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Assessing electronic structure modulation strategies toward the development of low‐cost oxygen evolution reaction catalysts

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Electron 2024年第4期2卷 112-121页

作者： Zhen Zhang Shaobo Han Cheng Li Chao Cai Meng Danny Gu Department of Materials Science and Engineering Southern University of Science and Technology(SUSTech)ShenzhenChina Department of Materials Science and Engineering City University of Hong KongKowloonHong KongChina Eastern Institute for Advanced Study Eastern Institute of TechnologyNingboZhejiangChina Department of Materials Science and Engineering University of CaliforniaIrvineCaliforniaUSA

Oxygen evolution reactions(OER)are critical to electrochemical syn-thesis reactions,including hydrogen production and organic ***,the high cost of existing OER catalysts(primarily Ir/Ru and its derived oxides)limits their practical application for electro-chemical *** develop a low‐cost,high‐efficiency alternative,we need a deeper understanding of both the mechanisms that drive OER and the relationship between the catalyst's electronic structure and active ***,we summarized recent developments of catalysts,especially focusing on the electronic structure modulation strategies and their subsequent activity *** importantly,we pointed out the study directions for further work.

关键词： coordination state intermediates quantifying charge density single‐atom catalysts surface defects

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Chloride-Ion Blocking in Seawater Electrolysis:Narrating the Tale of Likes and Dislikes Between Anode and Ions

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Energy & Environmental materials 2025年第1期8卷 255-272页

作者： Ashish Gaur Enkhtuvshin Enkhbayar Jatin Sharma Sungwook Mhin HyukSu Han Department of Energy Science Sungkyunkwan UniversitySuwon 16419Korea Institute of Nano Science and Technology Sector-81Knowledge CitySahibzada Ajit Singh NagarMohali 140306PunjabIndia Department of Advanced Materials Engineering Kyonggi UniversitySuwon 16227Korea

Seawater is the most abundant source of molecular *** the hydrogen reserves present in the seawater may inaugurate innovative strategies aimed at advancing sustainable energy and environmental preservation endeavors in the ***,there has been a surge in study in the field addressing the production of hydrogen through the electrochemical seawater ***,the performance and durability of the electrode have limitations due to the fact that there are a few challenges that need to be addressed in order to make the technology suitable for the industrial *** active site blockage caused by chloride ions that are prevalent in seawater and chloride corrosion is the most significant issue;it has a negative impact on both the activity and the durability of the anode *** this particular issue is of upmost importance in the seawater splitting *** review concentrates on the newly developed materials and techniques for inhibiting chloride ions by blocking the active sites,simultaneously preventing the chloride *** is anticipated that the concept will be advantageous for a large audience and will inspire researchers to study on this particular area of concern.

关键词： chloride ion blocking electrocatalysis Lewis acid oxygen evolution reaction seawater electrolysis

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Boring holes in Au nanoplates by active surface etching

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Nano Research 2024年第9期17卷 8610-8617页

作者： Haiyang Hu Yuntao Wang Qian Wang Xudong Peng An Su Hong Wang Hongyu Chen Institute of Advanced Synthesis(IAS)and School of Chemistry and Molecular Engineering Jiangsu National Synergetic Innovation Centre for Advanced MaterialsNanjing Tech UniversityNanjing 211816China Department of Environmental Science and Engineering University of Science and Technology of ChinaHefei 230026China Department of Chemistry School of Science and Key Laboratory for Quantum Materials of Zhejiang ProvinceResearch Center for Industries of the FutureWestlake UniversityHangzhou 310030China Institute of Natural Sciences Westlake Institute for Advanced StudyHangzhou 310024China

In contrast to the conventional etching that makes nanoparticles rounder and our previous sharpening etching mode that causes serrated edges,here,we developed a new boring etching mode that targets the faces of Au nanoplates to make *** critical factors are the pre-incubation step with the ligand 2-mercapto-5-benzimidazolecarboxylic acid(MBIA)and the subsequent removal of excess ligands in the ***,etching is focused onto the few sites with initial loss of ligands,which cannot be quickly *** choice of ligand MBIA is also of importance,as it carries negative charge and repels each *** inability of forming a dense layer probably plays a critical role in the site-selectivity for faces,because ligands at the higher curvature edges and corners are expected to have less *** etching results from the comproportionation reaction between Au3+and Au0 in the nanoplates,where Br-coordination to Au and the extra stabilization from cetyltrimethylammonium bromide(CTAB)are *** believe that the ability of boring holes is an important tool for future synthetic designs.

关键词： Au nanoplates active surface etching boring etching mode cetyltrimethylammonium bromide(CTAB)passivation holes

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Impact of uneven distribution of grain characteristics on yield strength and martensitic transformation of as-hot-rolled medium-entropy alloys

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Journal of materials science & technology 2024年第10期177卷 234-245页

作者： Jungwan Lee Hyojin Park Sujung Son Jae Wung Bae Jin You Kim Sung Kyu Kim Jae-il Jang Hyoung Seop Kim Department of Materials Science and Engineering Pohang University of Science and Technology(POSTECH)Pohang 37673Republic of Korea Department of Metallurgical Engineering Pukyong National UniversityBusan 48513Republic of Korea Technical Research Laboratories Energy and Shipbuilding Steel Research GroupPOSCOPohangRepublic of Korea Division of Materials Science and Engineering Hanyang UniversitySeoul 04763Republic of Korea Graduate Institute of Ferrous&Eco Materials Technology(GIFT) Pohang University of Science and Technology(POSTECH)Pohang 37673Republic of Korea Center for Heterogenic Metal Additive Manufacturing Pohang University of Science and Technology(POSTECH)Pohang 37673Republic of Korea Advanced Institute for Materials Research(WPI-AIMR) Tohoku UniversitySendai 980-8577Japan

As-hot-rolled medium-entropy alloys(MEAs)with unevenly distributed grain sizes of face-centered cubic grains exhibit better yield strength without uniform elongation loss compared to cold-rolled and an-nealed *** operation of dynamic recrystallization(DRX)during several hot rolling passes leads to a wide range of grain sizes from submicrons to tens of micrometers due to the grain growth after nucleation:early recrystallized grains are coarser than recently recrystallized *** only the grain size but internal dislocation density of the recently recrystallized grain is *** the tensile deformation of the hot-rolled MEAs at-196 ℃,dislocation pile-ups in the relatively soft and fine DRX grains enhance yield stress and hetero-deformation-induced strain *** to the enhanced yield stress of the as-hot-rolled MEAs,stress-induced martensitic transformation easily ***,partially DRXed MEAs hot-rolled at 800 ℃ have lower yield stress than fully DRXed ones,hot-rolled at 900 and 1000 ℃.This is attributed to the softening effect of the stress-induced body-centered cubic martensitic transformation in unrecrystallized coarse grains prior to the yielding,which lowers the yield stress of the partially DRXed *** yielding,the martensitic transformation facilitates strain hard-ening and early necking is *** study presents a fresh outlook on the uneven distribution of grain sizes by hot rolling beneficial to mechanical responses of uniform elongation of~45%despite the as-rolled states with an advantage of simplified thermo-mechanical processes.

关键词： Dynamic recrystallization Nucleation and growth Heterogeneity Grain size distribution Deformation-induced martensitic transformation

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Regulating the electrolyte solvation structure by weakening the solvating power of solvents for stable lithium metal batteries

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science China Chemistry 2023年第12期66卷 3620-3627页

作者： Jia-Lin Liang Shu-Yu Sun Nan Yao Zhao Zheng Qian-Kui Zhang Bo-Quan Li Xue-Qiang Zhang Jia-Qi Huang School of Materials Science and Engineering Beijing Institute of TechnologyBeijing 100081China Advanced Research Institute of Multidisciplinary Science Beijing Institute of TechnologyBeijing 100081China Department of Chemical Engineering Tsinghua UniversityBeijing 100081China

Rational electrolyte design is essential for stabilizing high-energy-density lithium(Li)metal batteries but is plagued by poor understanding on the effect of electrolyte component properties on solvation structure and interfacial ***,regulating the solvation structure in localized high-concentration electrolytes(LHCE)by weakening the solvating power of solvents is proposed for high-performance LHCE.1,3-dimethoxypropane(DMP)solvent has relatively weak solvating power but maintains the high solubility of Li salts,thus impelling the formation of nanometric aggregates where an anion coordinates to more than two Li-ions(referred to AGG-n)in *** decomposition of AGG-n increases the Li F content in solid electrolyte interphase(SEI),further enabling uniform Li *** cycle life of Li metal batteries with DMP-based LHCE is 2.1 times(386 cycles)as that of advanced ether-based LHCE under demanding ***,a Li metal pouch cell of 462Wh kg^(-1)undergoes 58 cycles with the DMP-based LHCE *** work inspires ingenious solvating power regulation to design high-performance electrolytes for practical Li metal batteries.

关键词： lithium metal anodes solvation structure 1,3-dimethoxypropane nanometric aggregates pouch cells

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Interfacial and Vacancies engineering of Copper Nickel Sulfide for Enhanced Oxygen Reduction and Alcohols Oxidation Activity

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Energy & Environmental materials 2023年第5期6卷 288-298页

作者： Zhaoyang Wang Xiaobin Liao Min Zhou Fuzhi Huang Kwadwo Asare Owusu Jiantao Li Zifeng Lin Qi Sun Xufeng Hong Congli Sun Yibing Cheng Yan Zhao Liqiang Mai State Key Laboratory of Silicate Materials for Architectures International School of Materials Science and Engineering Wuhan University of TechnologyNo.122 Luoshi RoadWuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China The Institute of Technological Sciences Wuhan UniversityWuhan 430072China Department of Materials Science and Engineering Monash UniversityClayton Victoria 3800Australia Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu hydrogen ValleyFoshan 528216China

Rational design and construction of highly efficient nonprecious electrocatalysts for oxygen reduction and alcohols oxidation reactions(ORR,AOR)are extremely vital for the development of direct oxidation alkaline fuel cells,metal-air batteries,and water electrolysis system involving hydrogen and value-added organic products generation,but they remain a great ***,a bifunctional electrocatalyst is prepared by anchoring CuS/NiS_(2)nanoparticles with abundant heterointerfaces and sulfur vacancies on graphene(Cu_(1)Ni_(2)-S/G)for ORR and *** from the synergistic effects between strong interfacial coupling and regulation of the sulfur vacancies,Cu_(1)Ni_(2)-S/G achieves dramatically enhanced ORR activity with long term ***,when ethanol is utilized as an oxidant for AOR,an ultralow potential(1.37 V)at a current density of 10 mA cm-2 is achieved,simultaneously delivering a high Faradaic efficiency of 96%for ethyl acetate ***_(1)Ni_(2)-S/G also exhibits catalytic activity for other alcohols electrooxidation process,indicating its *** work not only highlights a viable strategy for tailoring catalytic activity through the synergetic combination of interfacial and vacancies engineering,but also opens up new avenues for the construction of a self-driven biomass electrocatalysis system for the generation of value-added organic products and hydrogen under ambient conditions.

关键词： alcohols oxidation reaction heterointerface metal sulfide oxygen reduction reaction sulfur vacancies

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Rare earth lanthanum pinning effect for corrosion resistance ultraefficient microwave absorption FeCo@rGO composites

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Journal of materials science & technology 2024年第10期177卷 181-190页

作者： Junru Yao Jintang Zhou Lu Lu Feng Yang Zhengjun Yao Bo Ouyang Erjun Kan Yuxin Zuo Renchao Che Fan Wu College of Materials Science and Technology Nanjing University of Aeronautics and AstronauticsNanjing 211100China Ministry of Industry and Information Technology Key Laboratory of Material Preparation and Protection for Harsh Environment(Nanjing University of Aeronautics and Astronautics)Nanjing 211100China MIIT Key Laboratory of Semiconductor Microstructure and Quantum Sensing School of ScienceNanjing University of Science and TechnologyNanjing 210094China School of Chemistry and Chemical Engineering Anhui UniversityHefei 230601China Laboratory of Advanced Materials Shanghai Key Lab of Molecular Catalysis and Innovative MaterialsDepartment of Materials ScienceFudan UniversityShanghai 200438China School of Mechanical Engineering Nanjing University of Science and TechnologyNanjing 210094China

Magnetic metal absorbers exhibit remarkable microwave absorption ***,their practical application is severely limited due to their susceptibility to corrosion,particularly in marine *** address this challenge,we propose a novel approach involving the modification and control of FeCo/rGO microwave absorbers using rare earth lanthanum(La).This strategy aims to achieve both high-performance microwave absorption and enhanced resistance to marine *** this study,we employ a La_(2)O_(3) modifying control strategy to refine the FeCo magnetic particles and coat them with CoFe_(2)O_(4) on the surface,leveraging the pinning effect of in situ generated La_(2)O_(3) .This process enhances the interface polarization of the absorbers,thereby improving their electromagnetic performance and ma-rine corrosion ***,the La_(2)O_(3) modified FeCo@rGO composites exhibit broadband ab-sorption,covering a wide frequency range of 6.11 GHz at 1.55 ***,the electromagnetic proper-ties of the La_(2)O_(3) modified FeCo@rGO absorbers remain stable even after prolonged exposure to a 3.5 wt% NaCI solution,simulating marine conditions,for at least 15 ***,we perform first-principle calculations on FeCo and FeCo-O to validate the corrosion resistance of the La_(2)O_(3) modified FeCo@rGO composites at the atomic *** comprehensive investigation explores the control of rare earth lan-thanum modification on the size of magnetic metal particles,enabling efficient electromagnetic wave absorption and marine corrosion *** results of this study provide a novel and facile strategy for the control of microwave absorbers,offering promising prospects for future research and development in this field.

关键词： Rare earth lanthanum FeCo@rGO Microwave absorption Marine corrosion resistance

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LATP-coated LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)cathode with compatible interface with ultrathin PVDF-reinforced PEO-LLZTO electrolyte for stable solid-state lithium batteries

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Journal of Materiomics 2024年第3期10卷 682-693页

作者： Xiao Chen Yinda Li Yunhao Lu Jian Xie Cheng Huang Xiongwen Xu Jian Tu Xinbing Zhao Tiejun Zhu State Key Laboratory of Silicon and Advanced Semiconductor Materials School of Materials Science and EngineeringZhejiang UniversityHangzhou310058China Department of Physics Zhejiang UniversityHangzhou310058China LI-FUN Technology Corporation Limited Zhuzhou412000China

LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)is considered as a promising cathode for high-energy-density solid-sate Li metal battery for its high theoretical ***,the high oxidizability and structural instability during charge limit its practical *** this work,1%(in mass)of nanosized Li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3)(LATP)was coated on NCM811 to enhance its electrochemical stability with a ceramic/polymer com-posite electrolyte.A robust,ultrathin(11 mm)composite electrolyte film was prepared by combining poly(vinylidene fluoride)(PVDF)with polyethylene oxide(PEO)-Li_(6.5)La_(3)Zr_(1.5)Ta_(0.5)O_(12)(LLZTO).An in-situ polymerization process was used to enhance the interface between the PVDF/PEO-LLZTO(PPL)com-posite electrolyte and the LATP-coated NCM811(LATP-NCM811).Coin-type Li|LATP-NCM811 cell with the PPL electrolyte exhibits stable cycling with an 81%capacity retention after 100 cycles at 0.5 ***-type cell was also fabricated,which can be stably cycled for 70 cycles at 0.5 C/1.0 C(80%retention),and withstand abuse tests of bending,cutting and nail *** work provides an applicable method to fabricate solid-state Li metal batteries with high performance.

关键词： Ultrathin electrolyte film LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) Li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3)coating In-situ polymerization Li metal battery

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Breakthrough in porous liquids for carbon capture and catalysis

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National science Review 2025年第4期12卷 87-88页

作者： Weijin Li Soumya Mukherjee MIIT Key Laboratory of Advanced Display Materials and Devices Jiangsu Province Engineering Research Center of Quantum Dot Display School of Materials Science and Engineering Institute of Optoelectronics &Nanomaterials Nanjing University of Science and Technology Department of Chemical Sciences Bernal Institute and Research Ireland Centre for Pharmaceuticals (SSPC) University of Limerick

Carbon dioxide（CO2） emissions remain a pressing environmental challenge, underscoring the urgent need for innovative,energy-efficient solutions. In line with national and global commitments to climate action, advancing carbon capture and conversion technologies is missioncritical to sustainably reducing emissions and achieving a net-zero future. In this context, a recent study by Yuan-Biao Huang and co-workers has introduced a disruptive material—a prototypical covalent organic framework（COF）-based smart porous liquid（PL）, COF-301-PL,

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Space-confined vapor deposited molecular ferroelectric film for photovoltaic devices

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Nano Research 2025年第3期18卷 611-618页

作者： Chen Wang Shan Cong Lingbo Xiao Chao-ran Huang Ruonan Wang Ruijie Li Lutao Li Guifu Zou Qiang Zhang College of Mechanical and Electronic Engineering Shandong University of Science and TechnologyQingdao 266590China College of Energy Soochow Institute for Energy and Materials Innovationsand Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu ProvinceSoochow UniversitySuzhou 215000China Department of Applied Physics Zhejiang University of Science and TechnologyHangzhou 310023China School of Advanced Energy Sun Yat-sen UniversityShenzhen 518107China

Molecular ferroelectrics,characterized by outstanding photoelectric and unique ferroelectric properties,invigorate the field of ferroelectric ***,the performance of molecular ferroelectric devices is hindered by fine grains resulting from poor high-temperature *** this work,we successfully achieved micron-grained molecular ferroelectric films by using the space-confined vapor deposited *** optimized film exhibited a significant increase in grain size from the nanometer level(0.08μm)to the micrometer level(~2μm),leading to improved optoelectronic and ***,it optimizes the energy level and enhances the photovoltaic performance of vertical *** on the mechanism shows that high annealing temperature and inhibiting component loss play an important role in obtaining large grain *** work provides new research ideas for improving the quality of molecular ferroelectric films and provides valuable reference for the fabrication of high performance molecular ferroelectric photovoltaic devices.

关键词： molecular ferroelectric large grain space confinement photovoltaic devices

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