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Crystallization Regulation and Morphological Evolution for HTM-free Tin-Lead (1.28eV) Alloyed Perovskite Solar Cells

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Energy & Environmental materials 2023年第2期6卷 113-119页

作者： Hang Hu Xianyong Zhou Jiabang Chen Deng Wang Dongyang Li Yulan Huang Luozheng Zhang Yuanjun Peng Feng Wang Jingxia Huang Naichao Chen Liang Sun Xuesong Liu Xingzhu Wang Jianyong Ouyang Baomin Xu Department of Materials Science and Engineering Southern University of Science and TechnologyShenzhen 518055China Department of Materials Science and Engineering National University of SingaporeSingapore 117576Singapore Shenzhen Engineering Research and Development Center for Flexible Solar Cells Southern University of Science and TechnologyShenzhen 518055China Key Laboratory of Energy Conversion and Storage Technologies(Southern University of Science and Technology) Ministry of EducationShenzhen 518055China Guangdong-Hong Kong-Macao Joint Laboratory for Photonic-Thermal-Electrical Energy Materials and Devices Southern University of Science and TechnologyShenzhen 518055China SUSTech Academy for Advanced Interdisciplinary Studies Southern University of Science and TechnologyShenzhen 518055China Shenzhen Putai Technology Co. LtdShenzhen 518110China

There have been huge achievements of all-perovskite tandem solar cells,which recently realized the highest power conversion efficiency of 24.8%.However,the complex device structure and complicated manufacture processes severely restrict the further development of all-perovskite tandem solar *** this work,we successfully fabricated high-efficiency hole transport material-free(HTM-free)Sn−Pb alloyed narrow bandgap perovskite solar cells(PSCs)by introducing guanidinium thiocyanate(GASCN)and hydroiodic acid(HI)into the perovskite precursor *** and HI play a positive synergy effect during perovskite crystallization process resulting in larger grain size,fewer surface defects,and lower trap density to suppress the Sn^(2+)oxidation ***,they could effectively adjust the energy level of perovskite materials,reduce the energy level difference between perovskite and ITO resulting in more efficiently transport of free hole charge *** a result,with adding GASCN and HI,the achieved highest power conversion efficiency of HTM-free devices increased from 12.58%to 17.85%,which is one of the highest PCEs among all values reported to date for the HTM-free narrow-bandgap(1.2-1.4 eV)Sn−Pb binary ***,the optimized device shows improved environmental *** additive strategy manifests a remarkable step towards the facile,cost-efficient fabrication of HTM-free perovskite-based tandem solar cells with both high efficiency and simple fabrication process.

关键词： crystallization regulation hole transport layer-free mixed tin-lead narrow bandgap perovskite solar cells

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Fabrication of wear-resistant PA6 composites with superior thermal conductivity and mechanical properties via constructing highly oriented hybrid network of SiC-packed BN platelets

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Journal of materials science & technology 2023年第15期146卷 200-210页

作者： Jing Chen Jiaming Zhu Yang Pan Hong Wu Shaoyun Guo Jianhui Qiu The State Key Laboratory of Polymer Materials Engineering Sichuan Provincial Engineering Laboratory of PlasticRubber Complex Processing TechnologyPolymer Research Institute of Sichuan UniversityChengdu 610065China Jiangsu Industrial Technology Research Institute of Advanced Polymer Materials Nanjing 211899China Department of Mechanical Engineering Faculty of Systems Science and TechnologyAkita Prefectural UniversityAkita 015-0055Japan

Herein,a strong extensional and shearing field was introduced to construct highly oriented hybrid networks of silicon carbide(SiC)-packed boron nitride(BN)platelets to fabricate high-performance wearresistant PA6 *** show that in-plane and through-plane thermal conductivity(TC)of the prepared PA6 composites with a total filler loading of 20 wt.%reached 1.31 and 0.35 W/(m K),352%and 25%higher than those of pure PA6,*** is attributed to the highly oriented hybrid network that facilitates the formation of efficient thermal conductivity *** monitoring results during friction confirm that high TC favors the friction heat dissipation ***,the yield strength of PA6 composites increased by 39.1%and they still have excellent ductility with an elongation at break of 207.1%.Finally,the wear rate of PA6 composites decreased sharply by 92.5%.This method can be used to manufacture advanced linear bearing and guideway parts,etc。

关键词： Polymer-matrix composites(PMCs) Hybrid Wear Thermal properties

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Continuous-Time Prediction of Industrial Paste Thickener System With Differential ODE-Net

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IEEE/CAA Journal of Automatica Sinica 2022年第4期9卷 686-698页

作者： Zhaolin Yuan Xiaorui Li Di Wu Xiaojuan Ban Nai-Qi Wu Hong-Ning Dai Hao Wang the Beijing Advanced Innovation Center for Materials Genome Engineering Institute of Artificial IntelligenceBeijing Key Laboratory of Knowledge Engineering for Materials ScienceSchool of Computer and Communication EngineeringUniversity of Science and Technology Beijing the Department of ICT and Natural Science Norwegian University of Science and Technology IEEE the Institute of Systems Engineering and Collaborative Laboratory for Intelligent Science and SystemsMacao University of Science and Technology the Department of Computing and Decision Sciences Lingnan University the Department of Computer Science Norwegian University of Science and Technology

It is crucial to predict the outputs of a thickening system,including the underflow concentration(UC)and mud pressure,for optimal control of the *** proliferation of industrial sensors and the availability of thickening-system data make this ***,the unique properties of thickening systems,such as the non-linearities,long-time delays,partially observed data,and continuous time evolution pose challenges on building data-driven predictive *** address the above challenges,we establish an integrated,deep-learning,continuous time network structure that consists of a sequential encoder,a state decoder,and a derivative module to learn the deterministic state space model from thickening *** a case study,we examine our methods with a tailing thickener manufactured by the FLSmidth installed with massive sensors and obtain extensive experimental *** results demonstrate that the proposed continuous-time model with the sequential encoder achieves better prediction performances than the existing discrete-time models and reduces the negative effects from long time delays by extracting features from historical system *** proposed method also demonstrates outstanding performances for both short and long term prediction tasks with the two proposed derivative types.

关键词： Industrial 24 paste thickener ordinary differential equation(ODE)-net recurrent neural network time series prediction

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Roles of concentration-dependent Cu doping behaviors on the thermoelectric properties of n-type Mg_(3)Sb_(1.5)Bi_(0.5)

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Journal of Materiomics 2024年第1期10卷 154-162页

作者： Xinxin Yang Heng Ni Xiaotong Yu Biao Cao Juanjuan Xing Qiyong Chen Lili Xi Jiandang Liu Jiye Zhang Kai Guo Jing-Tai Zhao School of Materials Science and Engineering Shanghai University99 Shangda RoadShanghai200444China Materials Genome Institute Shanghai University99 Shangda RoadShanghai200444China State Key Laboratory of Particle Detection and Electronics University of Science and Technology of ChinaHefeiAnhui230026China School of Physics and Materials Science Guangzhou UniversityGuangzhou510006China Research Center for Advanced Information Materials(CAIM) Huangpu Research&Graduate School of Guangzhou UniversitySino-Singapore Guangzhou Knowledge CityHuangpu DistrictGuangzhou510555China Key Lab of Si-based Information Materials&Devices and Integrated Circuits Design Department of Education of Guangdong ProvinceChina School of Materials Science and Engineering Guilin University of Electronic TechnologyGuilin541004China Guangxi Key Laboratory of Information Materials Guilin University of Electronic TechnologyGuilin541004China

Large Seebeck coefficients induced by high degeneracy of conduction band minimum,and low intrinsic lattice thermal conductivity originated from large lattice vibrational anharmonicity render Mg_(3)Sb_(2)as a promising n-type thermoelectric ***,we demonstrated unique concentration-dependent occupation behaviors of Cu in Mg_(3.4)Sb_(1.5)Bi_(0.49)Te_(0.01)matrix,evidenced by structural characterization and transport property *** is found that Cu atoms prefer to enter the interstitial lattice sites in Mg_(3)Sb_(2)host with low doping level(Mg_(3.4)Sb_(1.5)Bi_(0.49)Te_(0.01)+x%Cu,x<0.3%),acting as donors for providing additional electrons without deteriorating the carrier *** x is larger than 0.3%,the excessive Cu atoms are inclined to substitute Mg atoms,yielding acceptors to decrease the electron *** a result,the electrical conductivity of the Mg_(3.4)Sb_(1.5)Bi_(0.49)Te_(0.01)+0.3%Cu sample reaches 2.3×10^(4)S/m at 300 K,increasing by 300%compared with that of the pristine *** figure of merit zT values in the whole measured temperature range are significantly improved by the synergetic improvement of power factor and reduction of thermal *** average zT∼1.07 from 323 K to 773 K has been achieved for the Mg_(3.4)Sb_(1.5)Bi_(0.49)Te_(0.01)+0.3%Cu sample,which is about 30%higher than that of the Mg_(3.4)Sb_(1.5)Bi_(0.49)Te_(0.01) sample.

关键词： Mg_(3)Sb_(2) Cu doping Concentration-dependent occupation Thermoelectric properties Average zT

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Epitaxial ferroelectric hafnia stabilized by symmetry constraints

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Physical Review B 2023年第6期108卷 L060102-L060102页

作者： Tianyuan Zhu Shiqing Deng Shi Liu Key Laboratory for Quantum Materials of Zhejiang Province Department of Physics School of Science Westlake University Hangzhou Zhejiang 310024 China Institute of Natural Sciences Westlake Institute for Advanced Study Hangzhou Zhejiang 310024 China Beijing Advanced Innovation Center for Materials Genome Engineering University of Science and Technology Beijing Beijing 100083 China

Ferroelectric memories experienced a revival in the last decade due to the discovery of ferroelectricity in HfO2-based nanometer-thick thin films. These films exhibit exceptional silicon compatibility, overcoming the scaling and integration obstacles that impeded perovskite ferroelectrics' use in high-density integrated circuits. The exact phase responsible for ferroelectricity in hafnia films remains debated with no single factor identified that could stabilize the ferroelectric phase thermodynamically. Here, supported by density functional theory (DFT) high-throughput (HT) calculations that screen a broad range of epitaxial conditions, we demonstrate conclusively that specific epitaxial conditions achievable with common substrates such as yttria-stabilized zirconia (YSZ) and SrTiO3 can favor the polar Pca21 phase thermodynamically over other polar phases such as R3m and Pmn21 and nonpolar P21/c phase. The substrate's symmetry constraint-induced shear strain is crucial for the preference of Pca21. The strain-stability phase diagrams resolve experiment-theory discrepancies and can guide the improvement of ferroelectric properties of epitaxial hafnia thin films.

关键词： Epitaxial strain Ferroelectrics Density functional theory

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High-performance localized high-concentration electrolytes by diluent design for long-cycling lithium metal batteries

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Chinese Chemical Letters 2024年第4期35卷 244-247页

作者： Zhe Wang Li-Peng Hou Qian-Kui Zhang Nan Yao Aibing Chen Jia-Qi Huang Xue-Qiang Zhang College of Chemical and Pharmaceutical Engineering Hebei University of Science and TechnologyShijiazhuang 050018China Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology Department of Chemical EngineeringTsinghua UniversityBeijing 100084China Advanced Research Institute of Multidisciplinary Science Beijing Institute of TechnologyBeijing 100081China School of Materials Science and Engineering Beijing Institute of TechnologyBeijing 100081China

Electrolyte design is essential for stabilizing lithium metal anodes and localized high-concentration electrolyte(LHCE) is a promising one. However, the state-of-the-art LHCE remains insufficient to ensure long-cycling lithium metal anodes. Herein, regulating the solvation structure of lithium ions in LHCE by weakening the solvating power of diluents is proposed for improving LHCE performance. A diluent,1,1,2,2,3,3,4,4-octafluoro-5-(1,1,2,2-tetrafluoroethoxy) pentane(OFE), with weaker solvating power is introduced to increase the proportion of aggregates(an anion interacts with more than two lithium ions,AGG-n) in electrolyte compared with the commonly used 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether(TTE). The decomposition of AGG-n in OFE-based LHCE intensifies the formation of anion-derived solid electrolyte interphase and improves the uniformity of lithium deposition. Lithium metal batteries with OFE-based LHCE deliver a superior lifespan of 190 cycles compared with 90 cycles of TTE-based LHCE under demanding conditions. Furthermore, a pouch cell with OFE-based LHCE delivers a specific energy of 417 Wh/kg and undergoes 49 cycles. This work provides guidance for designing high-performance electrolytes for lithium metal batteries.

关键词： Lithium metal anodes Electrolyte Diluents Solid electrolyte interphase Pouch cells

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Application of a Self-Assembly Sensing Layer to Grating Sensor Cabinets for Biomedical Sensing of Rheumatoid Arthritis Antigen-Antibodies

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IEEE Sensors Journal 2024年第7期24卷 10039-10047页

作者： Wen, Hsin-Yi Hsu, Hsiang-Cheng Feng, Wen-Kai Jhan, Kai-Siang Yeh, Yao-Tsung Chiang, Chia-Chin National Kaohsiung University of Science and Technology Department of Chemical and Materials Engineering Kaohsiung80778 Taiwan National Kaohsiung University of Science and Technology College of Maritime Department of Ph.D. Program in Maritime Science and Technology Kaohsiung807618 Taiwan National Kaohsiung University of Science and Technology Department of Mechanical Engineering Kaohsiung80778 Taiwan Fooyin University Department of Medical Laboratory Science and Biotechnology Kaohsiung83102 Taiwan

In this article, we harnessed biomedical applications in laser-assisted etching long-period fiber gratings (LLPFGs) sensors, subsequently deploying them within the realm of biomedical applications. The primary aim of this study was to devise a sensitive method for the detection of antigen-antibodies associated with rheumatoid arthritis (RA) using LLPFGs. Sensing the antigen binding took place on the surface of the optical fiber through a self-assembling process. Given the inherent limitations of conventional rheumatoid factor (RF) testing in terms of specificity, we introduced an innovative serum-based approach geared toward the identification of anti-cyclic citrullinated peptide (Anti-CCP) antibodies. This method exhibited an impressive diagnostic accuracy rate of approximately 80% for RA cases, coupled with an exceptional specificity level of 98% for individuals without RA. The incorporation of LLPFGs in the detection of RA antigen-antibodies presents a highly promising avenue for enhancing the precision and reliability of RA diagnosis. Furthermore, this research aligns closely with the United Nations Sustainable Development Goal (SDG)3, which strives to promote well-being across all age groups and advance sustainable development by addressing health-related challenges, including the accurate diagnosis of diseases like RA. © 2023 IEEE.

关键词： Antibodies

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Strengthening-softening transition and maximum strength in Schwarz nanocrystals

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Nano materials science 2024年第3期6卷 320-328页

作者： Hanzheng Xing Jiaxi Jiang Yujia Wang Yongpan Zeng Xiaoyan Li Center for Advanced Mechanics and Materials Applied Mechanics LaboratoryDepartment of Engineering MechanicsTsinghua UniversityBeijing100084China Institute of High Performance Computing(IHPC) Agency for ScienceTechnology and Research(A*STAR)Singapore138632Singapore

Recently,a Schwarz crystal structure with curved grain boundaries(GBs)constrained by twin-boundary(TB)networks was discovered in nanocrystalline Cu through experiments and atomistic *** Cu with nanosized Schwarz crystals exhibited high strength and excellent thermal ***,the grainsize effect and associated deformation mechanisms of Schwarz nanocrystals remain ***,we performed large-scale atomistic simulations to investigate the deformation behaviors and grain-size effect of nanocrystalline Cu with Schwarz *** simulations showed that similar to regular nanocrystals,Schwarz nanocrystals exhibit a strengthening-softening transition with decreasing grain *** critical grain size in Schwarz nanocrystals is smaller than that in regular nanocrystals,leading to a maximum strength higher than that of regular *** simulations revealed that the softening in Schwarz nanocrystals mainly originates from TB migration(or detwinning)and annihilation of GBs,rather than GB-mediated processes(including GB migration,sliding and diffusion)dominating the softening in regular *** analyses of simulation data further showed that compared with those in regular nanocrystals,the GB-mediated processes in Schwarz nanocrystals are suppressed,which is related to the low volume fraction of amorphous-like GBs and constraints of TB *** smaller critical grain size arises from the suppression of GB-mediated processes.

关键词： Schwarz nanocrystal Curved grain boundary Atomistic simulation Grain size effect Maximum strength

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Dealloyed TiCuMn efficiently catalyze the NO reduction and Zn-NO batteries

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Frontiers of Chemical science and engineering 2024年第9期18卷 51-59页

作者： Lang Zhang Tong Hou Weijia Liu Yeyu Wu Tianran Wei Junyang Ding Qian Liu Jun Luo Xijun Liu State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures MOE Key Laboratory of New Processing Technology for Nonferrous Metals and MaterialsSchool of ResourcesEnvironment and MaterialsGuangxi UniversityNanning 530004China Education Department of Guangxi Zhuang Autonomous Region Key Laboratory of Applied Analytical ChemistryGuangxi Collaborative Innovation Center for Chemistry and Engineering of Forest ProductsGuangxi Key Laboratory of Chemistry and Engineering of Forest ProductsKey Laboratory of Chemistry and Engineering of Forest ProductsState Ethnic Affairs CommissionSchool of Chemistry and Chemical EngineeringGuangxi Minzu UniversityNanning 530006China Institute for New Energy Materials&Low-Carbon Technologies School of Materials Science and EngineeringTianjin University of TechnologyTianjin 300384China Institute for Advanced Study Chengdu UniversityChengdu 610106China ShenSi Lab Shenzhen Institute for Advanced StudyUniversity of Electronic Science and Technology of ChinaShenzhen 518110China

Electrocatalytic NO reduction reaction offers a sustainable route to achieving environmental protection and NH3 production targets as *** this work,a class of dealloyed Ti_(60)Cu_(33)Mn_(7)ribbons with enough nanoparticles for the high-efficient NO reduction reaction to NH_(3)is fabricated,reaching an excellent Faradaic efficiency of 93.2%at–0.5 V vs reversible hydrogen electrode and a high NH_(3) synthesis rate of 717.4μmol·h^(-1)·mg_(cat).^(-1) at–0.6 V vs reversible hydrogen *** formed nanoparticles on the surface of the catalyst could facilitate the exposure of active sites and the transportation of various reactive ions and ***,the Mn content in the TiCuMn ribbons modulates the chemical and physical properties of its surface,such as modifying the electronic structure of the Cu species,optimizing the adsorption energy of N^(*)atoms,decreasing the strength of the NO adsorption,and eliminating the thermodynamic energy barrier,thus improving the NO reduction reaction catalytic ***,a Zn-NO battery was fabricated using the catalyst and Zn plates,generating an NH_(3) yield of 129.1µmol·h^(-1)·cm^(-2)while offering a peak power density of 1.45 mW·cm^(-2).

关键词： nitric oxide reduction NH_(3)electrosynthesis TiCuMn alloy Mn modulation Zn-NO battery

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ZnIn_(2)S_(4)/MOF S-scheme photocatalyst for H_(2)production and its femtosecond transient absorption mechanism

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Journal of materials science & technology 2024年第30期197卷 183-193页

作者： Jiajie Cai Bowen Liu Shumin Zhang Linxi Wang Zhen Wu Jianjun Zhang Bei Cheng State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Hunan Key Laboratory of Applied Environmental Photocatalysis Changsha UniversityChangsha 410022China Laboratory of Solar Fuel Faculty of Materials Science and ChemistryChina University of Geosciences68 Jincheng StreetWuhan 430078China Department of Chemical Engineering Ordos Institute of TechnologyOrdos 017000China

Photocatalytic water splitting is a popular pathway for H_(2)evolution,but the slow water oxidation greatly hampers the overall *** harness photogenerated holes in an efficient and lucrative way,the wa-ter oxidation reaction is replaced by selective oxidation of organic compounds to achieve simultaneous production of H_(2)and value-added ***,an alternative tactic is reported where an organic compound(benzylamine,BA)not only serves as the precursor for N-benzylidene-benzylamine(NBBA)production but also provides hydrogen sources for H_(2)evolution,achieving the goal under anhydrous *** process is realized using an S-scheme photocatalyst composed of ZnIn_(2)S_(4)and the UiO-66-NH_(2)(U6N)metal-organic framework(MOF).The S-scheme carrier transfer mechanism was validated by in-situ irradiated X-ray photoelectron spectroscopy(ISI-XPS)and femtosecond transient absorption(fs-TA)*** increased carrier efficiency and reinforced redox power endowed by the S-scheme heterojunction,the composite performed better than ZnIn2 S4 and *** performance was further ameliorated by Pt-cocatalyst modification,achieving an H_(2)production rate of 5275μmol h^(-1)g^(-1)as well as BA conversion of 94.3%with 99.3%NBBA *** studies reveal that BA is ini-tially oxidized to carbon-centered radicals and further to imines along with the release of *** imine reacts with another BA molecule to form NBBA,while the protons are reduced to H_(2).This work provides new insights into concurrent photocatalytic H_(2)production and selective organic oxidation from organic amines using S-scheme photocatalysts.

关键词： Photocatalysis S-scheme heterojunction Hydrogen production Selective oxidation Benzylamine Femtosecond transient absorption

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