The trajectory tracking problem is a fundamental control task in the study of mechanical systems. Hamiltonian systems are posed on the cotangent bundle of configuration space of a mechanical system, however, symmetrie...
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The trajectory tracking problem is a fundamental control task in the study of mechanical systems. Hamiltonian systems are posed on the cotangent bundle of configuration space of a mechanical system, however, symmetries for the full cotangent bundle are not commonly used in geometric controltheory. In this paper, we propose a group structure on the cotangent bundle of a Lie group and leverage this to define momentum and configuration errors for trajectory tracking, drawing on recent work on equivariant observer design. We show that this error definition leads to error dynamics that are themselves “Euler-Poincare like” and use these to derive simple, almost global trajectory tracking control for fully-actuated Euler-Poincare systems on a Lie group state space.
Noble metal materials have been identified as high efficiency catalysts for electrocatalytic reduction of nitrate,and the synthesis and manufacture of high catalytic activity and environmentally friendly catalysts of ...
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Noble metal materials have been identified as high efficiency catalysts for electrocatalytic reduction of nitrate,and the synthesis and manufacture of high catalytic activity and environmentally friendly catalysts of activating hydrogen for water purification applications is extremely *** this work,the Pd-Cu single-atom catalysts(Pd-Cu-N-BC)were first prepared by direct growth of Pd-Cu single-atom on bamboo biochar by regulating the concentration of precursors and doping method,and then enhanced electrocatalytic reduction nitrate performance and N2 *** results showed that Pd-Cu-N-BC displayed excellent catalytic activity and reusability in electrocatalytic reduction nitrate with a low potential of 0.47 V ***(@10 mA cm−2).The maximum nitrate removal efficiency and N2 generation could reach about 100%and 72.32%within 180 min,*** density functional theory(DFT)calculations confirmed that Cu atoms could catalyze the electrochemical reduction of nitrate to nitrite,and Pd atoms anchored in the nitrogen-doped biochar(N-BC)lattice could catalyze electrochemical reduction of nitrite to N2 involving the formation of hydrogen radical(H*).The characterization results of XANES showed that electronic synergistic effect between Pd and Cu single atoms significantly promotes the N2 production through hydrogenation while inhibiting the generation of byproducts,leading to significantly enhanced electrocatalytic reduction of nitrate to ***,Pd-Cu-N-BC was designed as a 3D particle electrode for enhanced electrocatalytic reduction of nitrate,exhibiting excellent stability and reusability,which could be considered as a suitable candidate for applications in the remediation of nitrate contamination.
This paper addresses model predictive control of a class of linear systems subject to additive stochastic disturbances and constraints. The underlying stochastic optimal control problem combines inverse cumulative dis...
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This paper addresses model predictive control of a class of linear systems subject to additive stochastic disturbances and constraints. The underlying stochastic optimal control problem combines inverse cumulative distribution functions with ellipsoid-in-polyhedron formulations to reduce the conservatism induced by constraint satisfaction. By use of terminal constraints and time-varying weights within the cost functional, the presented control scheme satisfies criteria for mean-square stability and can be adapted to reference-tracking problems for arbitrary reference signals.
In order to address the problem that the control effect of the galvanometer motor is often dependent on the accuracy of the model parameters, this paper proposes a control method that is based on reinforcement learnin...
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Antibiotics may be exposed in a mixed state in natural *** toxicity of antibiotic mixtures exhibits time-dependent characteristics,and data on the time-dependent toxicity of antibiotic mixtures is also relatively *** ...
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Antibiotics may be exposed in a mixed state in natural *** toxicity of antibiotic mixtures exhibits time-dependent characteristics,and data on the time-dependent toxicity of antibiotic mixtures is also relatively *** this study,the toxicities of 45 binary mixtures composed of five antibiotics were investigated against Vibrio qinghaiensis sp.-Q67(Q67)at multiple exposure times(4,6,8,10,and 12 h).Quantitative structure–activity relationship(QSAR)models were developed for predicting the time-dependent toxicities of 45 binary *** results showed that the best QSAR models presented coefficient of determination(R2)of(0.818–0.913)and explained variance in prediction leave-one-out(Q2LOO)of(0.781–0.894)and predictive ability(Q2F1,Q2F2,Q2F3>0.682,concordance correlation coefficient>0.859).The R2 values of QSAR models outperformed the R2(0.628–0.810)of the conventional concentration addition models and the R2(0.654–0.792)of the independent action ***,the QSAR models showed higher R2 and Q2LOO values at 4 h compared to other exposure ***,the model at the 30%effective concentration(EC30)had R2 of 0.902 and Q2LOO of 0.883,while the model at the 50%effective concentration(EC50)had R2 of 0.913 and Q2LOO of *** CATS2D_04_DP descriptor was found to be the most dominant and negatively correlated factor influencing the toxicity of mixed antibiotics against Q67 in the nine QSAR models developed over five exposure *** reduction in the number of DP pharmacophore point pairs with a topological distance of 4 in the represented molecules is the primary cause for the rise in the time-dependent toxicity of the antibiotics against Q67.
Inspired by the increasing demand for energy-storage capacitors in electrical and electronic systems, dielectrics with high energy-storage performance have attracted more and more attention. AgNbO_(3) -based lead-free...
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Inspired by the increasing demand for energy-storage capacitors in electrical and electronic systems, dielectrics with high energy-storage performance have attracted more and more attention. AgNbO_(3) -based lead-free ceramics serve as one of the most promising environmental-friendly candidates. However, their energy storage optimization is seriously limited by the low breakdown strength. Fortunately, thin film as a form of AgNbO3 materials can effectively improve the breakdown strength. In this work, AgNbO_(3)film with ∼550 nm in thickness was deposited on SrRuO_(3 )/(001)SrTiO_(3) using pulsed laser deposition. The AgNbO_(3) film reveals typical relaxor ferroelectric hysteresis loops due to the new nanopillar structure, which contributes to high breakdown strength of up to 1200 kV cm^(-1) . Benefiting from the high breakdown strength, a recoverable energy storage density of 10.3 J cm^(-3) and an energy efficiency of 72.2% are obtained in the AgNbO_(3) film, which demonstrates the promising prospect of AgNbO_(3) film for energy storage applications.
This paper is concerned the problem of multi-sensor state estimation with cross-correlated noise, this paper adopts sequential fusion to estimate the state. The statistical characteristics of measurement noise of diff...
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Inspired by the skin structure,an asymmetric wettability tri-layer nanofiber membrane(TNM)consisting of hydrophilic inner layer loaded with lidocaine hydrochloride(LID),hydrophobic middle layer with ciprofloxacin(CIP)...
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Inspired by the skin structure,an asymmetric wettability tri-layer nanofiber membrane(TNM)consisting of hydrophilic inner layer loaded with lidocaine hydrochloride(LID),hydrophobic middle layer with ciprofloxacin(CIP)and hydrophobic outer layer has been *** hydrophobic outer layer endows the TNM with waterproof function and anti-adhesion from *** hydrophobic middle layer with CIP preserves long-term inhibition of bacteria growth and the hydrophilic inner layer with LID possesses optimal waterabsorbing capacity and air *** TNM dramatically elevates the water contact angles from 10°(inner layer)to 120(outer layer),indicating an asymmetric wettability,which could directionally transport wound exudate within the materials and meanwhile maintain a comfortable and moist environment to promote wound ***,the sequential release of LID and CIP could relieve pain rapidly and achieve antibacterial effect in the long run,*** addition,the TNM shows superior biocompatibility towards L929 *** in vivo results show the TNM could prevent infection,accelerate epithelial regeneration and significantly accelerate wound *** study indicates the developed TNM with asymmetrical wettability and synergetic drug release shows great potential as a wound dressing in clinical application.
The positioning accuracy of a signal source is influenced by where the sensors are deployed. Studies in the literature for the optimal sensor placement (OSP) of localization often ignore the presence of sensor positio...
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Shared workspaces between humans and robots are a significant part of Industry 4.0. Modern planning algorithms aim to increase human safety in collaborative scenarios and dynamic environments by considering motion for...
Shared workspaces between humans and robots are a significant part of Industry 4.0. Modern planning algorithms aim to increase human safety in collaborative scenarios and dynamic environments by considering motion forecasts of obstacles. While highly accurate approaches exist, the question arises whether their often greater complexity justifies the benefits that motion planners can draw from them. The paper at hand compares two motion forecasters and evaluates their effectiveness in a robot motion planner to generate collision-free trajectories online. One motion forecaster uses neural networks for predicting, while the other estimates and extrapolates the state of a customized human skeleton. The evaluation shows that simple and online capable motion extrapolations constitute towards human safety in varying situations more than highly accurate neural network predictions.
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