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Controllable Secondary Through-Space Interaction and Clusteroluminescence

CCS Chemistry 2023年第12期5卷 2832-2844页

作者： Zuping Xiong Jianyu Zhang Lei Wang Yuan Xie Yipu Wang Zujin Zhao Haoke Zhang Jing Zhi Sun Feihe Huang Ben Zhong Tang MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027 Zhejiang-Israel Joint Laboratory of Self-Assembling Functional Materials ZJU-Hangzhou Global Scientific and Technological Innovation CenterZhejiang UniversityHangzhou 311215 Department of Chemistry Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and ReconstructionThe Hong Kong University of Science and TechnologyHong Kong Center for AIE Research College of Materials Science and EngineeringShenzhen UniversityShenzhen 518061 State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular AggregatesSouth China University of TechnologyGuangzhou 51064 Centre of Healthcare Materials Shaoxing InstituteZhejiang UniversityShaoxing 312000 Stoddart Institute of Molecular Science Department of ChemistryZhejiang UniversityHangzhou 310058 School of Science and Engineering Shenzhen Institute of Aggregate Science and TechnologyThe Chinese University of Hong KongShenzhen 518172

Nonconjugated clusteroluminogens(CLgens),such as proteins and polystyrene,have become increasingly important in *** show many advantages over traditional conjugated dyes with fused aromatic rings in biological ***,CLgens have historically been unheeded because of their weak visible emissions in the aggregate state,namely clusteroluminescence(CL).Changing the electronic structures of CLgens by precisely regulating the intramolecular throughspace interaction(TSI)to improve their photophysical properties remains an enormous ***,we propose a general strategy to construct a higher-level intramolecular TSI,namely secondary TSI constructed by the primary TSI and a TSI linker,in multi-aryl-substituted alkanes(MAAs).By introducing methyl and phenyl into 1,1,3,3-tetraphenylpropane,the modified MAAs show efficient CL with high luminescence quantum yield(-40%)and long emission wavelength(-530 nm).Then,comprehensive experiments and theoretical studies demonstrate that molecular rigidity and overlap of subunits play pivotal roles in improving these hierarchical *** work not only provides a feasible strategy to achieve controllable manipulation of hierarchical TSIs and CL but also establishes comprehensive TSI-based aggregate photophysics.

关键词： through-space interaction clusteroluminescence aggregation-induced emission alkanes electronic structures aggregate photophysics

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High-quality Mid-infrared Chalcogenide Ring Resonator

High-quality Mid-infrared Chalcogenide Ring Resonator

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CLEO: science and Innovations in CLEO 2024, CLEO: S and I 2024 - Part of Conference on Lasers and Electro-Optics

作者： Lu, Bright Xu, Bo Krueper, Greg Zohrabi, Mo Gopinath, Juliet T. Park, Wounjhang Department of Electrical Computer and Energy Engineering University of Colorado BoulderCO80309 United States Department of Physics University of Colorado BoulderCO80309 United States Materials Science and Engineering Program University of Colorado BoulderCO80309 United States

We report Ge23Sb7S70 chalcogenide ring resonators with up to 8 × 104 quality factors operating around 3.6 µm wavelength fabricated through e-beam lithography. Their rib waveguide geometry can be engineered to support close-to-zero dispersion modes needed for mid-infrared microcomb generation. © Optica Publishing Group 2024

关键词： Infrared devices

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Synthesis of nickel-backboned polymers by incorporating triazine groups

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science Bulletin 2025年

作者： Zhang, Yifeng Zeng, Kaiwen Wu, Yanruzhen Huang, Fuyao Peng, Huisheng State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular Science Institute of Fiber Materials and Devices and Laboratory of Advanced Materials Fudan University Shanghai200438 China

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Cyclic thermal treatment parameters of bagasse particle reinforced epoxy bio-composites for sustainable applications

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Discover Polymers 2025年第1期2卷 1-22页

作者： Oladele, Isiaka Oluwole Falana, Samuel Olumide Ilesanmi Akinbamiyorin, Michael Onuh, Linus Nnabuike Taiwo, Anuoluwapo Samuel Adelani, Samson Oluwagbenga Olajesu, Olanrewaju Favor Department of Metallurgical and Materials Engineering Federal University of Technology Akure Nigeria Department of Materials Science and Engineering Iowa State University Ames USA Faculty of Materials and Chemical Engineering University of Miskolc Miskolc Hungary Department of School of Aerospace Transport and Manufacturing School of Aerospace Transport and Manufacturing Cranfield University Cranfield UK Materials Science and Engineering Program University of Colorado Boulder USA

The demand for sustainable, high-performance materials has led to increased interest in bio-based composites. However, optimizing the mechanical properties of such materials for engineering applications remains a challenge. This study addresses this gap by developing and characterizing an epoxy-based biocomposite reinforced with sugarcane bagasse particles, focusing on the influence of cyclic thermal treatment on its properties. The bagasse particles were chemically treated with 1 M NaOH to remove impurities, improve interfacial bonding with the epoxy matrix, and enhance the overall composite performance. The treated particles j were pulverized to 470 µm and incorporated into the epoxy matrix (0–20 wt%) using the hand layup method. The composites were divided into untreated and thermally treated groups, with the latter subjected to cyclic thermal treatment (100 °C for 3 h over 7 days). Mechanical, wear, and water absorption properties were evaluated, while fractured surface morphologies were analyzed using SEM. Results revealed that cyclic thermal treatment significantly enhanced the composites’ performance, with the 15 wt% heat-treated composite showing optimal properties: density of 1.102 g/cm3, flexural strength of 29.13 MPa, ultimate tensile strength of 103.50 MPa, impact strength of 3.49 kJ/m2, hardness of 64.70 HS, and wear indices of 0.034 mg. These findings demonstrate that alkali treatment and cyclic thermal treatment synergistically enhance the performance of bio-composites, making them suitable for diverse applications, including automotive, aerospace, and other engineering fields.

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An Anti-Plasma Etching Film of Y2O3 Film 10

An Anti-Plasma Etching Film of Y2O3 Film

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10th International Conference on Applied System Innovation, ICASI 2024

作者： Wei, Chia-Chih Chen, Hsuan-Jung Lee, Yi-Mu Chang, Shao-Fu Chen, Chien-Chon College of Engineering and Science Ph.D. Program in Materials and Chemical Engineering National United University Miaoli Taiwan Michigan State University Department of Chemistry MI48824 United States National United University Department of Electronic Miaoli Taiwan National United University Department of Energy Engineering Miaoli Taiwan

ISBN: (纸本)9798350394924

In this paper, we have presented our experiment results including (a) use a slowly thermal spray process deposition an yttrium oxide (Y2O3) film with thickness of $200\ \mu\mathrm{m}$ on the aluminum alloy (AA6061). The image analysis showed that the porosity of Y2O3 film can be reduced to less than 2%. The further aerosol deposition can be used filling the pores and can reduce the porosity of the film to less than 0.5%. This low-porosity Y2O3 film will be able to meet the increasingly stringent requirements for surface coating protection of semiconductor vacuum chamber. (b) Compared the corrosion characterization in 3.5 wt. % NaCl solution between naked AA6061 and AA6061 with Y2O3 coating, a high corrosion reactivity ($\mathrm{I}_{\text{corr}}=10^{-3.3}\mathrm{A}/\text{cm}^{2}$) of naked AA6061 then AA6061 with Y2O3 coating ($\mathrm{I}_{\text{corr}}=10^{-5.8}\mathrm{A}/\text{cm}^{2}$). The corrosion reactivity of AA6061 with Y2O3 is reduced by 316 times to a naked AA6061. © 2024 IEEE.

关键词： Porosity

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Ultrastable supported oxygen evolution electrocatalyst formed by ripening-induced embedding

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science (New York, N.Y.) 2025年第6735期387卷 791-796页

作者： Shi, Wenjuan Shen, Tonghao Xing, Chengkun Sun, Kai Yan, Qisheng Niu, Wenzhe Yang, Xiao Li, Jingjing Wei, Chenyang Wang, Ruijie Fu, Shuqing Yang, Yong Xue, Liangyao Chen, Junfeng Cui, Shiwen Hu, Xiaoyue Xie, Ke Xu, Xin Duan, Sai Xu, Yifei Zhang, Bo State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular Science Fudan University Shanghai China Collaborative Innovation Center of Chemistry for Energy Materials Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials MOE Key Laboratory of Computational Physical Sciences Department of Chemistry Fudan University Shanghai China Department of Chemistry and Department of Electrical and Computer Engineering Northwestern University Evanston IL United States Hefei National Laboratory Hefei China

The future deployment of terawatt-scale proton exchange membrane water electrolyzer (PEMWE) technology necessitates development of an efficient oxygen evolution catalyst with low cost and long lifetime. Currently, the stability of the most active iridium (Ir) catalysts is impaired by dissolution, redeposition, detachment, and agglomeration of Ir species. Here we present a ripening-induced embedding strategy that securely embeds the Ir catalyst in a cerium oxide support. Cryogenic electron tomography and all-atom kinetic Monte Carlo simulations reveal that synchronizing the growth rate of the support with the nucleation rate of Ir, regulated by sonication, is pivotal for successful synthesis. A PEMWE using this catalyst achieves a cell voltage of 1.72 volts at a current density of 3 amperes per square centimeter with an Ir loading of just 0.3 milligrams per square centimeter and a voltage degradation rate of 1.33 microvolts per hour, as demonstrated by a 6000-hour accelerated aging test.

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Electrochemical synthesis,structure characterization and magnetic properties of Tb_(x)Fe_(7)Co_(3)(x=0,0.6,0.8) nanowires

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Journal of Rare Earths 2021年第5期39卷 565-571页

作者： Licong Kang Chunxiang Cui Yuanyuan Zhang Wei Yang Qiong Li Sen Cui Key Lab.for New Type of Functional Material in Hebei Province School of Materials Science and EngineeringHebei University of TechnologyTianjin 300130China Department of Macromolecular Science and Engineering Case Western Reserve UniversityClevelandOH44106United States

Highly ordered Tb_(x)Fe_(7)Co_(3)(x=0,0.6,0.8)nanowires were synthesized in alumina templates by electrochemical deposition ***,the effects of Tb content and annealing treatment on the phase composition,morphology,crystalline structure and magnetic properties were *** asdeposited Tb_0 Fe_(7)Co_(3)nanowires comprise Fe_(7)Co_(3)*** after adding Tb,the diffraction peaks slightly shift left,indicating the infiltration of Tb atoms into Fe_(7)Co_(3)*** annealing,Tb_0 Fe_(7)Co_(3)nanowires still consist of Fe_(7)Co_(3)phase with a slight enhancement on *** the annealed nanowires with Tb doped present a complex phase composition containing Fe3 Tb,Fe_(2)Tb,Co_(3)Tb,Co_(17)Tb_(2),TbFeO_(3)and Fe_(2)O_(3)phases distribute in the central portion,and Co_(0.72)Fe_(0.28)at the nanowire outer *** annealed Tb_(x)Fe_(7)Co_(3)(x=0.6,0.8)nanowires show higher magnetic performance owing to the formation of hard magnetic phases,the interfacial elastic coupling between hard and soft phases and the coherent Fe3 Tb/Co_(3)Tb interface which restrain the domain wall *** be specific,the coercivity and remanence ratio of TbxFe_(7)Co_(3)(x=0.6,0.8)nanowires significantly enhance with increasing Tb content.

关键词： Tb-Fe-Co nanowires Electrodeposition Crystal structure Magnetic properties Coercivity mechanism Rare earths

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Oxygen and sulfur-based pure n-electron dendrimeric systems:generation-dependent clusteroluminescence towards multicolor cell imaging and molecular ruler

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science China Chemistry 2021年第11期64卷 1990-1998页

作者： Zhijun Zhang Haoke Zhang Miaomiao Kang Na Li Dong Wang Ben Zhong Tang Center for AIE Research Shenzhen Key Laboratory of Polymer Science and TechnologyGuangdong Research Center for Interfacial Engineering of Functional MaterialsCollege of Material Science and EngineeringShenzhen UniversityShenzhen518060China Key Laboratory of Macromolecular Synthesis and Functionalization(Ministry of Education) Department of Polymer Science and EngineeringZhejiang UniversityHangzhou310027China Shenzhen Institute of Molecular Aggregate Science and Engineering School of Science and EngineeringThe Chinese University of Hong KongShenzhen518172China

Dendrimers,as the latest generation of artificial macromolecules,have aroused great attention in the field of clusteroluminescence owing to their unique structural and photophysical ***,previously reported dendrimers with clusteroluminescenence property usually containπelectrons-involved carbonyl groups and/or environment-sensitive aliphatic amine moieties in their structures,thus complicating the interpretation of the emission *** the other hand,a systematic investigation on the luminescence performance of dendrimers with diverse generations is significantly important for the researchers to gain further mechanistic insights into the clusteroluminescence,but has still been scarcely *** this contribution,we reported a series of oxygen and sulfur-based pure n-electron dendrimers with different generations from G1 to *** from the highly-branched three-dimensional crowded molecular structures,all these dendrimers exhibited bright fluorescence emission in visible light region due to their prominent clusteroluminescence ***,the fluorescence intensity and emission wavelength were simultaneously boosted as their generation increased due to the more crowded molecular architectures,as well as the formation of tighter and larger clusters at higher ***,these dendrimers also showed concentration-and aggregation-enhanced luminescence behaviors,presenting typical aggregation-induced emission(AIE)*** with remarkable water solubility and biocompatibility as well as the excellent photostability,the G3 dendrimer selected as a representative was successfully applied in the multicolor cell *** addition,the G3 dendrimer was also proved to be capable of acting as a molecular ruler to detect specific-sized molecule in aqueous *** work not only validated the rationality of the clusteroluminescence mechanism but also offered high-performance clusteroluminogens for practical application.

关键词： clusteroluminescence aggregation-induced emission dendrimer cell imaging molecular ruler

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Bubble-pen lithography:Fundamentals and applications

Aggregate

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Aggregate 2022年第4期3卷 85-100页

作者： Pavana Siddhartha Kollipara Ritvik Mahendra Jingang Li Yuebing Zheng Walker Department of Mechanical Engineering The University of Texas at AustinAustinTexasUSA Department of Electrical and Computer Engineering The University of Texas at AustinAustinTexasUSA Material Science and Engineering Program Texas Materials InstituteThe University of Texas at AustinAustinTexasUSA

Developing on-chip functional devices requires reliable fabrication methods with high resolution for miniaturization,desired components for enhanced performance,and high throughput for fast prototyping and mass ***,laser-based bubble-pen lithography(BPL)has been developed to enable sub-micron linewidths,in situ synthesis of custom materials,and on-demand patterning for various functional components and *** exploits Marangoni convection induced by a laser-controlled microbubble to attract,accumulate,and immobilize particles,ions,and molecules onto different *** years have witnessed tremendous progress in theory,engineering,and application of BPL,which motivated us to write this ***,an overview of experimental demonstrations and theoretical understandings of BPL is ***,we discuss the advantages of BPL and its diverse applications in quantum dot displays,biological and chemical sensing,clinical diagnosis,nanoalloy synthesis,and *** conclude this review with our perspective on the challenges and future directions of BPL.

关键词： additive manufacturing capillary flow lithography marangoni convection microbubbles sensing

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Assessment of Simple Adhesive Substrates for Quantifying Microplastics

SSRN

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SSRN 2022年

作者： Rieland, Julie M. Hu, Zeyuan Deese, Julian S. Love, Brian J. The University of Michigan United States Department of Materials Science and Engineering Department of Biomedical Engineering Macromolecular Science and Engineering Graduate Program

Microplastics are a growing environmental concern, with a large body of evidence documenting substantial distribution of plastic material in virtually all environmental compartments. Countermeasures that help to bind, aggregate, or coalesce these distributed particles might result in lower human and animal exposures. Pressure sensitive adhesives (PSAs) have been identified as a viable microplastic (MP) capture mechanism with a range of potential use conditions. As with any countermeasure, there is a need to evaluate potential solutions in terms of collection efficiency, cost, ease of installation, etc. Expanding on our previous work, spray-coated PSAs were investigated as submerged surfaces as tools to assess MP binding in aqueous dispersions. Resins containing two differing molecular weights of poly(2-ethylhexyl acrylate) PSA (92k and 950k), and a 50:50 by weight mixture of the two resins were applied as spray-coated substrates to compare the effect of resin composition on MP-adhesive binding. Thin films of PSA (92k 6 ± 1 μm, 950k 4 ± 2 μm, 50:50 BD 6.5 ± 1 μm) were sprayed on borosilicate glass slides using a commercial air brush. Polydisperse nylon-12 particles varying in size from 15-30 µm in diameter were dispersed in deionized water at concentrations between 0.01 and 5 mg mL -1 and agitated under ambient conditions to assess adhesive binding as quantitative comparisons of microparticle capture. Mixed assays were also performed comparing binding of common MP species including polyethylene (50, 200 µm), polystyrene (10 µm), and polyester fibers (1000 µm) to understand how varying composition, size, and form factor affect adsorption. The glass slide method showed increasing linear trends of particle binding with increased adhesive exposure time and MP concentration. The lower molecular weight 92K adhesive had lower viscosity, higher wettability for microplastics but also led to a less stable adhesive film complicating analysis. As a field-deployable scheme for mi

关键词： Aggregates

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