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The effect of Zn2+ ion substitution on nanoparticles of ZnxMn(1-X) Fe2O4 (X = 0.2, 0.4, 0.6, 0.8) towards signal surface plasmon resonance (SPR)

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Materials Research Innovations 2023年第6期27卷 420-428页

作者： Almi Putra, Rachmad Andi Fadlly, Teuku Asmara, Vina Monica, Desy Sartika Hijrahnisa Novia, Wina Yakob, Muhammad Indrayana, Ipt Geubrina Raszky, Rachmita Mujahid Hamdan, Abd Arfi, Febrina Rahwanto, Adi Jalil, Zulkarnain Physics Study Program Faculty of Engineering Universitas Samudra Langsa Indonesia Doctoral Study Program School of Engineering Universitas Syiah Kuala Banda Aceh Indonesia Department of Physics Education Faculty of Teaching and Education Universitas Samudra Langsa Indonesia Physics Study Program Faculty of Natural Science and Engineering Technology Universitas Udayana Denpasar Indonesia Department of Environmental Engineering Faculty of Science and Technology UIN Ar-Raniry Banda Aceh Indonesia Department of Chemistry Faculty of Science and Technology UIN Ar-Raniry Banda Aceh Indonesia Department of Physics Faculty of Mathematics and Natural Sciences Syiah Kuala University Banda Aceh Indonesia

This study examined the effect of Zn2+ ion substitution on ZnxMn(1-x) Fe2O4 nanoparticles (x = 0.2, 0.4, 0.6, 0.8) towards signal Surface Plasmon Resonance (SPR). The co-precipitation method synthesised the nanoparticles at a temperature of 90°C. The X-Ray Diffraction (XRD) results showed a polycrystalline structure with a crystallite size varied from 19.05 nm to 19.77 nm. In addition, as the Zn element increased in the ZnxMn(1-x)Fe2O4 nanoparticles, the degree of crystallinity increased by 21.72%, respectively. The optical properties of the nanoparticles ZnxMn(1-x) Fe2O4 indicate absorbance at wavelengths of 330.36–331.74 nm. The absorbance level increased as the Zn element decreased, resulting a direct optical gap of 3.47 eV and an indirect optical gap of 3.23 eV. The Attenuated Total Reflection (ATR) curve in the SPR biosensor indicated a shift in the reflective angle of the Prism/Au/Air configuration, which is 47.78° on Prisma/Au/nanoparticle of Zn0.8Mn0.2Fe2O4/air by 50.75°, and the prism/Au/nanoparticle of Zn0.2Mn0.8Fe2 O4/air by 51.04°. The substitution of Zn ions in the compound Zn x Mn(1-x)Fe2O4 affects the resulting ATR curve. The shift in the SPR angle is caused by changes in the refractive index in each layer which is influenced by the concentration of each material which has an impact on the absorbance ability and photon reflectance. This research has the potential to continue with the testing of dielectric and magnetic properties, as well as special testing for biological analytes compatible with ZnxMn(1-x)Fe2O4 nanoparticles. © 2023 Informa UK Limited, trading as Taylor & Francis Group.

关键词： Surface plasmon resonance

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Secondary Structure Modulation of Triptycene-Based One-Handed Helical Ladder Polymers through π-Extension of Achiral Segments

Organic Materials

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Organic Materials 2023年第4期5卷 184-190页

作者： Ikai, Tomoyuki Tanaka, Atsuya Shiotani, Takumi Oki, Kosuke Yashima, Eiji Department of Molecular and Macromolecular Chemistry Graduate School of Engineering Nagoya University Chikusa-ku Nagoya 464-8603 Japan Precursory Research for Embryonic Science and Technology (PRESTO) Japan Science and Technology Agency (JST) Kawaguchi Saitama 332-0012 Japan

A series of enantiopure triptycene-based one-handed helical ladder polymers containing π-extended achiral segments with naphthalene, fluorene, and carbazole spacers was synthesized through quantitative and chemoselective ladderization of the corresponding precursor polymers with random-coil conformations. The helical handedness (right- or left-handed) and geometry (loose coil or ribbon) of the resulting ladder polymers were readily modulated by tuning the structure of the achiral spacers despite the incorporation of the same point chirality of the triptycene unit. All the helical secondary structures are stable and robust due to the shape-persistent ladder structures, showing the characteristic and environment-independent chiroptical properties. © 2023. The Author(s).

关键词： alkyne benzannulations chirality helical polymers ladder formation secondary structures π-extension

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Recent Progress of Chiral Hierarchical Assemblies from a Chinese Perspective

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CCS chemistry 2023年第12期5卷 2736-2759页

作者： Wei Gong Wei Wang Jinqiao Dong Xiangcheng Pan Yan Liu Hai-Bo Yang Xuefeng Fu Yong Cui School of Chemistry and Chemical Engineering Frontiers Science Center for Transformative Molecules and State Key Laboratory of Metal Matrix CompositesShanghai Jiao Tong UniversityShanghai 200240 Shanghai Key Laboratory of Green Chemistry and Chemical Processes Shanghai Frontiers Science Center of Molecule Intelligent Synthesesand Chang-Kung Chuang InstituteSchool of Chemistry and Molecular EngineeringEast China Normal UniversityShanghai 200062 State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular ScienceFudan UniversityShanghai 200438 Department of Chemical Sciences National Natural Science Foundation of ChinaBeijing 10085

Self-assembly of predesigned chiral molecules to form structurally diverse functional materials has been one of the most exciting recent developments in materials science and nanotechnology over the past ***,the rationally designed chiral supermolecules and their hierarchical assemblies result in superior microenvironments,in which they interact distinctly with molecularly asymmetric guests for enantiospecific *** chemistry of chiral supermolecule-based materials(CSMs)has become a lively research topic,and thus this review seeks to shed light on a range of synthetic CSMs at differing length scales developed in the past 5 years,with emphasis on the representative work from *** review includes cavity-containing chiral supermolecules,chiral polymers,and chiral crystalline materials,aiming to tackle important issues from their design,synthesis,and structure to cutting-edge ***,in turn,allows for fundamental understanding of the transfer,amplification,and functional expression of chirality from the molecular to the supramolecular to the macroscopic ***,we provide perspectives on the promises,opportunities,and key challenges for the future development of useful chiral functional materials.

关键词： chirality hierarchical assembly supramolecular complex organic polymer crystalline material

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High sulfur loading and shuttle inhibition of advanced sulfur cathode enabled by graphene network skin and N,P,F-doped mesoporous carbon interfaces for ultra-stable lithium sulfur battery

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Nano Research Energy 2023年第1期2卷 148-156页

作者： Haotian Liu Fan Liu Zehua Qu Jieling Chen Hui Liu Yiqing Tan Jiabao Guo Yan Yan Shuang Zhao Xinsheng Zhao Xinming Nie Xin Ma Zengxia Pei Mingkai Liu School of Chemistry&Materials Science Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional MaterialsJiangsu Normal UniversityXuzhou 221116China School of Physics and Astronomy Sun Yat-sen UniversityZhuhai 519082China State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular ScienceFudan UniversityShanghai 200433China School of Physics and Electronic Engineering Jiangsu Normal UniversityXuzhou 221116China School of Chemistry and Materials Science Nanjing University of Information Science and TechnologyNanjing 210044China School of Chemical and Biomolecular Engineering The University of SydneySydneyNew South Wales 2006Australia

Achieving high loading of active sulfur yet rational regulating the shuttle effect of lithium polysulfide(LiPS)is of great significance in pursuit of high-performance lithium-sulfur(Li-S)***,we develop a free-standing graphene nitrogen(N),phosphorus(P)and fluorine(F)co-doped mesoporous carbon-sulfur(G-NPFMC-S)film,which was used as a binder-free cathode in Li-S *** developed mesoporous carbon(MC)achieved a high specific surface area of 921 m^(2)·g^(-1)with a uniform pore size distribution of 15 *** inserted graphene network inside G-NPFMC-S cathode can effectively improve its electrical conductivity and simultaneously restrict the shuttle of LiPS.A high sulfur loading of 86%was achieved due to the excellent porous structures of graphene-NPFMC(G-NPFMC)*** implemented as a freestanding cathode in Li-S battery,this G-NPFMC-S achieved a high specific capacity(1,356 mAh·g^(-1)),favorable rate capability,and long-term cycling stability up to 500 cycles with a minimum capacity fading rate of 0.025%per cycle,outperforming the corresponding performances of NPFMC-sulfur(NPFMC-S)and MC-sulfur(MC-S).These promising results can be ascribed to the featured structures that formed inside G-NPFMC-S film,as that highly porous NPFMC can provide sufficient storage space for the loading of sulfur,while,the N,P,F-doped carbonic interface and the inserted graphene network help hinder the shuttle of LiPS via chemical adsorption and physical barrier *** proposed unique structure can provide a bright prospect in that high mass loading of active sulfur and restriction the shuttle of LiPS can be simultaneously achieved for Li-S battery.

关键词： lithium sulfur battery high sulfur loading shuttle inhibition heteroatoms doped interface graphene network barrier

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Pt_(1)/Ni_(6)Co_(1)layered double hydroxides/N-doped graphene for electrochemical non-enzymatic glucose sensing by synergistic enhancement of single atoms and doping

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Nano Research 2023年第1期16卷 318-324页

作者： Baojun Long Peiyu Cao Yuanmeng Zhao Qianqian Fu Yan Mo Yueming Zhai Juejing Liu Xingyi Lyu Tao Li Xiaofeng Guo Changsheng Shan Minghua Zeng Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules College of Chemistry and Chemical EngineeringHubei UniversityWuhan 430062China Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources School of Chemistry and Pharmaceutical SciencesGuangxi Normal UniversityGuilin 541004China The Institute for Advanced Studies(IAS) Wuhan UniversityWuhan 430072China Material Science and Engineering Program Washington State UniversityPullmanWA 99164USA Department of Chemistry and Alexandra Navrotsky Institute for Experimental Thermodynamics Washington State UniversityPullmanWA 99164USA X-ray Science Division Argonne National LaboratoryArgonneIL 60439USA Department of Chemistry and Biochemistry Northern Illinois UniversityDeKalbIL 60115USA

The development of novel single-atom catalysts is important for highly efficient electrochemical catalysis and *** this work,a novel Pt single atoms(SAs)supported on Ni_(6)Co_(1)layered double hydroxides/nitrogen-doped graphene(Pt_(1)/Ni_(6)Co_(1)LDHs/NG)was constructed for electrochemical enzyme-free catalysis and sensing towards *** loading of Pt single atoms increases with doping of Co atoms that generate more anchoring sites for Pt *** resulting Pt_(1)/Ni_(6)Co_(1)LDHs/NG exhibits low oxidative potential of 0.440 V with high sensitivity of 273.78μA·mM^(−1)·cm^(−2)toward glucose,which are 85 mV lower and 15 times higher than those of Ni(OH)_(2),***_(1)/Ni_(6)Co_(1)LDHs/NG also shows excellent selectivity and great stability during 5-week *** and experimental results show that the boosted performance of Pt_(1)/Ni_(6)Co_(1)LDHs/NG originates from its stronger binding energy with glucose and the synergistic effect of Pt SAs,Co doping,and *** work provides a general strategy of designing highly active SACs for extending their application in electrochemical sensing.

关键词： single-atom catalysts electrochemical sensor layered double hydroxides nitrogen-doped graphene synergistic effect

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Synthesis and study on the properties of polysaccharides modified via the Steglich reaction

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Applied Nanoscience (Switzerland) 2023年第12期13卷 7413-7423页

作者： Nahorniak, Mykhailo Fihurka, Nataliia Nosova, Nataliya Varvarenko, Serhii Bendoraitiene, Joana Peciulyte, Laura Rutkaite, Ramune Samaryk, Volodymyr Institute of Macromolecular Chemistry Czech Academy of Sciences Heyrovského Nám. 2 Prague160 00 Czech Republic Division of Nanotechnology and Functional Materials Department of Materials Science and Engineering Uppsala University Uppsala75121 Sweden Organic Chemistry Department Lviv Polytechnic National University Bandera St 12 Lviv79013 Ukraine Department of Polymer Chemistry and Technology Kaunas University of Technology Radvilenu Rd. 19 Kaunas50254 Lithuania

Modified polysaccharides are widely used as polymers for medical and biomedical purposes. Among them, the products with a crosslinked macromolecular structure occupy an important place. For instance, using N-derivatives of glutamic acid as a crosslinking agent makes it is possible to obtain non-toxic biodegradable polymer materials. In the current work, the results of study on the polysaccharides modification with N-derivatives of glutamic acid via the Steglich esterification reaction are provided. The factors influencing the efficiency of developed synthetic approach were considered, and the structure and composition of the obtained reaction products were investigated. The reaction was shown to proceed successfully by exploiting both carboxyl groups of N-derivatives of glutamic acid, resulting in the cross-linking of polysaccharide molecules under mild conditions. The study of the properties of the obtained products and the NMR study of their structure and composition showed that two fundamentally different polymers were formed—macromolecules with branched and crosslinked structures. The latter, under certain reaction conditions, formed microhydrogels while dispersing in water. Meanwhile, the branched macromolecules were capable of forming self-stabilized aqueous dispersions. Thus, the article presents the research results on the creation of novel polymers for potential medical applications. © 2023, King Abdulaziz City for science and Technology.

关键词： Polysaccharides

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Nanofiber Materials for Lithium‑Ion Batteries

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Advanced Fiber Materials 2023年第4期5卷 1141-1197页

作者： Xinwang Cao Chang Ma Lei Luo Lei Chen Hui Cheng Raphael Simha Orenstein Xiangwu Zhang National Engineering Laboratory for Advanced Yarn and Fabric Formation and Clean Production College of Textiles Science and EngineeringWuhan Textile UniversityWuhan 430200China Tianjin Municipal Key Lab of Advanced Fiber and Energy Storage Technology Tiangong UniversityTianjin 300387China Fiber and Polymer Science Program Department of Textile EngineeringChemistry and ScienceWilson College of TextilesNorth Carolina State UniversityRaleighNC 27695USA

The lithium-ion(Li-ion)battery has received considerable attention in the field of energy conversion and storage due to its high energy density and *** academic and commercial progress has been made in Li-ion battery *** area of advancement has been the addition of nanofiber materials to Li-ion batteries due to their unique and desirable structural features including large aspect ratios,high surface areas,controllable chemical compositions,and abundant composite *** the past few decades,considerable research efforts have been devoted to constructing advanced nanofiber materials possessing conductive networks to facilitate efficient electron transport and large specific surface areas to support catalytically active sites,both for the purpose of boosting electrochemical ***,we focus on recent advancements of nanofiber materials with carefully designed structures and enhanced electrochemical properties for use in Li-ion *** synthesis,structure,and properties of nanofiber cathodes,anodes,separators,and electrolytes,and their applications in Li-ion batteries are *** research challenges and prospects of nanofiber materials in Li-ion battery applications are delineated.

关键词： Nanofiber Lithium-ion battery Cathode Anode Separator Electrolyte

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Integrated microalgae culture with food processing waste for wastewater remediation and enhanced biomass productivity

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Chinese Chemical Letters 2023年第2期34卷 636-643页

作者： Angela Paul Peter Kit Wayne Chew Apurav Krishna Koyande Heli Siti Halimatul Munawaroh Amit Bhatnagar Yang Tao Chihe Sun Fubao Sun Zengling Ma Pau Loke Show Department of Chemical and Environmental Engineering Faculty of Science and EngineeringUniversity of Nottingham MalaysiaJalan Broga43500 SemenyihSelangor Darul EhsanMalaysia Zhejiang Provincial Key Laboratory for Subtropical Water Environment and Marine Biological Resources Protection Wenzhou UniversityWenzhou 325035China Study Program of Chemistry Department of Chemistry EducationFaculty of Mathematics and Science EducationUniversitas Pendidikan IndonesiaBandung 40154Indonesia Department of Separation Science LUT School of Engineering ScienceLUT UniversitySammonkatu 12FI 50130MikkeliFinland College of Food Science and Technology Nanjing Agricultural UniversityNanjing 210095China Key Laboratory of Industrial Biotechnology Ministry of EducationSchool of BiotechnologyJiangnan UniversityWuxi 214122China Department of Sustainable Engineering Saveetha School of EngineeringSIMATSChennai 602105India

Waste generation from food manufacturing facilities poses a serious hazard like environmental degradation, water pollution, and land pollution due to its high nutrient composition. Specifically, solid waste(powder) disposal requires additional energy sources in terms of scientific treatment, structured collection, and disposal packaging according to the safety regulation. Thus, this research discusses the viewpoint of integrating food processing waste as an organic carbon source with BG-11 medium for Chlorella vulgaris(FSP-E) growth. The food processing waste powders investigated in this study were obtained from milk, and biscuit manufacturing facilities. The culture medium was modified by combining both BG-11 and food processing waste powders to identify the optimal algal growth and biochemical *** to the microalgae grown in BG-11 alone(IBG), the combination of biscuit waste and IBG produced higher biomass concentration(44%), with increased lipid(11%), protein(20%), and carbohydrate(57%) contents. Chlorella vulgaris was able to uptake nutrients from the culture medium with combination of food processing waste and IBG thus enhancing its growth. The results obtained also indicate that an integrated culture system using food processing waste and synthetic sources can generate energy out of waste by improving the bio-composition of the microalgae biomass.

关键词： Medium contamination Food processing Waste powder Organic medium Waste remediation

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Edge atomic Fe sites decorated porous graphitic carbon as an efficient bifunctional oxygen catalyst for Zinc-air batteries

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Journal of Energy chemistry 2023年第8期83卷 602-611,I0014页

作者： Ruihui Gan Yali Wang Xiangwu Zhang Yan Song Jingli Shi Chang Ma Tianjin Municipal Key Lab of Advanced Fiber and Energy Storage Technology Tiangong UniversityTianjin 300387China Fiber and Polymer Science Program Department of Textile EngineeringChemistry and ScienceWilson College of TextilesNorth Carolina State UniversityRaleighNC 27695-8301uNITED sTATES CAS Key Laboratory of Carbon Materials Institute of Coal ChemistryChinese Academy of SciencesTaiyuan 030001ShanxiChina

The development of advanced bifunctional oxygen electrocatalysts for oxygen reduction and evolution reactions(ORR and OER) is critical to the practical application of zinc-air batteries(ZABs). Herein, a silica-assisted method is reported to integrate numerous accessible edge Fe-Nx sites into porous graphitic carbon(named Fe-N-G) for achieving highly active and robust oxygen electrocatalysis. Silica facilitates the formation of edge Fe-Nx sites and dense graphitic domains in carbon by inhibiting iron *** purification process creates a well-developed mass transfer channel for Fe-N-G. Consequently,Fe-N-G delivers a half-wave potential of 0.859 V in ORR and an overpotential of 344 m V at10 m A cm^(-2)in OER. During long-term operation, the graphitic layers protect edge Fe-Nx sites from demetallation in ORR and synergize with Fe OOH species endowing Fe-N-G with enhanced OER *** functional theory calculations reveal that the edge Fe-Nx site is superior to the in-plane Fe-Nx site in terms of OH* dissociation in ORR and OOH* formation in OER. The constructed ZAB based on Fe-N-G cathode shows a higher peak power density of 133 m W cm^(-2)and more stable cycling performance than Pt/C + RuO2counterparts. This work provides a novel strategy to obtain high-efficiency bifunctional oxygen electrocatalysts through space mediation.

关键词： Bifunctionality EdgeFe-Nxsites Oxygen catalysis Graphitic domains Zinc-air batteries

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C-176 loaded Ce DNase nanoparticles synergistically inhibit the cGAS-STING pathway for ischemic stroke treatment

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Bioactive Materials 2023年第11期29卷 230-240页

作者： Zhixin Zhu Haipeng Lu Lulu Jin Yong Gao Zhefeng Qian Pan Lu Weijun Tong Pik Kwan Lo Zhengwei Mao Haifei Shi Department of Orthopedics 1st Affiliated Hospital of Zhejiang University School of MedicineQingchun Road 79Hangzhou31000China MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and EngineeringZhejiang UniversityHangzhou310027China Department of Chemistry and State Key Laboratory of Marine Pollution City University of Hong KongTat Chee AvenueKowloonHong Kong

The neuroinflammatory responses following ischemic stroke cause irreversible nerve cell *** free-double strand DNA(dsDNA)segments from ischemic tissue debris are engulfed by microglia and sensed by their cyclic GMP-AMP synthase(cGAS),which triggers robust activation of the innate immune stimulator of interferon genes(STING)pathway and initiate the chronic inflammatory *** decomposition of immunogenic dsDNA and inhibition of the innate immune STING are synergistic immunologic targets for ameliorating *** combine the anti-inflammatory strategies of STING inhibition and dsDNA elimination,we constructed a DNase-mimetic artificial enzyme loaded with *** are self-assembled by amphiphilic copolymers(P[CL35-b-(OEGMA20.7-co-NTAMA14.3)]),C-176,and Ce^(4+)which is coordinated with nitrilotriacetic acid(NTA)group to form corresponding catalytic *** work developed a new nano-drug that balances the cGAS-STING axis to enhance the therapeutic impact of stroke by combining the DNase-memetic Ce^(4+)enzyme and STING inhibitor *** conclusion,it is a novel approach to modulating central nervus system(CNS)inflammatory signaling pathways and improving stroke prognosis.

关键词： Ischemic stroke Ce-based nano-nuclease The cGAS-STING signaling pathway Anti-inflammation

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