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Recent trends in metal ion based hydrogel biomaterials for tissue engineering and other biomedical applications

Journal of Materials science & Technology 2021年第4期63卷 35-53页

作者： Gopinathan Janarthanan Insup Noh Department of Chemical and Biomolecular Engineering Seoul National University of Science and TechnologySeoul01811Republic of Korea Convergence Institute of Biomedical Engineering and Biomaterials Seoul National University of Science and TechnologySeoul01811Republic of Korea

Recently,the metal ion cross-linked hydrogels have gained enormous interest because of its excellent properties like self-healing,fast recovery,biocompatibility and high mechanical properties combined with multi-stimuli *** this review article,we have summarized the recent trends in the development of metal ion cross-linked hydrogels for tissue engineering and biomedical applications.A number of metal ions and their contribution in the synthesis of various cross-linked hydrogels are discussed with respect to their crosslinking mechanisms,compositions,physio-chemical and biological properties.A special emphasis has been given to ferric(Fe^(3+))ion cross-linked hydrogels and their different combinations owing to their numerous researches reported in the recent past with exceptional *** application of these metal ion based hydrogels in biomedical applications including tissue engineering,sensing,wound healing,drug delivery and as tissue adhesive and tissue sealants are reviewed with specific ***,the application of these metal ion cross-linked hydrogels as inks in 3 D printing is explained in a separate ***,the possible toxic effects of the different metal ions and their effects have been *** directions and comprehensive applications of the hydrogels are highlighted.

关键词： properties. biomaterials exceptional

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Advances in green synthesis and applications of graphene

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Nano Research 2021年第11期14卷 3724-3743页

作者： Qi Yu Jianchao Jiang Liyun Jiang Qingqing Yang Ning Yan Shaanxi Key Laboratory of Catalysis School of Materials Science and EngineeringShaanxi University of TechnologyHanzhong723001China Department of Chemical and Biomolecular Engineering National University of SingaporeSingapore117585Singapore

Green synthesis has grabbed appreciable attention to eliminate the negative effects associated with various chemical processes. Due to the unparalleled electrical, mechanical, thermal and excellent physical properties, graphene, as the thinnest two-dimensional material with high surface area, has the unfathomable potential in the domain of green chemistry in terms of both synthesis and application. In this regard, we present an overview of the research progresses on the greener synthesis of graphene, including micromechanical exfoliation, chemical reduction of graphene oxide (GO), chemical vapor synthesis and popping of GO. Meanwhile, various applications of graphene pertinent to sustainable developments, such as energy storage, catalysis, electrochemistry, fuel cell, supercapacitor and biomedicine have also been highlighted.

关键词： green chemistry graphene synthesis catalysis supercapacitor

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Heterogeneous Catalyst as a Functional Substrate Governing the Shape of Electrochemical Precipitates in Oxygen-Fueled Rechargeable Batteries

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Journal of the American chemical Society 2023年第28期145卷 15425-15434页

作者： Park, Mihui Cho, Seonyong Yang, Junghoon Lau, Vincent Wing-Hei Kim, Kwang Hee Park, Jong Hyeok Ringe, Stefan Kang, Yong-Mook Department of Materials Science and Engineering Korea University Seoul02841 Korea Republic of Department of Energy and Materials Engineering Dongguk University-Seoul Seoul04620 Korea Republic of Jeonju54853 Korea Republic of Department of Chemistry National Cheng Kung University Tainan City701 Taiwan Department of Chemical and Biomolecular Engineering Yonsei University Seoul03722 Korea Republic of Department of Chemistry Korea University Seoul02841 Korea Republic of KU-KIST Graduate School of Converging Science and Technology Korea University Seoul02841 Korea Republic of

Lithium-oxygen batteries have the potential to become the most eminent solution for future energy storage with their theoretical energy density exceeding all existing batteries. However, the insulating and insoluble discharge product (lithium peroxide;Li2O2) impairs practical application. Conventional catalyst designs based on the electronic structure and interfacial charge transfer descriptors have not been able to overcome these limitations due to Li2O2. Herein, we revisit the role of heterogeneous catalysts as substrates to regulate Li2O2 growth and the formation of solid/solid reaction interfaces. We demonstrate that controlled solid/solid interfacial structure design is a critical performance parameter beyond the inherent electronic structure. In particular, the Cu2O substrate in this study induces a homogeneous deposition of Pd atoms, which leads to well-controlled growth of Li2O2 resolving mass and charge transport limits (i.e., the bottleneck of oxygen reduction/evolution reactions), thus improving reversibility, capacity, and durability of the cells by dissipating electrochemical and mechanical stress. We thus verified the essential role of solid/solid interfaces to regulate the nucleation and growth process of Li2O2 in lithium-oxygen batteries. © 2023 American chemical Society.

关键词： Lithium compounds

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Optimizing Neural Networks for Academic Performance Classification Using Feature Selection and Resampling Approach

Mendel

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Mendel 2023年第2期29卷 261-272页

作者： Supriyadi, Didi Purwanto, Purwanto Warsito, Budi Doctorate Program of Information Systems School of Postgraduate Studies Universitas Diponegoro Semarang Indonesia Department of Chemical Engineering Faculty of Engineering Universitas Diponegoro Semarang Indonesia Department of Statistics Faculty of Science and Mathematics Universitas Diponegoro Semarang Indonesia Department of Information System Faculty of Informatics Institut Teknologi Telkom Purwokerto Banyumas Indonesia

The features present in large datasets significantly affect the performance of machine learning models. Redundant and irrelevant features will be rejected and cause a decrease in machine learning model performance. This paper proposes HyFeS-ROS-ANN: Hybrid Feature Selection and Resampling combination method for binary classification using artificial neural network multilayer perceptron (MLP). The first stage of this approach is to use a combination of two feature selection methods to select essential features that are highly correlated with model performance. The second stage of this approach is to use a combination of resampling methods to handle unbalanced data classes. Both approaches are applied to the academic performance classification model using the MLP neural network. This research dataset is obtained using three-dimensional (3D) frameworks such as the Big Five Personality to determine the Personality that affects academic performance from the student dimension, the Family Influence Scale (FIS), which measures factors that affect academic performance from the family dimension, and Higher Education Institutions Service Quality (HEISQUAL) to measure service quality and its influence on academic performance from the Education institution dimension. Previous research shows that the CoR-ANN algorithm has a model accuracy rate of 94%. The research results based on the dataset show that our proposed method can improve accuracy by selecting more relevant and essential features in improving model performance. The results show that the features are reduced from 135 to 108, while the HyFS-ROS-ANN model for binary classification accuracy increases to 100%. © 2023, Brno University of Technology. All rights reserved.

关键词： Feature Selection

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Universal nanocomposite coating with antifouling and redox capabilities for electrochemical affinity biosensing in complex biological fluids

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Nanoscale Horizons 2024年第5期9卷 843-852页

作者： Bharti, Aditya Manu Rakesh Kumar, R.K. Chuang, Cheng-Hsin Shaikh, Muhammad Omar International PhD Program for Science National Sun Yat-sen University Kaohsiung80424 Taiwan Institute of Medical Science and Technology National Sun Yat-sen University Kaohsiung80424 Taiwan Department of Chemical Engineering National Taiwan University Taipei City10617 Taiwan Institute of Biomedical Engineering and Nanomedicine National Healthcare Research Institutes Miaoli County350 Taiwan National Sun Yat-sen University Kaohsiung80424 Taiwan Sustainability Science and Management Program Tunghai University Taichung407224 Taiwan

Electrochemical affinity biosensors have the potential to facilitate the development of multiplexed point-of-care diagnostics in complex biological fluids. However, their commercial viability has been hindered by challenges such as electrode biofouling and the lack of inherent redox properties. To address this unmet need, we have developed a universal nanocomposite coating which is unique in its ability to not only allow oriented conjugation of the biorecognition element but also specific detection directly in complex biological fluids like serum and urine owing to its built-in antifouling and redox capabilities, thus improving suitability for point of care testing. This multifunctional coating comprises a 3D porous crosslinked bovine serum albumin matrix for oriented conjugation and antifouling properties with embedded graphene nanosheets modified with amino-ferrocene for enhanced conductivity and mediator-free biosensing. The coating showed minimal signal degradation despite prolonged exposure to 1% bovine serum albumin, artificial urine and untreated human serum for up to 30 days. To demonstrate its utility, we fabricated and tested proof-of-concept electrochemical immunosensors for bladder cancer protein biomarkers, specifically interleukin-8 (IL-8) and vascular endothelial growth factor (VEGF). The practical feasibility was highlighted by the excellent sensitivity and specificity observed for IL-8 and VEGF with a limit of detection of 41 pg mL−1 and 67 pg mL−1, respectively. Consequently, this universal nanocomposite-based electrochemical biosensing platform can be extended to the point of care testing of a broad spectrum of biomarkers present in complex biological fluids, thus enabling reliable and early diagnostics. © 2024 The Royal Society of Chemistry

关键词： Biomarkers

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Hydrocarbon ionomer/polytetrafluoroethylene composite membranes containing radical scavengers for robust proton exchange membrane water electrolysis

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European Polymer Journal 2025年 234卷

作者： Park, Ga Young Noh, Yi Sak Jeong, Hwan Yeop Yoon, Sang Jun Oh, Keun-Hwan So, Soonyong Kim, Jeonghun Choi, Jaewon Yu, Duk Man Daejeon34114 Cuba Department of Polymer Science and Engineering Kyungpook National University Daegu41566 Cuba Department of Chemical and Biomolecular Engineering Yonsei University Seoul03722 Cuba

A hydrocarbon-based composite membrane incorporating radical scavengers is successfully fabricated using sulfonated poly(arylene ether sulfone) copolymers with a 50 % sulfonation degree (SP50), porous polytetrafluoroethylene (PTFE) substrates, and cerium oxide (CeO2) nanoparticles for proton exchange membrane water electrolysis (PEMWE). The CeO2 nanoparticles are uniformly dispersed in the SP50 solution through a ball milling, and the PTFE substrate is treated with n-propyl alcohol to improve the interfacial compatibility between the SP50/CeO2 solution and PTFE. Additionally, a five-layered structure incorporating two PTFE layers is employed to form robust interlocking interfaces between SP50 and PTFE. Consequently, the composite membrane with CeO2 exhibits excellent dimensional stability, mechanical properties, and a 3.8-fold reduction in hydrogen permeability as compared with that of the Nafion 212 (N212) membrane. In the hydrothermal tests, the composite membrane demonstrates excellent chemical stability due to the inclusion of CeO2. During PEMWE operation, the cell performance of the composite membrane is 7.42 A/cm2 at 1.9 V, surpassing those of SP50 (5.95 A/cm2) and N212 (5.66 A/cm2). Over the course of the durability test, the composite membrane exhibits the lowest degradation rate (DR). Furthermore, the molecular weight of the composite membrane decreases by only 5 %, significantly outperforming SP50, which shows a 50 % reduction. Therefore, the composite membrane with a radical scavenger provides excellent physical and chemical stability for PEMWE applications. © 2025

关键词： Composite membranes

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Zeolitic imidazolate framework-67 derived Al-Co-S hierarchical sheets bridged by nitrogen-doped graphene:Incorporation of PANI derived carbon nanorods for solid-state asymmetric supercapacitors

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Journal of Energy Chemistry 2022年第11期31卷 429-445,I0012页

作者： Emad S.Goda Bidhan Pandit Sang Eun Hong Bal Sydulu Singu Seong K.Kim Essam B.Moustafa Kuk Ro Yoon Kuk Ro Yoon Organic Nanomaterials Lab Department of ChemistryHannam UniversityDaejeon 34054Republic of Korea Gas Analysis and Fire Safety Laboratory Chemistry DivisionNational Institute for Standards136Giza 12211Egypt Department of Materials Science and Engineering and Chemical Engineering Universidad Carlos Ⅲ de MadridAvenida de La Universidad 3028911 LeganésMadridSpain Department of Chemical and Biomolecular Engineering Yonsei UniversitySeoul 03722Republic of Korea Department of Chemical Engineering Hannam University1646 Yuseongdae-roYuseong-guDaejeon 34054Republic of Korea Mechanical Engineering Department Faculty of EngineeringKing Abdulaziz UniversityP.O.Box 80204Jeddah 22254Saudi Arabia

Metal sulfides have been widely enticed as battery-type electrodes in supercapacitor devices because of their maximal theoretical ***,their lower conductivity and ion transport kinetics can largely restrict their rate performance,hence the practical usage in fields of demanding high power ***,the design of new electrodes with higher energy and power densities remains a highly challenging *** the best of our knowledge,a novel hierarchical composite of Al-CoS_(2) on nitrogendoped graphene(NG)is prepared based on a zeolite imidazole framework using a simple and scalable hydrothermal *** this hybrid,ultrathin Al-CoS_(2) nanosheet arrays are vertically orientated on the NG framework to limit self-aggregation,hence increasing the electrical property and cycle stability of *** is investigated that the Al/Co feeding ratio plays a crucial role in controlling the obtained hierarchical structure of Al-Co-S sheets and their electrode ***,Al^(3+) can influence remarkably the morphology and electrochemical property of the resultant graphene *** effective synergism is noticed between the redox Al-CoS_(2) and NG resulting in fast electron transfer and chargingdischarging ***,when the as-developed composite is utilized as a positive electrode at an applied current density of 1 A/g,a specific capacitance of 1915.8 F/g is attained with ultra-long cycle stability(96%,10,000 cycles)and an excellent retention rate(~89%).As a consequence,when a solid-state asymmetric supercapacitor(ASC)device is made by combining an Al-CoS_(2) @NG hybrid with a negative electrode made of polyaniline(PANI)derived carbon nanorods(PCNRs),it demonstrates remarkable specific capacitance(188 F/g),energy density(66.9 Wh/kg),and cyclic stability of 92%after 10,000 *** may open the pathway for the application of the next-generation supercapacitors in the future.

关键词： Hierarchical sheets MOFs Al-doped CoS_(2) Nitrogen-doped graphene Solid-state supercapacitor

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Optimization of photocatalytic ceramic membrane filtration by response surface methodology: Effects of hydrodynamic conditions on organic fouling and removal efficiency

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Chemosphere 2024年 356卷 141885页

作者： Jang, Hoseok Lee, Chang Soo Kim, Jong Hak Kim, Jeonghwan Department of Environmental Engineering Program of Environmental and Polymer Engineering Inha University Michuholgu Incheon22212 Korea Republic of Department of Chemical Engineering Pukyong National University Busan48513 Korea Republic of Department of Chemical and Biomolecular Engineering Yonsei University Seoul03722 Korea Republic of

The effects of the operating conditions, including the applied pressure, feed organic concentration, and recirculation flowrate along the TiO2-coated ceramic membrane, on the normalized membrane permeability and organic removal efficiency were systematically investigated by operating a photocatalytic membrane reactor (PMR). Response surface methodology (RSM) was conducted to better understand the interactive effect of operational conditions as well as their individual and combined effects to control membrane performance. Our results showed that the applied pressure and feed organic concentration, as single parameter, affected the normalized membrane permeability and organic removal efficiency more dominantly than the recirculation flowrate. The polynomial performance equations generated by RSM successfully predicted the membrane performance of the PMR. The responses to the normalized membrane permeability and organic removal efficiency with respect to the operational conditions were less sensitive to any combination of operational conditions than to their individual impacts. The combined effects of the operating conditions were less pronounced in promoting the catalytic performance of organic contaminants on the TiO2 surface. Our RSM analysis based on experimental observations designed by Box–Behnken Design (BBD) suggested that 1.3 bar of applied pressure, 44 mg/L of feed organic dye concentration and 0.8 L/min as recirculation flowrate as optimum conditions achieved more than 98% of organic removal efficiency and less than 5% of decline in normalized membrane permeability. This research shows that the RSM provides effective tool to optimize operational conditions to determine fouling rate and organic removal in PMR. © 2024 Elsevier Ltd

关键词： Titanium dioxide

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Fused-ring induced end-on orientation in conjugated molecular dyads toward efficient single-component organic solar cells

Aggregate

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Aggregate 2023年第2期4卷 291-299页

作者： Dongdong Xia Shengxi Zhou Wen Liang Tan Safakath Karuthedath Chengyi Xiao Chaowei Zhao Frédéric Laquai Christopher R.McNeill Weiwei Li Institute of Applied Chemistry Jiangxi Academy of SciencesNanchangChina Beijing Advanced Innovation Center for Soft Matter Science and Engineering&State Key Laboratory of Organic-Inorganic Composites Beijing University of Chemical TechnologyBeijingChina Department of Materials Science and Engineering Monash UniversityClaytonAustralia KAUST Solar Center(KSC) Physical Sciences and Engineering Division(PSE)Material Science and Engineering Program(MSE)King Abdullah University of Science and Technology(KAUST)ThuwalSaudi Arabia

The molecular orientations of conjugated materials on the substrate mainly include edge-on,face-on,and ***-on and face-on orientations have been widely observed,while end-on orientation has been rarely *** in organic solar cells(OSCs)charge transport is along the vertical direction,end-on orientation with conjugated backbones perpendicular to the substrate is recognized as the ideal microstructure for *** this work,we for the first time obtained the preferential end-on orientation in a conjugated molecular dyad that contains a conjugated backbone as donor and perylene bisimide side units as *** was realized by introducing a fused-ring structure to replace linear terthiophenes with conjugated backbones,yielding F-MDPBI and L-MDPBI ***,a shifting trend of the molecular orientation from dominating edge-on in L-MDPBI to preferential end-on in F-MDPBI was *** a consequence,vertical charge carrier mobilities in F-MDPBI are one order of magnitude higher than those with preferential edge-on orientation,so single-component OSCs based on this molecular dyad as a single photoactive layer provided a power conversion efficiency of 4.89% compared to 1.70% based on L-MDPBI with preferential edge-on orientation.

关键词： conjugated molecular dyads crystallinity edge-on end-on single-component organic solar cells

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Catalytic conversion of soluble aniline into insoluble N-phenylphenazine for wastewater treatments

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Chemosphere 2024年 366卷 143492页

作者： Wang, Ying Zhang, Zhuang Yang, Kun-Lin Department of Chemical and Biomolecular Engineering National University of Singapore 4 Engineering Drive 4 117585 Singapore Department of Materials Science & Engineering National University of Singapore 7 Engineering Drive 1 117574 Singapore

Aniline, a common pollutant in industrial wastewater, requires an effective treatment method with minimal chemical usage. In this study, a two-stage catalytic oligomerization process has been developed to address this issue by converting soluble aniline into insoluble oligomers for wastewater treatment. In the first stage, aniline is oxidized using hydrogen peroxide (H2O2) and a green catalyst, iron tetraamido macrocyclic ligand (Fe-TAML) to form aniline tetramers or pentamers. In the second stage, these oligoanilines undergo further oxidation with H2O2 alone at a higher temperature, resulting in the formation of N-phenylphenazine or its derivatives. These macrocyclic compounds precipitate from the wastewater due to π− π stacking, allowing easy separation through decantation or gravity filtration. After process optimization, only 3 mg/L of Fe-TAML and 2 g/L of H2O2 are required to treat 1 g/L of aniline, achieving a remarkable 96.8% aniline removal efficiency and a 62.5% precipitate yield. This two-stage oxidation approach shows promise for treating aniline and similar aromatic compounds in real industrial wastewater. © 2024 Elsevier Ltd

关键词： Wastewater treatment

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