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Optimization of photocatalytic ceramic membrane filtration by response surface methodology: Effects of hydrodynamic conditions on organic fouling and removal efficiency

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Chemosphere 2024年 356卷 141885页

作者： Jang, Hoseok Lee, Chang Soo Kim, Jong Hak Kim, Jeonghwan Department of Environmental Engineering Program of Environmental and Polymer Engineering Inha University Michuholgu Incheon22212 Korea Republic of Department of Chemical Engineering Pukyong National University Busan48513 Korea Republic of Department of Chemical and Biomolecular Engineering Yonsei University Seoul03722 Korea Republic of

The effects of the operating conditions, including the applied pressure, feed organic concentration, and recirculation flowrate along the TiO2-coated ceramic membrane, on the normalized membrane permeability and organic removal efficiency were systematically investigated by operating a photocatalytic membrane reactor (PMR). Response surface methodology (RSM) was conducted to better understand the interactive effect of operational conditions as well as their individual and combined effects to control membrane performance. Our results showed that the applied pressure and feed organic concentration, as single parameter, affected the normalized membrane permeability and organic removal efficiency more dominantly than the recirculation flowrate. The polynomial performance equations generated by RSM successfully predicted the membrane performance of the PMR. The responses to the normalized membrane permeability and organic removal efficiency with respect to the operational conditions were less sensitive to any combination of operational conditions than to their individual impacts. The combined effects of the operating conditions were less pronounced in promoting the catalytic performance of organic contaminants on the TiO2 surface. Our RSM analysis based on experimental observations designed by Box–Behnken Design (BBD) suggested that 1.3 bar of applied pressure, 44 mg/L of feed organic dye concentration and 0.8 L/min as recirculation flowrate as optimum conditions achieved more than 98% of organic removal efficiency and less than 5% of decline in normalized membrane permeability. This research shows that the RSM provides effective tool to optimize operational conditions to determine fouling rate and organic removal in PMR. © 2024 Elsevier Ltd

关键词： Titanium dioxide

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Hydrocarbon ionomer/polytetrafluoroethylene composite membranes containing radical scavengers for robust proton exchange membrane water electrolysis

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European polymer Journal 2025年 234卷

作者： Park, Ga Young Noh, Yi Sak Jeong, Hwan Yeop Yoon, Sang Jun Oh, Keun-Hwan So, Soonyong Kim, Jeonghun Choi, Jaewon Yu, Duk Man Daejeon34114 Cuba Department of Polymer Science and Engineering Kyungpook National University Daegu41566 Cuba Department of Chemical and Biomolecular Engineering Yonsei University Seoul03722 Cuba

A hydrocarbon-based composite membrane incorporating radical scavengers is successfully fabricated using sulfonated poly(arylene ether sulfone) copolymers with a 50 % sulfonation degree (SP50), porous polytetrafluoroethylene (PTFE) substrates, and cerium oxide (CeO2) nanoparticles for proton exchange membrane water electrolysis (PEMWE). The CeO2 nanoparticles are uniformly dispersed in the SP50 solution through a ball milling, and the PTFE substrate is treated with n-propyl alcohol to improve the interfacial compatibility between the SP50/CeO2 solution and PTFE. Additionally, a five-layered structure incorporating two PTFE layers is employed to form robust interlocking interfaces between SP50 and PTFE. Consequently, the composite membrane with CeO2 exhibits excellent dimensional stability, mechanical properties, and a 3.8-fold reduction in hydrogen permeability as compared with that of the Nafion 212 (N212) membrane. In the hydrothermal tests, the composite membrane demonstrates excellent chemical stability due to the inclusion of CeO2. During PEMWE operation, the cell performance of the composite membrane is 7.42 A/cm2 at 1.9 V, surpassing those of SP50 (5.95 A/cm2) and N212 (5.66 A/cm2). Over the course of the durability test, the composite membrane exhibits the lowest degradation rate (DR). Furthermore, the molecular weight of the composite membrane decreases by only 5 %, significantly outperforming SP50, which shows a 50 % reduction. Therefore, the composite membrane with a radical scavenger provides excellent physical and chemical stability for PEMWE applications. © 2025

关键词： Composite membranes

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Electrospinning spinneret:A bridge between the visible world and the invisible nanostructures

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The Innovation 2023年第2期4卷 5-6页

作者： Wenliang Song Yunxin Tang Cheng Qian Bumjoon J.Kim Yaozu Liao Deng-Guang Yu School of Materials and Chemistry University of Shanghai for Science and TechnologyShanghai 200093China Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology(KAIST)Daejeon 34141Republic of Korea State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and EngineeringDonghua UniversityShanghai 201620China

Electrospinning spinneret:A bridge between the visible world and the invisible *** Innovation 4(2),*** novel structures allows for the development of innovative technologies in *** methods to fabricate nanomaterials can be categorized based on the key elements determining the final structures of the *** exhibits unparalleled advantages in the fabrication of nanofiberbased structures by benefitting from the effective interactions between the electrostatic energy and working fluids on a *** a convergence point of fluids and energy,the structure of the spinneret nozzle plays an important role in the working process and the resulting quality of the fibrous structures.

关键词： materials. spinning visible

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Ternary structured magnesium cobalt oxide/graphene/polycarbazole nanohybrids for high performance electrochemical supercapacitors

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Materials Science for Energy Technologies 2023年第1期6卷 399-408页

作者： Babu, Akhil Somesh, T.E. Ani Dechamma, C.D. Hemavathi, A.B. Kakarla, Raghava Reddy Kulkarni, Raghavendra V. Raghu, Anjanapura V. Department of Polymer Science and Technology Sri Jayachamarajendra College of Engineering JSS Science and Technology University Karnataka Mysore570006 India School of Chemical and Biomolecular Engineering The University of Sydney SydneyNSW2006 Australia Department of Pharmaceutics BLDEA's SSM College of Pharmacy and Research Centre Karnataka Vijayapur586 103 India Vijayapura586 103 India

In the present work, polycarbazole (PCz)/magnesium cobalt oxide (MgCo2O4)/reduced graphene oxide (RGO) based ternary nanocomposite was prepared through in-situ polymerization, and utilized it as an active electrodes for electrochemical energy storage supercapacitor applications. The electrochemical behaviour of PCz and its nanocomposites were investigated by measuring specific capacitance using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and Galvanostatic charge–discharge (GCD) analysis. The PCz/MgCo2O4/RGO hybrids exhibited higher capacitance (548.54 F/g) than that of PCz (117.65 F/g) and PCz/MgCo2O4 (482.92 F/g) at the scan rate of 50 mV/s, as determined by CV method. The enhanced supercapacitance indicates high power and energy storage capabilities of the ternary metal oxide-graphene based polycarbazole nanocomposites. Electrochemical impedance spectroscopy confirmed low solution resistance of PCz/MgCo2O4/RGO. Thermogravimetric analysis affirmed the increased thermal stability of PCz/MgCo2O4/RGO composite compared to that of pure polycarbazole and PCz/MgCo2O4 nanocomposite. The scanning electron micrographs of nanocomposite confirmed the successful incorporation of nanofillers into the PCz matrix. On the basis of the research findings, PCz/MgCo2O4/RGO can be expected to be a promising electrode active material for high performance energy storage supercapacitors. © 2023

关键词： Cobalt compounds

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Boost Up the Mechanical and Electrical Property of CNT Fibers by Governing Lyotropic Liquid Crystalline Mesophases with Aramid polymers for Robust Lightweight Wiring Applications

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Advanced Fiber Materials 2023年第2期5卷 514-526页

作者： Ki‑Hyun Ryu Jeong‑Gil Kim Dongju Lee Seo Gyun Kim Bon‑Cheol Ku Jun Yeon Hwang Kwang‑Un Jeong Nam Dong Kim Dae‑Yoon Kim Functional Composite Materials Research Center Korea Institute of Science and TechnologyWanju 55324Republic of Korea Carbon Composite Materials Research Center Korea Institute of Science and TechnologyWanju 55324Republic of Korea Department of Polymer‑Nano Science and Technology Department of Nano Convergence EngineeringJeonbuk National UniversityJeonju 54896Republic of Korea Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and TechnologyDaejeon 34141Republic of Korea

Monofilament type of polyaromatic amide(PA)and carbon nanotube(CNT)composite fibers is presented.A concept of a lyotropic liquid crystal(LLC)constructed via a spontaneous self-assembly is introduced to mitigate the extremely low com-patibility between PA and *** approaches provide an effective co-processing route of PA and CNT simultaneously to fabricate the uniform,continuous,and reliable composite fibers through a ***,the addition of a small amount PA into the dope solution of CNT governs the LLC mesophase not only in a spinneret stage but also in a coagulant ***,the developed PA/CNT composite fibers have the high uniaxial orientational order and the close interfacial packing compared to the pure CNT *** PA/CNT composite fibers achieve the outstanding tensile strength,electrical conductivity,and electrochemical response,while maintaining a *** also exhibit the chemical,mechanical,and thermal *** of these advantages can make flexible,sewable,and washable PA/CNT composite fibers ideal nanocomposite materials for use in next-generation information and energy transporting system by replacing conventional metal electrical conductors.

关键词： Carbon nanotube Aramid polymer Liquid crystal Composite fiber Electrical wire

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Insightful analysis of physical properties, kinetics, absorption capacity, and regeneration heat duty of monoethanolamine and N-methyl-4-piperidinol blended solvent in post-combustion carbon capture

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Environmental Science and Pollution Research 2024年第40期31卷 52868-52885页

作者： Apaiyakul, Rattanaporn Khuenkaew, Wachiramon Sirirathomsud, Ornicha Boonprasop, Sutthichai Liu, Heilei Gao, Hongxia Liang, Zhiwu Tontiwachwuthikul, Paitoon Sema, Teerawat Petrochemistry and Polymer Science Program Faculty of Science Chulalongkorn University Pathumwan Bangkok10330 Thailand Department of Chemical Engineering Faculty of Engineering Mahidol University Nakhon Pathom73170 Thailand Department of Biotechnology Faculty of Science Mahidol University Bangkok10400 Thailand School of Chemistry and Chemical Engineering Beijing Institute of Technology Beijing100081 China Provincial Hunan Key Laboratory for Cost-Effective Utilization of Fossil Fuel Aimed at Reducing CO₂ Emissions College of Chemistry and Chemical Engineering Hunan University Changsha410082 China Faculty of Engineering and Applied Science University of Regina ReginaSKS4S 0A2 Canada Department of Chemical Technology Faculty of Science Chulalongkorn University Pathumwan Bangkok10330 Thailand

In this study, the high potential tertiary N-methyl-4-piperidinol or MPDL (0.25–1.00 M) was blended with 5 M monoethanolamine (MEA) to formulate 5.25–6.00 M MEA-MPDL solvent and compare with the benchmark 5 M MEA. It was found that the density and the Henry’s constant slightly decreased, while the viscosity increased as the MPDL concentration in the blend increased. Even though the equilibrium CO2-loaded viscosity considerably increased (by 34.3–40.2%) as the MPDL content increased, it was still in a great operating region of less than 10 mPa.s. Experimental overall reaction kinetics constant (kov) was well corresponding with the zwitterion mechanism of MEA and the base-catalyze hydration mechanism of MPDL based absorption kinetics model, with %AAD of 0.56%. Interestingly, an addition of MPDL into 5 M MEA slightly enhanced kov (1.2–3.3% increment) and considerably favored absorption capacity (13–31% elevation), and regeneration heat duty (28–47% reduction), respecting 5 M MEA. The proposed strategic blending can maintain the overall solvent reactivity at the same level of the benchmark, while obviously increase the absorption capacity and largely reduce the regeneration heat duty. This highly favors a solvent upgrading for the existing 5 M MEA based CO2 capture plant. According to the recent data, 5 M MEA + 1.00 M MPDL was suggested. Since the blend was formulated at high concentration, its corrosiveness should also be considered. Graphical abstract: (Figure presented.) © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.

关键词： Carbon capture and utilization

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engineering of hollow polymeric nanosphere-supported imidazolium-based ionic liquids with enhanced antimicrobial activities

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Nano Research 2022年第6期15卷 5556-5568页

作者： Yu Zhang Shuwei Li Yixin Xu Xinyun Shi Mingxin Zhang Yingning Huang Ying Liang Yaqiong Chen Wanli Ji Jung Rae Kim Wenliang Song Deng-Guang Yu Il Kim School of Pharmacy Shanghai University of Medicine&Health SciencesShanghai 201318China School of Materials Science&Engineering University of Shanghai for Science and TechnologyShanghai 200093China Department of Polymer Science and Engineering Pusan National UniversityBusan 46241Republic of Korea School of Chemical and Biomolecular Engineering Pusan National UniversityBusan 46241Republic of Korea

The design of stable,efficient and processable bactericidal materials represents a significant challenge for combating multidrugresistant bacteria in a variety of engineering ***,we report a facile strategy for the preparation of hollow polymeric nanosphere(HPN)-supported imidazolium-based ionic liquids(denoted as HPN-ILs)with superior antimicrobial *** were tailored by moderate Friedel−Crafts polymerization followed by the sequential covalent bonding of imidazole and *** resultant HPN-ILs have uniform hollow spherical morphology,an adequate surface area,and excellent physicochemical ***,they are highly active against both Gram-positive and Gram-negative bacteria and exhibit typical time/dosage-dependent antibacterial *** rational combination of porous HPNs and antibacterial ILs to generate an all-in-one entity may open new avenues for the design and fabrication of efficient bacteriostatic ***,HPN-ILs have good biocompatibility and can also be loaded onto diverse matrices,and thus could extend their practical bactericidal application in the potential biomedical-active field.

关键词： antibacterial materials bioactive materials hollow nanospheres ionic liquids porous polymers

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Nanoconfinement effect of nanoporous carbon electrodes for ionic liquid-based aluminum metal anode

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Journal of Energy Chemistry 2022年第11期31卷 121-127,I0005页

作者： Juhee Yoon Seongbak Moon Son Ha Hyung-Kyu Lim Hyoung-Joon Jin Young Soo Yun Program in Environmental and Polymer Engineering Inha UniversityIncheon 22212South Korea Department of Polymer Science and Engineering Inha UniversityIncheon 22212South Korea KU-KIST Graduate School of Converging Science and Technology Korea UniversitySeoul 02841South Korea Division of Chemical Engineering and Bioengineering Kangwon National UniversityGangwon-do 24341South Korea Department of Integrative Energy Engineering Korea UniversitySeoul 02841South Korea

Rechargeable aluminum batteries(RABs),which use earth-abundant and high-volumetric-capacity metal anodes(8040 m Ah cm-3),have great potential as next-generation power sources because they use cheaper resources to deliver higher energies,compared to current lithium ion ***,the mechanism of charge delivery in the newly developed,ionic liquid-based electrolytic system for RABs differs from that in conventional organic ***,targeted research efforts are required to address the large overpotentials and cycling decay encountered in the ionic liquid-based electrolytic *** this study,a nanoporous carbon(NPC)electrode with well-developed nanopores is used to develop a high-performance aluminum *** negatively charged nanopores can provide quenched dynamics of electrolyte molecules in the aluminum deposition process,resulting in an increased collision *** fast chemical equilibrium of anionic species induced by the facilitated anionic collisions leads to more favorable reduction reactions that form aluminum *** nanoconfinement effect causes separated nucleation and growth of aluminum nanoparticles in the multiple confined nanopores,leading to higher coulombic efficiencies and more stable cycling performance compared with macroporous carbon black and 2D stainless steel electrodes.

关键词： Nanoconfinement effect Nanoporous carbon Ionic liquid electrolyte Metal anode Aluminum batteries Multivalent batteries

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Ni Flower/MXene-Melamine Foam Derived 3D Magnetic/Conductive Networks for Ultra-Efficient Microwave Absorption and Infrared Stealth

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Nano-Micro Letters 2022年第4期14卷 142-157页

作者： Haoran Cheng Yamin Pan Xin Wang Chuntai Liu Changyu Shen Dirk W.Schubert Zhanhu Guo Xianhu Liu Key Laboratory of Advanced Material Processing&Mold(Ministry of Education) National Engineering Research Center for Advanced Polymer Processing TechnologyCollege of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450002People’s Republic of China Institute of Polymer Materials Friedrich-Alexander-University Erlangen-NurembergMartensstr.791058 ErlangenGermany Integrated Composites Laboratory(ICL) Department of Chemical&Biomolecular EngineeringUniversity of TennesseeKnoxvilleTN 37996USA

The development of multifunctional and efficient electromagnetic wave absorbing materials is a challenging research ***,the magnetized Ni flower/MXene hybrids are successfully assembled on the surface of melamine foam(MF)through electrostatic self-assembly and dip-coating adsorption process,realizing the integration of microwave absorption,infrared stealth,and flame ***,the Ni/MXene-MF achieves a minimum reflection loss(RLmin)of−62.7 dB with a corresponding effective absorption bandwidth(EAB)of 6.24 GHz at 2 mm and an EAB of 6.88 GHz at 1.8 *** electromagnetic wave absorption is attributed to the three-dimensional magnetic/conductive networks,which provided excellent impedance matching,dielectric loss,magnetic loss,interface polarization,and multiple *** addition,the Ni/MXene-MF endows low density,excellent heat insulation,infrared stealth,and flame-retardant *** work provided a new development strategy for the design of multifunctional and efficient electromagnetic wave absorbing materials.

关键词： Ni-MXene/Melamine foam Microwave absorption Heat insulation Infrared stealth Flame-retardant

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Two-dimensional MXenes:New frontier of wearable and flexible electronics

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InfoMat 2022年第4期4卷 1-28页

作者： Abbas Ahmed Sudeep Sharma Bapan Adak Md Milon Hossain Anna Marie LaChance Samrat Mukhopadhyay Luyi Sun Polymer Program Institute of Materials ScienceUniversity of ConnecticutStorrsConnecticutUSA Advanced Sensor and Energy Research(ASER)Lab Department of Electronic EngineeringKwangwoon UniversitySeoulSouth Korea Department of Textile and Fiber Engineering Indian Institute of TechnologyNew DelhiIndia Department of Textile Engineering Chemistry and ScienceNorth Carolina State UniversityRaleighNorth CarolinaUSA Department of Textile Engineering Khulna University of Engineering&TechnologyKhulnaBangladesh Department of Chemical and Biomolecular Engineering University of ConnecticutStorrsConnecticutUSA

Wearable electronics offer incredible benefits in mobile healthcare monitoring,sensing,portable energy harvesting and storage,human-machine interactions,etc.,due to the evolution of rigid electronics structure to flexible and stretchable ***,transition metal carbides and nitrides(MXenes)are highly regarded as a group of thriving two-dimensional nanomaterials and extraordinary building blocks for emerging flexible electronics platforms because of their excellent electrical conductivity,enriched surface functionalities,and large surface *** article reviews the most recent developments in MXene-enabled flexible electronics for wearable *** MXeneenabled electronic devices designed on a nanometric scale are highlighted by drawing attention to widely developed nonstructural attributes,including 3D configured devices,textile and planer substrates,bioinspired structures,and printed ***,the unique progress of these nanodevices is highlighted by representative applications in healthcare,energy,electromagnetic interference(EMI)shielding,and humanoid control of *** emerging prospects of MXene nanomaterials as a key frontier in nextgeneration wearable electronics are envisioned and the design challenges of these electronic systems are also discussed,followed by proposed solutions.

关键词： flexible electronics MXene nanostructures wearable electronics

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