineering and Biotechnology Nanyang Technological University 62 Nanyang Drive 637459 Singapore

This study presents a two-stage process to recover phosphorus (P) from sewage sludge (SS) hydrochar, aimed at reducing trace element (TE) contamination. SS, mixed with Al-rich alum sludge (AS), underwent acidic HTC to convert Ca-P to Al-P. Alkaline extraction of hydrochar produced a P-rich, TE-deficient extract, as Al-P dissolves at high pH (> 12), leaving TEs insoluble. Optimal conditions for maximum P recovery were high temperature (~240°C), Al/P molar ratio (APMR) of ~4, and feedstock pH of ~3 – 4. This design process achieved 82% alkaline P recovery, 34% higher than the reference process. Overall P recovery ranged from 59 – 75% in the design process, compared to 30 – 37% in the reference process. Solid-state NMR revealed the Al-P association in hydrochar through surface complexation. TEs were mainly concentrated in the hydrochar, not the alkaline extract. This method offers a potentially cost-effective, and energy-efficient solution for P recovery. © 2024, The Authors. All rights reserved.

关键词： Heavy metals

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Emerging contaminants:A One Health perspective

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The Innovation 2024年第4期5卷 140-170,139页

作者： Fang Wang Leilei Xiang Kelvin Sze-Yin Leung Martin Elsner Ying Zhang Yuming Guo Bo Pan Hongwen Sun Taicheng An Guangguo Ying Bryan WBrooks Deyi Hou Damian EHelbling Jianqiang Sun Hao Qiu Timothy MVogel Wei Zhang Yanzheng Gao Myrna JSimpson Yi Luo Scott XChang Guanyong Su Bryan MWong Tzung-May Fu Dong Zhu Karl JJobst Chengjun Ge Frederic Coulon Jean Damascene Harindintwali Xiankui Zeng Haijun Wang Yuhao Fu Zhong Wei Rainer Lohmann Changer Chen Yang Song Concepcion Sanchez-Cid Yu Wang Ali El-Naggar Yiming Yao Yanran Huang Japhet Cheuk-Fung Law Chenggang Gu Huizhong Shen Yanpeng Gao Chao Qin Hao Li Tong Zhang Natàlia Corcoll Min Liu Daniel SAlessi Hui Li Kristian KBrandt Yolanda Pico Cheng Gu Jianhua Guo Jianqiang Su Philippe Corvini Mao Ye Teresa Rocha-Santos Huan He Yi Yang Meiping Tong Weina Zhang Fidèle Suanon Ferdi Brahushi Zhenyu Wang Syed AHashsham Marko Virta Qingbin Yuan Gaofei Jiang Louis A.Tremblay Qingwei Bu Jichun Wu Willie Peijnenburg Edward Topp Xinde Cao Xin Jiang Minghui Zheng Taolin Zhang Yongming Luo Lizhong Zhu Xiangdong Li DamiàBarceló Jianmin Chen Baoshan Xing Wulf Amelung Zongwei Cai Ravi Naidu Qirong Shen Janusz Pawliszyn Yong-guan Zhu Andreas Schaeffer Matthias C.Rillig Fengchang Wu Gang Yu James M.Tiedje State Key Laboratory of Soil and Sustainable Agriculture Institute of Soil ScienceChinese Academy of SciencesNanjing 210008China University of Chinese Academy of Sciences Beijing 100049China Department of Chemistry Hong Kong Baptist UniversityHong KongChina HKBU Institute of Research and Continuing Education Shenzhen Virtual University ParkShenzhenChina Technical University of Munich TUM School of Natural SciencesInstitute of Hydrochemistry85748 GarchingGermany School of Resources&Environment Northeast Agricultural UniversityHarbin 150030China Climate Air Quality Research UnitSchool of Public Health and Preventive MedicineMonash UniversityMelbourneVICAustralia Faculty of Environmental Science&Engineering Kunming University of Science&TechnologyKunming 650500China Ministry of Education Key Laboratory of Pollution Processes and Environmental Criteria College of Environmental Science and EngineeringNankai UniversityTianjin 300350China Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control School of Environmental Science and EngineeringInstitute of Environmental Health and Pollution ControlGuangdong University of TechnologyGuangzhou 510006China Ministry of Education Key Laboratory of Environmental Theoretical Chemistry South China Normal UniversityGuangzhouGuangdong 510006China Department of Environmental Science Baylor UniversityWacoTXUSA Center for Reservoir and Aquatic Systems Research(CRASR) Baylor UniversityWacoTXUSA School of Environment Tsinghua UniversityBeijing 100084China School of Civil and Environmental Engineering Cornell UniversityIthacaNY 14853USA Key Laboratory of Microbial Technology for Industrial Pollution Control of Zhejiang Province Zhejiang University of TechnologyHangzhou 310014China School of Environmental Science and Engineering Shanghai Jiao Tong UniversityShanghai 200240China Laboratoire d’Ecologie Microbienne Universite Claude Bernard Lyon 1UMR CNRS 5557UMR INRAE 1418VetAgro Sup69622 VilleurbanneFrance Department of Pla

environmental pollution is escalating due to rapid global development that often prioritizes human needs over planetary *** global efforts to mitigate legacy pollutants,the continuous introduction of new substances remains a major threat to both people and the *** response,global initiatives are focusing on risk assessment and regulation of emerging contaminants,as demonstrated by the ongoing efforts to establish the UN’s Intergovernmental Science-Policy Panel on Chemicals,Waste,and Pollution *** review identifies the sources and impacts of emerging contaminants on planetary health,emphasizing the importance of adopting a One Health *** for monitoring and addressing these pollutants are discussed,underscoring the need for robust and socially equitable environmental policies at both regional and international *** actions are needed to transition toward sustainable pollution management practices to safeguard our planet for future generations.

关键词： pollution planet contaminants

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Understanding the role of study strategies and learning disabilities on student academic performance to enhance educational approaches: A proposal using artificial intelligence

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Computers and Education: Artificial Intelligence 2024年 6卷

作者： Bressane, Adriano Zwirn, Daniel Essiptchouk, Alexei Saraiva, Antônio Carlos Varela Carvalho, Fernando Luiz de Campos Formiga, Jorge Kennety Silva Medeiros, Líliam César de Castro Negri, Rogério Galante São Paulo State University Presidente Dutra Highway Km 1378 SP São José dos CamposCEP 12247-004 Brazil Graduate Program in Civil and Environmental Engineering São Paulo State University Eng. Luís Coube Avenue 2085 SP BauruCEP 17033-360 Brazil Graduate Program in Natural Disasters São Paulo State University Presidente Dutra Highway Km 1378 SP São José dos CamposCEP 12247-004 Brazil

Statement of problem: The students’ academic performance is influenced by a complex interplay among several factors. Traditional educational approaches often struggle to accommodate the diverse needs of students, leading to suboptimal learning outcomes. Purpose: This article aims to comprehensively understand the role of study strategies and learning disabilities in shaping academic performance. Through the integration of artificial intelligence (AI) tools, the purpose is to propose a decision support system (DSS) for recommendations to improve the educational approach. Method: To identify features with higher explanatory power based on empirical data, we employed an artificial neural network (ANN) to recognize patterns of association between study strategies, learning disabilities, and academic performance. Using the pondered features, a Fuzzy-based AI was built for offering recommendations into effective educational interventions. Conclusions: The findings underscore the significance of study strategies in mitigating the negative impact of learning disabilities on academic performance. By leveraging the proposed AI tools framework, educators can make informed decisions to tailor educational approaches, catering to the unique cognitive profiles of students. Personalized interventions based on identified patterns can lead to improved academic outcomes and greater inclusivity in the learning environment. Practical implications: Educators and policymakers can adopt the proposed data-driven strategies to enhance teaching methodologies, thereby accommodating the varying needs of students with learning disabilities. This approach fosters a more inclusive and equitable educational landscape, promoting academic success for all learners. © 2023 The Author(s)

关键词： Students

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A First-Principles and Calphad-Assisted Phase-Field Model for Microstructure Evolution: Application to Mo-V Binary Alloy Systems

SSRN

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SSRN 2023年

作者： Thakur, Abhishek Kumar Kovacevic, Sasa Manga, Venkateswara Rao Deymier, Pierre Alix Muralidharan, Krishna Department of Materials Science and Engineering University of Arizona TucsonAZ85721 United States Department of Civil and Environmental Engineering Imperial College London LondonSW7 2AZ United Kingdom Lunar and Planetary Laboratory University of Arizona TucsonAZ85721 United States Graduate Interdisciplinary Program in Applied Mathematics India

A multiscale computational framework combining the first-principles calculations and the CALPHAD approach with the phase-field method is presented to simulate the microstructure evolution in multicomponent steel alloys. We demonstrate the potential of the framework by predicting the microstructural evolution in elastically periodic arrays of the Mo-V binary sub-system. The framework utilizes the first-principles calculations using special quasi-random structures. Hitherto unavailable thermodynamic and material properties of the alloy are obtained by employing the first-principles calculations and the CALPHAD approach and fed into the phase-field model to predict the microstructure evolution at different temperatures within the miscibility gap region. In addition to the temperature and cooling rates, the model incorporates the role of mechanical fields in decomposition kinetics in the Mo-V binary alloy system. Regimes for temperatures and cooling rates at which spinodal decomposition occurs are identified. Applying external loading leads to directional phase separation in the Mo-V binary system. The elastic inhomogeneity in terms of material properties between the two phases initiates the directional alignment while eigenstrains and applied external loading control the degree of alignment. The framework developed is general and extendable to higher multicomponent sub-systems in steel alloys. © 2023, The Authors. All rights reserved.

关键词： Temperature

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Photodegradation of Profenofos in Aqueous Solution by Vacuum Ultraviolet

SSRN

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SSRN 2022年

作者： Ratpukdi, Thunyalux Siripattanakul-Ratpukdi, Sumana Thongprowh, Prapaipim Soontharo, Somphong Jenjaiwit, Supitchaya Prasertwongchai, Anuchit Anotai, Jin Nongsung, Pawonkorn Khan, Eakalak Department of Environmental Engineering Faculty of Engineering Research Center for Environmental and Hazardous Substance Management Khon Kaen University Khon Kaen40002 Thailand Department of Environmental Engineering Faculty of Engineering King Mongkut’s University of Technology Thonburi Bangkok10140 Thailand Bangkok10330 Thailand International Postgraduate Program in Environmental Management Graduate School Chulalongkorn University Bangkok10330 Thailand Department of Civil and Environmental Engineering and Construction University of Nevada Las VegasNV89154 United States

Profenofos is a widely used organophophorous pesticide for several crops and is detected in drinking water sources. This study investigated the degradation of profenofos using vacuum ultraviolet (VUV) compared with ultraviolet (UV). The factors affecting the degradation performance including pH, profenofos concentration, bicarbonate, nitrate, nitrite, natural organic matter (NOM), and aeration were examined. Profenofos removal efficiencies were 84% and 52% by VUV and UV after 7 min of irradiation, respectively (Initial profenofos concentration of 2 mg/L). Degradation of profenofos by VUV were 3 times faster than UV. The degradation rates decreased with increasing initial profenofos concentration. Direct photolysis at 185 nm and OH • played major roles for profenofos removal by VUV. Aeration enhanced the profenofos degradation and mineralization by VUV but not UV. Bicarbonate inhibited the profenofos degradation while nitrate (≤50 mg-NO 3 - /L) acted as a photosensitizer enhancing profenofos degradation. NOM from groundwater and surface water sources also inhibited the profenofos removal by VUV as high as 39% compared to deionized water. However, NOM promoted the profenofos removal by UV because degradation by OH • formed via NOM photolysis became the main degradation mechanism. The result of profenofos degradation under isolated NOM fractions elucidated that hydrophobic fractions had less inhibition compared to hydrophilic fractions. Identified products suggested the pathway of profenofos photodegradation were the breaking of the O-P bond and reduction of Br. © 2022, The Authors. All rights reserved.

关键词： Irradiation

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Development of a Coupled Hydrological and Buildup/Washoff Watershed Model

Development of a Coupled Hydrological and Buildup/Washoff Wa...

引用

World environmental and Water Resources Congress 2020: Water Resources Planning and Management and Irrigation and Drainage

作者： Pasetti, Daniel Manabe Garcia, Joaquin Ignácio Bonnecarrère Graduate Program in Civil Engineering Polytechnic School Univ. of São Paulo Brazil Dept. of Hydraulic and Environmental Engineering Univ. of São Paulo Brazil

ISBN: (数字)9780784482957

ISBN: (纸本)9780784482957

Modifications in land use and occupation, caused mainly by anthropization in both urban and rural regions, alter processes in the hydrological cycle. Such changes to watershed often lead to conflicts regarding the multiple water uses, due to issues in water quantity or quality. Mathematical models are a useful tool in determining and foreseeing such conflicts, as well as analyzing potential solutions and compromises to them. Among those, process-oriented simulation models can predict different behaviours undertaken by water throughout distinct media, enabling a comprehensive view on the watershed. This article describes the development of a generic aggregated hydrological model in a programming environment, coupled with an empirical buildup/washoff model. These models were then implemented in a region of the Alto Paranapanema watershed, in the state of São Paulo, Brazil. © 2020 American Society of civil Engineers.

关键词： Watersheds

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Budget-constrained rail network electrification problem

arXiv

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arXiv 2021年

作者： Patil, Priyadarshan N. Walthall, Rydell Boyles, Stephen D. Graduate Program in Operations Research and Industrial Engineering The University of Texas Austin United States Department of Civil Architectural and Environmental Engineering The University of Texas Austin United States

We consider a budget constrained rail network electrification problem with associated changes in costs of energy usage (via path gradient and curvature), operations, and long-term maintenance. In particular, we consider that freight flows on such a network form a user equilibrium. Interactions between electric and diesel trains on the same corridor are represented with nonseparable link performance functions, which nevertheless have a symmetric Jacobian. This bi-level formulation is solved for the North American railroad network using a genetic algorithm (GA), incorporating domain-specific insights to reduce the number of solutions which must be considered. We analyze solution characteristics and decision-making implications. Results show that broad connectivity would be beneficial for most impact. Increasing demand shifts electrified corridors towards the more populous east and gulf coasts, while increased operational costs results in electrification of routes through mountainous terrains. © 2021, CC BY.

关键词： Electric utilities

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How different spatial resolutions of digital models affects the geospatial distribution evaluation of the Index of Connectivity

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Journal of South American Earth Sciences 2025年 163卷

作者： Eberval Marchioro Geraldo André Rosseto Barreto Ialy Gomes Ferreira Adelsom Soares Filho Diogo Costa Buarque Department of Geography (DGEO) Graduate Program in Geography (PPGG) Federal University of Espírito Santo/Brazil (UFES) Coordinator of the Laboratory for Monitoring and Modeling Environmental Systems (Lamosa) Brazil Graduate Program in Management and Regulation of Water Resources (ProfÁgua/UFES) Brazil Graduate Program in Geography at UFES Brazil Graduate Program in Civil Engineering at UFV Brazil Department of Geography Graduate Program in Geography Federal University of Grande Dourados (UFGD) Brazil Department of Environmental Engineering Graduate Program in Environmental Engineering (PPGEA) Professional Master's in Water Resources Management and Regulation (ProfÁgua/UFES) Federal University of Espírito Santo/Brazil (UFES) Brazil

Digital Terrain Models (DTM) and Digital Elevation Models (DEM) are important for obtaining the Index of Connectivity, as they provide valuable information to assess the possibility of sediments reaching the riverbed in watershed basins. This is crucial for proactive management, as it allows the adoption of preventive and mitigating measures. Therefore, this study aims to analyze the effect of the spatial resolution of DEMs with resolutions of 5 m and 2 m, and between the DTM and DEM at 2 m, in determining the Index of Connectivity (IC). Additionally, it was investigated whether it is possible to use only one spatial resolution of digital models to assess the geospatial distribution of IC for all hydrogeomorphological landscapes of the Duas Bocas River watershed, located in the Metropolitan Region of Greater Vitória, in the state of Espírito Santo, Southeast Brazil. For this study, the Borselli Index of Connectivity model (et al., 2008) was used, originally developed for rural areas of Italy and widely applied in different regions worldwide. The data used, including Digital Elevation and Terrain Models and land use and cover information, were obtained from the Integrated Geospatial Base System of the State of Espírito Santo (Brazil), which is publicly *** results indicate that a better geospatial representation of IC occurs when changing the spatial resolution of DEMs from a 5 m pixel to a 2 m pixel and when using the 2 m DTM instead of the 2 m DEM. When analyzing the relationship between IC and the hydrogeomorphological landscapes in the basin, it was observed that, in the absence of models with an even finer pixel resolution, the 2 m DTM is the most suitable option, as it presented IC values consistent within and between landscapes in the Escalated Terraces of Southern Espírito Santo, Coastal Hills and Massifs, and Coastal Plateaus sectors. The exception was the fluvio-lagoon plain, which requires an even finer pixel resolution, necessitating further st

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Inverse designing metamaterials with programmable nonlinear functional responses in graph space

arXiv

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arXiv 2024年

作者： Maurizi, Marco Xu, Derek Wang, Yu-Tong Yao, Desheng Hahn, David Oudich, Mourad Satpati, Anish Bauchy, Mathieu Wang, Wei Sun, Yizhou Jing, Yun Zheng, Xiaoyu Rayne Department of Materials Science and Engineering University of California Berkeley Berkeley94720 United States Department of Computer Science University of California Los Angeles Los Angeles90095 United States Graduate Program in Acoustics Penn State University PA16802 United States Universite’ de Lorraine CNRS Institut Jean Lamour NancyF-54000 France Department of Civil and Environmental Engineering University of California Los Angeles Los Angeles90095 United States

Material responses to static and dynamic stimuli, represented as nonlinear curves, are design targets for engineering functionalities like structural support, impact protection, and acoustic and photonic bandgaps. Three-dimensional metamaterials offer significant tunability due to their internal structure, yet existing methods struggle to capture their complex behavior-to-structure relationships. We present GraphMetaMat, a graph-based framework capable of designing three-dimensional metamaterials with programmable responses and arbitrary manufacturing constraints. Integrating graph networks, physics biases, reinforcement learning, and tree search, GraphMetaMat can target stress-strain curves spanning four orders of magnitude and complex behaviors, as well as viscoelastic transmission responses with varying attenuation gaps. GraphMetaMat can create cushioning materials for protective equipment and vibration-damping panels for electric vehicles, outperforming commercial materials, and enabling the automatic design of materials with on-demand functionalities. Copyright © 2024, The Authors. All rights reserved.

关键词： Metamaterials

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