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Highly stable hybrid single-micelle:A universal nanocarrier for hydrophobic bioimaging agents

Nano Research 2022年第5期15卷 4582-4589页

作者： Qiaoyu Zhou Tiancong Zhao Mengli Liu Dongrui Yin Minchao Liu Ahmed AElzatahry Fan Zhang Dongyuan Zhao Xiaomin Li Department of Chemistry State Key Laboratory of Molecular Engineering of PolymersiChemShanghai Key Laboratory of Molecular Catalysis and Innovative MaterialsFudan UniversityShanghai 200433China Materials Science and Technology Program College of Arts and SciencesQatar UniversityPO Box 2713DohaQatar

As the first-line technology,micelles play a pivotal role in in vivo delivery of theranostic agents because of their high biocompatibility and ***,in complex physiological environments(extreme dilution,pH,and oxidation or reduction,etc.),they generally suffer from structural instability and insufficient protection for encapsulated *** is urgent to reinforce the structural stability of the micelles at the single-micelle *** using the FDA-approved Pluronic F127 surfactants and indocyanine green(ICG)bioimaging agents as model,herein,we propose the silane-crosslinking assisted strategy to reinforce the structural stability of the *** from the traditional silane hydrolysis under the harsh experimental conditions(acidic,alkaline,and high temperature hydrothermal,etc.),the ICG loaded F127@SiO_(2) hybrid single-micelles(ICG@H-micelles)with controllable sizes(15-35 nm)are synthesized at neutral pH and room temperature,which is crucial for the maintenance of the physicochemical properties of the encapsulated *** the ultra-thin SiO_(2)(<5 nm)at hydrophilic layer of the single-micelle,the structural and fluorescence stability of ICG@H-micelles are much higher than the conventional micelle(ICG@micelles)in the simulated physiological environments of dilution,oxidation or reduction,and low *** of the high structural and fluorescence stability,the ICG@H-micelles also exhibit longer duration time in the tumor and gastrointestinal tract bioimaging.

关键词： micelle SiO_(2) inorganic-organic hybrid mesoporous material bioimaging

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An ultraefficient surface functionalized Ti3C2Tx MXene piezocatalyst: synchronous hydrogen evolution and wastewater treatment

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Journal of materials Chemistry A 2023年第6期12卷 3340-3351页

作者： Lai, Sz-Nian Chen, Winston Yenyu Yen, Chao-Chun Liao, Yin-Song Chen, Po-Han Stanciu, Lia Wu, Jyh Ming Department of Materials Science and Engineering National Tsing Hua University 101 Section 2 Kuang Fu Road Hsinchu300 Taiwan PhD Program in Prospective Functional Materials Industry National Tsing Hua University 101 Section 2 Kuang Fu Road Hsinchu300 Taiwan High Entropy Materials Center National Tsing Hua University 101 Section 2 Kuang Fu Road Hsinchu300 Taiwan Tsing Hua Interdisciplinary Program National Tsing Hua University 101 Section 2 Kuang Fu Road Hsinchu300 Taiwan School of Materials Engineering Purdue University 610 Purdue Mall West LafayetteIN47907 United States Department of Materials Science and Engineering National Chung Hsing University 145 Xingda Road Taichung402 Taiwan

The Ti3C2Tx surface contains hydroxyl groups that can be modified through self-assembled monolayers by using (3-chloropropyl) trimethoxysilane (CPTMS) and fluoroalkylsilane (FOTS). This study demonstrates that an ultrahigh level of piezoelectricity can be achieved by modifying the Si-O bond of organo-silane headgroups in Ti3C2Tx. The theoretical calculation of surface functionalized Ti3C2Tx-FOTS reveals that its Si-O bond causes localized lattice distortion and enhances the noncentrosymmetric structure on the Ti3C2Tx surface. Ti3C2Tx-FOTS exhibits significantly higher butterfly loops than pristine Ti3C2Tx. The calculated rate constant of Ti3C2Tx-FOTS for dye degradation was 0.9 min−1, 15-fold higher than that of Ti3C2Tx-CPTMS and 111-fold higher than that of pristine Ti3C2Tx. The hydrogen evolution rate of Ti3C2Tx-FOTS is 900.46 μmo1 g−1 h−1, three times higher than that of Ti3C2Tx. The bifunctional surface functionalized Ti3C2Tx-FOTS can simultaneously catalyse the hydrogen evolution reaction (HER) and decomposition of wastewater, demonstrating that Ti3C2Tx-FOTS, obtained through the surface engineering of Ti3C2Tx, is a superior piezocatalyst. © 2024 The Royal Society of Chemistry.

关键词： Rate constants

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Method for assessing atomic sources of flicker noise in superconducting qubits

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npj Computational materials 2021年第1期7卷 1502-1507页

作者： Almog Reshef Maytal Caspary Toroker Department of Materials Science and Engineering Technion–Israel Institute of TechnologyHaifaIsrael The Nancy and Stephen Grand Technion Energy Program HaifaIsrael

Flicker noise causes decoherence in Josephson junction-based superconducting qubits,thus limiting their practical potential as building blocks for quantum *** is due to limited length and complexity of executable algorithms,and increased dependency on error-correcting ***,identifying and subsiding the atomic sources of flicker noise are of great importance to the development of this *** developed a method that combines ab initio DFT calculations and quantum dynamics to model charge transport across a Josephson junction,by which it is possible to more accurately assess different defects as sources of flicker *** demonstrate the use of our method in an investigation of various atomic defects,including vacancies,trapping,and substitutions,in an Al|Al_(2)O_(3)|Al Josephson *** demonstration both reveals weaknesses in previous attempts to pinpoint the atomic sources of flicker noise and highlights new candidates.

关键词： Josephson quantum limiting

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Terahertz phonon polariton concentrator based on perovskite oxides

Terahertz phonon polariton concentrator based on perovskite ...

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2023 Conference on Lasers and Electro-Optics, CLEO 2023

作者： Xu, Rui Lin, Tong Luo, Jiaming Chen, Xiaotong Blackert, Elizabeth R. Moon, Alyssa R. JeBailey, Khalil M. Zhu, Hanyu Department of Materials Science and Nano Engineering Rice University Houston United States Applied Physics Graduate Program Rice University Houston United States Program Rice University Houston United States

ISBN: (纸本)9781957171258

We report the experimental demonstration of surface phonon-polaritonic devices in a broad spectral range of 7-13 THz based on SrTiO3. We designed planar ultrafast concentrators that amplifies transient electric field by 6 times and measured an average field of 0.5 GV/m in an optically resolvable area in the far field. © 2023 The Author(s)

关键词： Perovskite

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Temperature-Responsive and Passive Wireless Mechanical Metamaterial Sensors 14

Temperature-Responsive and Passive Wireless Mechanical Metam...

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14th International Workshop on Structural Health Monitoring: Designing SHM for Sustainability, Maintainability, and Reliability, IWSHM 2023

作者： Naidu, Vishnu R. Park, Yujin Loh, Kenneth J. Materials Science and Engineering Program University of California La Jolla San DiegoCA92093 United States Department of Structural Engineering University of California La Jolla San DiegoCA92093 United States

ISBN: (纸本)9781605956930

Knowing the location and environmental conditions of sailors that have fallen overboard can greatly facilitate open water search and rescue operations. Currently, active sensors that trigger an alarm when a sailor falls overboard exist, and it works by detecting a loss of signal from a transmitter. However, their applications have been limited because of the dependence on a working battery, as well as the fact that sailor location cannot be tracked beyond the one-time loss-of-signal event. In this study, a passive, person-overboard sensing concept is proposed, and the focus is to demonstrate monitoring of seawater conditions. The passive sensor was designed by incorporating a temperature-responsive hydrogel with an auxetic star pattern unit cell geometry, which transforms from a two- to three-dimensional geometry when immersed in low temperature liquid. First, the passive sensor was formed by incorporating a temperature-responsive hydrogel at opposite ends of the star pattern. The time-dependent swelling and de-swelling behavior of the copolymer hydrogel was characterized to understand the mechanical strains induced after exposure to low temperature water. Second, the design of the star pattern geometry was optimized, and artificial imperfections in the form of notches were employed to allow shape transformation to take place at appropriate and minimal applied strains. The vision is that these shape morphing structures with integrated antennas can serve as passive sensors, which, when interrogated by a remote reader, can be used to monitor how long overboard sailors have been in a low-temperature open sea environment. © 2023 by DEStech Publi cations, Inc. All rights reserved

关键词： Water temperature

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Density Functional Theory Study of Surface Stability and Phase Diagram of Orthorhombic CsPbI3

arXiv

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arXiv 2024年

作者： Li, Kejia Wang, Mengen Department of Electrical and Computer Engineering and Materials Science and Engineering Program SUNY BinghamtonNY13902 United States

CsPbI3 has been recognized as a promising candidate for optoelectronic device applications. To further improve the efficiency of the devices, it is imperative to better understand the surface properties of CsPbI3, which affect charge carrier transport and defect formation properties. In this study, we perform density functional theory calculations to explore the stability of the (001), (110), and (100) surfaces of orthorhombic CsPbI3, considering different stoichiometries and surface reconstructions. Our results show that, under the chemical potentials confined by the thermodynamically stable region of bulk CsPbI3, the CsI-terminated surfaces of (001) and (110) and the stoichiometric surface of (100) are stable. Among these three surfaces, the CsI-terminated (110) surface has the lowest surface energy and no mid-gap states, which benefits the transport properties of the material. © 2024, CC BY-NC-SA.

关键词： Stoichiometry

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Electronic structure and optical spectra of MSi2N4 (M = Mo, Ta, V) materials with single-atom decoration: a first-principles study

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Journal of materials Chemistry C 2023年第43期11卷 15097-15105页

作者： Wu, Tzu-Cheng Liao, Yin-Song Kao, Jui-Cheng Chou, Jyh-Pin Department of Physics National Tsing Hua University Hsinchu300044 Taiwan The Affiliated Senior High School of National Taiwan Normal University Taipei10658 Taiwan Tsing Hua Interdisciplinary Program National Tsing Hua University Hsinchu300044 Taiwan Department of Materials Science and Engineering National Tsing Hua University Hsinchu300044 Taiwan Department of Materials Science and Engineering National Yang Ming Chiao Tung University Hsinchu30010 Taiwan Department of Physics National Changhua University of Education Changhua50007 Taiwan

MoSi2N4 has outstanding potential for applications in electronics, spintronics, and semiconducting fabrication. This attractive scenario can be attributed to its remarkable electronic properties. In this study, we investigate the electronic structure and optical spectra of the MSi2N4 (M = Mo, Ta, and V) materials with single atom (H, N, and O) decoration using first-principles calculations. Pristine MoSi2N4 and VSi2N4 are semiconductors, and TaSi2N4 shows the half-metal properties. Decorating MoSi2N4 with single hydrogen and nitrogen atoms induces a magnetic moment. Single oxygen decorated TaSi2N4 does not change its intrinsic electronic properties, which is suitable for spintronic applications. On top of that, the semiconductor VSi2N4 can be turned into a half-metal via single hydrogen atom decoration. The absorption spectra demonstrate an enhancement in optical absorption for VSi2N4 after the decoration with a single nitrogen atom. Single atom decoration is one of the effective methods of tailoring the electronic properties of the two-dimensional MoSi2N4 family. Our findings can accelerate the development of the advanced electronic devices. © 2023 The Royal Society of Chemistry.

关键词： Silicon compounds

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In vitro and in vivo study on fine-grained Mg-Zn-RE-Zr alloy as a biodegradeable orthopedic implant produced by friction stir processing

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Bioactive materials 2023年第10期28卷 448-466页

作者： Vasanth C.Shunmugasamy Marwa AbdelGawad Muhammad Umar Sohail Talal Ibrahim Talha Khan Thomas Daniel Seers Bilal Mansoor Mechanical Engineering Program Texas A&M University at QatarEducation CityDohaQatar Department of Mechanical Engineering Texas A&M University3123 TAMUCollege StationTX 77843USA Proteomics Core Weill Cornell MedicineEducation CityDohaQatar Department of Surgery Division of Orthopedic SurgerySidra MedicineDohaQatar Clinical Orthopedic Surgery Weill Cornell MedicineEducation CityDohaQatar Petroleum Engineering Program Texas A&M University at QatarEducation CityDohaQatar Department of Materials Science and Engineering Texas A&M University3003 TAMUCollege StationTX 77843USA

Magnesium alloys containing biocompatible components show tremendous promise for applications as temporary biomedical devices. However, to ensure their safe use as biodegradeable implants, it is essential to control their corrosion rates. In concentrated Mg alloys, a microgalvanic coupling between the α-Mg matrix and secondary precipitates exists which results in increased corrosion rate. To address this challenge, we engineered the microstructure of a biodegradable Mg-Zn-RE-Zr alloy by friction stir processing (FSP), improving its corrosion resistance and mechanical properties simultaneously. The FS processed alloy with refined grains and broken and uniformly distributed secondary precipitates showed a relatively uniform corrosion morphology accompanied with the formation of a stable passive layer on the alloy surface. In vivo corrosion evaluation of the processed alloy in a small animal model showed that the material was well-tolerated with no signs of inflammation or harmful by-products. Remarkably, the processed alloy supported bone until it healed till eight weeks with a low in vivo corrosion rate of 0.7 mm/year. Moreover, we analyzed blood and histology of the critical organs such as liver and kidney, which showed normal functionality and consistent ion and enzyme levels, throughout the 12- week study period. These results demonstrate that the processed Mg-Zn-RE-Zr alloy offers promising potential for osseointegration in bone tissue healing while also exhibiting controlled biodegradability due to its engineered microstructure. The results from the present study will have profound benefit for bone fracture management, particularly in pediatric and elderly patients.

关键词： Biodegradable magnesium Bone healing Friction stir processing Microstructure Corrosion resistance

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Control of skyrmion lattice order in the van der Waals ferromagnet Fe3GeTe2 16

Control of skyrmion lattice order in the van der Waals ferro...

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Spintronics XVI 2023

作者： Li, Yue McCray, Arthur R.C. Wang, Wei Basnet, Rabindra Pandey, Krishna Ma, Xuedan Hu, Jin Petford-Long, Amanda K. Phatak, Charudatta Materials Science Division Argonne National Laboratory LemontIL60439 United States Applied Physics Program Northwestern University EvanstonIL60208 United States Center for Nanoscale Materials Argonne National Laboratory LemontIL60439 United States Department of Physics University of Arkansas FayettevilleAR72701 United States Materials Science and Engineering Program University of Arkansas FayettevilleAR72701 United States Department of Materials Science and Engineering Northwestern University EvanstonIL60208 United States

ISBN: (纸本)9781510665262

Van der Waals ferromagnets are an intersting class of materials for exploring fundamental physics of magnetic order in the 2D limit as well as for technological applicaitons due to possibility of creating novel heterostructures. These materials have shown to host magnetic skyrmion lattices with their organization controlled by the magnetic properties such as anisotropy, exchange, and Dzyaloshinkii-Moriya interaction. For technological applications, it is also necessary to understand to the behavior of skyrmions in response to electric currents. In this work, we show the effect of electric current pulses on the magnetic skyrmions formed in Fe3GeTe2which has a Curie temperature of 220 K. We demonstrate via real-space in situ imaging using Lorentz transmission electron microscopy (LTEM) the effect of temperture and pulse width. © 2023 SPIE.

关键词： High resolution transmission electron microscopy

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Two-dimensional MXenes:New frontier of wearable and flexible electronics

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InfoMat 2022年第4期4卷 1-28页

作者： Abbas Ahmed Sudeep Sharma Bapan Adak Md Milon Hossain Anna Marie LaChance Samrat Mukhopadhyay Luyi Sun Polymer Program Institute of Materials ScienceUniversity of ConnecticutStorrsConnecticutUSA Advanced Sensor and Energy Research(ASER)Lab Department of Electronic EngineeringKwangwoon UniversitySeoulSouth Korea Department of Textile and Fiber Engineering Indian Institute of TechnologyNew DelhiIndia Department of Textile Engineering Chemistry and ScienceNorth Carolina State UniversityRaleighNorth CarolinaUSA Department of Textile Engineering Khulna University of Engineering&TechnologyKhulnaBangladesh Department of Chemical and Biomolecular Engineering University of ConnecticutStorrsConnecticutUSA

Wearable electronics offer incredible benefits in mobile healthcare monitoring,sensing,portable energy harvesting and storage,human-machine interactions,etc.,due to the evolution of rigid electronics structure to flexible and stretchable ***,transition metal carbides and nitrides(MXenes)are highly regarded as a group of thriving two-dimensional nanomaterials and extraordinary building blocks for emerging flexible electronics platforms because of their excellent electrical conductivity,enriched surface functionalities,and large surface *** article reviews the most recent developments in MXene-enabled flexible electronics for wearable *** MXeneenabled electronic devices designed on a nanometric scale are highlighted by drawing attention to widely developed nonstructural attributes,including 3D configured devices,textile and planer substrates,bioinspired structures,and printed ***,the unique progress of these nanodevices is highlighted by representative applications in healthcare,energy,electromagnetic interference(EMI)shielding,and humanoid control of *** emerging prospects of MXene nanomaterials as a key frontier in nextgeneration wearable electronics are envisioned and the design challenges of these electronic systems are also discussed,followed by proposed solutions.

关键词： flexible electronics MXene nanostructures wearable electronics

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