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Elevated temperature-driven coordinative reconstruction of an unsaturated single-Ni-atom structure with low valency on a polymer-derived matrix for the electrolytic oxygen evolution reaction

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Nanoscale 2024年第15期16卷 7467-7479页

作者： Patil, Rahul Rajput, Anubha Matsagar, Babasaheb M. Chen, Norman C. R. Ujihara, Masaki Salunkhe, Rahul R. Yadav, Praveen Wu, Kevin C.-W. Chakraborty, Biswarup Dutta, Saikat Electrochemical Energy & Sensor Research Laboratory Amity Institute of Click Chemistry Research & Studies Amity University Noida India Department of Chemistry Indian Institute of Technology New Delhi India Department of Chemical Engineering National Taiwan University Taipei10617 Taiwan Molecular Science and Technology Program Taiwan International Graduate Program Academia Sinica Taiwan National Taiwan University Taiwan Graduate Institute of Applied Science and Technology National Taiwan University of Science and Technology Taipei Taiwan Materials Research Laboratory Department of Physics Indian Institute of Technology Jammu India Synchrotron X-ray Facility Raja Ramanna Centre for Advanced Technology Rajendra Nagar Madhya Pradesh 452013 Indore India

A high-temperature pyrolysis-controlled coordination reconstruction resulted in a single-Ni-atom structure with a Ni-Nx-C structural unit (x = N atom coordinated to Ni). Pyrolysis of Ni-phen@ZIF-8-RF at 700 °C resulted in NiNP-NC-700 with predominantly Ni nanoparticles. Upon elevating the pyrolysis temperature from 700 to 900 °C, a coordination reconstruction offers Ni-Nx atomic sites in NiSA-NC-900. A combined investigation with X-ray absorption spectroscopy, X-ray photoelectron spectroscopy, and soft X-ray L3-edge spectroscopy suggests the stabilization of low-valent Niδ+ (0 −2 was achieved. The cell potential recorded with Pt(−)/(+)NiSA-NC-900/NF was much lower than that obtained for other cells, i.e., Pt(−)/NF and NF(−)/(+)NF, which enhances the potentials of low-valent NiSAs for insightful understanding of the OER. At a constant applied potential of 1.61 V (vs. RHE) for 12 h, an small increase in current for initial 0.6 h followed by a constant current depicts the fair stability of catalyst for 12 h. Our results offer an insightful angle into the OER with a coordinatively reconstructed single-Ni-atom structure at lower valency ( © 2024 The Royal Society of Chemistry.

关键词： Reaction kinetics

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Porous silicon on paper sensors: Factors affecting biosensing performance 17

Porous silicon on paper sensors: Factors affecting biosensin...

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Frontiers in Biological Detection: From Nanosensors to Systems XVII 2025

作者： An, Huijin Laibinis, Paul E. Locke, Andrea K. Weiss, Sharon M. Interdisciplinary Material Science Program Vanderbilt University NashvilleTN37235 United States Department of Electrical and Computer Engineering Vanderbilt University NashvilleTN37235 United States Department of Chemical and Biomolecular Engineering Vanderbilt University NashvilleTN37235 United States Department of Chemistry Vanderbilt University NashvilleTN37235 United States Department of Biomedical Engineering Vanderbilt University NashvilleTN37235 United States

ISBN: (纸本)9781510684249

A paper-based biosensor integrating a functionalized porous silicon (PSi) membrane as the active sensing element for quantifiable protein detection has been developed. For similar short-time exposures to an analyte, improved molecular transport in PSi membranes when on paper leads to larger signal changes compared to traditional PSi films that remain on a silicon substrate. In this work, we discuss controlling the incubation time of the analyte and the overall testing time of the sensor by incorporating different combinations of wicking and absorbent paper beneath the PSi membrane. With this control, the PSi-on-paper sensor platform has the potential to serve as an effective low-cost rapid diagnostic test with highly sensitive, quantitative readout for a wide range of analytes. © 2025 SPIE.

关键词： Porous silicon

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Optimizing cultivation strategies and scaling up for fucoxanthin production using Pavlova sp.

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Bioresource Technology 2024年 399卷 130609页

作者： Chen, Chun-Yen Liu, Ping-Yung Chang, Yu-Han Nagarajan, Dillirani Latagan, Mary Joy D. de Luna, Mark Daniel G. Chen, Jih-Heng Chang, Jo-Shu University Center for Bioscience and Biotechnology National Cheng Kung University Tainan Taiwan Department of Biotechnology and Bioindustry Sciences National Cheng Kung University Tainan701 Taiwan Department of Chemical Engineering National Cheng Kung University Tainan Taiwan Institute of Aquatic Science and Technology College of Hydrosphere Science National Kaohsiung University of Science and Technology Nanzih Campus Kaohsiung City Taiwan Energy Engineering Program National Graduate School of Engineering University of the Philippines Diliman Quezon City1101 Philippines Environmental Engineering Program National Graduate School of Engineering University of the Philippines Quezon City Diliman1101 Philippines Department of Chemical Engineering University of the Philippines Diliman Quezon City1101 Philippines Department of Chemical and Materials Engineering National Kaohsiung University of Science and Technology Kaohsiung807 Taiwan Department of Chemical and Materials Engineering Tunghai University Taichung407 Taiwan Research Center for Smart Sustainable Circular Economy Tunghai University Taichung407 Taiwan Department of Chemical Engineering and Materials Science Yuan Ze University Chung-Li Taiwan

The microalgal-based production of fucoxanthin has emerged as an imperative research endeavor due to its antioxidant, and anticancer properties. In this study, three brown marine microalgae, namely Skeletonema costatum, Chaetoceros gracilis, and Pavlova sp., were screened for fucoxanthin production. All strains displayed promising results, with Pavlova sp. exhibiting the highest fucoxanthin content (27.91 mg/g) and productivity (1.16 mg/L·day). Moreover, the influence of various cultivation parameters, such as culture media, salinity, sodium nitrate concentration, inoculum size, light intensity, and iron concentration, were investigated and optimized, resulting in a maximum fucoxanthin productivity of 7.89 mg/L·day. The investigation was further expanded to large-scale outdoor cultivation using 50 L tubular photobioreactors, illustrating the potential of Pavlova sp. and the cultivation process for future commercialization. The biomass and fucoxanthin productivity for the large-scale cultivation were 70.7 mg/L·day and 4.78 mg/L·day, respectively. Overall, the findings demonstrated considerable opportunities for fucoxanthin synthesis via microalgae cultivation and processing. © 2024 Elsevier Ltd

关键词： Microalgae

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Study on the Flow, Foaming Characteristics and Structural Strength of Polypropylene Structural Foam Injection Molding by Innovative Nitrogen and Molten Plastic Mixing Mechanism

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Polymers 2023年第9期15卷 2116-2116页

作者： Huang, Po-Wei Peng, Hsin-Shu Hwang, Sheng-Jye Huang, Chao-Tsai Program of Mechanical and Aeronautical Engineering Feng Chia University of Engineering and Science Taichung407102 Taiwan Department of Mechanical and Computer Aided Engineering Feng Chia University of Engineering and Science Taichung407102 Taiwan Department of Mechanical Engineering National Cheng Kung University of Engineering Tainan70101 Taiwan Department of Chemical and Materials Engineering Tamkang University of Engineering New Taipei City251301 Taiwan

Plastic foam molding methods include thermoforming, extrusion and injection molding. Injection foam molding is a one-time molding method with high production efficiency and good product quality. It is suitable for foamed plastic products with complex shapes and strict size requirements. It is also the main method for producing structural bubbles. In this investigation, we developed a structural foam injection molding technology using the gas supply equipment connected to the unique plasticizing mechanism of the injection machine and studied its influence on the specimens’ melt rheology quality and foam structures. In the experiment, the forming material was polypropylene (PP), and the gas for mixing/forming foaming characteristics was nitrogen (N2). Additionally, in order to observe the rheological properties of N2/melt mixing, a melt flow specimen mold cavity was designed and the change in the melt viscosity index was observed using a melt pressure sensing element installed at the nozzle position. With the nitrogen supply equipment connected to a unique plasticizing mechanism, the mixing of gas and molten plastic can be achieved at the screw plasticizing stage, where the foaming effect is realized during the melt-filling process due to the thermodynamic instability of the gas. It was also found that an increase in N2 fill content increased melt fluidity, and the trend of melt pressure and melt viscosity index showed that the higher the gas content, the lower the trend. The foaming characteristic depends on the gas thermodynamic instability and the pressure release, so it can be seen from the melt fill path that, the greater the pressure near the gate, the lower the foaming amount and the internal structure (SEM) after molding;the farther from the gate, the greater the relative increase in the foaming growth/amount. This phenomenon will be more obvious when the N2 fill content is increased. © 2023 by the authors.

关键词： Gases

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Biosorption of chromium by live and dead cells of Bacillus nitratireducens isolated from textile effluent

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Chemosphere 2024年 359卷 142389页

作者： Imron, Muhammad Fauzul Setiawan, Wahyu Putranto, Trisnadi Widyaleksono Catur Abdullah, Siti Rozaimah Sheikh Kurniawan, Setyo Budi Study Program of Environmental Engineering Department of Biology Faculty of Science and Technology Universitas Airlangga Campus C UNAIR Jalan Mulyorejo Surabaya60115 Indonesia Department of Water Management Faculty of Civil Engineering and Geosciences Delft University of Technology Stevinweg 1 CN Delft2628 Netherlands Study Program of Environmental Science Postgraduate Program Sriwijaya University Palembang30139 Indonesia Department of Chemical and Process Engineering Faculty of Engineering and Built Environment Universiti Kebangsaan Malaysia UKM Bangi Selangor 43600 Malaysia

Bacillus nitratireducens was isolated from textile effluent and showed high tolerance to chromium (Cr), reaching up to a 1000 mg/L MIC value. This research was aimed at utilizing biosorbents from live and dead cells of B. nitratireducens to remove Cr from an aqueous solution. A batch biosorption test was performed, and mechanisms analysis was approached by an adsorption-desorption test, SEM-EDS, and FTIR analysis. Cr removal by dead cells in 25, 50, and 100 mg/L of Cr were 58.99 ± 0.7%, 69.8 ± 0.2%, and 82.87 ± 0.11%, respectively, while that by live cells was 73.08 ± 1.9%, 80.27 ± 6.33%, and 86.17 ± 1.93%, respectively. Live cells showed significantly higher Cr removal and adsorption capacities as compared to dead cells. In all concentrations, absorption contributed more than adsorption to the Cr removal by both live and dead cells. Absorption of Cr was subjected to occur due to passive mechanisms in dead cells while involving some active mechanisms in live cells. SEM-EDS confirmed the detection of Cr on the cell surface, while FTIR revealed the shifting of some peaks after the biosorption test, suggesting interactions between Cr and functional groups. Further TEM analysis is suggested to be conducted as a future approach to reveal the inner structure of cells and confirm the involvement of absorption mechanisms. © 2024 Elsevier Ltd

关键词： Heavy metals

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A Review of Multifunctional Nanocomposite Fibers:Design,Preparation and Applications

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Advanced Fiber Materials 2024年第1期6卷 68-105页

作者： Lijun Liu Dan Chang Chao Gao MOE Key Laboratory of Macromolecular Synthesis and Functionalization International Research Center for X PolymerKey Laboratory of Novel Adsorption and Separation Materials and Application Technologies of Zhejiang ProvinceDepartment of Polymer Science and EngineeringZhejiang University866 Yuhangtang RoadHangzhou 310058People’s Republic of China Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering Taiyuan 030032People’s Republic of China

Nanocomposite fibers are fibrous materials with specific properties and functionalities,which are prepared by introducing nanomaterials or nanostructures in the *** nanocomposite fibers exhibit multiple functionalities,showing great application potential in healthcare,aerospace,mechanical engineering,and energy ***,six functionalities of polymer nanocomposite fibers are reviewed:mechanical reinforcement,resistance to electromagnetic interference and flame,thermal and electrical conduction,generation of far-infrared ray,negative ion and electricity,energy storage,and *** each functionality,the fiber component selection and preparation methods are *** commonly used polymers comprise natural and synthetic polymers,and typical nanomaterials include carbon-based,polymer-based,metal-based,and metal oxide-based *** compounding strategies and spinning approaches,such as wet-spinning,melt-spinning,and electrospinning,are ***,the functional properties of fibers fabricated from different constituents and by different strategies are compared,providing a reference for performance ***,the prospective directions of research and application are discussed,and possible approaches are suggested to facilitate the development of advanced nanocomposite fibers.

关键词： Nanocomposite fibers Multifunctional applications Polymers Nanomaterials

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Enhancing PV solar panel efficiency through integration with a passive Multi-layered PCMs cooling system: A numerical study

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International Journal of Thermofluids 2024年 23卷

作者： Sheikh, Yahya Jasim, Muhammad Qasim, Muhammad Qaisieh, Alaa Hamdan, Mohammad O. Abed, Farid Materials Science and Engineering Program American University of Sharjah Sharjah United Arab Emirates Department of Mechanical Engineering American University of Sharjah Sharjah United Arab Emirates Department of Chemical and Biological Engineering American University of Sharjah Sharjah United Arab Emirates Civil Engineering Department American University of Sharjah Sharjah United Arab Emirates

Photovoltaic (PV) solar cells are at the forefront of sustainable electricity generation technologies, yet they exhibit relatively low efficiency. Typically, less than 20 % of the solar energy absorbed is converted into electrical energy, with the remainder converts into heat. This heat increases the PV panel's operating temperature, negatively impacting its efficiency and life expectancy. To mitigate this, a novel approach using multi-layered phase change materials (PCMs) has been examined in this study. The approach involves integrating organic PCMs (OPCMs) with metallic PCMs (MPCMs), enhancing PV panel cooling efficiency by attaching the multi-layer PCM to the panel's rear. This study, employing ANSYS FLUENT software's solidification and melting model, explores the impact of multi PCM layers thickness and total multi layers thickness on PV cell temperature and electrical efficiency. The analysis reveals that a multi-layered PCMs configuration with a thickness ratio of 15:85 between MPCM (CERROLOW-117® alloy) and OPCM (RT44) significantly decreases temperature rise in PV cells, resulting in a temperature drop of 59.6 °C. This improvement boosts PV panel performance by an average of 35.8 % compared to panels lacking cooling systems during peak sun hours under hot climate conditions characterized by ambient temperatures of 40 °C and high solar radiation exceeding 1000 W/m². This suggests that a carefully optimized PCM layering approach could markedly improve PV system efficiency, offering a practical solution to the overheating problem and extending the operational life of PV installations. © 2024 The Author(s)

关键词： Phase change materials

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Materials and devices for flexible and stretchable photodetectors and light-emitting diodes

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Nano Research 2021年第9期14卷 2919-2937页

作者： Jun-Kyul Song Min Sung Kim Seungwon Yoo Ja Hoon Koo Dae-Hyeong Kim Center for Nanoparticle Research Institute for Basic Science(IBS)Seoul 08826Republic of Korea School of Chemical and Biological Engineering and Institute of Chemical Processes Seoul National UniversitySeoul 08826Republic of Korea Interdisciplinary Program for Bioengineering Seoul National UniversitySeoul 08826Republic of Korea Department of Materials Science and Engineering Seoul National UniversitySeoul 08826Republic of Korea

Recently,significant efforts have been directed at overcoming the limitations of conventional rigid optoelectronic devices,particularly their poor mechanical stability under bending,folding,and stretching *** of major approaches for rendering optoelectronic devices mechanically deformable is to replace the conventional electronic/optoelectronic materials with functional nanomaterials or organic materials that are intrinsically flexible/***,advanced device designs and unconventional fabrication methods have also contributed to the development of soft optoelectronic ***,new devices such as bio-inspired curved image sensors,wearable light emitting devices,and deformable bio-integrated optoelectronic devices have been *** this review,recent progress in the development of soft optoelectronic materials and devices is ***,various materials such as nanomaterials,organic materials,and their hybrids that are suitable for developing deformable photodetectors,are ***,the nanomaterials and organic/polymeric materials that are applicable in deformable light-emitting diodes are ***,representative system-level applications of flexible and stretchable photodetectors and light-emitting diodes are reviewed,and future prospects are discussed.

关键词： nanomaterial organic material photodetector light-emitting diode flexible optoelectronics stretchable optoelectronics

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Design of Non-fused Ring Acceptors toward High-Performance,Stable,and Low-Cost Organic Photovoltaics

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Accounts of Materials Research 2022年第6期3卷 644-657页

作者： Qing Shen Chengliang He Shuixing Li Lijian Zuo Minmin Shi Hongzheng Chen State Key Laboratory of Silicon Materials MOE Key Laboratory of Macromolecular Synthesis and FunctionalizationInternational Research Center for X PolymersDepartment of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027P.R.China Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering Hangzhou 310027P.R.China

Toward future commercial applications of organic solar cells(OSCs),organic photovoltaic materials that enable high efficiency,excellent stability,and low cost should be ***-ring electron acceptors(FREAs)have declared that OSCs are capable of showing efficiencies over 19%,whereas stability and cost are not solved *** the counterparts of FREAs,non-fused ring electron acceptors(NFREAs)are more flexible in molecular *** have better stability because of the reduction of intramolecular tension via breaking fused backbone and have more advantages in cost with the reduction of synthetic ***,the challenge for NFREAs is the relatively lower efficiencies(around 15%at current stage),which require better molecular designs for addressing the issues of conformational unicity and effective molecular *** this Account,we comprehensively summarize works about NFREAs carried out in our group from three main frameworks,including molecular design and efficiency optimization,material cost,and ***,in the part of molecular design and efficiency optimization,the existing rotatable single bond in NFREAs will bring the problem of conformational uncertainty,but it can be solved through proper molecular design,which also regulates the energy levels,light absorption range,and the packing mode of the molecule for obtaining higher ***,in this part,we discuss the evolution of NFREAs in three aspects,including molecular skeleton optimization,terminal modification,and side chain *** strategies are used in the design of a molecular skeleton,such as utilizing the quinoid effect,introducing functional groups with the electron push−pulling effect,and using multiple conformational ***,simplifying the skeleton is also the preferred development *** for the terminal,the main modification strategy is adjusting the conjugation length and halogen *** is more,by adjusting the side chain to induce appropr

关键词： stability fused stability

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Effect of dimethyl carbonate on the behavior of water confined in carbon nanotube

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Chinese Journal of chemical engineering 2021年第3期34卷 177-185页

作者： Qingwei Gao Yumeng Zhang Aatto Laaksonen Yudan Zhu Xiaoyan Ji Shuangliang Zhao Yaojia Chen Xiaohua Lu College of Chemical Engineering State Key Laboratory of Materials-oriented Chemical EngineeringNanjing Tech UniversityNanjing 211816China Energy Engineering Division of Energy ScienceLuleåUniversity of Technology97187 LuleåSweden State Key Laboratory of Chemical Engineering East China University of Science and TechnologyShanghai 200237China Department of Materials and Environmental Chemistry Arrhenius LaboratoryStockholm UniversitySE-10691 StockholmSweden Centre of Advanced Research in Bionanoconjugates and Biopolymers Petru Poni Institute of Macromolecular ChemistryAleea Grigore Ghica-Voda41A700487 IasiRomania Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology and School of Chemistry and Chemical Engineering Guangxi UniversityNanning 530004China

The dehydration of water by dimethyl carbonate(DMC)is of great significance for its application in electrochemistry and oil *** the rapid development of nanomaterial,one-dimensional(*** nanotube(CNT))and two-dimensional(*** graphene)materials have been widely used for molecular *** this work,the molecular behavior of dimethyl carbonate/water mixture confined in CNT with varying diameters was studied based on molecular dynamics *** to different van der Waals interactions for the components in the mixtures with the solid surface,DMC molecules are preferentially adsorbed on the inner surface of the pore wall and formed an adsorption *** with the pure water molecules confined in CNT,the adsorption DMC layer shows notable effect on the local compositions and microstructures of water molecules under nanoconfinement,which may result in different water *** analysis shows that the surface-induced DMC molecules can destroy the hydrogen bonding network of water molecules and result in an uniform and dispersed distribution of water molecules in the *** clear molecular understandings can be useful in material design for membrane separation.

关键词： Dimethyl carbonate Carbon nanotube Solid/fluid interface Adsorbed layer Molecular simulation

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