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Overcoming small-bandgap charge recombination in visible and NIR-light-driven hydrogen evolution by engineering the polymer photocatalyst structure

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Nature communications 2024年第1期15卷 707页

作者： Mohamed Hammad Elsayed Mohamed Abdellah Ahmed Zaki Alhakemy Islam M A Mekhemer Ahmed Esmail A Aboubakr Bo-Han Chen Amr Sabbah Kun-Han Lin Wen-Sheng Chiu Sheng-Jie Lin Che-Yi Chu Chih-Hsuan Lu Shang-Da Yang Mohamed Gamal Mohamed Shiao-Wei Kuo Chen-Hsiung Hung Li-Chyong Chen Kuei-Hsien Chen Ho-Hsiu Chou Department of Chemistry Faculty of Science Al-Azhar University Nasr City 11884 Cairo Egypt. Institute of Atomic and Molecular Sciences Academia Sinica Taipei 10617 Taiwan. Center for Condensed Matter Sciences National Taiwan University Taipei 10617 Taiwan. Department of Chemical Engineering National Tsing Hua University Hsinchu 300044 Taiwan. Department of Chemistry United Arab Emirates University Al Ain P.O. Box 15551 United Arab Emirates. Department of Chemistry Qena Faculty of Science South Valley University 83523 Qena Egypt. Chemical Physics and NanoLund Lund University 22100 Lund Sweden. Chemistry Department Faculty of Science Al-Azhar University Assiut 71542 Egypt. Sustainable Chemical Science and Technology Taiwan International Graduate Program Taipei Taiwan. Department of Applied Chemistry National Yang Ming Chiao Tung University Hsinchu 30010 Taiwan. Institute of Chemistry Academia Sinica 128 Sec 2 Academia Rd. Nankang Taipei 11529 Taiwan. Institute of Photonics Technologies National Tsing Hua University Hsinchu 300044 Taiwan. Center of Atomic Initiative for New Materials National Taiwan University Taipei 10617 Taiwan. Department of Chemical Engineering National Chung Hsing University Taichung 40227 Taiwan. Department of Materials and Optoelectronic Science Center for Functional Polymers and Supramolecular Materials National Sun Yat-Sen University Kaohsiung 804 Kaohsiung Taiwan. Department of Physics National Taiwan University Taipei 10617 Taiwan. Department of Chemical Engineering National Tsing Hua University Hsinchu 300044 Taiwan. hhchou@mx.nthu.edu.tw.

Designing an organic polymer photocatalyst for efficient hydrogen evolution with visible and near-infrared (NIR) light activity is still a major challenge. Unlike the common behavior of gradually increasing the charge recombination while shrinking the bandgap, we present here a series of polymer nanoparticles (Pdots) based on ITIC and BTIC units with different π-linkers between the acceptor-donor-acceptor (A-D-A) repeated moieties of the polymer. These polymers act as an efficient single polymer photocatalyst for H2 evolution under both visible and NIR light, without combining or hybridizing with other materials. Importantly, the difluorothiophene (ThF) π-linker facilitates the charge transfer between acceptors of different repeated moieties (A-D-A-(π-Linker)-A-D-A), leading to the enhancement of charge separation between D and A. As a result, the PITIC-ThF Pdots exhibit superior hydrogen evolution rates of 279 µmol/h and 20.5 µmol/h with visible (>420 nm) and NIR (>780 nm) light irradiation, respectively. Furthermore, PITIC-ThF Pdots exhibit a promising apparent quantum yield (AQY) at 700 nm (4.76%).

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Morfology, Microstrucuture and Electrocatalytical Properties of Sol-Gel Spin Coated Bi05na05ba(Tio3)2 Thin Films

SSRN

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SSRN 2022年

作者： Batista, Carlos Yago Pereira Romaguera–Barcelay, Yonny Matos, Robert Saraiva Pedraça, Aline dos Santos Amâncio, Moisés do Amaral Kourouma, Ansoumane Ruiz, Yurimiler Leyet Cotta, Eduardo Adriano Brito, Walter Ricardo Gandarilla, Ariamna María Dip do Nascimento, Marcus Valério Botelho Nobre, Francisco Xavier Ferreira, Nilson S. Salerno, Marco da Fonseca Filho, Henrique Duarte Technological Materials Processing Laboratory Federal University of Amazonas Amazonas Manaus69067-005 Brazil BioMark UC Department of Chemical Engineering Faculty of Sciences and Technology University of Coimbra Coimbra3030-790 Portugal Department of Physics Federal University of Amazonas Amazonas Manaus69067-005 Brazil Department of Physics Federal University of Amapá Amapá Macapá68902-280 Brazil Electrical Engineering postgraduate program Federal University of Amazonas Amazonas Manaus69067-005 Brazil Department of Chemistry Federal University of Amazonas Amazonas Manaus69067-005 Brazil Department of Pharmaceutical Sciences Gamal Abdel Nasser University of Conakry Guinea-bissau Federal Institute of Amazonas—Campus Coari Coari69460-000 Brazil Department of Physics Federal University of Sergipe São Cristovão Sergipe49100-000 Brazil Institute for Materials Science Max Bergmann Center of Biomaterials Technische Universität Dresden Dresden01069 Germany Laboratory of Nanomaterials Synthesis and Nanoscopy Department of Physics Federal University of Amazonas Amazonas Manaus69067-005 Brazil

Herein, we report, for the first time, the reduction reaction kinetics of ciprofloxacin organic molecules based on structural and micromorphological conditions of an electrocatalytic system of Bi05Na05Ba(TiO3)2 (BNT-BT) thin films. XRD analysis showed the coexistence of rhombohedral and tetragonal structures for the BNT-BT thin films annealed at 600, 650, and 700°C, showing that the first one had a greater number of surface defects, which was confirmed by Raman Spectroscopy. Analysis of the 3D micromorphological evaluation showed that an annealing temperature increase from 600 to 700 °C does not induce significant changes in the topographical profile. However, BNT-BT thin films annealed at 600 °C displayed more anisotropic surface microtexture, high spatial complexity, and low spatial frequencies. For the reactive surface of BNT-BT films, the electroanalytical assays showed that electrons from the conduction band are captured by oxygen adsorbed on the film surface, forming superoxide radicals that attack ciprofloxacin molecules, promoting their degradation. The best performance observed for the BNT-BT thin films annealed at 600 ºC is attributed to their unique structural and micromorphological properties compared to the films annealed with higher temperatures. Our results prove that the proposed thin film deposition process is a promising approach for developing new electrocatalytic devices. © 2022, The Authors. All rights reserved.

关键词： Sol-gels

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Critical pore radius and transport properties of disordered hard- And overlapping-sphere models

arXiv

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arXiv 2021年

作者： Klatt, Michael A. Ziff, Robert M. Torquato, Salvatore Department of Physics Princeton University PrincetonNJ08544 United States Institut für Theoretische Physik FAU Erlangen-Nürnberg Staudtstr. 7 Erlangen91058 Germany Center for the Study of Complex Systems Department of Chemical Engineering University of Michigan Ann ArborMI48109 United States Department of Physics Princeton University PrincetonNJ08544 United States Department of Chemistry Princeton Institute for the Science and Technology of Materials Program in Applied and Computational Mathematics Princeton University PrincetonNJ08544 United States

Transport properties of porous media are intimately linked to their pore-space microstructures. We quantify geometrical and topological descriptors of the pore space of certain disordered and ordered distributions of spheres, including pore-size functions and the critical pore radius δc. We focus on models of porous media derived from maximally random jammed sphere packings, overlapping spheres, equilibrium hard spheres, "quantizer" sphere packings, and crystalline sphere packings. For precise estimates of the percolation thresholds, we use a strict relation of the void percolation around sphere configurations to weighted bond percolation on the corresponding Voronoi networks. We use the Newman-Ziff algorithm to determine the percolation threshold using universal properties of the cluster size distribution. The critical pore radius δc is often used as the key characteristic length scale that determines the fluid permeability k. A recent study [Torquato. Adv. Wat. Resour. 140,103565 (2020)] suggested for porous media with a well-connected pore space an alternative estimate of k based on the second moment of the pore size hδ2i, which is easier to determine than δc. Here, we compare δc to the second moment of the pore size hδ2i, and indeed confirm that, for all porosities and all models considered, δc2 is to a good approximation proportional to hδ2i. However, unlike hδ2i, the permeability estimate based on δc2 does not predict the correct ranking of k for our models. Thus, we confirm hδ2i to be a promising candidate for convenient and reliable estimates of the fluid permeability for porous media with a well-connected pore space. Moreover, we compare the fluid permeability of our models with varying degrees of order, as measured by the τ order metric. We find that (effectively) hyperuniform models tend to have lower values of k than their nonhyperuniform counterparts. Our findings could facilitate the design of porous media with desirable transport properties via target

关键词： Porous materials

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Charge and spin degrees of freedom in A-site ordered YCu3Co4O12 and CaCu3Co4O12

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Physical Review B 2021年第11期103卷 115149-115149页

作者： Yi-Ying Chin Zhiwei Hu Yuichi Shimakawa Junye Yang Youwen Long A. Tanaka Liu Hao Tjeng Hong-Ji Lin Chien-Te Chen Department of Physics National Chung Cheng University Chiayi 62102 Taiwan Max Planck Institute for Chemical Physics of Solids Nöthnitzer Strasse 40 01187 Dresden Germany Institute for Chemical Research Kyoto University Kyoto 611-0011 Japan Beijing National Laboratory for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences Beijing 100190 China Songshan Lake Materials Laboratory Dongguan Guangdong 523808 China Quantum Matter Program Graduate School of Advanced Science and Engineering Hiroshima University Higashi-hiroshima 739-8530 Japan National Synchrotron Radiation Research Center (NSRRC) 101 Hsin-Ann Road Hsinchu 30076 Taiwan

Using soft x-ray absorption spectroscopy we were able to determine unambiguously the charge and spin states of the transition metal ions in stoichiometric YCu3Co4O12 and CaCu3Co4O12. The trivalent and low-spin nature of both the Cu and Co ions in YCu3Co4O12 makes this correlated system to be effectively a nonmagnetic band semiconductor. The substitution of Y by Ca produces formally tetravalent Co ions but the doped holes are primarily on the oxygen ligands. Concerning the spin degrees of freedom, the trivalent Co ions in YCu3Co4O12 remain low spin upon the Y-Ca substitution, very much unlike the La1−xSrxCoO3 system. The tetravalent Co ions in CaCu3Co4O12 are interestingly also in the low-spin state, which then explains the good electrical conductivity of CaCu3Co4O12 since charge exchange between neighboring Co3+ and Co4+ ions will not be hampered by the spin-blockade mechanism that otherwise would be in effect if the Co4+ and Co3+ spin quantum numbers were to differ by more than one-half. We infer that the stability of the Co low-spin state is related to the very short Co-O bond lengths.

关键词： Electrical conductivity Oxides Strongly correlated systems X-ray absorption spectroscopy

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The effectiveness of distance learning through Edmodo and Video Conferencing Jitsi Meet

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Journal of Physics: Conference Series 2021年第1期1760卷

作者： A M I T Asfar A M I A Asfar Department of Mathematics Education STKIP Muhammadiyah Bone Indonesia Doctoral Program Science Education Universitas Negeri Makassar Indonesia Department of Chemical Engineering of Politeknik Negeri Ujung Pandang Indonesia

Distance learning is intensively used since the outbreak of the Covid-19 requires the lecture to be done from home. A variety of applications to support distance learning, including e-learning Edmodo as a learning management system with video conference jits meet to optimize lectures online. The purpose of this study is to see the course's effectiveness by using e-learning Edmodo with or without a video conference Jitsi Meet in reducing students' mistakes in answering the questions given. Research design using experimental type posttest, only group control design. The object of research consists of two classes, namely class control and class comparison. The analysis results indicate the use of an e-learning Edmodo integrated video conference Jitsi Meet provides advantages compared to only using e-learning Edmodo because it can reduce the level of error in answering questions by 50%.

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Learning design: Integrated local tradition ma'dawa-dawa, ma'manu-manu, ma'pettuada based on android

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Journal of Physics: Conference Series 2021年第1期1760卷

作者： A Nurannisa A M I T Asfar A M I A Asfar Department of Mathematics Education STKIP Muhammadiyah Bone Indonesia Doctoral Program Science Education Universitas Negeri Makassar Indonesia Department of Chemical Engineering of Politeknik Negeri Ujung Pandang Indonesia

Mathematical skills that are of major concern at this time are extrapolation abilities which require students to be able to solve mathematical problems with abstract and hierarchical concepts. To improve this capability, it can be done by integrating local technology-based traditions that have an educational philosophy. This study aims to review the integrated learning design of the local culture of Ma'dawa-dawa, Ma'manu-manu, Ma'pettuada based on android in improving extrapolation abilities. This research uses a descriptive qualitative research method with data in the form of analysis of some literature that supports research studies and is arranged descriptively containing a theoretical basis. The results of the study indicate that designed learning can be a means of developing extrapolation abilities through the integration of technology-based local cultures.

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Carbon free high loading silicon anodes enabled by sulfide solid electrolytes for robust all solid-state batteries

arXiv

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arXiv 2021年

作者： Tan, Darren H.S. Chen, Yu-Ting Yang, Hedi Bao, Wurigumula Sreenarayanan, Bhagath Doux, Jean-Marie Li, Weikang Lu, Bingyu Ham, So-Yeon Sayahpour, Baharak Scharf, Jonathan Wu, Erik A. Deysher, Grayson Han, Hyea Eun Hah, Hoe Jin Jeong, Hyeri Chen, Zheng Meng, Ying Shirley Department of NanoEngineering University of California San Diego San diegoCA92093 United States LG Energy Solution Ltd. LG Science Park Magokjungang 10-ro Gangseo-gu Seoul07796 Korea Republic of Program of Chemical Engineering University of California San Diego San diegoCA92093 United States University of California San Diego San diegoCA92093 United States

The development of silicon anodes to replace conventional graphite in efforts to increase energy densities of lithium-ion batteries has been largely impeded by poor interfacial stability against liquid electrolytes. Here, stable operation of 99.9 weight% micro-Si (µSi) anode is enabled by utilizing the interface passivating properties of sulfide based solid-electrolytes. Bulk to surface characterization, as well as quantification of interfacial components showed that such an approach eliminates continuous interfacial growth and irreversible lithium losses. In µSi || layered-oxide full cells, high current densities at room temperature (5 mA cm-2), wide operating temperature (-20°C to 80°C) and high loadings (>11 mAh cm-2) were demonstrated for both charge and discharge operations. The promising battery performance can be attributed to both the desirable interfacial property between µSi and sulfide electrolytes, as well as the unique chemo-mechanical behavior of the Li-Si alloys. © 2021, CC BY.

关键词： Solid-State Batteries

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Lignin Extracted from Green Coconut Waste Impregnated with Sodium Octanoate for Removal of Cu2+ in Aqueous Solution

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Processes 2025年第5期13卷 1590-1590页

作者： Pereira, Jéssyca E. S. Neto, Eduardo L. Barros Duarte, Lindemberg J. N. Ferreira, Ruan L. S. Melo, Ricardo P. F. Nascimento, Paula F. P. Chemical Engineering Graduate Program Federal University of Rio Grande do Norte Rio Grande do Norte Natal59072-970 Brazil Petroleum Engineering Department Federal University of Rio Grande do Norte Rio Grande do Norte Natal59078-900 Brazil Science and Technology of Pernambuco Civil Construction Department Federal Institute of Education Pernambuco Pesqueira55200-000 Brazil Exact and Natural Sciences Department Federal University of Semi-Árido Ferros Rio Grande do Norte59900-000 Brazil SENAI Institute of Innovation in Renewable Energy ISI-ER Natal Rio Grande do Norte59063-400 Brazil

Investigating viable processes for the use of lignocellulosic biomass in clean fuels and high-value-added chemical products is essential for sustainable development. Large amounts of lignin are available every year as by-products of the paper and biorefinery industries, causing a series of problems, particularly environmental ones. Its structure and composition make lignin compatible with the concept of sustainability, since it can be used to produce new chemical products with high added value. As such, this study aims to extract lignin from green coconut fiber (LIG), with the subsequent impregnation of a sodium-octanoate-based surfactant (LIG-SUR), and determine its applicability as an adsorbent for removing copper ions from synthetic waste. To this end, the green coconut fiber lignocellulosic biomass was initially subjected to alkaline pre-treatment with 2% (w/v) sodium hydroxide in an autoclave. Next, the surface of the lignin was modified by impregnating it with sodium octanoate, synthesized from the reaction of octanoic acid and NaOH. The physical and chemical traits of the lignin were studied before and after surfactant impregnation, as well as after copper ion adsorption. The lignin was analyzed by X-ray fluorescence (XRF), Fourier transform infrared (FTIR) and scanning electron microscopy (SEM). The adsorption tests were carried out using lignin pre-treated with surfactant in a batch system, where the effects of pH and adsorbent concentration were investigated. XRF and SEM analyses confirmed surfactant impregnation, with Na2O partially replaced by CuO after Cu2+ adsorption. FTIR analysis revealed shifts in O–H, C–H, C=O, and C=C bands, indicating electrostatic interactions with lignin. Adsorption kinetics followed the pseudo-second-order model, suggesting chemisorption, with equilibrium reached in approximately 10 and 60 min for LIG-SUR and LIG, respectively. The Langmuir model best described the isotherm data, indicating monolayer adsorption. LIG-SUR remove

关键词： Impregnation

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Unpredictability in seasonal infectious diseases spread

arXiv

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arXiv 2022年

作者： Gabrick, Enrique C. Sayari, Elaheh Protachevicz, Paulo R. Szezech, José D. Iarosz, Kelly C. de Souza, Silvio L.T. Almeida, Alexandre C.L. Viana, Ricardo L. Caldas, Iberê L. Batista, Antonio M. Graduate Program in Science State University of Ponta Grossa PR Ponta Grossa84030-900 Brazil Institute of Physics University of São Paulo SP São Paulo Brazil Institute for Complex Systems and Mathematical Biology University of Aberdeen Aberdeen United Kingdom Department of Mathematics and Statistics State University of Ponta Grossa PR Ponta Grossa84030-900 Brazil University Center UNIFATEB Telêmaco Borba PR 84266-010 Brazil Graduate Program in Chemical Engineering Federal Technological University of Paraná PR Ponta Grossa Brazil Federal University of São João del-Rei Campus Centro-Oeste Divinópolis MG 35501-296 Brazil Physics and Mathematics Department Federal University of São João del-Rei MG Ouro Branco36415-000 Brazil Department of Physics Federal University of Paraná PR Curitiba Brazil

In this work, we study the unpredictability of seasonal infectious diseases considering a SEIRS model with seasonal forcing. To investigate the dynamical behaviour, we compute bifurcation diagrams type hysteresis and their respective Lyapunov exponents. Our results from bifurcations and the largest Lyapunov exponent show bistable dynamics for all the parameters of the model. Choosing the inverse of latent period as control parameter, over 70% of the interval comprises the coexistence of periodic and chaotic attractors, bistable dynamics. Despite the competition between these attractors, the chaotic ones are preferred. The bistability occurs in two wide regions. One of these regions is limited by periodic attractors, while periodic and chaotic attractors bound the other. As the boundary of the second bistable region is composed of periodic and chaotic attractors, it is possible to interpret these critical points as tipping points. In other words, depending on the latent period, a periodic attractor (predictability) can evolve to a chaotic attractor (unpredictability). Therefore, we show that unpredictability is associated with bistable dynamics preferably chaotic, and, furthermore, there is a tipping point associated with unpredictable dynamics. © 2022, CC BY.

关键词： Dynamics

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Bioinspired graphene-based silver nanoparticles: Fabrication, characterization and antibacterial activity 11

Bioinspired graphene-based silver nanoparticles: Fabrication...

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11th National Conference on Solid State Chemistry and Allied Areas, NCSCA 2019

作者： Potbhare, Ajay K. Umekar, Mayuri S. Chouke, Prashant B. Bagade, Mahendra B. Tarik Aziz, S.K. Abdala, Ahmed A. Chaudhary, Ratiram G. Post Graduate Department of Chemistry Seth Kesarimal Porwal College of Arts Commerce and Science Kamptee441001 India Bar Ilan University Ramat-Gan52900 Israel Chemical Engineering Program Texas AandM University at Qatar POB 23784 Doha Qatar

Herein we present a fabrication and antibacterial assays of novel silver nanoparticles (Ag NPs) on the surface of graphene oxide (GO) nanosheets as a multifunctional antibacterial material by using Pseudomonas aeruginosa biomass extract the nanocomposites has fabricated. as a synthesized material were characterized by spectroscopic technique including XRD, FTIR, EDX, Raman and TEM. XRD analysis specified the cubic crustal structure of NCs, while TEM rendered an average particle size of 25»nm of Ag-GO NCs. As a result, the fabricated Ag-GO NCs was tested against gram-positive and gram-negative strains and the results shows the Ag-GO NCs to be more effective against gram-negative bacteria (***). © 2019 Elsevier Ltd.

关键词： Graphene

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