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Author Correction: Elastic electronics based on micromesh-structured rubbery semiconductor films (vol 5, pg 881, 2022)

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NATURE ELECTRONICS 2023年第1期6卷 86-86页

作者： Guan, Ying-Shi Ershad, Faheem Rao, Zhoulyu Ke, Zhifan da Costa, Ernesto Curty Xiang, Qian Lu, Yuntao Wang, Xu Mei, Jianguo Vanderslice, Peter Hochman-Mendez, Camila Yu, Cunjiang Institute of Advanced Materials and School of Chemistry and Chemical Engineering Southeast University Nanjing China Department of Mechanical Engineering University of Houston Houston TX USA Department of Biomedical Engineering Pennsylvania State University University Park PA USA Department of Biomedical Engineering University of Houston Houston TX USA Department of Engineering Science and Mechanics Pennsylvania State University University Park PA USA Materials Science and Engineering Program University of Houston Houston TX USA Department of Materials Science and Engineering Materials Research Institute Pennsylvania State University University Park PA USA Department of Chemistry Purdue University West Lafayette IN USA Regenerative Medicine Research Texas Heart Institute Houston TX USA Molecular Cardiology Research Laboratory Texas Heart Institute Houston TX USA

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Molecular Insights into the Structure-Property Relationships of 3d Printed Polyamide Reverse-Osmosis Membrane for Desalination

SSRN

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SSRN 2022年

作者： He, Jinlong Yang, Jason McCutcheon, Jeffrey R. Li, Ying Department of Mechanical Engineering University of Connecticut StorrsCT06269 United States Division of Chemistry and Chemical Engineering California Institute of Technology PasadenaCA91125 United States Department of Chemical & Biomolecular Engineering Center for Environmental Sciences and Engineering University of Connecticut StorrsCT06269 United States Department of Mechanical Engineering Polymer Program Institute of Materials Science University of Connecticut StorrsCT06269 United States

3D-printing is an emerging method for manufacturing polyamide (PA) reserve osmosis (RO) membranes for water treatment and desalination, which can precisely control membrane structural properties, such as thickness, roughness, and resolution. However, the synthesis-structure (i.e., degree of cross-linking (DC), m-phenylenediamine/trimesoyl chloride (MPD/TMC) ratio, and membrane thickness) to property (permeability and water-salt selectivity) relationships for these membranes has not been well understood. At the same time, a microscopic understanding of the physical mechanism of water and salt transport is needed to guide the design of high-performance 3D-printed membranes and improve printing efficiency. Thus, the atomic-scale transport features and energetics of water and salt ions are studied at high pressure for the 3D-printed PA RO membranes with the different DCs and MPD/TMC ratios through non-equilibrium molecular dynamics (NEMD) simulations. Factoring in membrane structure properties, rejection ratio of salt ions and pressure-dependent water flux, 3D-printed PA membranes having an MPD/TMC ratio of 3.0:2.0 and a DC between 80%~90% attains ideal performance: high water flux, high rejection of salt ions, and excellent structural integrity. Mechanistically, water permeability for highly cross-linked PA RO membranes depends on the temporary on-and-off channels that allow water molecules to jump from one cavity to another at high pressure. In addition, higher pressures cause a rapid compaction of PA membranes’ free volume and membrane thickness. Membrane failure at high pressure is determined by the DC and MPD/TMC ratios-dependent compressive yield strength. In short, these findings provide physical insights for optimizing existing PA membranes and designing next-generation desalination membranes at the molecular level. © 2022, The Authors. All rights reserved.

关键词： Molecular dynamics

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Wearable strain sensor utilizing the synergistic effect of Ti3C2Tx MXene/AgNW nanohybrid for point-of-care respiratory monitoring

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Materials Today Chemistry 2024年 37卷

作者： Kumar, Amit Kumar, R.K. Rakesh Shaikh, Muhammad Omar Yang, Jia-Yu Bharti, Aditya Manu Huang, Bo-Yan Chang, Hsu-Liang Lee, Da-Huei Chuang, Cheng-Hsin Institute of Medical Science and Technology National Sun Yat-sen University Kaohsiung80424 Taiwan Department of Chemical Engineering National Taiwan University Taipei City10617 Taiwan Institute of Biomedical Engineering and Nanomedicine National Healthcare Research Institutes 350 Miaoli County Taiwan National Sun Yat-sen University Kaohsiung80424 Taiwan Sustainability Science and Engineering Program Tunghai University Taichung407224 Taiwan Department of Internal Medicine Kaohsiung Municipal Ta-Tung Hospital Kaohsiung Medical University Hospital Kaohsiung Medical University Kaohsiung Taiwan Department of Electrical Engineering National Chung-Kung University Tainan Taiwan

Respiratory signals are significant indicators for detecting changes in physiological conditions and early diagnosis of numerous respiratory illnesses. Herein, we have integrated a high-performance strain sensor and portable circuit board (PCB) with personalized interface to develop point-of-care respiratory monitoring device. The ultrasensitive strain sensor utilizes a conductive polymeric nanocomposite that harnesses the synergistic effect of Ti3C2Tx (MXene)/AgNW nanohybrid to develop a wearable device. The wearable device is capable of analysing pulmonary volumes, such as forced volume capacity (FVC) and forced expiratory volume (FEV1), while accurately recognizing various breathing patterns in a resting state (such as normal, forced, and obstructive), as well as during different physical activities. It shows excellent correlation (>93%) with commercial spirometer for measurement of pulmonary parameters. In addition, we present a wireless device for lab rat respiratory monitoring in anaesthetic state. The device is implemented for real-time respiratory monitoring under mild, normal and high anaesthesia doses. The levels of anaesthesia doses including a critical limit can be significantly discriminated by means of breathing frequency and amplitude, which ultimately results in saving their lives. These results demonstrate the practical feasibility of the strain sensing device as wearable electronics for point-of-care respiratory monitoring in humans and other species. © 2024 Elsevier Ltd

关键词： Diagnosis

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Naked-eye observation of water-forming reaction on palladium etalon:transduction of gas-matter reaction into light-matter interaction

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PhotoniX 2023年第1期4卷 349-363页

作者： Jongsu Lee Eui-Sang Yu Taehyun Kim In Soo Kim Seok Chung Seung Jae Kwak Won Bo Lee Yusin Pak Yong-Sang Ryu Sensor System Research Center Korea Institute of Science and TechnologySeoul 02792Republic of Korea Department of Electrical and Computer Engineering Seoul National UniversitySeoul 08826Republic of Korea Smart Materials Research Section Electronics and Telecommunications Research InstituteDaejeon 34129Republic of Korea Department of Micro/Nano Systems Korea University02841 SeoulRepublic of Korea Nanophotonics Research Center Korea Institute of Science and TechnologySeoul 02792Republic of Korea School of Mechanical Engineering Korea UniversitySeoul 02841Republic of Korea School of Chemical and Biological Engineering Seoul National UniversitySeoul 08826Republic of Korea Interdisciplinary Program in Precision Public Health Korea UniversitySeoul 02481Republic of Korea School of Biomedical Engineering Korea UniversitySeoul 02481Republic of Korea

Palladium is the most prominent material in both scientific and industrial research on gas storage,purification,detection,and catalysis due to its unique properties as a catalyst and hydrogen *** the dynamic optical phenomena of palladium reacting with hydrogen,transduction of the gas-matter reaction into light-matter interaction is attempted to visualize the dynamic surface chemistry and reaction *** simple geometry of the metal-dielectric-metal structure,Fabry-Perot etalon,is employed for a colorimetric reactor,to display the catalytic reaction of the exposed gas via water-film/bubble formation at the dielectric/palladium *** adsorption/desorption behavior and catalytic reaction of hydrogen and oxygen on the palladium surface display highly repeatable and dramatic color changes based on two distinct water formation trends:the foggy effect by water bubbles and the whiteout effect by water film *** and experiments demonstrate the robustness of the proposed Fabry-Perot etalon as an excellent platform for monitoring the opto-physical phenomena driven by heterogeneous catalysis.

关键词： Palladium Hydrogen Oxygen Fabry-Perot resonators Colorimetric sensors Water-forming reaction

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Single-Molecule Vibrational Characterization of Binding Geometry Effects on Isocyanide-Metal Interactions

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Nano letters 2025年第22期25卷 2025 May 26页

作者： Liya Bi Zhe Wang Krista P Balto Andrea R Tao Tod A Pascal Yanning Zhang Joshua S Figueroa Shaowei Li Department of Chemistry and Biochemistry University of California San Diego La Jolla California 92093-0309 United States. Program in Materials Science and Engineering University of California San Diego La Jolla California 92093-0418 United States. Department of Physics and Astronomy University of California Irvine California 92697-4575 United States. Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of China Chengdu 611731 China. Aiiso Yufeng Li Family Department of Chemical and Nano Engineering University of California San Diego La Jolla California 92093-0448 United States.

Isocyanide-metal binding is governed by σ-donation and π-back-bonding, which affects the isocyanide stretching energy, a characteristic probe for ligand-metal interactions. While extensive correlations exist between structure and spectroscopy in molecular isocyanide-metal systems, interactions of isocyanide with crystalline metallic surfaces, where ligands often bind in various geometries, remain underexplored. Conventional vibrational spectroscopies such as infrared and Raman spectroscopies lack the molecular-scale resolution to distinguish this binding inhomogeneity. In contrast, inelastic electron tunneling spectroscopy with scanning tunneling microscopy (STM-IETS) directly visualizes ligand adsorption geometries and their vibrational signatures. Using STM-IETS, we investigate a metal-adsorbed -terphenyl isocyanide ligand and find that the adsorption geometry on Cu(100) induces a significant shift in isocyanide stretching frequency, more prominent than replacing Cu(100) with Ag(111). Density functional theory confirms that this shift arises from atomic-scale variations in coordination environments. This study elucidates how precise binding influences the vibrational fingerprints of isocyanide ligands, an often-overlooked factor in understanding the isocyanide-metal interplay.

关键词： inelastic electron tunneling spectroscopy m-terphenyl isocyanide ligand metal−isocyanide interaction scanning tunneling microscopy σ−π donations

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Fabrication and bioactivity studies of wollastonite/polycaprolactone composites

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International Journal of Nano and Biomaterials 2023年第2期10卷 86-99页

作者： Lakshmi, R. Choudhary, Rajan Senatov, Fedor Kaloshkin, Sergey Kothandam, Shobana Ponnamma, Deepalekshmi Sadasivuni, Kishor Kumar Swamiappan, Sasikumar Department of Chemistry Auxilium College Tamil Nadu Vellore632006 India Faculty of Materials Science and Applied Chemistry Rudolfs Cimdins Riga Biomaterials Innovations and Development Centre of RTU Institute of General Chemical Engineering Riga Technical University Pulka St 3 RigaLV-1007 Latvia Baltic Biomaterials Centre of Excellence Headquarters at Riga Technical University Kipsala Street 6A RigaLV-1048 Latvia National University of Science and Technology "MISiS" Moscow119049 Russia Department of Chemistry School of Advanced Sciences Vellore Institute of Technology Tamil Nadu Vellore632014 India Materials Science and Technology Program Department of Mathematics Statistics and Physics College of Arts and Sciences Qatar University P.O. Box 2713 Doha Qatar Center for Advanced Materials Qatar University P.O. Box 2713 Doha Qatar Department of Chemistry School of Advanced Sciences Vellore Institute of Technology Tamil Nadu Vellore632014 India

Current work investigates the influence of wollastonite on mechanical stability and biomineralisation ability of wollastonite/ polycaprolactone (PCL) composites (WP composites). The solvent casting particulate leaching method was used to prepare these composites. FT-IR spectra indicated the presence of functional groups associated with PCL and wollastonite. Scanning electron microscopy showed aggregated morphology and wollastonite particles were embedded in the PCL matrix. The incorporation of wollastonite leads to a more than three-fold increase in the compressive strength of the composites. Moreover, the composites containing 50% wollastonite exhibited better compressive strength than 80%. This observation suggested that if the concentration of a filler is exceeded beyond its critical concentration then the mechanical stability of the composite will be compromised. The composites revealed good apatite deposition ability. Thus, the biomineralisation ability and compressive strength of PCL can be improved by preparing its composites with bioceramics. © 2023 Inderscience Enterprises Ltd.

关键词： Bioceramics

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Ionic Liquid-Triggered Charge Regulation of Polydopamine-Based Surface for Antibacterial Nanofiltration

SSRN

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SSRN 2024年

作者： Zhang, Wen-Ting Zhao, Zi-Yang Jing, Ya-Juan Li, Hao-Nan Cao, Ye Weng, Rui-Bin Wu, Bai-Heng Li, Yongjin Yang, Jing Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education Key Laboratory of Organosilicon Material Technology of Zhejiang Province College of Material Chemistry and Chemical Engineering Hangzhou Normal University No. 2318 Yuhangtang Rd. Hangzhou311121 China MOE Key Laboratory of Macromolecular Synthesis and Functionalization Key Laboratory of Adsorption and Separation Materials & Technologies of Zhejiang Province Department of Polymer Science and Engineering Zhejiang University Hangzhou310027 China

The charged surfaces with desirable performance are of high concern in membrane separation but there exist challenges to tailor them over a task-specific range. Herein, we propose an ionic liquid (IL)-triggered charge regulation strategy for polydopamine (PDA)-based surfaces by tuning the number and position of amino groups of ILs. By strategically manipulating the location of amino groups in either the anion, cation, or both, we realize a complete inversion in the surface charge nature of PDA coatings from highly negative to negative and even highly positive (zeta potential: -25 mV to +25 mV), which is attributed to both the number of protonable groups and shielding effect provided by counter ions. Such charge flip enhances Donna effect when the PDA/IL coatings serve as the skin layer of nanofiltration membranes, thereby enabling high rejection to both negative and positive target molecules. Despite charge regulation, ILs with dual amino groups cross link the PDA aggregates, largely narrowing the pore size distribution of the skin layer. The IL cross-linked PDA skin layer with uniform pores thus shows a nearly 100% rejection to the target solutes. Meanwhile, the IL synchronously endow the PDA coatings with tunable charge characteristics, imidazolium functional groups and exceptional superoleophobicity, compensating for the originally inferior antibacterial activity of membranes in a wide pH range © 2024, The Authors. All rights reserved.

关键词： Ionic liquids

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Giant Deep-Ultraviolet Circular Dichroism in Synthetic Architectures of Ordered Carbon Nanotubes

Giant Deep-Ultraviolet Circular Dichroism in Synthetic Archi...

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2023 Conference on Lasers and Electro-Optics, CLEO 2023

作者： Doumani, Jacques Lou, Minhan Dewey, Oliver Hong, Nina Fan, Jichao Baydin, Andrey Pasquali, Matteo Yomogida, Yohei Yanagi, Kazuhiro Saito, Riichiro Kono, Junichiro Gao, Weilu Department of Electrical and Computer Engineering Rice University HoustonTX United States Applied Physics Graduate Program Smalley-Curl Institute Rice University HoustonTX United States Department of Electrical and Computer Engineering The University of Utah Salt Lake CityUT United States Carbon Hub Rice University HoustonTX United States Department of Chemical and Biomolecular Engineering Rice University HoustonTX United States J.A. Woollam Co. LincolnNE United States The Smalley-Curl Institute Rice University HoustonTX United States Department of Chemistry Rice University HoustonTX United States Department of Materials Science and NanoEngineering Rice University HoustonTX United States Department of Physics and Astronomy Tokyo Metropolitan University Tokyo Japan Department Physics Tohoku University Sendai Japan Department Physics and Astronomy Rice University HoustonTX United States

We demonstrate tunable, giant, and structure-induced deep-ultraviolet circular dichroism in macroscopically chiral assemblies of racemic carbon nanotubes prepared using two approaches: mechanical-rotation-assisted vac... 详细信息

ISBN: (纸本)9781957171258

关键词： Dichroism

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Fabrication of PSf/P84-blended membranes with low P84 content: Characteristics and gas separation performance

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Case Studies in chemical and Environmental engineering 2024年 10卷

作者： Kayadoe, Victor Widiastuti, Nurul Gunawan, Triyanda Salleh, Wan Norhayati Wan Fansuri, Hamzah Romadiansyah, Taufik Qodar Pratama, Agus Wedi Department of Chemistry Faculty of Science and Data Analytical Institut Teknologi Sepuluh Nopember Chemistry Education Study Program Faculty of Teacher Training and Educational Pattimura University School of Chemical and Energy Engineering Faculty of Engineering Universiti Teknologi Malaysia Advanced Membrane Technology Research Center (AMTEC) Universiti Teknologi Malaysia

The demand for efficient and sustainable gas separation technologies is ever-increasing in various industries, including petrochemicals, natural gas processing, and carbon capture. Polymer-based membranes offer a promising solution due to their potential for high selectivity and energy efficiency. However, achieving optimal gas separation performance often requires overcoming the limitations of individual polymers through modifications such as polymer blending. In this study, PSf/P84 blended membranes with low P84 content were fabricated using the phase separation technique with a mixture of N-methyl-2-pyrrolidone and tetrahydrofuran as solvents. The effect of varying the mass ratio of PSf to P84 on membrane characteristics and gas separation performance was investigated. Characterization techniques included FTIR, XRD, SEM, TGA, Water Contact Angle (WCA) measurement, and mechanical property testing. Gas permeation tests were conducted with single gases at room temperature and 1 bar pressure. The results revealed that the addition of P84 increased membrane thickness, Young's modulus, and thermal stability, while decreasing d-spacing, dense layer thickness, hydrophilicity, tensile strength, and elongation. The F_index values, indicating the competence of the blended membranes compared to the ideal quality, demonstrated the positive impact of P84 addition on gas separation performance compared to pure PSf membranes. The optimal gas separation selectivity was achieved with the PSf/P84 1:0.025 blended membrane for H₂/CH₄ (11.28, 58 % increase), H₂/CO₂ (6.25, 193 % increase), and H₂/N₂ (5.25, 35 % increase). The highest N₂/CH₄ selectivity (6.29, 253 % increase) was observed with the 1:0.10 composition. Regarding commercially relevant separations based on the 2008 Robeson curve, the PSf/P84 1:0.20 blend showed promise for H₂/CO₂ separation, while the 1:0.

关键词： Findex Low P84 content PSf/P84 blended membrane Robeson curve

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High‑Performance Thick Cathode Based on Polyhydroxyalkanoate Binder for Li Metal Batteries

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Advanced Fiber Materials 2024年第1期6卷 214-228页

作者： Dong Hyuk Kang Minhyuck Park Jeonghun Lee Chan Yeol Kim Jimin Park Youn‑Ki Lee Jong Chan Hyun Son Ha Jin Hwan Kwak Juhee Yoon Hyemin Kim Hyun Soo Kim Do Hyun Kim Sangmin Kim Ji Yong Park Robin Jang Seung Jae Yang Hee‑Dae Lim Se Youn Cho Hyoung‑Joon Jin Seungjin Lee Yunil Hwang Young Soo Yun KU‑KIST Graduate School of Converging Science and Technology Korea University145 Anam‑roSeongbuk‑guSeoul 02841South Korea Carbon Composite Materials Research Center Korea Institute of Science and Technology(KIST)92 Chundong‑roBongdong‑eupWanju‑gunJeollabuk‑do 55324South Korea Energy Storage Research Center Korea Institute of Science and Technology(KIST)514‑gil Hwaraong‑roSeoul 02792South Korea Program in Environmental and Polymer Engineering Inha University100 Inha‑ro Michuhol‑guIncheon 22212South Korea Advanced Analysis Data Center Korea Institute of Science and Technology(KIST)514‑gil Hwaraong‑roSeoul 02792South Korea Advanced Nanohybrids Laboratory Department of Chemistry and Chemical EngineeringInha University100 Inha‑roMichuhol‑guIncheon 22212South Korea CJ CheilJedang Corporation 55 Gwanggyo‑ro 42Beon‑gilYeongtong‑guSuwon 16495South Korea Department of Chemical Engineering Hanyang University222 Wangsimni‑roSeongdong‑guSeoul 04763South Korea Department of Integrative Energy Engineering Korea University145 Anam‑roSeongbuk‑guSeoul 02841South Korea

Thick cathodes can overcome the low capacity issues,which mostly hamper the performance of the conventional active cathode materials,used in rechargeable Li ***,the typical slurry-based method induces cracking and flaking during the fabrication of thick *** addition,a significant increase in the charge-transfer resistance and local cur-rent overload results in poor rate capabilities and cycling stabilities,thereby limiting electrode *** this study,a synergistic dual-network combination strategy based on a conductive nanofibrillar network(CNN)and a nano-bridging amor-phous polyhydroxyalkanoate(aPHA)binder is used to demonstrate the feasibility of constructing a high-performance thick *** CNN and aPHA dual network facilitates the fabrication of a thick cathode(≥250μm thickness and≥90 wt%active cathode material)by a mass-producible slurry *** thick cathode exhibited a high rate capability and excel-lent cycling *** addition,the thick cathode and thin Li metal anode pair(Li//t-NCM)exhibited an optimal energy performance,affording high-performance Li metal batteries with a high areal energy of~25.3 mW h cm^(-2),a high volumetric power density of~1720 W L^(-1),and an outstanding specific energy of~470 W h kg^(-1)at only 6 mA h cm^(-2).

关键词： Thick cathode Polyhydroxyalkanoate binder Nano-bridging Conductive nano-fibrillar network Lithium metal battery

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