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Aggregate 2022年第4期3卷 41-60页

作者： Hao Ding Abbas Ahmed Kuangyu Shen Luyi Sun Polymer Program Institute of Materials ScienceUniversity of ConnecticutStorrsConnecticutUSA Department of Chemical and Biomolecular Engineering University of ConnecticutStorrsConnecticutUSA Department of Biomedical Engineering University of ConnecticutStorrsConnecticutUSA

α-Zirconium phosphate(Zr(HPO_(4))_(2)⋅H_(2)O,α-ZrP)is an inorganic layered *** the first report of crystallineα-ZrP in 1964,thanks to its simple synthesis and unique physiochemical properties,α-ZrP has found widespread application in many fields including mechanical reinforcing,barrier improvement,flame retardancy,anticorrosion,catalysis,environment,energy,and *** of the ease of exfoliation ofα-ZrP to obtain single-layer nanosheets,as well as its rich surface chemistry thanks to the high density of orderly arranged surface acidic hydroxyl groups,α-ZrP single-layer nanosheets are ideal building blocks for self-assembly or assembly with other *** assembly ofα-ZrP nanosheets could form a randomly dispersed structure(isotropic),roughly ordered structure(nematic),or highly ordered structure(smectic)within liquid colloids or solid hybrids(including hydrogels).Thanks to the combination of the unique structures and the novel functions of the components,the assembled materials have found a wide verity of applications due to their excellent *** this article,the methods to synthesizeα-ZrP,the approaches and mechanisms to exfoliateα-ZrP,and the strategies to assembleα-ZrP nanosheets to form various structures,as well as the applications of the assembled materials are *** emerging prospects ofα-ZrP nanosheets as a key material in next-generation functional applications are envisioned.

关键词： application assembly exfoliation nanosheets α-zirconium phosphate

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Development of exosome membrane materialsfused microbubbles for enhanced stability and efficient drug delivery of ultrasound contrast agent

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Acta Pharmaceutica Sinica B 2023年第12期13卷 4983-4998页

作者： Yongho Jang Jeehun Park Pilsu Kim Eun-Joo Park Hyungjin Sun Yujin Baek Jaehun Jung Tai-kyong Song Junsang Doh Hyuncheol Kim Department of Chemical and Biomolecular Engineering Sogang UniversitySeoul 04107Republic of Korea Research Institute of Advanced Materials(RIAM) Institute of Engineering ResearchSeoul National UniversitySeoul 08826Republic of Korea Department of Electronic Engineering Sogang UniversitySeoul 04107Republic of Korea Biomedical Research Institute&Department of Radiology Seoul National University HospitalSeoul 03080Republic of Korea Interdisciplinary Program in Bioengineering Seoul National UniversitySeoul 08826Republic of Korea Department of Materials Science and Engineering Seoul National UniversitySeoul 08826Republic of Korea Institute of Engineering Research Bio-MAX InstituteSeoul National UniversitySeoul 08826Republic of Korea Department of Biomedical Engineering Sogang UniversitySeoul 04107Republic of Korea

Lipid-coated microbubbles are widely used as an ultrasound contrast agent,as well as drug delivery ***,the two main limitations in ultrasound diagnosis and drug delivery using microbubbles are the short half-life in the blood system,and the difficulty of surface modification of microbubbles for active *** exosome,a type of extracellular vesicle,has a preferentially targeting ability for its original *** this study,exosome-fused microbubbles(Exo-MBs)were developed by embedding the exosome membrane proteins into *** a result,the stability of Exo-MBs is improved over the conventional *** the same principle that under the exposure of ultrasound,microbubbles are cavitated and self-assembled into nano-sized particles,and Exo-MBs are self-assembled into exosome membrane proteins-embedded nanoparticles(Exo-NPs).The Exo-NPs showed favorable targeting properties to their original cells.A photosensitizer,chlorin e6,was loaded into Exo-MBs to evaluate therapeutic efficacy as a drug *** higher therapeutic efficacy of photodynamic therapy was confirmed,followed by cancer immunotherapy from immunogenic cell *** have therefore developed a novel ultrasound image-guided drug delivery platform that overcomes the shortcomings of the conventional ultrasound contrast agent and is capable of simultaneous photodynamic therapy and cancer immunotherapy.

关键词： Exosomes Microbubbles Photodynamic therapy Ultrasound Sonoporation Cancer immunotherapy Drug delivery

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Low-density diamondlike amorphous carbon at nanostructured metal-diamond interfaces

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Physical Review materials 2024年第9期8卷 096001页

作者： Brendan McBennett Yuka Esashi Nicholas W. Jenkins Albert Beardo Yunzhe Shao Emma E. Nelson Theodore H. Culman Begoña Abad Michael Tanksalvala Travis D. Frazer Samuel Marks Weilun Chao Sadegh Yazdi Joshua L. Knobloch Henry C. Kapteyn Margaret M. Murnane Department of Physics Materials Science and Engineering Center for X-Ray Optics Renewable and Sustainable Energy Institute and the Materials Science & Engineering Program 4775 Walnut Street #102 Boulder Colorado 80309 USA

Next-generation nanoelectronic, energy, and quantum technologies require increasingly stringent thermal, optical, mechanical, and electrical properties of component materials, often surpassing the limits of widely used materials such as silicon. Diamond, an ultrawide bandgap semiconductor, is a promising material for these applications because of its very high stiffness, thermal conductivity, and electron mobility. However, incorporating diamond into devices that require high-quality metal-diamond interfaces is challenging. In this work, we use a suite of electron microscopy measurements to reveal an ultrathin amorphous carbon layer that emerges at metal-diamond interfaces after electron beam lithography. Using extreme ultraviolet scatterometry, we nondestructively determine lower bounds on the layer's Young's modulus and thermal conductivity, which at >230GPa and >1.1 W/(mK) are indicative of a diamondlike form of amorphous carbon with high sp3 bonding. However, extreme ultraviolet coherent diffractive imaging reflectometry and energy-dispersive x-ray spectroscopy measurements indicate a low and likely inhomogeneous density in the range of 1–2g/cm3. The low density of such a stiff and conductive layer could indicate that it contains nanometer-scale voids or atomic-scale vacancies. The appearance of this unusual layer illustrates the nanofabrication challenges for diamond and highlights the need for better techniques to characterize surfaces and interfaces in nanoscale devices.

关键词： Amorphous materials Diamond Interfaces Thin films Electron energy loss spectroscopy Energy-dispersive x-ray spectroscopy High-harmonic generation Ultrafast femtosecond pump probe X-ray reflectivity

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Anomalous properties of spark plasma sintered boron nitride solids

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materials Today 2025年 86卷 42-51页

作者： Biswas, Abhijit Serles, Peter Alvarez, Gustavo A. Schimpf, Jesse Hache, Michel Kong, Jonathan Demingos, Pedro Guerra Yuan, Bo Pieshkov, Tymofii S. Li, Chenxi Puthirath, Anand B. Gao, Bin Gray, Tia Zhang, Xiang Murukeshan, Jishnu Vajtai, Robert Dai, Pengcheng Singh, Chandra Veer Howe, Jane Zou, Yu Martin, Lane W. Clancy, James Patrick Tian, Zhiting Filleter, Tobin Ajayan, Pulickel M. Department of Materials Science and Nanoengineering Rice University HoustonTX77005 United States Department of Mechanical & Industrial Engineering University of Toronto 5 King's College Road TorontoM5S 3G8 Canada Sibley School of Mechanical and Aerospace Engineering Cornell University IthacaNY14853 United States Department of Materials Science and Engineering University of California Berkeley94720 United States Department of Materials Science and Engineering University of Toronto 184 College St TorontoM5S 3E4 Canada Department of Physics and Astronomy McMaster University HamiltonL8S 4M1 Canada Applied Physics Graduate Program Smalley-Curl Institute Rice University HoustonTX77005 United States Department of Physics and Astronomy Rice University HoustonTX77005 United States Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley94720 United States

Hexagonal boron nitride (h-BN) is a brittle ceramic with a layered structure, however, recent experiments have suggested that inter-layer structural engineering could be key to new structural and functional properties. Here we report the scalable bulk synthesis of high-density crystalline h-BN solids, by using high-temperature spark plasma sintering (SPS) of h-BN powders, which show high values of mechanical strength, ductility, dielectric constant, thermal conductivity, and exceptional neutron radiation shielding capability. Through exhaustive characterizations we reveal that SPS induces non-basal plane crystallinity, twisting of layers, and facilitates inter-grain fusion with a high degree of in-plane alignment across macroscale dimensions, resulting in near-theoretical density and improved properties. Our findings highlight the importance of material design, via new approaches such as layer twisting and interlayer interconnections, to create novel ceramics with properties that could go beyond their intrinsic limits. © 2025

关键词： Ductility

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A Comparative Study of the Effect of Compounding Methods and Processing of PLA/GNPs on the Micromorphology and Electrical Conductivity 38

A Comparative Study of the Effect of Compounding Methods and...

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38th Technical Conference of the American Society for Composites, ASC 2023

作者： Anurakparadorn, Kanat Taub, Alan Department of Materials Science and Engineering Macromolecular Science and Engineering Program University of Michigan 2300 Hayward St Ann ArborMI48109 United States Department of Mechanical Engineering University of Michigan 2350 Hayward St Ann ArborMI48109 United States

ISBN: (纸本)9781605956916

In this work, the effects of different compounding and processing techniques on the DC electrical conductivity and density of polylactic acid (PLA)/graphene nanoplatelets (GNPs) composites were studied. It is found from the study that compounding by solution mixing via an ultrasonication technique can provide slightly higher DC electrical conductivity after compression molding than mixing through a twin-screw extruder due to better dispersion quality. In addition, a composite pellet from twin screw extrusion showed a slight increase in DC electrical conductivity and anisotropy when processed by filament extrusion due to the shear alignment of GNPs during the extrusion. The fused deposition modeling (FDM) process yields high anisotropy because the crystallization along the printing path allows gaps and polymer coating between the extruded lines and layers. It was found that the 7.5 wt% GNPs composites exhibited the best properties because it provides the best dispersion quality to meet the percolation threshold. Furthermore, the micromorphology of each sample was also studied to observe the dispersion and porosity inside the composite provided by each fabrication technique. This study can be used as a reference for compounding and processing techniques. © 2023 by DEStech Publications, Inc. and American Society for Composites. All rights reserved.

关键词： Mixing

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INTER- AND INTRA-LAMINAR PROPERTIES OF AN AFP POST-PROCESSED THERMOPLASTIC COMPOSITE

INTER- AND INTRA-LAMINAR PROPERTIES OF AN AFP POST-PROCESSED...

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SAMPE 2024 Conference and Exhibition

作者： Yap, Timothy S. Heathman, Nathaniel M. Kirchhoff, Joseph G. Tehrani, Mehran Walker Department of Mechanical Engineering The University of Texas at Austin AustinTX United States Department of Structural Engineering University of California La Jolla San DiegoCA United States Program in Materials Science and Engineering University of California La Jolla San DiegoCA United States

ISBN: (纸本)9781934551455

Transitioning to high-performance thermoplastic composites (TPCs) carries great potential due to their enhanced toughness, ease of repairability, and the possibility of bypassing the need for autoclaves that are essential for curing thermosetting composites. Full consolidation of parts may be achieved in-situ using automated fiber placement (AFP) at slow rates;alternatively, with higher rates, consolidation may only occur following vacuum-bag oven processing (vacuum-bag only or VBO) or compression molding (CM) post-processing. This study investigates the CM of AFP carbon fiber LM-PAEK™ composites at a low pressure of 0.2 MPa to simulate VBO post-processing, focusing on their intra- and inter-laminar behavior. Short-beam strength, fracture toughness modes I and II, and transverse tensile and compressive samples were manufactured via AFP using a fast layup rate, followed by low-pressure CM. As compared to previous studies, post-processing resulted in greater interlaminar bonding. This study demonstrates the viability of TPCs for the next generation of aerospace structures with a relatively simple oven post-processing. © 2024 Soc. for the Advancement of Material and Process engineering. All rights reserved.

关键词： Compression molding

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Fluorine-Free Cosolvent Chemistry Empowering Sodium-Sulfurized Polyacrylonitrile Batteries

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Advanced Energy materials 2025年第0期

作者： Pai, Min-Hao Manthiram, Arumugam Materials Science and Engineering Program & Walker Department of Mechanical Engineering The University of Texas at Austin AustinTX78712 United States

Localized high-concentration electrolytes (LHCE) show great promise for room-temperature sodium-sulfur batteries. However, the majority of diluents in LHCE systems consist of fluorinated ethers, which are not only dense and expensive but also demonstrate poor reductive stability with sodium metal. Herein, a low-density, non-fluorinated ether electrolyte is presented that demonstrates localized high-concentration behavior. This feature is driven by the weak solvating capabilities of 1,2-dimethoxypropane (DMP) and the ultra-weak solvating nature of cyclopentyl methyl ether (CPME). Impressively, the fluorine-free CPME cosolvent acts as a diluent within the electrolyte. Therefore, the electrolyte achieves a tailored solvation structure characterized by anion-rich species, which fosters the development of a resilient inorganic-rich SEI with superior Na-ion transport. Consequently, with a high sulfur-content sulfurized polyacrylonitrile (SPAN, S content > 45% in SPAN) loading of 4.4 mg cm⁻2 (sulfur loading: 2 mg cm⁻2) and a low electrolyte-to-SPAN ratio of 9 µL mg⁻¹ (E/SPAN = 9), the Na-SPAN cell demonstrates remarkable reversibility of 530 mA h gsulfur⁻¹ after 200 cycles at C/5 rate. This performance surpasses the majority of state-of-the-art Na-SPAN ether-based electrolyte systems reported to date. Hence, this work presents a novel approach for designing cost-effective, high-performance electrolytes for stable, practical Na-SPAN batteries. © 2025 Wiley-VCH GmbH.

关键词： Sodium-ion batteries

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Sensitivity improvement of fluoroalkylated EUV resist with electron-rich vinyl units 41

Sensitivity improvement of fluoroalkylated EUV resist with e...

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Advances in Patterning materials and Processes XLI 2024

作者： Kim, Gayoung Ku, Yejin Lee, Jin-Kyun Kim, Jiho Park, Byeong-Gyu Lee, Sangsul Jang, Yu Ha Jung, Byung Jun Koh, Chawon Nishi, Tsunehiro Kim, Hyun-Woo Program in Environment and Polymer Engineering Inha University Incheon22212 Korea Republic of Department of Polymer Science and Engineering Inha University Incheon22212 Korea Republic of Pohang Accelerator Laboratory Postech Pohang37673 Korea Republic of Department of Materials Science and Engineering University of Seoul Seoul02504 Korea Republic of Samsung Electronics Co. Ltd. Semiconductor R&d Center Suwon18448 Korea Republic of Department of Materials Science and Engineering Yonsei University Seoul03722 Korea Republic of

ISBN: (纸本)9781510672208

In this study, we present a method to enhance the sensitivity of fluorinated EUV resists by leveraging the rapid coupling reaction between electrophilic carbon radicals and electron-rich alkenes. To validate the impact of the vinyl groups, DVS-HNF was synthesized by introducing fluorinated alkyl chains and silyl vinyl functional groups into the model compound. Additionally, TMS-HNF and EDMS-HNF, which do not contain a vinyl moiety, were synthesized for comparison. To evaluate the patterning properties of the three materials, e-beam lithography experiments were conducted, resulting in the formation of negative-tone patterns for all three materials. Comparing sensitivities, DVS-HNF with two vinyl moieties exhibited the most excellent sensitivity, confirming the effective collaboration between fluorinated alkyl radicals and vinyl groups. After performing an EUV lithography experiment on DVS-HNF, it was confirmed that a 30 nm negative-tone pattern was successfully formed with excellent sensitivity. These results substantiate the potential of the single-component molecular resist for high performance EUV lithography. © COPYRIGHT SPIE. Downloading of the abstract is permitted for personal use only.

关键词： Extreme ultraviolet lithography

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A new class of high-entropy M_(3)B_(4) borides

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Journal of Advanced Ceramics 2021年第1期10卷 166-172页

作者： Mingde QIN Qizhang YAN Yi LIU Jian LUO Department of NanoEngineering Program of Materials Science and EngineeringUniversity of CaliforniaSan DiegoLa JollaCA92093USA

A new class of high-entropy M3B4 borides of the Ta_(3)B_(4)-prototyped orthorhombic structure has been synthesized in the bulk form for the first *** with compositions of(V0.2Cr0.2Nb0.2Mo0.2Ta0.2)3B4 and(V0.2Cr0.2Nb0.2Ta0.2W0.2)_(3)B_(4) were fabricated via reactive spark plasma sintering of high-energy-ball-milled elemental boron and metal *** sintered specimens were〜98.7%in relative densities with virtually no oxide contamination,albeit the presence of minor(4-5 vol%)secondary high-entropy M5B6 *** that Mo_(3)B_(4) or W_(3)B_(4) are not stable phase,20%of M03B4 and W3B4 can be stabilized into the high-entropy M3B4 *** hardness was measured to be 18.6 and 19.8 GPa at a standard load of 9.8 *** work has further expanded the family of different structures of high-entropy ceramics reported to date.

关键词： high-entropy ceramics high-entropy borides reactive sintering spark plasma sintering Ta_(3)B_(4)-prototyped orthorhombic structure

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Revisiting a hidden order at an ferromagnet/antiferromagnet interface and its switching dynamics

Revisiting a hidden order at an ferromagnet/antiferromagnet ...

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2023 IEEE International Magnetic Conference - Short Papers, INTERMAG Short Papers 2023

作者： Yang, Chao-Yao Chen, Sheng-Huai Lai, Chih-Huang National Yang Ming Chiao Tung University Department of Materials Science and Engineering Hsinchu300093 Taiwan National Yang Ming Chiao Tung University Undergraduate Degree Program of Systems Engineering and Technology Hsinchu300093 Taiwan National Tsing Hua University Department of Materials Science and Engineering Hsinchu300044 Taiwan

ISBN: (纸本)9798350338362

Study on the exchange bias (Hex) switching in a ferromagnet (FM)/antiferromagnet (AFM) bilayer driven by the spin-orbit torque (SOT) has been an explicit research field and current focus has been devoted to determining the approaches to drive the Hex switching along with specific SOT applications. Hex is magnetically dominant but only reveals the partial facet of IrMn, which is only responsible for the ferromagnetic component at the interface of AFM. Therefore, the complete facet of AFM and its interaction with SOT at an FM/AFM interface is still not fully uncovered. This research reports an SOT-driven hidden order transition behind Hex in a heavy metal (Pt)/FM (Co)/AFM (IrMn) trilayer along with the issue of switching activity at Co/IrMn interface. The exchange coupling across Co/IrMn interface allows a long-range spin order in the form of an exchange-spring configuration, yielding two kinds of order in IrMn: a canting-induced ferromagnetic order for hosting Hex and a hidden Néel order for preserving the antiferromagnetic nature. The former appears to be strongly coupled to the magnetization state of Co during the SOT switching, so it can be reversibly switched with Co on the Hex switching. On the contrary, the hidden Néel order transition re-orientated to the current direction appears to be irreversibly driven by SOT and independent on the current polarity, which can reflect on the magnetoresistance (MR) measurement and X-ray magnetic linear dichroism (XMLD) spectroscopy. Finally, a micromagnetic simulation reveals the dynamic IrMn spins are mainly based on a canting type interface instead of an uncompensated type via an exchange-spring coupling with Co. © 2023 IEEE.

关键词： Binary alloys

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