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Glycerol Electrooxidation over Precision-Synthesized Gold Nanocrystals with Different Surface Facets

Precision Chemistry 2024年第3期2卷 103-111页

作者： Hansen Mou Fang Lu Zechao Zhuang Qiaowan Chang Lihua Zhang Xiaobo Chen Yugang Zhang Jingguang G.Chen Department of Chemical Engineering Columbia UniversityNew YorkNew York 10027United States School of Chemical Engineering and Bioengineering Washington State UniversityPullmanWashington 99164United States Center for Functional Nanomaterials Brookhaven National LaboratoryUptonNew York 11973United States Materials Science and Engineering Program State University of New York at BinghamtonBinghamtonNew York 13902United States Chemistry Division Brookhaven National LaboratoryUptonNew York 11973United States

Electrochemical glycerol oxidation(EGO)emerges as a promising route to valorize glycerol,an underutilized byproduct from biodiesel production,into value-added *** study employed three types of gold(Au)nanocrystals with controlled shapes to elucidate the facet-dependent electrocatalytic behavior in ***,rhombic dodecahedral,and cubic Au nanocrystals with{111},{110},and{100}facets,respectively,were precisely synthesized with uniform size and *** dodecahedra exhibited the lowest onset potential for EGO due to facile AuOH formation,while octahedra showed enhanced electrochemical activity for glycerol oxidation and resistance to ***-situ FTIR analysis revealed that Au{111}surfaces selectively favored C_(2) products,whereas Au{100}surfaces promoted C_(3) product formation,highlighting the significant effect of facet orientation on EGO performance and informing catalyst design.

关键词： Electrochemical glycerol oxidation Precision synthesis Shaped nanocrystals Au nanocrystals SAXS In-situ FTIR

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Tuning Zinc-Copper Dual-Ion Electrolytes to Extend the Cycle Life of Zinc Ion Capacitors

Tuning Zinc-Copper Dual-Ion Electrolytes to Extend the Cycle...

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International Flexible Electronics Technology Conference (IFETC)

作者： Jinwook Jung Chanho Shin Tse Nga Ng Program in Materials Science and Engineering University of California San Diego La Jolla USA Department of Electrical and Computer Engineering University of California San Diego La Jolla USA

ISBN: (数字)9798331529468

ISBN: (纸本)9798331529475

We investigated the effect of copper ion concentration in zinc-copper dual-ion electrolytes to suppress dendrites and extend the cycle life of zinc ion capacitors. The devices were characterized in terms of changes in microstructure and cycling stability. The nuclei size was decreased in the optimal copper ion concentration to promote lateral deposition and avoid vertical dendrites. The device exhibited stable cycling performance with a capacitance retention of 95% after 10,000 redox cycles, compared to the device with single zinc ion electrolyte which short circuited at around 1,250 redox cycles.

关键词： Performance evaluation Capacitors Redox Ions Electrolytes Dendrites (neurons) Copper Microstructure Zinc Tuning

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Microporous polyimine membranes for efficient separation of liquid hydrocarbon mixtures

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science (New York, N.Y.) 2025年第6749期388卷 839-844页

作者： Tae Hoon Lee Marcel Balcik Zain Ali Taigyu Joo Matthew P Rivera Ingo Pinnau Zachary P Smith Department of Chemical Engineering Massachusetts Institute of Technology Cambridge MA USA. Department of Future Energy Engineering Sungkyunkwan University Suwon Republic of Korea. Advanced Membranes and Porous Materials Center Chemical Engineering Program Physical Science and Engineering Division King Abdullah University of Science and Technology Thuwal Saudi Arabia. Osmoflo Water Management Pty Ltd. Burton SA Australia.

Interfacial polymerization has been an industrial standard for preparing desalination membranes. Extending the same concept to molecular separation of organic solvents would be a key enabler for the decarbonization of the chemical and petrochemical industries through energy-efficient crude or biocrude oil fractionation. Here, we report a molecular engineering approach based on acid-catalyzed interfacial polymerization for efficient hydrocarbon separation. The design strategies include (i) changing the linkage from amide to imine and (ii) subsequent introduction of shape-persistent units such as triptycene and spirobifluorene. The prepared polyimine membranes exhibit ultrahigh microporosity and enhanced swelling and plasticization resistance compared with conventional polyamide counterparts. These membranes, which feature fast and selective transport of hydrocarbons, including multicomponent and industrially relevant mixtures, outperform commercial and state-of-the-art benchmark membranes.

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Multi-objective parametrization of interatomic potentials for large deformation pathways and fracture of two-dimensional materials

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npj Computational materials 2021年第1期7卷 1042-1052页

作者： Xu Zhang Hoang Nguyen Jeffrey T.Paci Subramanian K.R.S.Sankaranarayanan Jose L.Mendoza-Cortes Horacio D.Espinosa Theoretical and Applied Mechanics Program Northwestern UniversityEvanstonILUSA Department of Chemistry University of VictoriaVictoriaBCCanada Center for Nanoscale Materials Argonne National LaboratoryLemontILUSA Department of Chemical Engineering&Materials Science Michigan State UniversityEast LansingMIUSA Department of Mechanical Engineering Northwestern UniversityEvanstonILUSA

This investigation presents a generally applicable framework for parameterizing interatomic potentials to accurately capture large deformation *** incorporates a multi-objective genetic algorithm,training and screening property sets,and correlation and principal component *** framework enables iterative definition of properties in the training and screening sets,guided by correlation relationships between properties,aiming to achieve optimal parametrizations for properties of ***,the performance of increasingly complex potentials,Buckingham,Stillinger-Weber,Tersoff,and modified reactive empirical bond-order potentials are *** MoSe_(2)as a case study,we demonstrate good reproducibility of training/screening properties and superior *** MoSe_(2),the best performance is achieved using the Tersoff potential,which is ascribed to its apparent higher flexibility embedded in its functional *** results should facilitate the selection and parametrization of interatomic potentials for exploring mechanical and phononic properties of a large library of two-dimensional and bulk materials.

关键词： materials apparent enable

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Elevated temperature-driven coordinative reconstruction of an unsaturated single-Ni-atom structure with low valency on a polymer-derived matrix for the electrolytic oxygen evolution reaction

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Nanoscale 2024年第15期16卷 7467-7479页

作者： Patil, Rahul Rajput, Anubha Matsagar, Babasaheb M. Chen, Norman C. R. Ujihara, Masaki Salunkhe, Rahul R. Yadav, Praveen Wu, Kevin C.-W. Chakraborty, Biswarup Dutta, Saikat Electrochemical Energy & Sensor Research Laboratory Amity Institute of Click Chemistry Research & Studies Amity University Noida India Department of Chemistry Indian Institute of Technology New Delhi India Department of Chemical Engineering National Taiwan University Taipei10617 Taiwan Molecular Science and Technology Program Taiwan International Graduate Program Academia Sinica Taiwan National Taiwan University Taiwan Graduate Institute of Applied Science and Technology National Taiwan University of Science and Technology Taipei Taiwan Materials Research Laboratory Department of Physics Indian Institute of Technology Jammu India Synchrotron X-ray Facility Raja Ramanna Centre for Advanced Technology Rajendra Nagar Madhya Pradesh 452013 Indore India

A high-temperature pyrolysis-controlled coordination reconstruction resulted in a single-Ni-atom structure with a Ni-Nx-C structural unit (x = N atom coordinated to Ni). Pyrolysis of Ni-phen@ZIF-8-RF at 700 °C resulted in NiNP-NC-700 with predominantly Ni nanoparticles. Upon elevating the pyrolysis temperature from 700 to 900 °C, a coordination reconstruction offers Ni-Nx atomic sites in NiSA-NC-900. A combined investigation with X-ray absorption spectroscopy, X-ray photoelectron spectroscopy, and soft X-ray L3-edge spectroscopy suggests the stabilization of low-valent Niδ+ (0 −2 was achieved. The cell potential recorded with Pt(−)/(+)NiSA-NC-900/NF was much lower than that obtained for other cells, i.e., Pt(−)/NF and NF(−)/(+)NF, which enhances the potentials of low-valent NiSAs for insightful understanding of the OER. At a constant applied potential of 1.61 V (vs. RHE) for 12 h, an small increase in current for initial 0.6 h followed by a constant current depicts the fair stability of catalyst for 12 h. Our results offer an insightful angle into the OER with a coordinatively reconstructed single-Ni-atom structure at lower valency ( © 2024 The Royal Society of Chemistry.

关键词： Reaction kinetics

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Green Synthesis of Hierarchical Ag Nanostructures for Sers Detection of Rhodamine Dye

SSRN

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SSRN 2024年

作者： Sayson, Luce Vida A. Taaca, Kathrina Lois M. Madera, Rozen Grace B. Vasquez, Magdaleno R. Regulacio, Michelle D. Materials Science and Engineering Program College of Science University of the Philippines Diliman Quezon City1101 Philippines Department of Mining Metallurgical and Materials Engineering College of Engineering University of the Philippines Diliman Quezon City1101 Philippines Institute of Chemistry College of Science University of the Philippines Diliman Quezon City1101 Philippines

This study presents a simple benchtop synthetic protocol for the fabrication of silver (Ag) nanostructures in aqueous media using environmentally friendly and inexpensive reagents under mild experimental conditions. Natural organic acids that are known to be present in plants were employed as reducing and morphology-directing reagents. SEM and TEM imaging revealed that the resultant nanostructures are three-dimensional hierarchical structures that were formed from self-assembly of smaller nanoparticles. They are generally spherical in shape and possess highly roughened surfaces due to the interstitial gaps between their nanoparticle subunits. Their hierarchical architecture allows for strong absorption of light in a broad range of wavelengths that extends to the near-infrared region. In addition, their surface morphology has an abundance of hot spot regions, which are capable of inducing strong SERS enhancement effects. The green-synthesized Ag nanostructures showed remarkable SERS activity when used as substrates for the detection of rhodamine 6G dye, a highly toxic water contaminant. Overall, this study does not only provide a greener approach to hierarchical Ag nanostructures, but also demonstrates theimmense potential of these nanostructures in the sensitive detection of organic dyepollutants. © 2024, The Authors. All rights reserved.

关键词： Substrates

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Saturable intercalation doping enables scalable and selective graphene gas sensors on plastic

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Chemical engineering Journal 2025年 515卷

作者： Kwon, Bitnuri Lee, Jung Hun Jo, Sae Byeok Hwang, Jinhyun Lee, Donggeun Cha, Jonghyun Lim, Soomook Suk, Ji Won Lee, Wi Hyoung Department of Organic and Nano System Engineering Konkuk University Seoul05029 Cuba Department of Materials Science and Engineering and the Materials Research Center Northwestern University 2220 Campus Drive EvanstonIL60208-3108 United States School of Chemical Engineering Sungkyunkwan University Suwon16419 Cuba Sungkyunkwan University Suwon16419 Cuba Advanced Materials Program Department of Materials Science and Engineering Konkuk University Seoul05029 Cuba School of Mechanical Engineering Sungkyunkwan University Suwon16419 Cuba Department of Smart-Fab. Technology Sungkyunkwan University Suwon16419 Cuba Department of Materials Science and Engineering Konkuk University Seoul05029 Cuba

Developing highly sensitive and selective gas sensors for nitrogen dioxide (NO2) detection remains crucial for environmental monitoring and public health protection. Graphene-based chemiresistive sensors show promise due to their exceptional electronic properties and high surface area, which enhance gas adsorption. However, they face persistent challenges in selectivity, stability, and sensitivity characteristics. This study presents a facile one-step molecular intercalation doping approach that can effectively overcome these limitations. By intercalating carefully selected dopant molecules between graphene and flexible substrates during the wet-transfer process, we achieve uniform doping distribution while maintaining intrinsic carrier mobility. The resulting sensors demonstrate remarkable NO2 detection capabilities with a limit of detection of 1 ppb at room temperature. Importantly, the intercalated devices exhibit exceptional stability over extended periods of time and show minimal cross-sensitivity to common interfering gases. Moreover, the sensors retain their sensing characteristics under mechanical deformation, including fully transparent gas sensors with a dogbone structure, thereby enabling seamless integration into wearable monitoring systems. Our scalable fabrication process and comprehensive understanding of the intercalation doping mechanism provide a practical pathway for the development of reliable, flexible gas sensors capable of addressing real-world environmental and healthcare challenges. © 2025 Elsevier B.V.

关键词： pH sensors

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Color-fast semi-transparent organic photovoltaics 25

Color-fast semi-transparent organic photovoltaics

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Organic Photonic materials and Devices XXV 2023

作者： Sheriff, Hafiz K.M. Li, Yongxi Forrest, Stephen R. Applied Physics Program University of Michigan Ann ArborMI48109 United States Department of Electrical Engineering University of Michigan Ann ArborMI48109 United States Department of Materials Science and Engineering University of Michigan Ann ArborMI48109 United States Department of Physics University of Michigan Ann ArborMI48109 United States

ISBN: (纸本)9781510659414

Equipping buildings with energy harvesting windows is a practical way to reduce greenhouse gas (GhG) emission. Utilizing semi-transparent organic photovoltaics (ST-OPVs) for this application requires the device to be colorfast, allowing for no change in the aesthetics or light harvesting property of the window. Here, we demonstrate an ST-OPV that is colorfast under 1 Sun AM 1.5G illumination at 50 °C and relative humidity of 34 %. © 2023 SPIE.

关键词： Energy harvesting

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Adult dental epithelial stem cell-derived organoids deposit hydroxylapatite biomineral

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International Journal of Oral science 2023年第4期15卷 676-690页

作者： Hyun-Yi Kim Victoria Cooley Eun-Jung Kim Shujin Li Jong-Min Lee Dina Sheyfer Wenjun Liu Ophir D.Klein Derk Joester Han-Sung Jung NGeneS Inc. Ansan-siGyeonggi-doKorea Department of Materials Science and Engineering Northwestern UniversityEvanstonILUSA X-ray Science Division Advanced Photon SourceArgonne National LaboratoryLemontILUSA Division in Anatomy and Developmental Biology Department of Oral BiologyOral Science Research CenterBK21 FOUR ProjectYonsei University College of DentistrySeoulKorea Department of Orofacial Sciences and Program in Craniofacial Biology University of CaliforniaSan FranciscoCAUSA Department of Pediatrics Cedars-Sinai Guerin Children’sLos AngelesCAUSA

Ameloblasts are specialized cells derived from the dental epithelium that produce enamel,a hierarchically structured tissue comprised of highly elongated hydroxylapatite(OHAp)*** unique function of the epithelial cells synthesizing crystallites and assembling them in a mechanically robust structure is not fully elucidated yet,partly due to limitations with in vitro experimental ***,we demonstrate the ability to generate mineralizing dental epithelial organoids(DEOs)from adult dental epithelial stem cells(aDESCs)isolated from mouse incisor *** expressed ameloblast markers,could be maintained for more than five months(11 passages)in vitro in media containing modulators of Wnt,Egf,Bmp,Fgf and Notch signaling pathways,and were amenable to *** transplanted underneath murine kidney capsules,organoids produced OHAp crystallites similar in composition,size,and shape to mineralized dental tissues,including some enamel-like elongated *** are thus a powerful in vitro model to study mineralization process by dental epithelium,which can pave the way to understanding amelogenesis and developing regenerative therapy of enamel.

关键词： epithelium maintained specialized

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Experimental and theoretical study of the phase transition between perovskite polytypes of BaPtO3 under high pressure and temperature

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Physical Review B 2024年第9期110卷 094108页

作者： Hongze Li Yanyao Zhang Nisha Geng Jiaming He Stella Chariton Vitali Prakapenka Carlos Alberto López José Antonio Alonso Eva Zurek Jung-Fu Lin Jianshi Zhou Materials Science and Engineering Program Walker Department of Mechanical Engineering Department of Earth and Planetary Sciences Jackson School of Geosciences Department of Chemistry Center for Advanced Radiation Sources The INTEQUI (UNSL-CONICET) and Facultad de Química Bioquímica y Farmacia CSIC Cantoblanco 28049 Madrid Spain

APtO3 (A = Ca, Sr, Ba) is a unique family in the complex transition metal oxides with the AMO3 formula. Most 3d and 4dAMO3 compounds adopt the perovskite structure when synthesized at ambient or high pressure; however, APtO3 perovskites have not been reported, even if their geometric tolerance factor, t, falls in the range suitable for the perovskite structure. Herein, we studied the crystal structures of BaPtO3 by performing the in situ x-ray diffraction over a broad range in the pressure (P)–temperature (T) phase diagram. The perovskite BaPtO3 can be stabilized at P>35 GPa and T>1100 K. A variety of crystal structures, including the perovskite structure and its hexagonal polytypes, observed in the P–T phase diagram of BaPtO3 match the structure predictions from the first-principles calculations reasonably well.

关键词： High-pressure studies Structural phase transition Perovskites Density functional calculations Pressure techniques X-ray diffraction

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