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Microstructural evolution in lithium plating process and its effect on the calendar storage life

Nano Research 2024年第10期17卷 8834-8841页

作者： Ki Hwan Koh Dong Ju Lee Anthony Mu Kangwoon Kim Taehee Kim Zheng Chen Department of Chemical and Nano Engineering University of California San DiegoLa JollaCA 92093USA Program of Materials Science and Engineering University of California San DiegoLa JollaCA 92093USA Sustainable Power and Energy Center University of California San DiegoLa JollaCA 92093USA

The growing demand for electric vehicles highlights the need for energy storage solutions with higher densities,spotlighting Li metal anodes as potential successors to traditional Li-ion batteries(LIBs).Achieving longer calendar aging life for Li metal anodes is crucial for their practical use,given their propensity for corrosion due to a low redox potential,which leads to compromised cycling stability and significant capacity loss during *** research investigated that this susceptibility is mainly dependent on the surface area of Li metal anode and the properties of the solid electrolyte interphase(SEI),particularly its stability and growth *** research adds to this understanding by demonstrating that the amount of Li plating is a key factor in its corrosion during open-circuit storage,as assessed across various *** discovered that increasing the Li plating amount effectively reduces Coulombic efficiency(C.E.)loss during aging,due to a lower surface area-to-Li *** implies that the choice of electrolyte for optimal storage life should consider the amount of Li plating,with higher capacities promoting better storage characteristics.

关键词： lithium metal batteries anode-free batteries calendar life of batteries lithium anode corrosion

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Nanostructured Ni-MoCx:An efficient non-noble metal catalyst for the chemoselective hydrogenation of nitroaromatics

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Nano Research 2023年第7期16卷 8919-8928页

作者： Yifei Zhang Zhiwen Li Jingjing Zhang Liangliang Xu Zhong-Kang Han Alfons Baiker Gao Li Institute of Catalysis for Energy and Environment College of Chemistry and Chemical EngineeringShenyang Normal UniversityShenyang 110034China State Key Laboratory of Catalysis Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology(KAIST)Daejeon 34141Republic of Korea School of Materials Science and Engineering Zhejiang UniversityHangzhou 310027China Department of Chemistry and Applied Biosciences Institute for Chemical and BioengineeringETH ZurichHönggerbergHClZurich CH-8093Switzerland University of Chinese Academy of Sciences Beijing 100049China

Catalysts for chemoselective hydrogenation are of vital importance for the synthesis of various important chemicals and *** we developed a simple method for preparing a highly efficient Ni-MoC_(x)nanocomposite catalyst via temperature-programmed carburization of a polyoxometalate precursor.X-ray diffraction(XRD),scanning transmission electron microscopy(STEM),X-ray photoelectron spectroscopy(XPS),and X-ray absorption spectroscopy(XAS)analyses indicate that the resulting mesoporous nanocomposite catalyst is made up of well-dispersed metallic nickel particles embedded in a MoC_(x)*** catalyst exhibits high activity and selectivity(>99%)in the hydrogenation of various substituted nitroaromatics to corresponding *** high efficiency is attributed to the intimate contact of the constituents favoring electron transfer and hydrogen *** is physisorbed on the carbide support and dissociates on the nickel particles,as evidenced by Mo K-edge X-ray absorption near-edge structure(XANES)spectra,density functional theory(DFT),and hydrogen-deuterium *** remarkable catalytic performance of the catalyst could be traced back to the synergistic interaction between the Ni particles and the carbide ***-situ infrared spectroscopy and DFT simulations indicated that the adsorption/activation of the nitro group is favored compared to that of other substituents at the aromatic *** recyclability tests,the Ni-MoC_(x)nanocomposite showed no significant loss of catalytic performance in seven consecutive runs,indicating its robust nature.

关键词： Ni-MoC_(x)nanocomposite carburization of polyoxometalate hydrogenation nitroaromatics synergistic effect

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Lignin-based polyurethane composites enhanced with hydroxyapatite for controlled drug delivery and potential cellular scaffold applications

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Polymer Composites 2024年第16期45卷 15159-15172页

作者： Nugroho, Roshid Adi Saputra, Ozi Adi Pradita, Agung Lucky Fajar, Al Bukhori Nur Wibowo, Fajar Rakhman Department of Chemistry Faculty of Mathematics and Natural Sciences Universitas Sebelas Maret Central Java Surakarta Indonesia Sustainable Chemical Science and Technology Taiwan International Graduate Program Academia Sinica Taipei Taiwan Institute of Chemistry Academia Sinica Taipei Taiwan Department of Chemical Engineering Collage of Engineering National Taiwan University Taipei Taiwan

Polymer technology has rapidly advanced across diverse domains, particularly in biomedical applications. Among various polymers, polyurethane (PU) hold great potential in developing biomaterials such as biomedical scaffold and drug delivery. In this study, we have innovatively engineered eco-friendly polyurethane using lignin, a sustainable bio-polyol derived from oil palm empty fruit bunches. To enhance the physicochemical properties of the PU, we have incorporated hydroxyapatite (HA) into the composites. The inclusion of HA has led to notable improvements in crucial properties such as density, porosity, and water absorption, making these composites ideal candidates for tissue regeneration scaffolds. Furthermore, to assess their biomedical applicability in drug delivery and cell scaffolding, we have employed the quercetin drug model. The results revealed a sustained kinetic release behavior within the polyurethane/hydroxyapatite (PU/HA) composites, showcasing their potential for controlled drug delivery applications. Moreover, cytotoxicity assays conducted using neuro-2a cell models demonstrated the non-cytotoxic nature of both PU and PU/HA composites. This finding holds significant implications for biomedical applications, indicating that these composites offer biocompatible platforms for tissue engineering and regenerative medicine endeavors. The ability of these composites to support cell viability underscores their potential for a wide range of biomedical applications, including neural tissue engineering and drug delivery systems targeting brain diseases. These findings pave the way for the development of innovative and sustainable biomaterials with diverse biomedical applications. Highlights: An eco-friendly polyurethane has been engineered by harnessing liginin-derived oil palm empty fruit bunches. Incorporation of hydroxyapaptite enhance the physical properties of polyurethane. Controlled kinetic drug release is one of polyurethane/hydroxyapatite (PU/HA) com

关键词： Fruits

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Advances of photothermal chemistry in photocatalysis,thermocatalysis,and synergetic photothermocatalysis for solar-to-fuel generation

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Nano Research 2022年第12期15卷 9985-10005页

作者： Minmin Gao Tianxi Zhang Ghim Wei Ho Department of Electrical and Computer Engineering National University of Singapore4 Engineering Drive 3Singapore117583Singapore Department of Chemical and Biomolecular Engineering National University of Singapore4 Engineering Drive 4Singapore117585Singapore Institute of Materials Research and Engineering Agency for ScienceTechnology and Research(A*STAR)3 Research LinkSingapore117602Singapore

The urgency of reducing pollutants and greenhouse gas emissions while maintaining fuel supply for the development of society remains one of the greatest *** energy,a clean and sustainable energy resource,can be converted into fuels through solar-driven catalysis,and this provides an attractive solution for future energy *** current development of photothermal catalysis(PTC)based on the integration of solar thermal and photochemical contributions is becoming increasingly popular for full spectrum *** combination of the thermochemical and photochemical processes synergistically drives the catalytic reactions efficiently under relatively mild *** this review,the mechanisms of PTC are classified based on driving forces and the benefits of photothermal effects in different PTC reactions are ***,the techniques for differentiating and quantifying the various effects of PTC,including experimental designs,thermometry characterization techniques,and computational studies,are ***,the major determinant properties and architectural designs for efficient photothermal catalysts are ***,applications for fuel generation through water splitting and carbon dioxide reduction are ***,the current challenges and future directions of PTC are *** article aims to provide a comprehensive review of the current advances in PTC along with a guide for understanding the mechanisms and rational material designs to pursue solar fuel that would diversify and increase the sustainability of our energy supply.

关键词： photothermal chemistry photocatalysis thermocatalysis water splitting CO_(2)conversion solar fuel

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Scaled-up synthesis of defect-rich layered double hydroxide monolayers without organic species for efficient oxygen evolution reaction

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Green Energy & Environment 2022年第5期7卷 975-982页

作者： Haoyuan Chi Jingwen Dong Tian Li Sha Bai Ling Tan Jikang Wang Tianyang Shen Guihao Liu Lihong Liu Luyi Sun Yufei Zhao Yu-Fei Song State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing100029China College of Chemistry Key Laboratory of Theoretical&Computational Photochemistry of Ministry of EducationBeijing Normal UniversityBeijing100875China Polymer Program Institute of Materials Science and Department of Chemical&Biomolecular EngineeringUniversity of ConnecticutStorrsConnecticut06269USA Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical TechnologyBeijing100029China

The scaled-up synthesis of organic-free monolayer nanomaterials is highly desirable,especially in obtaining green energy by *** this study,a method for the scaled-up synthesis of the series of monolayer layered double hydroxides(LDHs)without the addition of organic solvents is reported via the separate nucleation and aging steps *** resulting monolayer LDHs with the thicknesses of less than 1 nm showed a narrow thickness distribution.X-ray absorption fine-structure revealed that monolayer NiFe-LDH nanosheets have a number of oxygen and metal vacancies *** a practical application,monolayer NiFe-LDH nanosheets containing defects showed an enhanced electrocatalytic water oxidation activity compared with that of bulk *** functional theory calculations uncovered that excellent catalytic activity is attributed to vacancies *** proposed method is an economical and universally applicable strategy for the scaled-up production of monolayer LDHs.

关键词： process synthesis monolayer

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A breathing A4 paper by in situ growth of green metal-organic frameworks for air freshening and cleaning

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Chinese Journal of chemical engineering 2022年第12期52卷 95-102页

作者： Bo Zhang Hongwen Chen Liming Jiang Youqing Shen Dan Zhao Zhuxian Zhou Key Laboratory of Biomass Chemical Engineering of Ministry of Education and Zhejiang Key Laboratory of Smart Biomaterials College of Chemical and Biological EngineeringZhejiang UniversityHangzhou 310027China Department of Polymer Science and Engineering Zhejiang UniversityHangzhou 310027China Department of Chemical&Biomolecular Engineering National University of Singapore117585Singapore Hangzhou Global Scientific and Technological Innovation Center Zhejiang UniversityHangzhou 311215China

Surface modification of natural cellulose fibers with nanomaterials is an effective strategy for producing functional textiles for multiple applications.A4-sized printing paper is a commonly used,cheap,and easily acquirable office supply which is mainly made of cellulose ***,we report green and simple nanofabrication of A4 paper to endow it with high capability for fragrance encapsulation and sustained release,and strong adsorption to indoor air *** method utilizes the sugar molecule of cellulose for in-situ growth ofγ-cyclodextrin(γ-CD)metal-organic frameworks(MOFs)on A4 *** obtainedγ-CD-MOF/A4 nanocomposites have superior specific surface area and high porous ***γ-CD-MOF/A4 nanocomposites can effectively encapsulate fragrant molecules through host-guest ***γ-CD-MOF/A4 nanocomposites also show strong absorption capability to formaldehyde and carbon dioxide through the formation of hydrogen bonding and chemical ***γ-CD-MOF/A4nanocomposites combine the advantages of both A4 paper andγ-CD-MOF,which can be used in indoor air freshening and cleaning.

关键词： Metal-organic frameworks A4 printing paper In situ synthesis Fragrance encapsulation Formaldehyde removal Carbon dioxide capture

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Celebrating the One-Year Anniversary of Nano Research Energ

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Nano Research Energy 2023年第2期2卷 1-2页

作者： Zhiqun Lin Chunyi Zhi Liangti Qu Department of Chemical and Biomolecular Engineering National University of SingaporeSingapore 117585Singapore Department of Materials Science&Engineering City University of Hong KongHong KongChina Department of Chemistry Tsinghua UniversityBeijing 100084 China

To celebrate this momentous occasion,we are very pleased to highlight the following significant accomplishments of this new journal in the *** Research Energy received more than 100 submissions and published 17 research articles,36 reviews,3 perspectives,6 highlights,1 comment and 2 editorials,amounting to a total of 65 papers to date.

关键词： journal accomplishment submission

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Autonomous self-healing 3D micro-suction adhesives for multi-layered amphibious soft skin electronics

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InfoMat 2024年第10期6卷 65-79页

作者： Dohyun Lim Min Woo Jeong Hyeongho Min Yeon Soo Lee Gui Won Hwang Seung Hwan Jeon Kyu Ho Jung Ngoc Thanh Phuong Vo Min-Seok Kim Da Wan Kim Jin Young Oh Changhyun Pang School of Chemical Engineering Sungkyunkwan University(SKKU)SuwonGyeonggi-doRepublic of Korea Department of Chemical Engineering(Integrated Engineering Program) Kyung Hee UniversityYonginGyeonggiRepublic of Korea Convergence Research Group for Meta-Touch Korea Research Institute of Standards and ScienceDaejeonRepublic of Korea Department of Electronic Engineering Korea National University of TransportationChungju-siChungbukRepublic of Korea Samsung Advanced Institute for Health Sciences and Technology(SAIHST) Sungkyunkwan UniversitySuwonGyunggi-doRepublic of Korea

Autonomously self-healing, reversible, and soft adhesive microarchitecturesand structured electric elements could be important features in stable and versatilebioelectronic devices adhere to complex surfaces of the human body(rough, dry, wet, and vulnerable). In this study, we propose an autonomousself-healing multi-layered adhesive patch inspired by the octopus, which possessself-healing and robust adhesion properties in dry/underwater *** implement autonomously self-healing octopus-inspired architectures, adynamic polymer reflow model based on structural and material design suggestscriteria for three-dimensional patterning self-healing elastomers. In addition,self-healing multi-layered microstructures with different moduli endowsefficient self-healing ability, human-friendly reversible bio-adhesion, and stablemechanical deformability. Through programmed molecular behavior ofmicrolevel hybrid multiscale architectures, the bioinspired adhesive patchexhibited robust adhesion against rough skin surface under both dry andunderwater conditions while enabling autonomous adhesion restoring performanceafter damaged (over 95% healing efficiency under both conditions for24 h at 30℃). Finally, we developed a self-healing skin-mountable adhesiveelectronics with repeated attachment and minimal skin irritation by laminatingthin gold electrodes on octopus-like structures. Based on the robust adhesionand intimate contact with skin, we successfully obtained reliable measurements during dynamic motion under dry, wet, and damagedconditions.

关键词： biomimetics dry adhesive self-healing polymer stretchable electronics

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Recent Progress and New Horizons in Emerging Novel MXene-Based Materials for Energy Storage Applications for Current Environmental Remediation and Energy Crises

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Electrochemical Energy Reviews 2024年第1期7卷 700-786页

作者： Karim Khan Ayesha Khan Tareen Muhammad Iqbal Ye Zhang Asif Mahmood Nasir mahmood Zhe Shi Chunyang Ma J.R.Rosin Han Zhang Additive Manufacturing Institute Shenzhen UniversityShenzhen 518060GuangdongChina School of Mechanical Engineering Dongguan University of TechnologyDongguan 523808GuangdongChina Shenzhen Engineering Laboratory of Phosphorene and Optoelectronics International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of EducationInstitute of Microscale OptoelectronicsEngineeringShenzhen UniversityShenzhen 518060GuangdongChina Department of Bio‑Chemistry Quaid-I-Azam UniversityIslamabad 45320Pakistan School of Chemistry and Chemical Engineering University of South ChinaHengyang 421001HunanChina School of Chemical and Biomolecular Engineering The University of SydneySydneyNSW 2006Australia School of Science The Royal Melbourne Institute of Technology UniversityMelbourneVIC 3000Australia Department of Mechanical Engineering City University of Hong Kong83 Tat Chee AvenueKowloonHong KongChina

Unsustainable fossil fuel energy usage and its environmental impacts are the most significant scientific challenges in the scientific ***-dimensional(2D)materials have received a lot of attention recently because of their great potential for application in addressing some of society’s most enduring issues with renewable *** metal-based nitrides,carbides,or carbonitrides,known as“MXenes”,are a relatively new and large family of 2D *** the discovery of the first MXene,Ti_(3)C_(2) in 2011 has become one of the fastest-expanding families of 2D materials with unique physiochemical *** surface terminations with hydroxyl,oxygen,fluorine,etc.,are invariably present in the so far reported materials,imparting hydrophilicity to their *** current finding of multi-transition metal-layered MXenes with controlled surface termination capacity opens the door to fabricating unique structures for producing renewable *** NMs-based flexible chemistry allows them to be tuned for energy-producing/storage,electromagnetic interference shielding,gas/biosensors,water distillation,nanocomposite reinforcement,lubrication,and photo/electro/chemical *** review will first discuss the advancement of MXenes synthesis methods,their properties/stability,and renewable energy ***,we will highlight the constraints and challenges that impede the scientific community from synthesizing functional MXene with controlled composition and *** will further reveal the high-tech implementations for renewable energy storage applications along with future challenges and their solutions.

关键词： Recent development in synthesis Structures Properties of MXenes nanomaterials Propose approaches of diverse MXene-based nanoplatforms MXenes for renewable energy applications Optimization strategies and mechanisms to enhance MXenes compatibility Current challenges and probable progress for MXenes in renewable energy applications

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Bending the Rule: Naphthobisthiadiazole-Based Terpolymers with Both High Solubility and Crystallinity for Organic Photovoltaics

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ACS Applied Polymer Materials 2024年第5期6卷 2586-2593页

作者： Chou, Li-Hui Chen, Fengkun Nakano, Kyohei Yamanaka, Kodai Mikie, Tsubasa Saito, Masahiko Liu, Cheng-Liang Tajima, Keisuke Osaka, Itaru Department of Applied Chemistry Graduate School of Engineering Hiroshima University Hiroshima Higashi-Hiroshima739-8527 Japan Department of Chemical and Materials Engineering National Central University Taoyuan32001 Taiwan Saitama Wako351-0198 Japan Applied Chemistry Program Graduate School of Advanced Science and Engineering Hiroshima University Hiroshima Higashi-Hiroshima739-8527 Japan Department of Materials Science and Engineering National Taiwan University Taipei10617 Taiwan

Achieving a good balance between the crystallinity and solubility is of great importance in the design of π-conjugated polymers. Here, we synthesized a series of terpolymers in which small fractions of a planar V-shaped fused ring, triphenyleno[1,2-c:7,8-c′]bis([1,2,5]thiadiazole) (TPTz), are incorporated into the linear-shaped backbone of a highly crystalline polymer based on naphtho[1,2-c:5,6-c′]bis([1,2,5]thiadiazole) (NTz), PNTz4T. Due to the "bending" structure induced by the TPTz unit, the terpolymers had greatly improved solubility by about 5-9 times compared to the linear-shaped PNTz4T. In particular, the terpolymers preserved the crystallinity of PNTz4T to a considerable extent with a higher fraction of face-on oriented domains in films. As a result, the highly solution-processable terpolymers exhibited high photovoltaic performances and slightly outperformed PNTz4T. Our results indicate that the incorporation of a V-shaped unit into a linearly shaped polymer is a good strategy to develop π-conjugated polymers with high solubility and crystallinity. © 2024 American chemical Society.

关键词： Solubility

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