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Effect of Mn Addition and Heat Treatment on the Corrosion Behaviour of Mg-Ag-Mn Alloy

Acta Metallurgica Sinica(English Letters) 2024年第4期37卷 665-677页

作者： You Lv Yupeng Zhang Xi Liu Zehua Dong Xiaorong Zhou Xinxin Zhang Key Laboratory of Material Chemistry for Energy Conversion and Storage Ministry of EducationHubei Key Laboratory of Material Chemistry and Service FailureSchool of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan430074China Hubei Engineering Research Centre for Biomaterials and Medical Protective Materials Huazhong University of Science and TechnologyWuhan430074China Corrosion and Protection Centre Department of MaterialsThe University of ManchesterManchesterM139PLUK

The high corrosion sensitivity and the potential bio-toxicity of Mg-Ag alloys limit their wide applications for the production of implanted devices. In the present work, Mn is added into the Mg-Ag alloy to optimize its corrosion behaviour. The corrosion behaviour of Mg-Ag-Mn alloys is investigated with the underlying microstructural factors examined. The Mg-Ag alloy with 2 wt% Mn exhibits the highest corrosion resistance after post-casting heat treatment at 440 ℃. The addition of Mn results in α-Mn phase with the incorporation of Fe, which suppresses the cathodic activity of impurity Fe. Further, heat treatment of the cast alloys homogenizes the distribution of Ag and promotes the precipitation of α-Mn phase. The former removes Ag segregations as potential cathodes;the latter promotes a more uniform distribution of cathodes and, therefore, prevents localized corrosion.

关键词： Mg-Ag alloy Mn addition Post-casting heat treatment Cathodic activity Corrosion mechanism

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Tunable multicolor luminescence in vanadates from yttrium to indium with enhanced luminous efficiency and stability for its application in WLEDs and indoor photovoltaics

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Nano Research 2023年第8期16卷 11486-11494页

作者： Yaoyang Zhang Jing Mao Peifen Zhu Guofeng Wang Key Laboratory of Functional Inorganic Material Chemistry Ministry of EducationSchool of Chemistry and Materials ScienceHeilongjiang UniversityHarbin 150080China Department of Electrical Engineering and Computer Science University of MissouriColumbiaMissouri 65211USA

The preparation of high-efficiency phosphor is the key to the construction of white light-emitting diode(WLED)devices and their application in indoor *** with YVO_(4),InVO_(4)is not suitable as the host material of lanthanide ions because of its strong ***,the work focused on combining the broadband emission from InVO_(4)and the red luminescence from YVO_(4):Eu^(3+)to obtain enhanced and stable multicolor *** band structure,density of state,and optical properties were studied by density functional *** spectral configuration of YVO_(4):In^(3+)/Eu^(3+)with(112)surface appears to be broadening and redshifts with increasing layer *** the In^(3+)concentration is 3.5 mol%,the YVO_(4):30%Eu^(3+)/In^(3+)emits the strongest *** Judd-Ofelt parameterΩ2 of YVO_(4):In^(3+)/Eu^(3+)increases with increaing In^(3+)concentration,indicating that the symmetry *** adjusting In^(3+)/Eu^(3+)contents,the YVO_(4):In^(3+)/Eu^(3+)not only can emit white light with a color rendering index of 95,but also can be used as high-efficiency red phosphor to build WLED devices with blue emitting N/Tb codoped carbon quantum dots(CQDs-N:Tb^(3+))and green emitting MOF:Tb^(3+)(MOF=metal organic framework),for which the color rendering index can also reach 95 and the color temperature is 5549 *** manufactured WLED devices were further used to excite the silicon solar cell and make it show good photoelectric characteristics.

关键词： luminescence enhancement multicolor stability density functional theory(DFT)calculation white light-emitting diodes(WLEDs) indoor photovoltaics

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Effect of austenitizing temperature on martensitic transformation in SA508Gr.4N steel

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Journal of materials science & Technology 2024年第19期186卷 244-255页

作者： Shumeng Lu Li Wan Shanju Zheng Mengnie Li Juanna Ren Baosheng Liu Manal F.Abou Taleb Zeinhom M.El-Bahy Zhongdong Xu Xiaojing Wang Mohamed M.Ibrahim Zhanhu Guo Faculty of Material Science and Engineering Kunming University of Science and TechnologyKunming 650093China Department of Materials Science and Engineering Inner Mongolia Zhongsheng Engineering Technology Co.Ltd.Alashan 750300China Department of Materials Science and Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China College of Materials Science and Engineering Taiyuan University of Science and TechnologyTaiyuan 030024China Department of Mechanical and Construction Engineering Faculty of Engineering and EnvironmentNorthumbria UniversityNewcastle Upon TyneNE18STUK Department of Chemistry College of Science and Humanities in Al-KharjPrince Sattam Bin Abdulaziz UniversityAl-Kharj11942Saudi Arabia Department of Chemistry Faculty of ScienceAl-Azhar UniversityNasr City 11884CairoEgypt Department of Chemistry College of ScienceTaif UniversityP.O.Box 11099Taif 21944Saudi Arabia

SA508Gr.4 N steel is commonly used in nuclear pressure vessels. The current study discloses the impact of austenitizing temperature on its martensitic transformation. Various austenitizing temperatures were employed to examine the martensitic transformation at different experimental conditions. The characteristics of grain boundaries, microstructure, transformation kinetics, and crystallography of the martensitic phase following the austenitizing process and martensitic transformation were analyzed. Austenitizing temperatures had minimal effects on the critical temperature of the austenitizing phase transition. However, an increase in austenitizing temperature resulted in larger grain sizes. The phase composition primarily consisted of lath martensite, accompanied by a small amount of residual austenite (RA). As the austenitizing temperature increased, the temperature of martensite-start temperature (Ms) initially decreased and then increased. On the other hand, the temperature of martensite-finish (Mf) showed no significant sensitivity to changes in the austenitizing temperature. Moreover, the average size of the lath martensite structure was increased, and there was an increased tendency for variant selection as the austenitizing temperature increased, and the combination of specific orientation relationships appeared. This study is very valuable for revealing the microstructure evolution at different temperatures.

关键词： SA508Gr.4 N steel Austenitizing temperature Martensitic transformation Microstructures characteristics

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Enhanced electromagnetic wave absorption via optical fiber-like PMMA@Ti_(3)C_(2)T_(x)@SiO_(2) composites with improved impedance matching

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Nano Research 2024年第3期17卷 1676-1686页

作者： Huanhuan Niu Xuewen Jiang Wei Li Zhiyu Min Budi Riza Putra Wulan Tri Wahyuni Hailong Wang Rui Zhang Bingbing Fan School of Material Science and Engineering Zhengzhou UniversityZhengzhou 450001China School of Materials Science and Engineering Tongji UniversityShanghai 201804China Department of Materials and Earth Sciences Technical University of DarmstadtDarmstadt 64287Germany School of Material Science and Engineering Luoyang Institute of Science and TechnologyLuoyang 471023China Research Center for Metallurgy National Research and Innovation Agency(BRIN)PUSPIPTEK Gd.470South TangerangBanten 15315Indonesia Analytical Chemistry Division Department of ChemistryFaculty of Mathematics and Natural SciencesIPB UniversityWest Java 16680Indonesia

Ti_(3)C_(2)T_(x) nanosheets have attracted significant attention for their potential in electromagnetic wave absorption(EWA).However,their inherent self-stacking and exorbitant electrical conductivity inevitably lead to serious impedance mismatch,restricting their EWA ***,the optimization of impedance matching becomes *** this work,we developed polymethyl methacrylate(PMMA)@Ti_(3)C_(2)T_(x)@SiO_(2) composites with a sandwich-like core–shell structure by coating SiO_(2) on PMMA@Ti_(3)C_(2)T_(x).The results demonstrate that the superiority of the SiO_(2) layer in combination with PMMA@Ti_(3)C_(2)T_(x),outperforming other relative graded distribution structures and meeting the requirements of EWA *** resulting PMMA@Ti_(3)C_(2)T_(x)@SiO_(2) composites achieved a minimum reflection loss of-58.08 dB with a thickness of 1.9 mm,and an effective absorption bandwidth of 2.88 *** analysis revealed that the structural design of SiO_(2) layer not only optimized impedance matching,but also synergistically enhanced multiple loss mechanisms such as interfacial polarization and dipolar ***,this work provides valuable insights for the future preparation of high-performance electromagnetic wave absorbing Ti_(3)C_(2)T_(x)-based composites.

关键词： polymethyl methacrylate(PMMA)@Ti_(3)C_(2)T_(x)@SiO_(2)composites impedance match SiO_(2)layer optical fiber-like structure interfacial polarization and dipolar polarization

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Tailored heterogeneous interface based on porous hollow In-Co-C nanorods to construct adjustable multi-band microwave absorber

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Journal of materials science & Technology 2024年第14期181卷 128-137页

作者： Zhengying Shen Di Lan Yi Cong Yuanyuan Lian Nannan Wu Zirui Jia School of Material Science and Engineering Shandong University of Science and TechnologyQingdao 266590China Department of Otolaryngology the Affiliated Hospital of Qingdao UniversityQingdao 266000China School of Materials Science and Engineering Hubei University of Automotive TechnologyShiyan 442002China College of Chemistry and Chemical Engineering Qingdao UniversityQingdao 266071China

By rationally controlling the growth of zeolite-imidazolium salt skeleton(ZIF-67)nanoparticles on the hollow indium oxide(In_(2)O_(3))and the subsequent pyrolysis process,In-Co-C hollow rod-like composites with multiple components were successfully prepared in this *** synergistic impact of diverse components including In_(2)O_(3),C,Co_(3)InC_(0.75),and In not only optimizes impedance matching and improves conductive loss,but also creates significant interfacial ***,the addition of Co source and pyrolysis temperature was found to have a significant affected on impedance matching and mi-crowave *** optimized In-Co-C sample displayed ultra-broad absorption bandwidth(EAB)of up to 7.12 GHz(10.88–18.0 GHz)at 2.26 mm thickness,which could cover the whole Ku band and part of X-band,outperforming the previously reported MOFs-derived ***,by adjusting the thickness to 2.91 mm and 4.01 mm,the EAB could cover the entire X band and most of the C *** attenuation mechanisms were systematically investigated through the delta function method and ANSYS high-frequency structure *** findings suggest that the MOFs-derived In-Co-C hollow nanorods could serve as high-performance microwave absorbers with ultra-broad absorption.

关键词： Microwave absorption Hollow rod-like MOFs-derived Conductive loss Interfacial polarization Impedance matching

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Utilization of CoFe2O4 nanoparticles to harness their electrochemical characteristics

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Nanomaterials and Energy 2024年第4期13卷 1-9页

作者： Kumar, Yogendra Pandey, Avinash Kumar Singh, Pragya Singh, Man Vir Raza, Waseem Hasan, Imran Department of Chemistry Institute of Applied Sciences & Humanities GLA University Mathura India Department of Chemistry Dev Bhoomi Uttarakhand University Dehradun India School of Material Science & Engineering Yeungnam University Gyeongsan Korea Republic of Department of Chemistry College of Science King Saud University Riyadh Saudi Arabia

The cobalt ferrite nanoparticles were synthesized using cobalt nitrate and ferric nitrate as precursor materials by combustion method using sucrose as a fuel. The cobalt ferrite nanoparticle materials were analyzed through field emission scanning electron microscope (FESEM) and X-ray diffraction (XRD) spectroscopy. FESEM and XRD techniques reveal that the cobalt ferrite particles are in the crystallite nano range, with their size ranging from 10 to 14 nm. The cobalt ferrite nanoparticle materials have been thermally analyzed by Mettler Toledo and thermogravimetric analysis/differential scanning calorimetry 3+ model;the nanoparticles were found thermally stable at 4508C temperature. Galvanstate 101 (the Netherlands) with three-electrodes system and AUTOLAB potentiostats were used to test electrochemical properties during the synthesis of cobalt ferrite nanoparticle materials;the oxidation and reduction potentials were found to be 384 mV and 186 mV, respectively. Oxidation and reduction currents were found at 35.9 μA and -25.5 μA, respectively. The electrode was made from cobalt ferrite nanoparticles for application, and their properties were excellent. © 2024 ICE Publishing. All rights reserved.

关键词： Field emission microscopes

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N-doped carbon confined ternary Pt_(2)NiCo intermetallics for efficient oxygen reduction reaction

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Chinese Chemical Letters 2025年第3期36卷 432-438页

作者： Chenhao Zhang Qian Zhang Yezhou Hu Hanyu Hu Junhao Yang Chang Yang Ye Zhu Zhengkai Tu Deli Wang Key Laboratory of Material Chemistry for Energy Conversion and Storage Hubei Key Laboratory of Material Chemistry and Service FailureSchool of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan 430074China China-EU Institute for Clean and Renewable Energy Huazhong University of Science and TechnologyWuhan 430074China Department of Applied Physics The Hong Kong Polytechnic UniversityHong Kong 999077China School of Energy and Power Engineering Huazhong University of Science and TechnologyWuhan 430074China

Developing high performance electrocatalysts for the cathodic oxygen reduction reaction(ORR)is essential for the widespread application of fuel ***,a promising Pt_(2)NiCo atomic ordered ternary intermetallic compound with N-doped carbon layer coating(o-Pt_(2)NiCo@NC)has been synthesized via a facile method and applied in acidic *** confinement effect provided by the carbon layer not only inhibits the agglomeration and sintering of intermetallic nanoparticles during high temperature process but also provides adequate protection for the nanoparticles,mitigating the aggregation,detachment and poisoning of nanoparticles during the electrochemical *** a result,the o-Pt_(2)NiCo@NC demonstrates a mass activity(MA)and specific activity(SA)of 0.65 A/mgPt and 1.41mA/cm_(Pt) ^(2) in 0.1mol/L HClO_(4),*** addition,after 30,000 potential cycles from 0.6 V to 1.0 V,the MA of o-Pt_(2)NiCo@NC shows much lower decrease than the disordered Pt_(2)NiCo alloy and Pt/*** cycling at high potential cycles of 1.5 V for 10,000 cycles,the MA still retains∼70%,demonstrating superior long-term ***,the o-Pt_(2)NiCo@NC also exhibits strong tolerance to CO,SO_(x),and PO_(x) molecules in toxicity tolerance *** strategy in this work provides a novel insight for the development of ORR catalysts with high catalytic activity,durability and toxicity tolerance.

关键词： Oxygen reduction reaction Electrocatalysis Ordered intermetallic Toxicity tolerance Carbon confinement

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Phase-separated bimetal enhanced sodium storage:Dimer-like Sn-Bi@C heterostructures with high capacity and long cycle life

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Journal of Energy chemistry 2023年第4期79卷 468-476页

作者： Xiaoxiao Hou Yansong Zhu Qian Yao Jinmei Song Chunsheng Wang Yanli Zhou Suyuan Zeng Jian Yang Yitai Qian Key Laboratory of Colloid and Interface Chemistry Ministry of EducationSchool of Chemistry and Chemical EngineeringShandong UniversityJinan 250100ShandongChina Department of Environmental and Material Engineering Yantai UniversityYantai 264005ShandongChina Department of Chemistry and Chemical Engineering Liaocheng UniversityLiaocheng 252059ShandongChina Hefei National Laboratory for Physical Science at Microscale Department of ChemistryUniversity of Science and Technology of ChinaHefei 230026AnhuiChina

Phase boundaries facilitate the charge transportation and alleviate the intrinsic stress upon ***,how to achieve regular phase boundaries is very ***,dimer-like Sn-Bi@C nanostructures,where is a well-defined phase boundary between Sn and Bi,have been prepared by a two-step process for the first *** phase boundary not only provides additional and fast transportation for Na+,but also mitigates the structure stress/strain upon ***,Sn-Bi@C exhibits a high capacity(472.1 m A h g^(-1)at 2 A g^(-1)for 200 cycles),an ultra-long cyclic life(355.6 mA h g^(-1)at 5 A g^(-1)for 4500cycles)and an excellent rate performance(372 mA h g^(-1)at 10 A g^(-1))for sodium storage,much higher than those of Sn@C,Bi@C,and Sn@C+Bi@***,the full cells of Sn-Bi@C//Na_(3)V_(2)(PO_(4))_(3)/rGO(SnBi@C//NVP/rGO)demonstrate impressive performance(323 mA h g^(-1)at 2 A g^(-1)for 300 cycles).The underlying mechanism for such an excellent performance is elucidated by in-situ X-ray diffraction,exsitu scanning electron microscopy/high-resolution transmission electron microscopy and atomic force microscopy,revealing the good electrode stability and improved mechanical properties of Sn-Bi@*** synthetic method is extended to dimer-like Sn-Pb@C and Sn-Ag@C heterostructures,which also exhibit the good cycle stability for sodium storage.

关键词： Bi Sn Alloy-type anodes Sodium-ion batteries Phase boundaries

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Recent Advances in the Electrochemical Defluorinative Transformations of C-F Bonds

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Chinese Journal of chemistry 2024年第16期42卷 1913-1928页

作者： Qinhui Wan Rui-Xue Liu Zhongyi Zhang Xia-Die Wu Zhong-Wei Hou Lei Wang Advanced Research Institute and Schoolof Pharmaceutical Sciences Taizhou UniversityJiaojiangZhejiang 318000China Department of Chemistry Southern University of Science and TechnologyhenzhenGuangdong 518055China College of Material Chemistry and Chemical Engineering Key Laboratory of Organosilicon Chemistry and Material Technology Ministryof EducationHangzhou Normal UniversityHangzhouZhejiang 311121China

Organic fluorine compounds are ubiquitous and pivotally important organic molecules,yet their activation and transformation have long been a formidable challenge due to the high energy and low reactivity of C-F *** electrosynthesis,an environmentally benign synthetic method in organic chemistry,enables a myriad of chemical transformations without the need for external redox *** recent years,organic electrochemistry has emerged as a powerful tool for achieving the activation and transformation of C-F bonds in fluorine-containing *** review aims to succinctly recapitulate the latest advancements in the electrochemical defluorinative transformations of C-F bonds and to delve into the reaction design,mechanistic insights,and developmental prospects ofthese methods.

关键词： Organic electrochemistry Electroreduction Defluorination C-F bond activation Organic fluorine compounds

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Rationally construction of atomic-precise interfacial charge transfer channel and strong build-in electric field in nanocluster-based Zscheme heterojunctions with enhanced photocatalytic hydrogen production

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Nano Research 2024年第6期17卷 5002-5010页

作者： Qingtao Zhu Honglei Shen Chao Han Liu Huang Yanting Zhou Yuanxin Du Xi Kang Manzhou Zhu Department of Materials Science and Engineering Centre for Atomic Engineering of Advanced MaterialsKey Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of EducationKey Laboratory of Functional Inorganic Material Chemistry of Anhui ProvinceAnhui UniversityHefei 230601China

The lack of effective charge transfer driving force and channel limits the electron directional migration in nanoclusters(NC)-based heterostructures,resulting in poor photocatalytic ***,a Z-scheme NC-based heterojunction(Pt1Ag28-BTT/CoP,BTT=1,3,5-benzenetrithiol)with strong internal electric field is constructed via interfacial Co-S bond,which exhibits an absolutely superiority in photocatalytic performance with 24.89 mmol·h^(−1)·g−1 H_(2)production rate,25.77%apparent quantum yield at 420 nm,and~100%activity retention in stability,compared with Pt1Ag28-BDT/CoP(BDT=1,3-benzenedithiol),Ag29-BDT/CoP,and *** enhanced catalytic performance is contributed by the dual modulation strategy of inner core and outer shell of NC,wherein,the center Pt single atom doping regulates the band structure of NC to match well with CoP,builds internal electric field,and then drives photogenerated electrons steering;the accurate surface S modification promotes the formation of Co-S atomic-precise interface channel for further high-efficient Z-scheme charge directional *** work opens a new avenue for designing NC-based heterojunction with matchable band structure and valid interfacial charge transfer.

关键词： atomically precise metal nanocluster Z-scheme heterojunction interfacial charge transfer build-in electric field photocatalytic hydrogen production

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