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Review Article Electrocatalysts in lithium-sulfur batteries

Nano Research 2023年第4期16卷 4438-4467页

作者： Shanying Wang Ziwei Wang Fangzheng Chen Bo Peng Jie Xu Junzhe Li Yaohui Lv Qi Kang Ailin Xia Lianbo Ma Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials&Low-Carbon New Materials Research Center&School of Materials Science and Engineering Anhui University of TechnologyMaanshan 243002China Department of Polymer Science and Engineering Shanghai Key Laboratory of Electrical Insulation and Thermal AgeingShanghai Jiao Tong UniversityShanghai 200240China Department of Mechanical and Aerospace Engineering The Hong Kong University of Science and Technology(HKUST)Clear Water BayHong KongChina

Lithium-sulfur(Li-S)batteries with the merits of high theoretical capacity and high energy density have gained significant attention as the next-generation energy storage ***,the main pressing issues of sluggish reaction kinetics and severe shuttling of polysulfides hampered their practical *** overcome these obstacles,various strategies adopting high-efficient electrocatalysts have been explored to enable the rapid polysulfide conversions and thereby suppressing the polysulfide *** review first summarizes the recent progress on electrocatalysts involved in hosts,interlayers,and protective ***,these electrocatalysts in Li-S batteries are analyzed by listing representative works,from the viewpoints of design concepts,engineering strategies,working principles,and electrochemical ***,the remaining issues/challenges and future perspectives facing electrocatalysts are given and *** review may provide new guidance for the future construction of electrocatalysts and their further utilizations in high-performance Li-S batteries.

关键词： lithium-sulfur batteries slow reaction kinetics polysulfide shuttling electrocatalysts electrochemical energy storage

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In-situ Observation of Inclusion Formation Behaviors during Solidification Process Using Model Alloy

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Tetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan 2025年第3期111卷 85-94页

作者： Kawanishi, Sakiko Tsukahara, Yuki Terashima, Shingo Nakao, Haruto Sukenaga, Sohei Shibata, Hiroyuki Department of Energy Science and Technology Graduate School of Energy Science Kyoto University Japan Department of Metallurgy Graduate School of Engineering Tohoku University Japan Institute of Multidisciplinary Research for Advanced Materials Tohoku University Japan

The formation of secondary inclusions during the solidification process of molten steel is a complex phenomenon triggered by microsegregation. Controlling the dispersion of secondary inclusions in the solidified steel is an important issue that greatly affects the properties of the steel;however, the distribution of inclusions after solidification does not always coincide with the locations of inclusion formation. Therefore, it is still difficult to estimate when, where, and at what supersaturation level inclusions crystallize in the liquid phase, and it is desirable to clarify their formation behavior to control the dispersion of inclusions. In this study, we investigated the formation process of inclusion using a ternary model material of succinonitrile-water-lumogen yellow by in-situ observation, where the formation of oversaturated lumogen yellow can be regarded as the inclusion formation. It was confirmed that the frequency of inclusion formation increased significantly when the solution was held at lower temperatures, i.e., when a large supersaturation ratio was given. The results of the formation frequency indicated that the formation of inclusions occurred in the liquid phase according to the classical nucleation theory. © 2025 The Iron and Steel Institute of Japan.

关键词： Dispersions

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Unlocking iron-based mixed-phosphate cathode for sodium-ion batteries through off-stoichiometry

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Nano Research 2024年第9期17卷 8119-8125页

作者： Zhaolu Liu Yongjie Cao Ning Wang Hui Yang Hao Zhang Xinyue Xu Nan Wang Jie Xu Yao Liu Junxi Zhang Yongyao Xia Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power Shanghai University of Electric PowerShanghai 200090China Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Fudan UniversityShanghai 200433China School of Materials Science and Engineering Anhui University of TechnologyMa’anshan 243002China Key Laboratory of Interfacial Physics and Technology Shanghai Institute of Applied PhysicsChinese Academy of SciencesShanghai 201800China

The off-stoichiometric iron-based phosphate(Na_(3.12)Fe_(2.44)(P_(2)O_(7))_(2),denoted as Na3.12)as a low cost and high structure stability cathode material has been widely studied for sodium-ion batteries(SIBs).However,the lower theoretical specific capacity(117 mAh·g^(-1))has seriously limited its practical *** this work,we incorporate varying proportion of sodium-iron phosphate(NaFePO_(4))into the Na3.12 to form a series of new high specific capacity mixed-phosphates Na_(3.12+x)Fe_(2.44+x)(P_(2)O_(7))_(2)(PO_(4))x cathode materials for *** optimizing the introduction amount of NaFePO_(4)into Na_(3.12),the practical reversible of Na_(3.12+x)Fe_(2.44+x)(P_(2)O_(7))_(2)(PO_(4))_(x) increased from 92 to 125.2 mAh·g^(-1).The nano-size Na5.12Fe4.44(P_(2)O_(7))_(2)(PO_(4))_(2) cathode material shows a reversible specific capacity of 125.2 mAh·g^(-1)at 0.1 C in *** at 60 C,it still exhibits a reversible specific capacity of 93.3 mAh·g^(-1)and keeps a capacity retention ratio of 87%after 3000 cycles at 20 ***,we present a novel approach to design a series of off-stoichiometric mixed-phosphates cathode materials for SIBs.

关键词： sodium-ion batteries cathode material iron-based mixed-phosphates off-stoichiometric

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A promoting nitric oxide-releasing coating containing copper ion on ZE21B alloy for potential vascular stent application

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Journal of Magnesium and Alloys 2023年第12期11卷 4542-4561页

作者： Qianying Jia Qinggong Jia Shijie Zhu Yufeng Zheng Yoji Mine Kazuki Takashima Shaokang Guan School of Materials Science and Engineering&Henan Key Laboratory of Advance Magnesium Alloy&Key Laboratory of Materials Processing and Mold Technology(Ministry of Education) Zhengzhou UniversityZhengzhou 450001China Department of Materials Science and Engineering Kumamoto University2-39-1 KurokamiChuo-kuKumamoto 860-8555Japan International Research Organization for Advanced Science and Technology(IROAST) Kumamoto University2-39-2 Kumamoto 860-8555Japan School of Materials Science and Engineering Peking UniversityBeijing 100871China

Magnesium-based biodegradable metals as cardiovascular stents have shown a lot of excellent performance, which have been used to treat coronary artery diseases. However, the excessive degradation rate, imperfect biocompatibility and delayed re-endothelialization still lead to a considerable challenge for its application. In this work, to overcome these shortcomings, a compound of catalyzing nitric oxide(NO) generation containing copper ions(Cu^(2+)) and hyaluronic acid(HA), an important component of the extracellular matrix, were covalently immobilized on a hydrofluoric acid(HF)-pretreated ZE21B alloy via amination layer for improving its corrosion resistance and endothelialization. Specifically,the Cu^(2+) chelated firmly with a cyclen 1,4,7,10-tetraazacyclododecane-N’, N’’, N’’’, N-tetraacetic acid(DOTA) could form a stability of hybrid coating, avoiding the explosion of Cu^(2+). The chelated Cu^(2+) enabled the catalytic generation of NO and promoted the adhesion and proliferation of endothelial cells(ECs) in vascular micro-environment. In this case, the synergistic effect of NO-generation and endothelial glycocalyx molecules of HA lead to efficient ECs promotion and smooth muscle cells(SMCs) inhibition. Meanwhile, the blood compatibility also had achieved a marked improvement. Moreover, the standard electrochemical measurements indicated that the functionalized ZE21B alloy had better anti-corrosion ability. In a conclusion, the dual-functional coating displays a great potential in the field of biodegradable magnesium-based implantable cardiovascular stents.

关键词： ZE21B alloy Functional coating Hyaluronic acid Nitric oxide Cardiovascular stent

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Promoting polysulfide conversions via cobalt single-atom catalyst for fast and durable lithium-sulfur batteries

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Nano Research 2023年第7期16卷 9335-9343页

作者： Ziwei Wang Yuwen Cheng Shanying Wang Jie Xu Bo Peng Dan Luo Lianbo Ma Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials&School of Materials Science and Engineering Anhui University of TechnologyMaanshan 243002China School of Information and Optoelectronic Science and Engineering South China Normal UniversityGuangzhou 510006China Department of Mechanical and Aerospace Engineering The Hong Kong University of Science and Technology(HKUST)Clear Water BayHong Kong 999077China

Although promising strategies have been developed to resolve the critical drawbacks of lithium-sulfur(Li-S)batteries,the intractable issues including undesirable shuttling of polysulfides and sluggish redox reaction kinetics have still been unresolved ***,a cobalt single-atom(CoSA)catalyst comprising of atomic Co distributed homogeneously within nitrogen(N)-doped porous carbon(Co-NPC)nanosphere is constructed and utilized as a separator coating in Li-S *** Co-NPC exposes abundant active sites participating in sulfur redox reactions,and remarkable catalytic activity boosting the rapid polysulfide *** a result,Li-S batteries with Co-NPC coating layer realize significantly enhanced specific capacity(1295 mAh·g^(-1)at 0.2 C),rate capability(753 mAh·g^(-1)at 3.0 C),and long-life cyclic stability(601 mAh·g^(-1)after 500 cycles at 1.0 C).Increasing the areal sulfur loading to 6.2 mg·cm^(-2),an extremely high areal capacity of 7.92 mAh·cm^(-2)is *** in situ X-ray diffraction,density functional theory calculations,and secondary ion mass spectrometry confirm the high catalytic capability of CoSA towards reversible polysulfide *** study supplies new insights for adopting single-atom catalyst to upgrade the electrochemical performance of Li-S batteries.

关键词： lithium-sulfur batteries polysulfide shuttling sluggish redox kinetics cobalt single-atom catalyst catalytic capability

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Improving toughness of medium-Mn steels after friction stir welding through grain morphology tuning

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Journal of materials science & technology 2022年第23期118卷 243-254页

作者： Mun Sik Jeong Tak Min Park Dong-Il Kim Hidetoshi Fujii Hye Ji Im Pyuck-Pa Choi Seung-Joon Lee Jeongho Han Division of Materials Science and Engineering Hanyang UniversitySeoul 04763Republic of Korea Department of Advanced Materials Engineering Korea Polytechnic UniversitySiheung 15073Republic of Korea Joining and Welding Research Institute Osaka UniversityOsaka 567-0047Japan Department of Materials Science and Engineering Korea Advanced Institute of Science and TechnologyDaejeon 34141Republic of Korea Department of Materials Science and Engineering Northwestern UniversityEvanstonIL 60208USA

This work demonstrated the viability of friction stir welding for the welding of medium-Mn steels when used as cryogenic vessel materials for liquefied gas *** used an intercritically annealed Fe-7 Mn-0.2 C-3 Al(wt.%)steel with a dual-phase(α'martensite andγ_(R) retained austenite)nanolaminate structure as a base material and systematically compared its microstructure and impact toughness after friction stir and tungsten inert gas *** friction stir welded specimen exhibited a large amount ofγ_(R) phase owing to a relatively low temperature during welding,whereas the tungsten inert gas welded specimen comprised only theα'***,the friction stir welded steel exhibited a tuned morphology of nanoscale globular microstructure at the weld zone and did not exhibit any prior austenite grain boundary due to active recrystallization caused by deformation during *** preserved fraction ofγ_(R) and morphological tuning in the weldment improved the impact toughness of the friction stir welded steel at low *** the steel processed by tungsten inert gas welding,the notch crack propagated rapidly along the prior austenite grain boundaries-weakened by Mn and P segregations-resulting in poor impact ***,the friction stir welded steel exhibited a higher resistance against notch crack propagation due to the slow crack propagation along the ultrafine ferrite/ferrite(α/α)interfaces,damage tolerance by the active transformation-induced plasticity from the large amount ofγR,and enhanced boundary cohesion by suppressed Mn and P segregations.

关键词： Charpy impact test Transformation-induced plasticity Friction stir welding Phase stability Medium-Mn steel

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Green supercapacitor patterned by synthesizing MnO/laser-induced-graphene hetero-nanostructures on wood via femtosecond laser pulses

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Biochar 2024年第1期6卷 641-654页

作者： Young-Ryeul Kim Han Ku Nam Younggeun Lee Dongwook Yang Truong-Son Dinh Le Seung-Woo Kim Sangbaek Park Young-Jin Kim Department of Mechanical Engineering Korea Advanced Institute of Science and Technology(KAIST)Science TownDaejeon 34141South Korea. Department of Materials Science and Engineering Chungnam National University(CNU)99 Daehak-roYuseong-guDaejeon 34134South Korea.

Eco-friendly next-generation energy storage devices with high energy density are required to meet the increasing demand for sustainable and green ***,their manufacturing requires a lot of chemical precursors and is usually accompanied by chemical waste;it also involves laborious and time-consuming processes such as mixing,heat treating,casting,and ***,we proposed that mass production of microsupercapacitors(MSCs)for green electronics can be achieved by embedding manganese monoxide(MnO)on wood-derived laser-induced-graphene(LIG)via femtosecond laser direct writing(FsLDW)*** direct synthesis of MnO/LIG hetero-nanostructures on wood was realized by drop-casting a small amount of precursor between the first and second *** preceding FsLDW thermochemically converted wood into LIG while the following FsLDW converted the precursor into MnO,resulting in MnO/LIG ***-fabricated MnO/LIG MSC exhibited enhanced areal capacitance(35.54 mF cm^(−2)at 10 mV s^(−1))and capacitance retention(approximately 82.31%after 10,000 cycles)with only a small inclusion of Mn sources(0.66 mg cm^(−2))and short production time(10 min cm^(−2)),which attributes to operate light-emitting diodes,digital clocks,and electronic paper as *** approach enables the green,facile,fast,and cost-effective fabrication of future sustainable energy storage devices from biomass for next-generation green electronics.

关键词： Laser-induced graphene Green energy storage Microsupercapacitors Laser direct writing Ultrafast pulse Biomass

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Synthesis and characterization of iron clusters with an icosahedral [Fe@Fe12]16+ Core

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National science Review 2024年第4期11卷 123-129页

作者： Gan Xu Yun-Shu Cui Xue-Lian Jiang Cong-Qiao Xu Jun Li Xu-Dong Chen Jiangsu Collaborative Innovation Center of Biomedical Functional Materials and Jiangsu Key Laboratory of New Power Batteries School of Chemistry and Materials Science Nanjing Normal University Department of Chemistry and Guangdong Provincial Key Laboratory of Catalytic Chemistry Southern University of Science and Technology Department of Chemistry and Engineering Research Center of Advanced Rare-Earth Materials of Ministry of Education Tsinghua University State Key Laboratory of Coordination Chemistry Nanjing University

Iron-metal clusters are crucial in a variety of critical biological and material systems,including metalloenzymes,catalysts,and magnetic storage ***,a synthetic high-nuclear iron cluster has been absent due to the extreme difficulty in stabilizing species with direct iron-iron *** this work,we have synthesized,crystallized,and characterized a（Tp*）4W4S12(Fe@Fe12) cluster(Tp*=tris（3,5-dimethyl-1-pyrazolyl）borate（1-）),which features a rare trideca-nuclear,icosahedral[Fe@Fe12] cluster core with direct multicenter iron-iron bonding between the interstitial iron（Fei） and peripheral irons（Fep）,as well as Fep…Fepferromagnetic *** chemistry studies reveal that the stability of the cluster arises from the 18-electron shell-closing of the [Fe@Fe12]16+core,assisted by its bonding interactions with the peripheral tridentate [（Tp*）WS3]4-ligands which possess both S→Fe donation and spin-polarized Fe-Wσ *** ground-state electron spin is theoretically predicted to be S=32/2 for the *** existence of low oxidation-state（OS～+1.23） iron in this compound may find interesting applications in magnetic storage,spintronics,redox chemistry,and cluster catalysis.

关键词： Fe13 cluster iron-sulfur cluster low-valence iron iron−iron bond high spin complex

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Optimizing hydrogen ad/desorption of Mg-based hydrides for energy-storage applications

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Journal of materials science & technology 2023年第10期141卷 221-235页

作者： Zeng-Yi Li Yu-Jia Sun Chen-Chen Zhang Sheng Wei Li Zhao Ju-Lan Zeng Zhong Cao Yong-Jin Zou Hai-Liang Chu Fen Xu Li-Xian Sun Hong-Ge Pan Guangxi Key Laboratory of Information Materials and Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials School of Material Science&EngineeringGuilin University of Electronic TechnologyGuilin 541004China Department of Radiology Stanford UniversityStanfordCA 94305USA School of Chemistry and Chemical Engineering Guangxi UniversityNanning 530004China Beijing Advanced Innovation Center for Materials Genome Engineering Institute for Advanced Materials and TechnologyUniversity of Science and Technology BeijingBeijing 100083China School of Chemistry and Chemical Engineering Changsha University Of Science&TechnologyChangsha 410114China Institute of Science and Technology for New Energy Xi’an Technological UniversityXi’an 710021China

Hydrogen energy is expected to be an“ideal fuel”in the era of *** discovery,de-velopment,and modification of high-performance hydrogen storage materials are the keys to the fu-ture development of solid-state hydrogen storage and hydrogen energy *** hydride(MgH_(2)),with its high hydrogen storage capacity,abundant natural reserves,and environmental friend-liness,has been extensively ***,we briefly summarize the typical structure and hy-drogenation/dehydrogenation reaction mechanism of MgH_(2)and provide a comprehensive overview of strategies to effectively tune the thermodynamics and kinetics of Mg-based materials,such as alloy-ing,nanosizing,the introduction of additives,and composite *** substantial efforts,great achievements have been achieved,such as lower absorption/desorption temperatures and better cy-cling ***,some pivotal issues remain to be addressed,such as unfavorable hydro-genation/dehydrogenation factors,harsh conditions,slow kinetics,incomplete dehydrogenation,low hy-drogen purity,expensive catalysts,and a lack of valid exploration of mechanisms in the hydrogena-tion/dehydrogenation ***,some future development prospects of MgH_(2)in energy-efficient conversion and storage have been presented,including advanced manufacturing ways,stabilization of nanostructures,the introduction of additives combined with structural modification,and utilization of advanced characterization techniques.

关键词： Mg-based hydrides Hydrogen storage A lloying Catalysts Mechanism

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Understanding the creep behaviors and mechanisms of Mg-Gd-Zn alloys via machine learning

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Journal of Magnesium and Alloys 2024年第8期12卷 3281-3291页

作者： Shuxia Ouyang Xiaobing Hu Qingfeng Wu Jeong Ah Lee Jae Heung Lee Chenjin Zhang Chunhui Wang Hyoung Seop Kim Guangyu Yang Wanqi Jie Graduate Institute of Ferrous and Eco Materials Technology(GIFT) Pohang University of Science and Technology(POSTECH)Pohang 37673Republic of Korea State Key Laboratory of Solidification Processing Northwestern Polytechnical UniversityXi’an 710072China Xi’an Rare Metal Materials lnstitute Co.Ltd Xi’an 710016China Department of Materials Science and Engineering Pohang University of Science and Technology(POSTECH)Pohang 37673Republic of Korea DepartmentAdvanced Institute for Materials Research(WPI-AIMR) Tohoku UniversitySendai 980-8577Japan Institute for Convergence Research and Education in Advanced Technology Yonsei UniversitySeoul 03722South Korea

Mg-Gd-Zn based alloys have better creep resistance than other Mg alloys and attract more attention at elevated ***,the multiple alloying elements and various heat treatment conditions,combined with complex microstructural evolution during creep tests,bring great challenges in understanding and predicting creep *** this study,we proposed to predict the creep properties and reveal the creep mechanisms of Mg-Gd-Zn based alloys by machine *** the one hand,the minimum creep rates were effectively predicted by using a support vector regression *** complex and nonmonotonic effects of test temperature,test stress,alloying elements,and heat treatment conditions on the creep properties were *** the other hand,the creep stress exponents and creep activation energies were calculated by machine learning to analyze the variation of creep mechanisms,based on which the constitutive equations of Mg-Gd-Zn based alloys were *** study introduces an efficient method to comprehend creep behaviors through machine learning,offering valuable insights for the future design and selection of Mg alloys.

关键词： Mg-Gd-Zn based alloys Machine learning Creep rate Creep mechanism Constitutive equation

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