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Recent progress in C-N coupling for electrochemical CO_(2) reduction with inorganic nitrogenous species in aqueous solution

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materials Reports(Energy) 2023年第1期3卷 65-77,I0003页

作者： Shuxia Liu Tanyuan Wang Lior Elbaz Qing Li State Key Laboratory of Material Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhanHubei430074China Department of Chemistry and the Institute of Nanotechnology and Advanced Materials Bar-Ilan UniversityRamat-Gan5290002Israel

The electrocatalytic CO_(2) reduction in aqueous solution mainly involves bond cleavage and formation between C,H and O,and it is highly desirable to expand the bond formation reaction of C with other atoms to obtain novel and valuable *** electrochemical synthesis of N-containing organic chemicals in electrocatalytic CO_(2) reduction via introducing N sources is an effective strategy to expand the product scope,since chemicals con-taining C–N bonds(*** and amines)are important reactants/products for medicine,agriculture and *** article focuses on the research progress of C–N coupling from CO_(2) and inorganic nitrogenous species in aqueous ***,the reaction pathways related to the reaction intermediates for urea,formamide,acetamide,methylamine and ethylamine are ***,the electrocatalytic performance of different catalysts for these several N-containing products are summarized and ***,the challenges and op-portunities are analyzed,aiming to provide general insights into future research directions for electrocatalytic C–N coupling.

关键词： CO_(2) reduction C-N coupling Heterogeneous electrocatalysis Amide Amine

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Excitation-mode-selective emission through multiexcitonic states in a double perovskite single crystal

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Light(science & Applications) 2025年第1期14卷 186-196页

作者： Hao Suo Nan Wang Yu Zhang Xin Zhang Jinmeng Xiang Xiaojia Wang Guansheng Xing Dongxu Guo Jiwen Chang Yu Wang Panlai Li Zhijun Wang Yuhai Zhang Bing Chen Shuzhou Li Chongfeng Guo Feng Wang Hebei Key Laboratory of Optic-electronic Information and Materials College of Physics Science&TechnologyHebei UniversityBaoding071002China Department of Materials Science and Engineering City University of Hong KongKowloon999077Hong Kong SARChina State Key Laboratory of Photon-Technology in Western China Energy Institute of Photonics&Photon-TechnologyNorthwest UniversityXi’an710127China Institute for Advanced Interdisciplinary Research University of JinanJinanShandong250022China College of Electronic and Optical Engineering&College of Flexible Electronics(Future Technology) Nanjing University of Posts and TelecommunicationsNanjing210023China School of Materials Science and Engineering Nanyang Technological University50 Nanyang AvenueSingapore639798Singapore

Low-dimensional lead-free metal halide perovskites are highly attractive for cutting-edge optoelectronic ***,we report a class of scandium-based double perovskite crystals comprising antimony dopants that can generate multiexcitonic emissions in the ultraviolet,blue,and yellow spectral *** to the zero-dimensional nature of the crystal lattice that minimizes energy crosstalk,different excitonic states in the crystals can be selectively excited by ultraviolet light,X-ray irradiation,and mechanical action,enabling dynamic control of steady/transient-state spectral features by modulating the excitation ***,the transparent crystal exhibits highly efficient white photoluminescence(quantum yield>97%),X-ray excited blue emission with long afterglow(duration>9 h),and high-brightness self-reproducible violet-blue *** findings reveal the exceptional capability of low-dimensional perovskite crystals for integrating various excitonic luminescence,offering exciting opportunities for multi-level data encryption and all-in-one authentication technologies.

关键词： perovskite crystal excited

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The preparation and performance analysis of zirconium-modified aluminum phosphate-based high-temperature(RT-1500℃)resistant adhesive for joining alumina in extreme environment

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Journal of advanced Ceramics 2024年第7期13卷 911-932页

作者： Jingxuan Liu Yange Wan Bo Xiao Jiancun Li Zhanming Hu Ruoyu Zhang Xiaoxia Hu Jiachen Liu Guoshuai Cai Hongli Liu Mingchao Wang College of Science Civil Aviation University of ChinaTianjin 300300China Department of Safety Engineering Civil Aviation University of ChinaTianjin 300300China Binzhou Beicheng Construction Engineering Materials Testing Co. Ltd.Binzhou 256602China Department of Aviation Engineering Civil Aviation University of ChinaTianjin 300300China School of Materials and Engineering Key Lab of Advanced Ceramics and Machining Technology of Ministry of EducationTianjin UniversityTianjin 300072China

High-temperature-resistant adhesives are critical materials in the aerospace *** zirconium-modified aluminum phosphate-based adhesives developed in this work had the advantage of adjustable thermal expansibility,achieving a high matching of coefficient of thermal expansion(CTE)with *** introduction of zirconium can significantly improve the thermal stability of the adhesive matrix,and the Zr/Al ratio substantially affects the various reaction processes inside the adhesive,especially the types of zirconium-containing *** of the zirconium-containing compounds in the A7Z3 adhesive were ZrO_(2) only when the mass ratio of zirconium hydroxide to aluminum hydroxide was 3:7,which was the key reason why it had the highest *** room-temperature bonding strength of A7Z3 after heat treatment at 1500℃reached 67.2 *** pretreatment at 1500℃,the high-temperature bonding strength of A7Z3 was greater than 50 MPa in the range of(room temperature)RT-1000℃.After 40 thermal cycles between RT and 1500℃,the bonding strength still reached 10 *** bonding occurred at temperatures below 1000℃,while chemical bonding dominated above 1000℃based on the generation of Al5BO9 and mullite at the interfaces.

关键词： high-temperature-resistant adhesive thermal expansion property zirconium-modified aluminum phosphate bonding performance thermal cycling bonding mechanism

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Versatile Strategies of Nucleic Acid Synthesis for Rational Design and Biomedical Applications

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Nano Biomedicine 2024年第1期16卷 1-17页

作者： Akiyama, Yoshitsugu Katsushika Division Institute of Arts and Sciences Tokyo University of Science Tokyo Japan Department of Materials Science and Technology Graduate School of Advanced Engineering Tokyo University of Science 6-3-1 Niijuku Katsushika Tokyo125-8585 Japan

Nucleic acids, serving as both a repository for genetic information and the basis for biological activity, can be regarded as highly ordered functional molecules. Oligonucleotides (ONs) are oligomers of nucleic acids that can now be obtained by chemical synthesis. The ONs thus obtained have been approved as nucleic acid therapeutics for the treatment of various diseases. Importantly, chemically modified non-natural ONs with augmented functionality are useful when the functions of natural ONs fall short of achieving therapeutic efficacy. Chemical modification of ONs can also facilitate their complexation with other functional materials and further enhance the functionality of the resulting hybrid materials. Examples of such modifications include the combination of ONs with small molecular compounds, peptides, proteins, or highly ordered nanostructures with enhanced biological stability as building blocks for self-assembly. Thus, strategies for the precise chemical synthesis of ONs will play an important role in the sustained progress of biomedical materials. © 2024 Nano Biomedical Society.

关键词： Oligonucleotides

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Determination of interfacial heat transfer coefficient at the frozen sand mold casting process of ZL101 alloy

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Journal of materials science & technology 2024年第27期194卷 28-42页

作者： Shijie Dong Zhongde Shan Feng Lin Haoqin Yang Xiao Liang Department of Mechanical Engineering Tsinghua UniversityBeijing 100084China State Key Laboratory of Advanced Forming Technology and Equipment China Academy of Machinery Science and TechnologyBeijing 100037China Key Laboratory for Advanced Materials Processing Technology Ministry of Education of ChinaBeijing 100084China College of Mechanical and Electrical Engineering Nanjing University of Aeronautics and AstronauticsNanjing 210016China College of Material Science and Technology Nanjing University of Aeronautics and AstronauticsNanjing 210016China

Compared to the resin sand mold casting process, frozen casting is more environmentally friendly, providing a better working environment and enhanced supercooling degree. The interfacial heat transfer coefficient (IHTC) between frozen sand mold and metal is an important parameter that significantly influences the final mechanical properties and microstructure of the castings. This paper solved the inverse heat conduction problem using the finite difference method (FDM). In addition, the conjugate gradient method (CGM) was adopted to calculate the temperature distribution and heat flux in the molten metal. At the same time, the particle swarm optimization algorithm (PSO) was used in temperature distribution determination in frozen sand mold. The interfacial heat transfer coefficient (IHTC) was estimated during the solidification of ZL101. The results showed a good agreement between calculated and experimental data, obtaining accurate casting interface temperature Tm, frozen sand mold interface temperature Ts, heat flux q, and IHTC. The analysis of the IHTC variation revealed a water content value within the range of 4 wt.% to 5 wt.% resulted in IHTC in two types of interpretation, called ‘fluctuation type’ and ‘turning type’.

关键词： Frozen sand mold Interfacial heat transfer coefficient(IHTC) Finite difference method(FDM) Conjugate gradient method(CGM) Particle swarm optimization(PSO)

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Highly efficient electrocatalytic nitrogen fixation enabled by the bridging effect of Ru in plasmonic nanoparticles

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Nano Research 2023年第1期16卷 360-370页

作者： Hang Yin Jinwu Hu Caihong Fang Yuyang Wang Lixia Ma Nan Zhang Shouren Zhang Ruibin Jiang Jianfang Wang Shaanxi Key Laboratory for Advanced Energy Devices Shaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringShaanxi Normal UniversityXi’an 710119China College of Chemistry and Materials Science The Key Laboratory of Functional Molecular SolidsMinistry of EducationAnhui Laboratory of Molecular-Based MaterialsCenter for Nano Science and TechnologyKey Laboratory of Electrochemical Clean Energy of Anhui Higher Education InstitutesAnhui Normal UniversityWuhu 241000China Henan Provincial Key Laboratory of Nanocomposites and Applications Institute of Nanostructured Functional MaterialsHuanghe Science and Technology CollegeZhengzhou 450006China Department of Physics The Chinese University of Hong KongHong Kong 999077China

Plasmon-generated hot electrons show great potential for driving chemical *** utilization efficiency of hot electrons is highly dependent on the interaction of the electronic states at the interfaces between plasmonic nanoparticles and other materials/*** interaction can produce new hybridized electron states,which permit direct hot-electron transfer,a more efficient transfer ***,Au usually has very weak interaction with most molecules because of its inertness,which makes direct hot-electron transfer ***,the improvement of the hot-electron transfer efficiency from Au to N_(2)is demonstrated by introducing a Ru bridging *** the N_(2)fixation rate and Faradic efficiency(FE)are enhanced by the excitation of *** enhancement of the N_(2)fixation rate is found to arise from plasmon-generated hot *** calculations show that the strong interaction of the Ru electronic states with the N_(2)molecular orbitals produces new hybridized electronic states,and the Ru d electrons also strongly couple with the Au sp *** a bridging role of Ru makes direct hot-electron transfer from Au to N_(2)possible,improving the FE of nitrogen *** findings demonstrate a new approach to increasing the utilization efficiency of plasmonic hot electrons for chemical reactions and will be helpful to the design of plasmonic catalysts in the future.

关键词： electrocatalytic nitrogen fixation Au/Ru electrocatalysts localized surface plasmon resonance electronic state hybridization hot electron

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Bioinspired Zwitterionic Block Polymer-Armored Nitric Oxide-Generating Coating Combats Thrombosis and Biofouling

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Research 2025年第1期2024卷 870-884页

作者： Qing Ma Wentai Zhang Xiaohui Mou Nan Huang Haimang Wang Hongyu Zhang Zhilu Yang School of Materials Science and Engineering Key Lab of Advanced Technology of Materials of Education MinistrySouthwest Jiaotong UniversityChengdu610031China Dongguan Key Laboratory of Smart Biomaterials and Regenerative Medicine The Tenth Affiliated HospitalSouthern Medical UniversityDongguan523059China GuangZhou Nanchuang Mount Everest Company for Medical Science and Technology Guangzhou510670China State Key Laboratory of Tribology in Advanced Equipment Department of Mechanical EngineeringTsinghua UniversityBeijing100084China Wenzhou Institute University of Chinese Academy of SciencesWenzhou352001 ZhejiangChina

Thrombosis and infection are 2 major complications associated with central venous catheters(CVCs),resulting in substantial mortality and *** concurrent long-term administration of antibiotics and anticoagulants to address these complications have been demonstrated to cause severe side effects such as antibiotic resistance and *** mitigate these complications with minimal or no drug utilization,we developed a bioinspired zwitterionic block polymer-armored nitric oxide(NO)-generating functional coating for surface modification of *** armor was fabricated by precoating with a Cu-dopamine(DA)/selenocysteamine(SeCA)(Cu-DA/SeCA)network film capable of catalytically generating NO on the CVCs surface,followed by grafting of a zwitterionic p(DMA-b-MPC-b-DMA)polymer *** synergistic effects of active attack by NO and copper ions provided by Cu-DA/SeCA network and passive defense by zwitterionic polymer brush imparted the CVCs surface with durable antimicrobial properties and marked inhibition of platelets and *** in vivo studies confirmed that the surface-armored CVCs could effectively reduce inflammation and inhibit thrombosis,indicating a promising potential for clinical applications.

关键词： biofouling central venous catheters thrombosis nitric oxide zwitterionic block polymer central venous catheters cvcs resulting antibiotic resistance bioinspired coating

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First-principle prediction of structural and mechanical properties in NbMoTaWRe_(x) refractory high-entropy alloys with experimental validation

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Rare Metals 2022年第10期41卷 3343-3350页

作者： Jin-Yong Mo Yi-Xing Wan Zhi-Bin Zhang Xin Wang Xiao-Qing Li Bao-Long Shen Xiu-Bing Liang School of Chemistry and Chemical Engineering China University of Mining and TechnologyXuzhou221116China Defense Innovation Institute Academy of Military ScienceBeijing100071China Department of Materials Science and Engineering KTH Royal Institute of Technology10044StockholmSweden School of Materials Science and Engineering Jiangsu Key Laboratory for Advanced Metallic MaterialsSoutheast UniversityNanjing211189China

In this work,the effect of Re alloying on the phase composition,crystal structure,and mechanical properties of NbMoTaWRe_(x) (x=0,0.27,0.57,0.92,1.33) refractory high-entropy alloys (RHEAs) were systematically investigated by combining the calculation of phase diagram(CALPHAD),first-principle calculations and *** theoretical predictions showed good consistency with the experimental *** the increase in Re content,the theoretical results showed that all considered alloys have a single body-centered cubic (bcc) structure and the lattice constant and ductility were decreased,while the elastic moduli and hardness were *** avoid extreme brittleness,a strategic suggestion was given for the design of Re-containing RHEAs in the future.

关键词： alloys alloying entropy

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An intrinsically self-healing and anti-freezing molecular chains induced polyacrylamide-based hydrogel electrolytes for zinc manganese dioxide batteries

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Journal of Energy Chemistry 2024年第2期89卷 565-578,I0013页

作者： Haiyang Liao Wenzhao Zhong Chen Li Jieling Han Xiao Sun Xinhui Xia Ting Li Abolhassan Noori Mir F.Mousavi Xin Liu Yongqi Zhang Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 611731SichuanChina School of Mechanical Engineering Hunan University of TechnologyZhuzhou 412007HunanChina School of Materials Science and Engineering Zhejiang University of TechnologyHangzhou 310014ZhejiangChina Department of Chemistry Faculty of Basic SciencesTarbiat Modares UniversityTehran 14117-13116Iran State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430200HubeiChina

The anti-freezing strategy of hydrogels and their self-healing structure are often contradictory,it is vital to break through the molecular structure to design and construct hydrogels with intrinsic anti-freezing/self-healing for meeting the rapid development of flexible and wearable devices in diverse service ***,we design a new hydrogel electrolyte(AF/SH-Hydrogel)with intrinsic anti-freezing/self-healing capabilities by introducing ethylene glycol molecules,dynamic chemical bonding(disulfide bond),and supramolecular interaction(multi-hydrogen bond)into the polyacrylamide molecular *** to the exceptional freeze resistance(84%capacity retention at-20℃)and intrinsic self-healing capabilities(95%capacity retention after 5 cutting/self-healing cycles),the obtained AF/SH-Hydrogel makes the zinc||manganese dioxide cell an economically feasible battery for the state-of-the-art *** Zn||AF/SH-Hydrogel||MnO_(2)device offers a near-theoretical specific capacity of 285 m A h g^(-1)at 0.1 A g^(-1)(Coulombic efficiency≈100%),as well as good self-healing capability and mechanical flexibility in an ice *** work provides insight that can be utilized to develop multifunctional hydrogel electrolytes for application in next generation of self-healable and freeze-resistance smart aqueous energy storage devices.

关键词： Flexible aqueous battery Hydrogel electrolyte Anti-freezing Self-healing Dual-dynamic reversible bond

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Synergistic Effect of Nitrogen/Phosphorus Co-Doping and Molybdenum Carbide Induced Electron Redistribution of Carbon Layer to Boost Hydrogen Evolution Reaction

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Chinese Journal of Chemistry 2024年第1期42卷 55-60页

作者： Jiamin Xiao Peng Li Yanyan Sun Heng Liu Javid Khan Handong Zhang Han Zhou Yaqiong Su Shuangyin Wang Lei Han College of Materials Science and Engineering Hunan Joint International Laboratory of Advanced Materials and Technology for Clean EnergyHunan UniversityChangshaHunan 410082China School of Chemistry Engineering Research Center of Energy Storage Materials and Devices Ministry of EducationXi'an Key Laboratory of Sustainable Energy Materials ChemistryState Key Laboratory of Electrical Insulation and Power EquipmentXi'an Jiaotong UniversityXi'anShaanxi 710049China School of Materials Science and Engineering Central South UniversityChangshaHunan 410083China state Key Laboratory of Chem/Bio-Sensingand Chemometrics College of Chemistry and Chemical EngineeringHunan University ChangshaHunan 410082China Laboratory of Inorganic Materials and Catalysis Department of Chemical Engineering and ChemistryEindhoven University of Technology P.O.Box5135600 MB EindhovenThe Netherlands

The development of highly efficient non-precious-metal-based electrocatalysts for the hydrogen evolution reaction is imperative for promoting the large-scale application of electrochemical water ***,nitrogen/phosphorus co-doped carbon nanorods encapsulated Mo_(2)C nanoparticles(Mo_(2)C@PNc)have been prepared by pre-phosphating treatment in combination of the coordination with polydopamine and the subsequent *** phosphating temperature has a significant effect on the content of phosphorus within the resultant Mo_(2)C@PNC,and the optimal catalyst delivers superior HER activity with the low overpotential of 104 mV at a current density of 10 mAcm^(-2) and good stability for 8 h,which has been theoretically demonstrated to originate from the synergistic effect between P doping and Mo_(2)C induced electron redistribution of nitrogen-doped carbon layer.

关键词： Molybdenum carbide N/P co-doped carbon Hydrogen evolution Synergistic effect Electron redistribution Comprehensive

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