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Glycerol Electrooxidation over Precision-Synthesized Gold Nanocrystals with Different Surface Facets

Precision Chemistry 2024年第3期2卷 103-111页

作者： Hansen Mou Fang Lu Zechao Zhuang Qiaowan Chang Lihua Zhang Xiaobo Chen Yugang Zhang Jingguang G.Chen Department of Chemical Engineering Columbia UniversityNew YorkNew York 10027United States School of Chemical Engineering and Bioengineering Washington State UniversityPullmanWashington 99164United States Center for Functional Nanomaterials Brookhaven National LaboratoryUptonNew York 11973United States Materials Science and Engineering Program State University of New York at BinghamtonBinghamtonNew York 13902United States Chemistry Division Brookhaven National LaboratoryUptonNew York 11973United States

Electrochemical glycerol oxidation(EGO)emerges as a promising route to valorize glycerol,an underutilized byproduct from biodiesel production,into value-added *** study employed three types of gold(Au)nanocrystals with controlled shapes to elucidate the facet-dependent electrocatalytic behavior in ***,rhombic dodecahedral,and cubic Au nanocrystals with{111},{110},and{100}facets,respectively,were precisely synthesized with uniform size and *** dodecahedra exhibited the lowest onset potential for EGO due to facile AuOH formation,while octahedra showed enhanced electrochemical activity for glycerol oxidation and resistance to ***-situ FTIR analysis revealed that Au{111}surfaces selectively favored C_(2) products,whereas Au{100}surfaces promoted C_(3) product formation,highlighting the significant effect of facet orientation on EGO performance and informing catalyst design.

关键词： Electrochemical glycerol oxidation Precision synthesis Shaped nanocrystals Au nanocrystals SAXS In-situ FTIR

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Tuning Zinc-Copper Dual-Ion Electrolytes to Extend the Cycle Life of Zinc Ion Capacitors

Tuning Zinc-Copper Dual-Ion Electrolytes to Extend the Cycle...

引用

International Flexible Electronics Technology Conference (IFETC)

作者： Jinwook Jung Chanho Shin Tse Nga Ng Program in Materials Science and Engineering University of California San Diego La Jolla USA Department of Electrical and Computer Engineering University of California San Diego La Jolla USA

ISBN: (数字)9798331529468

ISBN: (纸本)9798331529475

We investigated the effect of copper ion concentration in zinc-copper dual-ion electrolytes to suppress dendrites and extend the cycle life of zinc ion capacitors. The devices were characterized in terms of changes in microstructure and cycling stability. The nuclei size was decreased in the optimal copper ion concentration to promote lateral deposition and avoid vertical dendrites. The device exhibited stable cycling performance with a capacitance retention of 95% after 10,000 redox cycles, compared to the device with single zinc ion electrolyte which short circuited at around 1,250 redox cycles.

关键词： Performance evaluation Capacitors Redox Ions Electrolytes Dendrites (neurons) Copper Microstructure Zinc Tuning

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Multi-objective parametrization of interatomic potentials for large deformation pathways and fracture of two-dimensional materials

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npj Computational materials 2021年第1期7卷 1042-1052页

作者： Xu Zhang Hoang Nguyen Jeffrey T.Paci Subramanian K.R.S.Sankaranarayanan Jose L.Mendoza-Cortes Horacio D.Espinosa Theoretical and Applied Mechanics Program Northwestern UniversityEvanstonILUSA Department of Chemistry University of VictoriaVictoriaBCCanada Center for Nanoscale Materials Argonne National LaboratoryLemontILUSA Department of Chemical Engineering&Materials Science Michigan State UniversityEast LansingMIUSA Department of Mechanical Engineering Northwestern UniversityEvanstonILUSA

This investigation presents a generally applicable framework for parameterizing interatomic potentials to accurately capture large deformation *** incorporates a multi-objective genetic algorithm,training and screening property sets,and correlation and principal component *** framework enables iterative definition of properties in the training and screening sets,guided by correlation relationships between properties,aiming to achieve optimal parametrizations for properties of ***,the performance of increasingly complex potentials,Buckingham,Stillinger-Weber,Tersoff,and modified reactive empirical bond-order potentials are *** MoSe_(2)as a case study,we demonstrate good reproducibility of training/screening properties and superior *** MoSe_(2),the best performance is achieved using the Tersoff potential,which is ascribed to its apparent higher flexibility embedded in its functional *** results should facilitate the selection and parametrization of interatomic potentials for exploring mechanical and phononic properties of a large library of two-dimensional and bulk materials.

关键词： materials apparent enable

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Elevated temperature-driven coordinative reconstruction of an unsaturated single-Ni-atom structure with low valency on a polymer-derived matrix for the electrolytic oxygen evolution reaction

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Nanoscale 2024年第15期16卷 7467-7479页

作者： Patil, Rahul Rajput, Anubha Matsagar, Babasaheb M. Chen, Norman C. R. Ujihara, Masaki Salunkhe, Rahul R. Yadav, Praveen Wu, Kevin C.-W. Chakraborty, Biswarup Dutta, Saikat Electrochemical Energy & Sensor Research Laboratory Amity Institute of Click Chemistry Research & Studies Amity University Noida India Department of Chemistry Indian Institute of Technology New Delhi India Department of Chemical Engineering National Taiwan University Taipei10617 Taiwan Molecular Science and Technology Program Taiwan International Graduate Program Academia Sinica Taiwan National Taiwan University Taiwan Graduate Institute of Applied Science and Technology National Taiwan University of Science and Technology Taipei Taiwan Materials Research Laboratory Department of Physics Indian Institute of Technology Jammu India Synchrotron X-ray Facility Raja Ramanna Centre for Advanced Technology Rajendra Nagar Madhya Pradesh 452013 Indore India

A high-temperature pyrolysis-controlled coordination reconstruction resulted in a single-Ni-atom structure with a Ni-Nx-C structural unit (x = N atom coordinated to Ni). Pyrolysis of Ni-phen@ZIF-8-RF at 700 °C resulted in NiNP-NC-700 with predominantly Ni nanoparticles. Upon elevating the pyrolysis temperature from 700 to 900 °C, a coordination reconstruction offers Ni-Nx atomic sites in NiSA-NC-900. A combined investigation with X-ray absorption spectroscopy, X-ray photoelectron spectroscopy, and soft X-ray L3-edge spectroscopy suggests the stabilization of low-valent Niδ+ (0 −2 was achieved. The cell potential recorded with Pt(−)/(+)NiSA-NC-900/NF was much lower than that obtained for other cells, i.e., Pt(−)/NF and NF(−)/(+)NF, which enhances the potentials of low-valent NiSAs for insightful understanding of the OER. At a constant applied potential of 1.61 V (vs. RHE) for 12 h, an small increase in current for initial 0.6 h followed by a constant current depicts the fair stability of catalyst for 12 h. Our results offer an insightful angle into the OER with a coordinatively reconstructed single-Ni-atom structure at lower valency ( © 2024 The Royal Society of Chemistry.

关键词： Reaction kinetics

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Green Synthesis of Hierarchical Ag Nanostructures for Sers Detection of Rhodamine Dye

SSRN

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SSRN 2024年

作者： Sayson, Luce Vida A. Taaca, Kathrina Lois M. Madera, Rozen Grace B. Vasquez, Magdaleno R. Regulacio, Michelle D. Materials Science and Engineering Program College of Science University of the Philippines Diliman Quezon City1101 Philippines Department of Mining Metallurgical and Materials Engineering College of Engineering University of the Philippines Diliman Quezon City1101 Philippines Institute of Chemistry College of Science University of the Philippines Diliman Quezon City1101 Philippines

This study presents a simple benchtop synthetic protocol for the fabrication of silver (Ag) nanostructures in aqueous media using environmentally friendly and inexpensive reagents under mild experimental conditions. Natural organic acids that are known to be present in plants were employed as reducing and morphology-directing reagents. SEM and TEM imaging revealed that the resultant nanostructures are three-dimensional hierarchical structures that were formed from self-assembly of smaller nanoparticles. They are generally spherical in shape and possess highly roughened surfaces due to the interstitial gaps between their nanoparticle subunits. Their hierarchical architecture allows for strong absorption of light in a broad range of wavelengths that extends to the near-infrared region. In addition, their surface morphology has an abundance of hot spot regions, which are capable of inducing strong SERS enhancement effects. The green-synthesized Ag nanostructures showed remarkable SERS activity when used as substrates for the detection of rhodamine 6G dye, a highly toxic water contaminant. Overall, this study does not only provide a greener approach to hierarchical Ag nanostructures, but also demonstrates theimmense potential of these nanostructures in the sensitive detection of organic dyepollutants. © 2024, The Authors. All rights reserved.

关键词： Substrates

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Color-fast semi-transparent organic photovoltaics 25

Color-fast semi-transparent organic photovoltaics

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Organic Photonic materials and Devices XXV 2023

作者： Sheriff, Hafiz K.M. Li, Yongxi Forrest, Stephen R. Applied Physics Program University of Michigan Ann ArborMI48109 United States Department of Electrical Engineering University of Michigan Ann ArborMI48109 United States Department of Materials Science and Engineering University of Michigan Ann ArborMI48109 United States Department of Physics University of Michigan Ann ArborMI48109 United States

ISBN: (纸本)9781510659414

Equipping buildings with energy harvesting windows is a practical way to reduce greenhouse gas (GhG) emission. Utilizing semi-transparent organic photovoltaics (ST-OPVs) for this application requires the device to be colorfast, allowing for no change in the aesthetics or light harvesting property of the window. Here, we demonstrate an ST-OPV that is colorfast under 1 Sun AM 1.5G illumination at 50 °C and relative humidity of 34 %. © 2023 SPIE.

关键词： Energy harvesting

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Adult dental epithelial stem cell-derived organoids deposit hydroxylapatite biomineral

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International Journal of Oral science 2023年第4期15卷 676-690页

作者： Hyun-Yi Kim Victoria Cooley Eun-Jung Kim Shujin Li Jong-Min Lee Dina Sheyfer Wenjun Liu Ophir D.Klein Derk Joester Han-Sung Jung NGeneS Inc. Ansan-siGyeonggi-doKorea Department of Materials Science and Engineering Northwestern UniversityEvanstonILUSA X-ray Science Division Advanced Photon SourceArgonne National LaboratoryLemontILUSA Division in Anatomy and Developmental Biology Department of Oral BiologyOral Science Research CenterBK21 FOUR ProjectYonsei University College of DentistrySeoulKorea Department of Orofacial Sciences and Program in Craniofacial Biology University of CaliforniaSan FranciscoCAUSA Department of Pediatrics Cedars-Sinai Guerin Children’sLos AngelesCAUSA

Ameloblasts are specialized cells derived from the dental epithelium that produce enamel,a hierarchically structured tissue comprised of highly elongated hydroxylapatite(OHAp)*** unique function of the epithelial cells synthesizing crystallites and assembling them in a mechanically robust structure is not fully elucidated yet,partly due to limitations with in vitro experimental ***,we demonstrate the ability to generate mineralizing dental epithelial organoids(DEOs)from adult dental epithelial stem cells(aDESCs)isolated from mouse incisor *** expressed ameloblast markers,could be maintained for more than five months(11 passages)in vitro in media containing modulators of Wnt,Egf,Bmp,Fgf and Notch signaling pathways,and were amenable to *** transplanted underneath murine kidney capsules,organoids produced OHAp crystallites similar in composition,size,and shape to mineralized dental tissues,including some enamel-like elongated *** are thus a powerful in vitro model to study mineralization process by dental epithelium,which can pave the way to understanding amelogenesis and developing regenerative therapy of enamel.

关键词： epithelium maintained specialized

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In situ formation of LDH-based nanocontainers on the surface of AZ91 magnesium alloy and detailed investigation of their crystal structure

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Journal of Magnesium and Alloys 2022年第5期10卷 1268-1285页

作者： Tatsiana Shulha M.Serdechnova M.H.Iuzviuk I.A.Zobkalo P.Karlova N.Scharnagl D.C.F.Wieland S.V.Lamaka A.A.Yaremchenko C.Blawert M.L.Zheludkevich Helmholtz-Zentrum Hereon Institute of Surface ScienceMax-Planck-Straβe 1Geesthacht 21502Germany Condensed Matter Department Petersburg Nuclear Physics Institute Named by B.P.Konstantinov of National Research Center“Kurchatov Institute”MKR Orlova roshcha 1Gatchina 188300Russian Federation Helmholtz-Zentrum Hereon Institute of Metallic BiomaterialsMax-Planck Straβe 1Geesthacht 21502Germany Department of Materials and Ceramic Engineering CICECO–Aveiro Institute of MaterialsUniversity of AveiroAveiro 3810-193Portugal Faculty of Engineering University of KielKaiserstraβe 2Kiel 24143Germany

In the presented work, the possibility of direct synthesis of LDH(layered double hydroxide) on the AZ91 surface in the presence of a chelating agent(diethylenetriaminepentaacetic acid-DTPA) is reported. Conversion layer of LDH nanocontainers were formed under ambient pressure conditions without carbonate addition in the electrolyte. The obtained LDH was characterized using experimental(SEM,XRD, TGA, XPS, Raman, etc.) and computational methods(thermodynamic calculation, modeling of possible LDH crystal structures). A comparison of three possible LDHs(LDH-OH,-NO_(3) and-CO_(3)) was performed. Based on the experimental results and crystal simulation approach, it was confirmed, that the mixed LDH-OH/CO_(3) is grown on the surface in the presence of DTPA pentasodium salt.

关键词： Layered double hydroxides Magnesium alloy Chelating agent Functional coating

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Experimental and theoretical study of the phase transition between perovskite polytypes of BaPtO3 under high pressure and temperature

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Physical Review B 2024年第9期110卷 094108页

作者： Hongze Li Yanyao Zhang Nisha Geng Jiaming He Stella Chariton Vitali Prakapenka Carlos Alberto López José Antonio Alonso Eva Zurek Jung-Fu Lin Jianshi Zhou Materials Science and Engineering Program Walker Department of Mechanical Engineering Department of Earth and Planetary Sciences Jackson School of Geosciences Department of Chemistry Center for Advanced Radiation Sources The INTEQUI (UNSL-CONICET) and Facultad de Química Bioquímica y Farmacia CSIC Cantoblanco 28049 Madrid Spain

APtO3 (A = Ca, Sr, Ba) is a unique family in the complex transition metal oxides with the AMO3 formula. Most 3d and 4dAMO3 compounds adopt the perovskite structure when synthesized at ambient or high pressure; however, APtO3 perovskites have not been reported, even if their geometric tolerance factor, t, falls in the range suitable for the perovskite structure. Herein, we studied the crystal structures of BaPtO3 by performing the in situ x-ray diffraction over a broad range in the pressure (P)–temperature (T) phase diagram. The perovskite BaPtO3 can be stabilized at P>35 GPa and T>1100 K. A variety of crystal structures, including the perovskite structure and its hexagonal polytypes, observed in the P–T phase diagram of BaPtO3 match the structure predictions from the first-principles calculations reasonably well.

关键词： High-pressure studies Structural phase transition Perovskites Density functional calculations Pressure techniques X-ray diffraction

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Assessment of Simple Adhesive Substrates for Quantifying Microplastics

SSRN

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SSRN 2022年

作者： Rieland, Julie M. Hu, Zeyuan Deese, Julian S. Love, Brian J. The University of Michigan United States Department of Materials Science and Engineering Department of Biomedical Engineering Macromolecular Science and Engineering Graduate Program

Microplastics are a growing environmental concern, with a large body of evidence documenting substantial distribution of plastic material in virtually all environmental compartments. Countermeasures that help to bind, aggregate, or coalesce these distributed particles might result in lower human and animal exposures. Pressure sensitive adhesives (PSAs) have been identified as a viable microplastic (MP) capture mechanism with a range of potential use conditions. As with any countermeasure, there is a need to evaluate potential solutions in terms of collection efficiency, cost, ease of installation, etc. Expanding on our previous work, spray-coated PSAs were investigated as submerged surfaces as tools to assess MP binding in aqueous dispersions. Resins containing two differing molecular weights of poly(2-ethylhexyl acrylate) PSA (92k and 950k), and a 50:50 by weight mixture of the two resins were applied as spray-coated substrates to compare the effect of resin composition on MP-adhesive binding. Thin films of PSA (92k 6 ± 1 μm, 950k 4 ± 2 μm, 50:50 BD 6.5 ± 1 μm) were sprayed on borosilicate glass slides using a commercial air brush. Polydisperse nylon-12 particles varying in size from 15-30 µm in diameter were dispersed in deionized water at concentrations between 0.01 and 5 mg mL -1 and agitated under ambient conditions to assess adhesive binding as quantitative comparisons of microparticle capture. Mixed assays were also performed comparing binding of common MP species including polyethylene (50, 200 µm), polystyrene (10 µm), and polyester fibers (1000 µm) to understand how varying composition, size, and form factor affect adsorption. The glass slide method showed increasing linear trends of particle binding with increased adhesive exposure time and MP concentration. The lower molecular weight 92K adhesive had lower viscosity, higher wettability for microplastics but also led to a less stable adhesive film complicating analysis. As a field-deployable scheme for mi

关键词： Aggregates

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