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Mo-terminated edges in two-dimensional molybdenum disulfide for site-specific hydrolysis and DNA cleavage

materials Today 2025年 86卷 162-171页

作者： Wang, Cong Wu, Menghan Li, Muqing Zhao, Yingcan Zhao, Mingchuang Zhang, Yunhao Bai, Yichao Gao, Jianxiang Wang, Xiaoxia Tian, Xilin Zhang, Han Chang, Liang Zou, Xiaolong Liu, Bilu Kang, Feiyu Terrones, Mauricio Lei, Yu Institute of Materials Research Shenzhen Key Laboratory of Advanced Layered Materials for Value-added Applications Guangdong Provincial Key Laboratory of Thermal Management Engineering and Materials & Center of Double Helix Tsinghua Shenzhen International Graduate School Tsinghua University Shenzhen518055 China Institute of Materials Research & Shenzhen Geim Graphene Center Shenzhen Key Laboratory of Advanced Layered Materials for Value-added Applications Tsinghua-Berkeley Shenzhen Institute and Tsinghua Shenzhen International Graduate School Tsinghua University Shenzhen518055 China Environmental Science Program Department of Life Sciences Beijing Normal University-Hong Kong Baptist University United International College Guangdong519087 China Tsinghua Shenzhen International Graduate School Tsinghua University Shenzhen518055 China Department of Physics Department of Chemistry Department of Materials Sciences Center for 2-Dimensional and Layered Materials The Pennsylvania State University University ParkPA16802 United States International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education Institute of Microscale Optoelectronics Shenzhen University Shenzhen518060 China

The hydrolysis of DNA serves as the foundational principle for gene engineering that enable precise gene cleavage at the molecular level. This process typically occurs in biological nucleases, which exhibit nucleobase-selective and catalytic hydrolysis capabilities rarely replicated in abiotic nanomaterials. Here, we demonstrate that molybdenum-terminated (Mo-terminated) edges of molybdenum disulfide (MoS2) possess the unique ability to abstract a proton (H+) from water molecules, thereby facilitating catalytic hydrolysis reactions that cleave the phosphodiester bonds in DNA through the action of hydroxide ions. The enhanced proton absorption at Mo-terminated edges of MoS2 significantly reduces the activation energy required for the DNA hydrolysis reaction. Furthermore, the favorable interaction between the Mo-terminated edges and thymine nucleobases promotes both charge transfer and P-O bond cleavage, enabling targeted DNA hydrolysis at 'TTTTTTT' sequences under dark conditions. This discovery underscores the potential of MoS2 as a stable, efficient nanosystem for precise genetic editing, heralding advanced applications in the field of gene engineering. © 2025 The Author(s)

关键词： Activation energy

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Study Of The Influence Of Milling Time On The Synthesis Temperature Of Monoclinic And Orthorhombic Nanostructured Cunb2o6 Via High-Energy Milling

Study Of The Influence Of Milling Time On The Synthesis Temp...

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Euro Powder Metallurgy 2023 Congress and Exhibition, PM 2023

作者： Gomes, Uilame Umbelino de Araújo, Kívia Fabiana Galvão José, Maria Lima, Santos De Souza, Vitor Manoel Silva Fernandes da Silva Lourenço, Cléber Raimundo, Rafael Alexandre Materials Science and Engineering Postgraduate Program Federal University of Rio Grande do Norte Natal59078-970 Brazil Department of Physics Federal University of Paraíba João Pessoa58051-900 Brazil

Copper niobate (CuNb2O6) has been studied for technological and environmental applications, such as in solar cells and photocatalysts, for example. And to make the application of CuNb2O6 even more feasible, in this study, therefore, high-energy milling was applied in its synthesis process with variation in the milling time, from the precursor powders Nb2O5 and CuO. The calcination occurred in a muffle with temperatures in the range of 500 °C to 1000 °C, for 3 h and heating rate of 5 °/min. Then, the powders were characterized by XRD, SEM, EDS and Raman. The powders showed crystallite sizes smaller than 80 nm, good homogeneity and high purity. The particle morphologies and the Raman spectrum are coherent with the literature. It was also verified that the increase in milling time reduced the initial formation temperature of the monoclinic phase and the calcination time for the complete formation of the orthorhombic phase. © European Powder Metallurgy Association (EPMA)

关键词： Mechanical alloying

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Improving self-healing characteristics of polyurethane composite coatings by surface modification of polyaniline using dodecylamine

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engineering Failure Analysis 2025年 176卷

作者： Ahmad, Shoaib Nawaz, Muddasir Mohammad, Solaiman Al-Qahtani, Noora Kahraman, Ramazan Mansoor, Bilal Shakoor, R.A. Qatar University Doha2713 Qatar Materials Science & Technology Program College of Arts & Sciences Qatar University Doha2713 Qatar Department of Mechanical and Industrial Engineering Qatar University Doha2713 Qatar Department of Chemical Engineering College of Engineering Qatar University Doha2713 Qatar Qatar University Doha2713 Qatar Department of Materials Science and Engineering Texas A&M University College Station United States

Corrosion is one of the most critical problems affecting the structural integrity of metals. Polymeric nanocomposite coatings reinforced with anti-corrosive pigments are currently being used to mitigate corrosion. This study involves the synthesis of polyaniline (PANI) nanoparticles and their modification with dodecylamine (DOC), which functions as a corrosion inhibitor. Polyurethane coatings (PU-PANI@DOC) were developed by incorporating modified nanoparticles (PANI@DOC) into the polyurethane matrix, and blank polyurethane coatings (PU-blank) were prepared without any nanoparticles. Fourier-transform infrared spectroscopy (FTIR), Transmission electron microscopy, and Scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM/EDX) analysis confirmed the successful modification of dodecylamine (DOC) with the surface of polyaniline (PANI) nanoparticles. The electrochemical impedance spectroscopy (EIS) and salt spray test (SST) revealed that the impedance values of the modified coating follow an inclined trend (1010 Ω.cm2) in comparison with PU-blank coatings (107 Ω.cm2) after the 14th day of immersion in 3.5 wt% NaCl. Moreover, the hydrophobic characteristics of PANI@DOC nanoparticles shift the contact angle from 60° to 90°, thus lowering the wettability nature of modified coatings. Overall, Polyurethane coatings (PU-PANI@DOC) exhibiting potential attributes such as barrier properties, hydrophobic nature, inhibition effect, and high compatibility with polyurethane matrix can be a suitable material for the development of smart self-healing coatings to protect the metals from the hostile effects of corrosion. © 2025 Elsevier Ltd

关键词： Fourier transform infrared spectroscopy

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Cr-modified CuAlBe shape memory alloy: Role of microstructure, thermodynamic parameters, superelasticity, dissipated energy and corrosion resistance

Journal of Alloys and Metallurgical Systems

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Journal of Alloys and Metallurgical Systems 2024年 7卷

作者： Silva, David D.S. Candido, Gemierson V.M. Alves, Ricardo F. Dias, Elisabeth A.M.G.S. Oliveira, Danniel F. Federal University of São Carlos Graduate Program in Materials Science and Engineering SP São Carlos13565-905 Brazil Colorado School of Mines George S. Ansell Department of Metallurgical and Materials Engineering GoldenCO80401 United States Federal University of Paraíba Graduate Program in Mechanical Engineering PB João Pessoa58051-900 Brazil Federal University of Rio Grande do Norte Graduate Program in Materials Science and Engineering RN Natal59078-970 Brazil Federal University of Paraíba Graduate Program in Materials Science and Engineering PB João Pessoa58051-900 Brazil

This study reports the effects of Cr addition on the microstructure, superelasticity and corrosion resistance improvement of CuAlBe shape memory alloy. Analysis via structural, morphological, thermal, mechanical and electrochemical characterizations were performed. The analyses revealed austenite as the stable phase at room temperature for all samples. The increase in the Cr content caused a slight increase in the recovery rate and dissipated energy. Electrochemical results demonstrate that a small addition of Cr (0.1–0.3 wt%) increase the corrosion resistance due the decreases of the corrosion current density and increase of the corrosion potential. © 2024 The Authors

关键词： Corrosion resistance

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Experimental and numerical investigation into the non-explosive excavation of tunnels

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Journal of Rock Mechanics and Geotechnical engineering 2022年第6期14卷 1885-1900页

作者： Quan Zhang Zhigang Tao Chun Yang Shan Guo Manchao He Chongyuan Zhang Huiya Niu Chao Wang Shen Wang School of Mines China University of Mining and TechnologyXuzhouJiangsu221116China State Key Laboratory of Geomechanics and Deep Underground Engineering China University of Mining and TechnologyBeijing100083China School of Resources and Safety Engineering Central South UniversityChangsha410083China Department of Mining and Materials Engineering McGill UniversityMontrealQCH3A 0E8Canada Institute of Geomechanics Chinese Academy of Geological SciencesBeijing100081China College of Environmental Science and Engineering Ocean University of ChinaQingdao266100China School of Energy Science and Engineering Henan Polytechnic UniversityJiaozuo454003China

The use of explosives is restricted on some important holidays,and the handling of unexploded charge is very ***,an innovative non-explosive technology called instantaneous expansion(IE)was developed for ***,whose components are derived from solid wastes such as coal gangue and straw conduces to realizing the reuse of ***,its cost is lower than *** guns of IE are easy to treat with *** IE tunneling method is classified into two categories,*** with a single fracture(IESF)and IE with multiple fractures(IEMF),which are used to form the tunnel crosssection directionally cross-section and to fragment the rocks inside the cross-section,*** this study,the principle of IE tunneling was elaborated ***,tunneling experiments and numerical simulations were performed on IE,conventional blasting(CB)and shaped charge blasting(SCB)in *** experimental and numerical results show that IE achieved the best performance of directional rock breaking and corresponded to the most minor excavation-induced damage zone of the surrounding ***,the tunnel cross-section created by IE was flat and *** IE with CB and SCB,the over/under-excavation area decreased by 64%and 17%,and the excavation-induced damage zone fell by 26%and 11%,*** range of the loose circle is reduced,which is conducive to improving the long-term stability of the *** research provides a safe and economical tunneling method with excellent application prospects.

关键词： Instantaneous expansion(IE) Non-explosive Tunneling Smooth tunnel cross-section Excavation-induced damage zone

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Grating Coupled Attachment of Optical Fiber Arrays for in situ Photonics Experimentation

Grating Coupled Attachment of Optical Fiber Arrays for in si...

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2024 Conference on Lasers and Electro-Optics, CLEO 2024

作者： Arnold, Kellen P. Slaby, Joel B. Dattilo, Hannah M. Kaylor, C. Alex Schrimpf, Ronald D. Fleetwood, Daniel M. Ralph, Stephen E. Reed, Robert Weiss, Sharon M. Interdisciplinary Materials Science Program Vanderbilt University 2201 West End Ave NashvilleTN37235 United States School of Electrical and Computer Engineering Georgia Institute of Technology AtlantaGA30332 United States Department of Electrical and Computer Engineering Vanderbilt University 2201 West End Ave NashvilleTN37235 United States

We report a simple, vacuum-compatible fiber attach process for in situ study of grating-coupled photonic devices. The robustness of this technique is demonstrated on grating-coupled waveguides exposed to multiple X-ra... 详细信息

ISBN: (纸本)9781957171395

关键词： X ray lasers

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Flexoelectric Catalysts Based on Hierarchical Wrinkling Surface of Centrosymmetric High-Entropy Oxide

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ACS Nano 2023年第17期17卷 17417-17426页

作者： Wu, Ping Yun Le, Kim Tuyen Lin, Hsun-Yen Chen, Yu-Ching Wu, Po-Han Wu, Jyh Ming Department of Materials Science and Engineering National Tsing Hua University 101 Section 2 Kuang Fu Road Hsinchu300 Taiwan High Entropy Materials Center National Tsing Hua University 101 Section 2 Kuang Fu Road Hsinchu300 Taiwan Ph.D. Program in Prospective Functional Materials Industry National Tsing Hua University 101 Section 2 Kuang Fu Road Hsinchu300 Taiwan

A high-entropy oxide nanocomposite with Ag(CuZn)(AlCr)2O4 and CuO phases is fabricated to form an abundantly hierarchical wrinkled surface. Application of a mechanical force to the nanocomposite resulted in a nonhomogeneous strain gradient at the interface between the Ag(CuZn)(AlCr)2O4 and CuO phases, changing the local charge distribution and creating flexoelectric polarization that delayed electron/hole recombination. Transmission electron microscopy energy-dispersive X-ray spectroscopy mapping revealed that the Ag, Cu, Zn, Al, Cr, and O elements were highly distributed throughout the nanocomposite. The nanocomposite produced 2116 μmol·g-1 h-1 of H2 without external light irradiation, which is 980% higher than the H2 produced by the same nanocomposite under the photocatalytic process. A strong electrical field is observed at the interface between the Ag(CuZn)(AlCr)2O4 and CuO phases, demonstrating that a flexoelectric potential (flexopotential) is established at the structural boundaries because the strain gradient is localized at these interfaces. The nanocomposite is a promising approach for environmentally friendly energy production. © 2023 American Chemical Society.

关键词： Nanocomposites

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Grating Coupled Attachment of Optical Fiber Arrays for in situ Photonics Experimentation

Grating Coupled Attachment of Optical Fiber Arrays for in si...

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CLEO: Applications and Technology in CLEO 2024, CLEO: A and T 2024 - Part of Conference on Lasers and Electro-Optics

关键词： Photonic devices

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Imaging atomic-scale chemistry from fused multi-modal electron microscopy

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npj Computational materials 2022年第1期8卷 164-171页

作者： Jonathan Schwartz Zichao Wendy Di Yi Jiang Alyssa J.Fielitz Don-Hyung Ha Sanjaya D.Perera Ismail El Baggari Richard D.Robinson Jeffrey A.Fessler Colin Ophus Steve Rozeveld Robert Hovden Department of Materials Science and Engineering University of MichiganAnn ArborMIUSA Mathematics and Computer Science Division Argonne National LaboratoryLemontILUSA Advanced Photon Source Facility Argonne National LaboratoryLemontILUSA Dow Chemical Co. MidlandMIUSA Department of Material Science and Engineering Cornell UniversityIthacaNew YorkUSA School of Integrative Engineering Chung-Ang UniversitySeoulRepublic of Korea Department of Physics Cornell UniversityIthacaNYUSA The Rowland Institute at Harvard CambridgeMAUSA Department of Electrical Engineering and Computer Science University of MichiganAnn ArborMIUSA National Center for Electron Microscopy Lawrence Berkeley National LaboratoryMolecular FoundryBerkeleyCAUSA Applied Physics Program University of MIchiganAnn ArborMIUnited States

Efforts to map atomic-scale chemistry at low doses with minimal noise using electron microscopes are fundamentally limited by inelastic ***,fused multi-modal electron microscopy offers high signal-to-noise ratio(SNR)recovery of material chemistry at nano-and atomic-resolution by coupling correlated information encoded within both elastic scattering(high-angle annular dark-field(HAADF))and inelastic spectroscopic signals(electron energy loss(EELS)or energy-dispersive x-ray(EDX)).By linking these simultaneously acquired signals,or modalities,the chemical distribution within nanomaterials can be imaged at significantly lower doses with existing detector *** many cases,the dose requirements can be reduced by over one order of *** high SNR recovery of chemistry is tested against simulated and experimental atomic resolution data of heterogeneous nanomaterials.

关键词： materials chemistry fused

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Robust training of machine learning interatomic potentials with dimensionality reduction and stratified sampling

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npj Computational materials 2024年第1期10卷 2796-2806页

作者： Ji Qi Tsz Wai Ko Brandon C.Wood Tuan Anh Pham Shyue Ping Ong Materials Science and Engineering Program University of California San Diego9500 Gilman DrLa JollaCA 92093-0448USA Quantum Simulations Group Lawrence Livermore National LaboratoryLivermoreCA 94550USA Department of NanoEngineering University of California San Diego9500 Gilman DrLa JollaCA 92093-0448USA Laboratory for Energy Applications for the Future(LEAF) Lawrence Livermore National LaboratoryLivermoreCA 94550USA

Machine learning interatomic potentials(MLIPs)enable accurate simulations of materials at scales beyond that accessible by ab initio methods and play an increasingly important role in the study and design of ***,MLIPs are only as accurate and robust as the data on which they are ***,we present DImensionality-Reduced Encoded Clusters with sTratified(DIRECT)sampling as an approach to select a robust training set of structures from a large and complex configuration *** applying DIRECT sampling on the materials Project relaxation trajectories dataset with over one million structures and 89 elements,we develop an improved materials 3-body graph network(M3GNet)universal potential that extrapolates more reliably to unseen *** further show that molecular dynamics(MD)simulations with the M3GNet universal potential can be used instead of expensive ab initioMDto rapidly create a large configuration space for target *** combined this scheme with DIRECT sampling to develop a reliable moment tensor potential for titanium hydrides without the need for iterative augmentation of training *** work paves the way for robust high-throughput development of MLIPs across any compositional complexity.

关键词： stratified potential titanium

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