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Healing the degradable organic–inorganic heterointerface for highly efficient and stable organic solar cells

InfoMat 2022年第2期4卷 162-170页

作者： Yangdan Tao Haoran Liu Di Wang Feng Zhao Zeng Chen Haiming Zhu Hongzheng Chen Chang-Zhi Li State Key Laboratory of Silicon Materials MOE Key Laboratory of Macromolecular Synthesis and FunctionalizationDepartment of Polymer Science and EngineeringZhejiang UniversityHangzhouChina Department of Chemistry Zhejiang UniversityHangzhouChina

The heterointerface between the contacted organic and inorganic semiconductors critically affects the charge extraction,hence overall performance of organic optoelectronics,especially for organic solar cells(OSCs).Herein,we develop an effective interfacial strategy that simultaneously boosts the chemical,electric,and electronic properties of the organic–inorganic heterointerface of the derived OSCs,through implanting conjugated molecules as selfassemble monolayers(SAMs)to metal oxide nanoparticles(MO NPs).As results,SAM passivated zinc oxide nanoparticles(ZnO NPs)as electron transport layers(ETLs)not only enable the best performed OSCs containing MO ETLs,but also exhibit the most desirable thickness insensitive features(up to 300 nm).In addition,SAM-ZnO ETLs help also substantially improving the photostability of the derived ***,this work can be beneficial to the further development of high-performance and cost-effective OSCs.

关键词： charge extraction organic-inorganic heterointerface organic solar cells photostability

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一体化可拉伸的多功能电化学传感纤维构建微量汗液健康监测织物

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science China materials 2024年第1期67卷 251-260页

作者：张安宁周靓靓梁琦敏王欣胡晓康贾康康储宏伟罗勇锋丘龙斌彭慧胜何思斯 Shenzhen Key Laboratory of Flexible Printed Electronics Technology School of ScienceHarbin Institute of Technology(Shenzhen)Shenzhen 518055China Department of Mechanical and Energy Engineering Southern University of Science and TechnologyShenzhen 518055China Hunan Province Key Laboratory of Materials Surface&Interface Science and Technology College of ScienceMaterial Science and Engineering SchoolCentral South University of Forestry and TechnologyChangsha 410004China State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular Science and Laboratory of Advanced MaterialsFudan UniversityShanghai 200438China

透气舒适的传感纺织品可以检测人体汗液中的多种生物标记物,是在日常生活中实现全面健康监测的有效途径.然而,目前的可穿戴柔性电化学纺织品缺乏伸展性,这可能会导致信号不稳定或在移动过程中损坏设备.此外,这些纺织品对多种指示器的集... 详细信息

透气舒适的传感纺织品可以检测人体汗液中的多种生物标记物,是在日常生活中实现全面健康监测的有效途径.然而,目前的可穿戴柔性电化学纺织品缺乏伸展性,这可能会导致信号不稳定或在移动过程中损坏设备.此外,这些纺织品对多种指示器的集成度有限,需要较大的表面积和大量的汗液来激活传感器.在此,我们报告了一种一体化多功能电化学生物传感器纤维,该纤维具有可拉伸性,通过微量汗液即可检测汗液中的多种生物标志物.这种生物传感器是通过将多功能碳纳米管条带以螺旋状排列的方式负载在预先拉伸的聚合物纤维芯上从而充当微电极,并且两者之间具有稳定界面.此外,通过引入超亲水鞘层,提高了生物传感器的汗液捕获效率.该生物传感器能够同时监测pH、K^(+)、Na^(+)、葡萄糖、乳酸和尿酸六种生物标记物,300%的应变下表现出稳定的传感性能.仅需1μL的汗液即可启动对六种生物标记物进行高效检测.由此编织的织物传感系统可以连续、实时地监测多种生物标记信息,从而完成人体健康状况的评估.

关键词：生物传感器生物标记物人体健康状况健康监测聚合物纤维损坏设备伸展性微电极

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Surface modification techniques of membranes to improve their antifouling characteristics:recent advancements and developments

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Frontiers of Chemical science and engineering 2023年第12期17卷 1837-1865页

作者： Muhammad Tawalbeh Haya Aljaghoub Muhammad Qasim Amani Al-Othman Sustainable and Renewable Energy Engineering Department University of SharjahSharjah 27272United Arab Emirates Sustainable Energy&Power Systems Research Centre RISEUniversity of SharjahSharjah 27272United Arab Emirates Industrial Engineering and Engineering Management Department University of SharjahSharjah 27272United Arab Emirates Department of Chemical and Biological Engineering American University of SharjahSharjah 26666United Arab Emirates Materials Science and Engineering Program College of Arts and SciencesAmerican University of SharjahSharjah 26666United Arab Emirates

Extensive research efforts are currently devoted to developing and improving conventional technologies for water treatment. Membrane-based water treatment technologies are among the most preferred options due to their commercial success, simple operation, low energy and space requirements, and high separation efficiency. Despite the advances made in membrane-based technologies, fouling remains a critical challenge. Fouling occurs upon the accumulation of unwanted impurities on the membrane surface and within the membrane pores which results in a significant decline in the membrane permeate flux. To alleviate the operational challenges from fouling, surface modification to develop antifouling membranes appears to be an effective technique. A comprehensive review of the surface modification techniques for the development of antifouling membranes is provided in this paper. Chemical surface modification techniques (grafting and plasma treatment), physical modification techniques (blending, coating, adsorption, and thermal treatment), and combined physical and chemical modification techniques have been discussed. Moreover, the challenges related to surface modification and the future research directions are addressed.

关键词： fouling antifouling membrane surface modification membrane pretreatment

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Effect of electrolyte anions on the cycle life of a polymer electrode in aqueous batteries

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escience 2022年第1期2卷 110-115页

作者： Ye Zhang Lihong Zhao Yanliang Liang Xiaojun Wang Yan Yao Department of Electrical and Computer Engineering Materials Science and Engineering ProgramUniversity of HoustonHoustonTX77204USA Texas Center for Superconductivity at the University of Houston HoustonTX77204USA

Redox polymers are a class of high-capacity, low-cost electrode materials for electrochemical energy storage, butthe mechanisms governing their cycling stability are not well understood. Here we investigate the effect of anionson the longevity of a p-dopable polymer through comparing two aqueous zinc-based electrolytes. Galvanostaticcycling studies reveal the polymer has better capacity retention in the presence of triflate anions than that withsulfate anions. Based on electrode microstructural analysis and evolution profiles of the cell stacking pressure, theorigin of capacity decay is ascribed to mechanical fractures induced by volume change of the polymer activematerials during repeated cycling. The volume change of the polymer with the triflate anion is 61% less than thatwith the sulfate anion, resulting in fewer cracks in the electrodes. The difference is related to the different anionsolvation structures—the triflate anion has fewer solvated water molecules compared with the sulfate anion,leading to smaller volume expansion. This work highlights that anions with low solvation degree are preferablefor long-term cycling.

关键词： Aqueous batteries Polymer electrode Anions Volume chang

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Nonaffinity of Liquid Networks and Bicontinuous Mesophases

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Physical Review Letters 2024年第21期132卷 218201-218201页

作者： Michael S. Dimitriyev Xueyan Feng Edwin L. Thomas Gregory M. Grason Department of Polymer Science and Engineering University of Massachusetts Amherst Massachusetts 01003 USA Department of Materials Science and Engineering Texas A&M University College Station Texas 77843 USA Department of Macromolecular Science State Key Laboratory of Molecular Engineering of Polymers Fudan University Shanghai China 200438

Amphiphiles self-assemble into a variety of bicontinuous mesophases whose equilibrium structures take the form of high-symmetry cubic networks. Here, we show that the symmetry-breaking distortions in these systems give rise to anomalously large, nonaffine collective deformations, which we argue to be a generic consequence of “mass equilibration” within deformed networks. We propose and study a minimal “liquid network” model of bicontinuous networks, in which acubic distortions are modeled by the relaxation of residually stressed mechanical networks with constant-tension bonds. We show that nonaffinity is strongly dependent on the valency of the network as well as the degree of strain-softening or strain-stiffening tension in the bonds. Taking diblock copolymer melts as a model system, liquid network theory captures quantitative features of two bicontinuous phases based on comparison with self-consistent field theory predictions and direct experimental characterization of acubic distortions, which are likely to be pronounced in soft amphiphilic systems more generally.

关键词： Self-assembly Shear deformation Block copolymers Lyotropic liquid crystals Polymer networks Network Models

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Fluorinated amphiphilic Poly(β-Amino ester)nanoparticle for highly efficient and specific delivery of nucleic acids to the Lung capillary endothelium

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Bioactive materials 2024年第1期31卷 1-17页

作者： Zicheng Deng Wen Gao Fatemeh Kohram Enhong Li Tanya V.Kalin Donglu Shi Vladimir V.Kalinichenko Phoenix Children’s Health Research Institute Department of Child HealthUniversity of Arizona College of Medicine-PhoenixPhoenixAZ85004USA Division of Pulmonary Biology Cincinnati Children’s Hospital Medical CenterCincinnatiOH45229USA The Materials Science and Engineering Program College of Engineering and Applied ScienceUniversity of CincinnatiCincinnatiOH45221USA Division of Neonatology Phoenix Children’s HospitalPhoenixAZ85016USA

Endothelial cell dysfunction occurs in a variety of acute and chronic pulmonary diseases including pulmonary hypertension,viral and bacterial pneumonia,bronchopulmonary dysplasia,and congenital lung diseases such as alveolar capillary dysplasia with misalignment of pulmonary veins(ACDMPV).To correct endothelial dysfunction,there is a critical need for the development of nanoparticle systems that can deliver drugs and nucleic acids to endothelial cells with high efficiency and *** several nanoparticle delivery systems targeting endothelial cells have been recently developed,none of them are specific to lung endothelial cells without targeting other organs in the *** the present study,we successfully solved this problem by developing non-toxic poly(β-amino)ester(PBAE)nanoparticles with specific structure design and fluorinated modification for high efficiency and specific delivery of nucleic acids to the pulmonary endothelial *** intravenous administration,the PBAE nanoparticles were capable of delivering non-integrating DNA plasmids to lung microvascular endothelial cells but not to other lung cell *** whole body imaging and flow cytometry demonstrated that DNA plasmid were functional in the lung endothelial cells but not in endothelial cells of other *** of PBAE was required for lung endothelial cell-specific *** analysis and liver and kidney metabolic panels demonstrated the lack of toxicity in experimental ***,fluorinated PBAE nanoparticles can be an ideal vehicle for gene therapy targeting lung microvascular endothelium in pulmonary vascular disorders.

关键词： Poly(β-amino)esters nanoparticle Lung microvascular endothelium Gene delivery Specific targeting

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Low-density diamondlike amorphous carbon at nanostructured metal-diamond interfaces

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Physical Review materials 2024年第9期8卷 096001页

作者： Brendan McBennett Yuka Esashi Nicholas W. Jenkins Albert Beardo Yunzhe Shao Emma E. Nelson Theodore H. Culman Begoña Abad Michael Tanksalvala Travis D. Frazer Samuel Marks Weilun Chao Sadegh Yazdi Joshua L. Knobloch Henry C. Kapteyn Margaret M. Murnane Department of Physics Materials Science and Engineering Center for X-Ray Optics Renewable and Sustainable Energy Institute and the Materials Science & Engineering Program 4775 Walnut Street #102 Boulder Colorado 80309 USA

Next-generation nanoelectronic, energy, and quantum technologies require increasingly stringent thermal, optical, mechanical, and electrical properties of component materials, often surpassing the limits of widely used materials such as silicon. Diamond, an ultrawide bandgap semiconductor, is a promising material for these applications because of its very high stiffness, thermal conductivity, and electron mobility. However, incorporating diamond into devices that require high-quality metal-diamond interfaces is challenging. In this work, we use a suite of electron microscopy measurements to reveal an ultrathin amorphous carbon layer that emerges at metal-diamond interfaces after electron beam lithography. Using extreme ultraviolet scatterometry, we nondestructively determine lower bounds on the layer's Young's modulus and thermal conductivity, which at >230GPa and >1.1 W/(mK) are indicative of a diamondlike form of amorphous carbon with high sp3 bonding. However, extreme ultraviolet coherent diffractive imaging reflectometry and energy-dispersive x-ray spectroscopy measurements indicate a low and likely inhomogeneous density in the range of 1–2g/cm3. The low density of such a stiff and conductive layer could indicate that it contains nanometer-scale voids or atomic-scale vacancies. The appearance of this unusual layer illustrates the nanofabrication challenges for diamond and highlights the need for better techniques to characterize surfaces and interfaces in nanoscale devices.

关键词： Amorphous materials Diamond Interfaces Thin films Electron energy loss spectroscopy Energy-dispersive x-ray spectroscopy High-harmonic generation Ultrafast femtosecond pump probe X-ray reflectivity

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Sensitivity improvement of fluoroalkylated EUV resist with electron-rich vinyl units 41

Sensitivity improvement of fluoroalkylated EUV resist with e...

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Advances in Patterning materials and Processes XLI 2024

作者： Kim, Gayoung Ku, Yejin Lee, Jin-Kyun Kim, Jiho Park, Byeong-Gyu Lee, Sangsul Jang, Yu Ha Jung, Byung Jun Koh, Chawon Nishi, Tsunehiro Kim, Hyun-Woo Program in Environment and Polymer Engineering Inha University Incheon22212 Korea Republic of Department of Polymer Science and Engineering Inha University Incheon22212 Korea Republic of Pohang Accelerator Laboratory Postech Pohang37673 Korea Republic of Department of Materials Science and Engineering University of Seoul Seoul02504 Korea Republic of Samsung Electronics Co. Ltd. Semiconductor R&d Center Suwon18448 Korea Republic of Department of Materials Science and Engineering Yonsei University Seoul03722 Korea Republic of

ISBN: (纸本)9781510672208

In this study, we present a method to enhance the sensitivity of fluorinated EUV resists by leveraging the rapid coupling reaction between electrophilic carbon radicals and electron-rich alkenes. To validate the impact of the vinyl groups, DVS-HNF was synthesized by introducing fluorinated alkyl chains and silyl vinyl functional groups into the model compound. Additionally, TMS-HNF and EDMS-HNF, which do not contain a vinyl moiety, were synthesized for comparison. To evaluate the patterning properties of the three materials, e-beam lithography experiments were conducted, resulting in the formation of negative-tone patterns for all three materials. Comparing sensitivities, DVS-HNF with two vinyl moieties exhibited the most excellent sensitivity, confirming the effective collaboration between fluorinated alkyl radicals and vinyl groups. After performing an EUV lithography experiment on DVS-HNF, it was confirmed that a 30 nm negative-tone pattern was successfully formed with excellent sensitivity. These results substantiate the potential of the single-component molecular resist for high performance EUV lithography. © COPYRIGHT SPIE. Downloading of the abstract is permitted for personal use only.

关键词： Extreme ultraviolet lithography

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Development of Mg-Al LDH and LDO as novel protective materials for deacidification of paper-based relics

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Chinese Chemical Letters 2024年第9期35卷 475-480页

作者： Sinong Wang Shanshan Jin Xue Yang Yanyan Huang Peng Liu Yi Tang Yuliang Yang Institute for Preservation and Conservation of Chinese Ancient Books Fudan University LibraryFudan UniversityShanghai 200433China Department of Chemistry Shanghai Key Laboratory of Molecular Catalysis and Innovative MaterialsCollaborative Innovation Centre of Chemistry for Energy MaterialsFudan UniversityShanghai 200433China State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular ScienceFudan UniversityShanghai 200433China Key Laboratory of Pulp and Paper Science&Technology of Ministry of Education Qilu University of Technology(Shandong Academy of Sciences)Ji’nan 250353China

Acidification of paper-based relics is a common problem,leading to their degradation and eventual *** deacidification is highly dependent on a limited variety of alkaline materials,and the development of new materials that are safe,efficient and easy-to-prepare is highly demanded to ensure a high level of safety and effective protection of paper-based *** study proposes the introduction of layered double hydroxide(LDH)and its calcined product,mixed metal oxide(layered double oxide(LDO)),as innovative protective materials for the deacidification of paper with varying levels of *** results demonstrate that treatment with Mg-Al LDH/LDO can effectively modify the p H of acidic paper(e.g.,pH~4.0–6.4)to a neutral or weakly basic state,maintaining this desirable p H range even under long-term accelerated aging ***,LDH proves to be well-suited for the protection of slightly acidified paper(e.g.,pH>5.5),while LDO serves as an especially option for the deacidification of severely acidified paper(e.g.,pH≤5.5).During aqueous deacidification,due to the memory effect of the LDH-based materials,LDO is converted to rehydrated LDH,which creates a mild and appropriate alkaline retention in the paper,avoiding damage caused by strong alkalinity such as cellulose degradation and pigment fading during subsequent long-term natural preservation of the ***,Mg-Al LDH/LDO materials also exhibit flame-retardant and bacteriostatic *** opens up opportunities for the safe,efficient and multifunctional protection of acidified paper-based relics.

关键词： Layered double hydroxide Layered double oxide Structural memory effect Paper protection Deacidification

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Effect of Yttrium Treatment on Germanium-Oxide-Based Interfacial Layer of Ge P-Channel Metal–Oxide–Semiconductor Field-Effect Transistor Fabricated Through In Situ Plasma-Enhanced Atomic Layer Deposition

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IEEE Transactions on Electron Devices 2024年第3期71卷 1-6页

作者： Li, Hui-Hsuan Lin, Kuan-Yu Tsai, Yi-He Lin, Yu-Hsien Chien, Chao-Hsin Institute of Electronics National Yang Ming Chiao Tung University Hsinchu Taiwan Graduate Program for Nanotechnology Department of Materials Science and Engineering National Yang Ming Chiao Tung University Hsinchu Taiwan Department of Electronic Engineering National United University Miaoli Taiwan

This study investigated the effect of yttrium (Y) treatment on a germanium (Ge)-oxide-based interfacial layer (IL) through in situ plasma-enhanced atomic layer deposition (PEALD). Time-of-flight secondary-ion mass spectrometry revealed that the surface reaction and deposition could be successfully performed with a Y precursor, and X-ray photoelectron spectroscopy (XPS) revealed that Y treatment on an IL can suppress GeO

$_{\text{x}}$

volatilization. A metal–oxide–semiconductor capacitor gate-stack with a Y-GeO

$_{\text{x}}$

IL has a low leakage current density (2.1

$\times$

$^{-\text{5}}$

A/cm

$^{\text{2}}$

) and a low interface trap density (approximately 5.5

$\times$

$^{\text{11}}$

$^{-\text{1}}$

$^{-\text{2}}$

) under optimized temperatures. Moreover, the Ge P-channel metal–oxide–semiconductor field-effect transistor (P-MOSFET) containing a gate-stack with a Y-treated Ge-oxide-based IL exhibited a high I

$_{\biosc{on}}$

$_{\biosc{off}}$

ratio and low OFF-state current. Therefore, applying the proposed Y treatment on the IL of a Ge P-MOSFET can help achieve a subnanometer equivalent oxide thickness (EOT) and an

关键词： Ge-oxide-based germanium germanium oxide (GeOx) in situ interfacial layer (IL) plasma-enhanced atomic layer deposition (PEALD) Y-GeOx yttrium

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