检索结果-内蒙古大学图书馆

Effect of solid-solution strengthening on deformation mechanisms and strain hardening in medium-entropy V_(1-x)Cr_(x)CoNi alloys

引用

Journal of materials science & technology 2022年第13期108卷 270-280页

作者： Hyun Chung Dae Woong Kim Woo Jin Cho Heung Nam Han Yuji Ikeda Shoji Ishibashi Fritz Körmann Seok Su Sohn Department of Materials Science and Engineering Korea UniversitySeoul 02841South Korea Center for High Entropy Alloys Pohang University of Science and TechnologyPohang 37673South Korea Department of Materials Science and Engineering and Research Institute of Advanced Materials Seoul National UniversitySeoul 08826South Korea Institute for Materials Science University of StuttgartPfaffenwaldring 55Stuttgart 70569Germany Computational Materials Design Max-Planck-Institut für Eisenforschung GmbHMax-Planck-Strabe 1Düsseldorf 40237Germany Research Center for Computational Design of Advanced Functional Materials(CD-Fmat) National Institute of Advanced Industrial Science and Technology(AIST)TsukubaIbaraki 305-8568Japan Department of Materials Science and Engineering Delft University of TechnologyMekelweg2Delft 2628 CDthe Netherlands

High-and medium-entropy alloys(HEAs and MEAs)possess high solid-solution *** investigations have been conducted on its impact on yield strength,however,there are limited reports regarding the relation between solid-solution strengthening and strain-hardening *** addition,no attempt has been made to account for the dislocation-mediated plasticity;most works focused on twinning-or transformation-induced plasticity(TWIP or TRIP).In this work we reveal the role of solidsolution strengthening on the strain-hardening rate via systematically investigating evolutions of deformation structures by controlling the Cr/V ratio in prototypical V_(1-x)Cr_(x)CoNi *** the TWIP of CrCoNi with the dislocation slip of V_(0.4)Cr_(0.6)CoNi,the hardening rate of CrCoNi was superior to slip-band refinements of V_(0.4)Cr_(0.6)CoNi due to the dynamic Hall-Petch ***,as V content increased further to V_(0.7)Cr_(0.3)CoNi and VCoNi,their rate of slip-band refinement in V_(0.7)Cr_(0.3)CoNi and VCoNi with high solid-solution strength surpassed that of *** it is generally accepted in conventional alloys that deformation twinning results in a higher strain-hardening rate than dislocation-mediated plasticity,we observed that the latter can be predominant in the former under an activated huge solid-solution strengthening *** high solid-solution strength lowered the cross-slip activation and consequently retarded the dislocation rearrangement rate,i.e.,the dynamic *** delay in the hardening rate decrease,therefore,increased the strain-hardening rate,results in an overall higher strain-hardening rate of V-rich alloys.

关键词： Medium-entropy alloy Tensile property Solid-solution strength Strain-hardening rate Stacking fault energy

来源：评论

学校读者我要写书评

暂无评论

Anionic entanglement-induced giant thermopower in ionic thermoelectric material Gelatin-CF_(3)SO_(3)K–CH_(3)SO_(3)K

引用

escience 2023年第5期3卷 105-112页

作者： Qikai Li Cheng-Gong Han Shuaihua Wang Cai-Chao Ye Xinbo Zhang Xiao Ma Tao Feng Yuchen Li Weishu Liu Department of Materials Science and Engineering Southern University of Science and TechnologyShenzhenGuangdong 518055China Shenzhen Engineering Research Center for Novel Electronic Information Materials and Devices Southern University of Science and TechnologyShenzhen 518055China Department of Mechanical Engineering The University of Hong KongPokfulam Road 999077Hong KongChina Center for Advanced Analytical Science Guangzhou Key Laboratory of Sensing Materials and DevicesGuangdong Engineering Technology Research Center for Photoelectric Sensing Materials and DevicesSchool of Chemistry and Chemical EngineeringGuangzhou UniversityGuangzhou 510006China

Ionic thermoelectric(i-TE)technologies can power Internet of Things(IoT)sensors by harvesting thermal energy from the environment because of their large *** research focuses mostly on using the interactions between ions and matrices to enhance i-TE performance,but i-TE materials can benefit from utilizing different methods to control ion ***,we introduced a new strategy that employs an ion entanglement effect.A giant thermopower of 28 mV K^(-1)was obtained in a quasi-solid-state i-TE Gelatin-CF_(3)SO_(3)K–CH_(3)SO_(3)K gel via entanglement between CF_(3)SO_(3)^(-)and CH_(3)SO_(3)^(-)*** anionic entanglement effect involves complex interactions between these two anions,slowing anionic thermodiffusion and thus suppressing bipolar effects and boosting p-type thermopower.A Au@Cu|Gelatin-CF_(3)SO_(3)K–CH_(3)SO_(3)K|Au@Cu i-TE device with a generator mode delivers a specific output energy density of 67.2 mJ m^(-2)K^(-2)during 2 h of ***-term operation.

关键词： Thermopower Thermodiffusion Ion interactions Energy harvesting Gelatin

来源：评论

学校读者我要写书评

暂无评论

Quasi-Solid-State Na-O2 Battery with Composite Polymer Electrolyte

引用

ACS Applied materials and Interfaces 2024年第28期16卷 36289-36294页

作者： Iputera, Kevin Tsai, Cheng-Fu Huang, Jheng-Yi Wei, Da-Hua Liu, Ru-Shi Department of Chemistry National Taiwan University Taipei106 Taiwan Department of Mechanical Engineering and Institute of Manufacturing Technology National Taipei University of Technology Taipei106 Taiwan Advanced Research Center For Green Materials Science and Technology Taipei106 Taiwan

Na-O2 batteries have emerged as promising candidates due to their high theoretical energy density (1,601 Wh kg-1), the potential for high energy storage efficiency, and the abundance of sodium in the earth’s crust. Considering the safety issue, quasi-solid-state composite polymer electrolytes are among the promising solid-state electrolyte candidates. Their higher mechanical toughness provides superior resistance to dendritic penetration compared with traditional liquid electrolytes. The flexibility of the composite polymer electrolyte matrix allows it to conform to various battery configurations and considerably reduces safety concerns related to the combustion risks associated with conventional liquid electrolytes. In this study, we employed poly(ethylene oxide) (PEO) and sodium bis(trifluoromethanesulfonyl)imide (NaTFSI) as the polymer matrix and sodium ion-conducting agent, respectively. We incorporated nanosized NZSP (25 wt %) to create the composite polymer electrolyte membrane. This CPE design facilitates ion conduction pathways through both sodium salt and NZSP. By utilizing a liquid electrolyte infiltration method, we successfully enhanced its ionic conductivity, achieving an ionic conductivity of 10-4 S cm-1 at room temperature. © 2024 The Authors. Published by American Chemical Society.

关键词： Sodium

来源：评论

学校读者我要写书评

暂无评论

Interface engineering and Anion engineering of Mo-Based Heterogeneous Electrocatalysts for Hydrogen Evolution Reaction

引用

Energy & Environmental materials 2023年第1期6卷 87-104页

作者： Zehao Yin Xuan Liu Siru Chen Tingli Ma Yanqiang Li State Key Laboratory of Fine Chemicals School of Chemical EngineeringDalian University of TechnologyPanjin CampusPanjin 124221China School of Material and Chemical Engineering Centre for Advanced Materials ResearchZhongyuan University of TechnologyZhengzhou 450007China Department of Materials Science and Engineering China Jiliang UniversityHangzhou 310018China Graduate School of Life Science and Systems Engineering Kyushu Institute of TechnologyKitakyushu Fukuoka 808-0196Japan

Development and utilization of hydrogen energy is an effective way to achieve carbon neutrality,only hydrogen production through electrolytic water splitting meets the goal of zero carbon *** facilitate the large-scale commercialization of water splitting devices,the development of highly efficient and low-cost catalysts to reduce the energy consumption is ***_(2)has been regarded as a promising electrocatalyst to replace platinum in hydrogen evolution reaction due to its low price and unique 2D layered ***,the poor conductivity and inert basal planes of MoS_(2)limited its wide-spread ***,researches have demonstrated that the conductivity and active sites of MoS_(2)can be improved by heteroatoms doping or constructing of heterogeneous *** this review,the recent progress of Mo-based catalysts are summarized centered on MoS_(2)based on interface engineering and anion engineering,including MoS_(2)–MoO_(2),MoS_(2)–Mo_(2)C,MoS_(2)–MoN_(x),MoS_(2)–MoP,and MoS_(2)–MoSe_(2).The preparation method,structure,and performance of the catalysts are introduced and the possible mechanism behind the improved catalytic activity are revealed to give readers an overall comprehension on the progress of the Mo-based electrocatalysts for hydrogen evolution *** addition,an outlook on future opportunities and development directions of Mo-based catalysts are proposed to facilitate the development of Mo-based catalysts for hydrogen production.

关键词： electrocatalysis heterostructure hydrogen evolution reaction Mo-based catalysts

来源：评论

学校读者我要写书评

暂无评论

Microstructure and Mechanical Properties of Ti–Ta Composites Prepared Through Cold Spray Additive Manufacturing

引用

Acta Metallurgica Sinica(English Letters) 2022年第9期35卷 1465-1476页

作者： Junrong Tang Naeem ul Haq Tariq Zhipo Zhao Mingxiao Guo Hanhui Liu Yupeng Ren Xinyu Cui Yanfang Shen Jiqiang Wang Tianying Xiong Shi-changxu Innovation Center for Advanced Materials Institute of Metal ResearchChinese Academy of SciencesShenyang110016China School of Materials Science and Engineering University of Science and Technology of ChinaShenyang110016China Department of Metallurgy and Materials Engineering Pakistan Institute of Engineering and Applied SciencesNiloreIslamabadPakistan

In this study, an innovative approach was used to fabricate Ti–Ta composite biomaterials through cold spray additive manufacturing followed by a diff usion treatment. The microstructure and mechanical properties of the composites were investigated in detail using field emission scanning electron microscopy, electron backscatter diff raction, 3D X-ray computed tomography, tensile test, nanohardness test and resonance vibration test. The obtained results indicated that the prepared composites have inhomogeneity in their microstructure and composition. A unique microstructure, composed of Ti-rich, Ta-rich and diff usion regions, was evolved in the composites due to incomplete diff usion between Ti and Ta splats. Further, Kirkendall pores were formed in the composites due to uneven diff usion of the two phases(of Ti and Ta) during high-temperature heat treatment. The prepared composites simultaneously showed low elastic modulus and high tensile strength which is required for a good biomaterial. Low elastic modulus was associated with the residual pores and the alloying eff ect of Ta in Ti, while high tensile strength was related to the solid solution strengthening eff ects. The obtained results indicated that the prepared Ti–Ta composites have a great potential to become a new candidate for biomedical applications.

关键词： Ti–Ta composites Cold spray additive manufacturing(CSAM) Biomaterials Mechanical properties X-ray computed tomography(XCT)

来源：评论

学校读者我要写书评

暂无评论

Composing atomic transition metal sites for high-performance bifunctional oxygen electrocatalysis in rechargeable zinc-air batteries

引用

Particuology 2023年第6期77卷 146-152页

作者： Juan Wang Chang-Xin Zhao Jia-Ning Liu Ding Ren Xinzhi Ma Bo-Quan Li Jia-Qi Huang Qiang Zhan School of Materials Science and Engineering Beijing Institute of TechnologyBeijing100081China Advanced Research Institute of Multidisciplinary Science Beijing Institute of TechnologyBeijing100081China Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology Department of Chemical EngineeringTsinghua UniversityBeijing100084China Key Laboratory for Photonic and Electronic Bandgap Materials Ministry of EducationSchool of Physics and Electronic EngineeringHarbin Normal UniversityHarbin150025China

Rechargeable zinc-air batteries have attracted extensive attention as clean,safe,and high-efficient en-ergy storage ***,the oxygen redox reactions at cathode are highly sluggish in kinetics and severely limit the actual battery *** transition metal sites demonstrate high electro-catalytic activity towards respective oxygen reduction and evolution,while high bifunctional electro-catalytic activity is seldomly *** a strategy of composing atomic transition metal sites is proposed to fabricate high active bifunctional oxygen electrocatalysts and high-performance recharge-able zinc-air ***,atomic Fe and Ni sites are composed based on their respective high electrocatalytic activity on oxygen reduction and *** composite electrocatalyst demonstrates high bifunctional electrocatalytic activity(ΔE=0.72 V)and exceeds noble-metal-based Pt/C+Ir/C(ΔE=0.79 V).Accordingly,rechargeable zinc-air batteries with the composite electrocatalyst realize over 100 stable cycles at 25 mA *** work affords an effective strategy to fabricate bifunctional oxygen electrocatalysts for high-performance rechargeable zinc-air batteries.

关键词： Rechargeable zinc-air batteries Bifunctional oxygen electrocatalysis Noble-metal-free electrocatalysts Oxygen reduction reaction Oxygen evolution reaction

来源：评论

学校读者我要写书评

暂无评论

Ultra-flexible graphene/nylon/PDMS coaxial fiber-shaped multifunctional sensor

引用

Nano Research 2023年第4期16卷 5541-5547页

作者： Peddathimula Puneetha Siva Pratap Reddy Mallem Sung Cheol Park Seoha Kim Dong Hun Heo Cheol Min Kim Jaesool Shim Sung Jin An Dong-Yeon Lee Kwi-Il Park Department of Robotics and Intelligent Machine Engineering/College of Mechanical and IT Engineering Yeungnam UniversityGyeongsan 38541Republic of Korea School of Materials Science and Engineering Kyungpook National UniversityDaegu 41566Republic of Korea Advanced Material Research Center Kumoh National Institute of TechnologyGumi 39177Republic of Korea School of Mechanical Engineering Yeungnam UniversityGyeongsan 38541Republic of Korea Department of Materials Science and Engineering Kumoh National Institute of TechnologyGumi 39177Republic of Korea

The development of flexible and wearable devices is mainly required for tactile sensing;as such devices can adapt to complicated nonuniform surfaces,they can be applied to the human ***,it remains necessary to simultaneously achieve small-scale,portable,and stable developments in such ***,this work aims at fabricating a novel,lightweight,ultra-flexible,and fiber-shaped coaxial structure with a diameter of 0.51 mm using polydimethylsiloxane/graphene/nylon material,based on piezoresistive and triboelectric *** piezoresistive-based robotic-hand-controlled sensor thus realized exhibits a response time of 120 ms and a fast recovery time of 55 ***,the piezoresistive-based sensors effectively feature whisker/joystick-guided behaviors and also sense the human finger *** to the triboelectric-based selfpowered nanogenerator behavior,the resulting sensor can convert mechanical motion into electrical energy,without adversely affecting human ***,this triboelectric-based human finger sensor can be operated under different bending modes at specific ***,this multifunctional sensor is cost-effective and suitable for various applications,including robotichand-controlled operations in medical surgery,whisker/joystick motions in lightweight drone technology,and navigation with highsensitivity components.

关键词： extremely lightweight ultra-flexible piezoresistive/triboelectric sensor human-machine whisker

来源：评论

学校读者我要写书评

暂无评论

Shining light on transition metal tungstate-based nanomaterials for electrochemical applications:Structures,progress,and perspectives

引用

Nano Research 2022年第8期15卷 6924-6960页

作者： Kaijia Feng Zhefei Sun Yong Liu Feng Tao Junqing Ma Han Qian Renhong Yu Kunming Pan Guangxin Wang Shizhong Wei Qiaobao Zhang National Joint Engineering Research Center for Abrasion Control and Molding of Metal Materials Henan Key Laboratory of Non–Ferrous Materials Science&Processing TechnologySchool of Materials Science and EngineeringHenan University of Science and TechnologyLuoyang 471023China Provincial and Ministerial Co–construction of Collaborative Innovation Center for Non-ferrous Metal New Materials and Advanced Processing Technology Henan Key Laboratory of High-temperature Structural and Functional MaterialsHenan University of Science and TechnologyLuoyang 471023China Department of Materials Science and Engineering College of MaterialsXiamen UniversityXiamen 361005China Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials Xiamen UniversityXiamen 361005China

Transition metal tungstate-based nanomaterials have become one of the research hotspots in electrochemistry due to their abundant natural resources,low costs,and environmental *** studies have demonstrated their significant potentials for electrochemical applications,such as supercapacitors,Li-ion batteries,Na-ion batteries,electrochemical sensing,and *** the rapidly growing research enthusiasm for this topic over the last several years,herein,a critical review of recent progress on the application of transition metal tungstates and their composites for electrochemical applications is *** relationships between synthetic methods,nano/micro structures and electrochemical properties are systematically ***,their promising prospects for future development are also *** is anticipated that this review will inspire ongoing interest in rational designing and fabricating novel transition metal tungstate-based nanomaterials for high-performance electrochemical devices.

关键词： transition metal tungstates supercapacitors lithium-ion batteries sodium-ion batteries electrochemical sensing electrocatalysis

来源：评论

学校读者我要写书评

暂无评论

Stretchable photosynaptic transistor with an ultralow energy consumption conferred using conjugated block copolymers/perovskite quantum dots nanocomposites

引用

materials Today 2023年 70卷 57-70页

作者： Chen, Wei-Cheng Lin, Yan-Cheng Hung, Chih-Chien Hsu, Li-Che Wu, Ya-Shuan Liu, Cheng-Liang Kuo, Chi-Ching Chen, Wen-Chang Department of Chemical Engineering and Advanced Research Center for Green Materials Science and Technology National Taiwan University Taipei10617 Taiwan Department of Molecular Science and Engineering Institute of Organic and Polymeric Materials National Taipei University of Technology Taipei10608 Taiwan Department of Chemical Engineering National Cheng Kung University Tainan70101 Taiwan Department of Materials Science and Engineering National Taiwan University Taipei10617 Taiwan

Emulation of photonic synapses offers a promising avenue for developing low-energy consumption of soft electronics, neurologically inspired robotics, and neuromorphic network computation. In this paper, a fully stretchable photosynaptic device with ultralow energy consumption using intrinsically stretchable poly(δ-decanolactone) (PDL)-based conjugated block copolymers (BCPs) with perovskite quantum dots (PeQDs) is first reported. The findings reveal that selectively choosing solvents for the PDL-based BCPs effectively regulates the assembly of P3HT and the accommodation of PeQDs, leading to improved self-aggregation of PeQDs, increased grain size, and optimized interfaces between P3HT and PeQDs The BCPs/PeQDs composite effectively emulates significant features of photonic synapses, such as paired-pulse facilitation (PPF), spike-dependent and short/long-term neuroplasticity, demonstrating excellent performance, including the fastest response time (1 ms), the highest current contrast (4.9 × 105), PPF (1.93) and ultra-low energy consumption (0.3 aJ) at an operating voltage of –0.1 mV. Furthermore, the BCP/PeQDs exhibit remarkable neuromuscular synapse characteristics, including high strain and bending tolerance and spike-dependent plasticity, enabling the devices to achieve high classification accuracy in artificial neural network simulations during tensile strain. The accommodation solvent selectivity of BCP/PeQDs suggests a promising strategy for advancing neurologically soft electronics, human-like pattern recognition, and neuromorphic computation. © 2023 Elsevier Ltd

关键词： Block copolymers

来源：评论

学校读者我要写书评

暂无评论

Tuning on passive interfacial cooling of covalent organic framework hydrogel for enhancing freshwater and electricity generation

引用

SusMat 2024年第5期4卷 139-153页

作者： Jianfei Wu Ziwei Cui Yuxuan Su Dongfang Wu Jundie Hu Jiafu Qu Jianzhang Li Fangyuan Kang Dan Tian Qichun Zhang Yahui Cai Co-Innovation Center of Efficient Processing and Utilization of Forest Resources College of Materials Science and EngineeringNanjing Forestry UniversityNanjingChina School of Materials Science and Engineering Suzhou University of Science and TechnologySuzhouChina State Key Laboratory of Efficient Production of Forest Resources Beijing Forestry UniversityBeijingChina Department of Materials Science and Engineering Department of ChemistryCenter of Super-Diamond and Advanced Films&Hong Kong Institute of Clean EnergyCity University of Hong KongHong KongChina

Developing an efficient freshwater and electricity co-generation device(FECGD)can solve the shortage of freshwater and ***,the poor salt resistance and refrigeration properties of the materials for FECGD put big challenges in the efficient and stable operation of these *** address these issues,we propose the covalent organic framework(COF)confined co-polymerization strategy to prepare COF-modified acrylamide cationic hydrogels(ACH-COF),where hydrogen bonding interlocking between negatively charged polymer chains and COF pores can form a salt resistant hydrogel for stabilizing tunable passive interfacial cooling(TPIC).The FECPDs based on the TPIC and salt resistance of ACH-COF display a maximum output power density of 2.28 W m-2,which is 4.3 times higher than that of a commercial thermoelec-tric generator under one solar *** production rate of freshwater can reach 2.74 kg m-2 *** results suggest that the high efficiency and scala-bility of the FECGD can hold the promise of alleviating freshwater and power shortages.

关键词： COF confined co-polymerization environmental sensing freshwater and electricity co-generation passive interfacial cooling salt resistance

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：