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Rapid Electronic Transport Channel of Co-P with Mo in a Heterostructure Embedded with P, N Dual Doped Porous Carbon for Electrocatalytic Oxygen and Hydrogen Evolution

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ChemNanoMat 2024年第7期10卷

作者： Dey, Tapan Rajput, Anubha Jhaa, Gaurav Matsagar, Babasahab M. Chen, Norman C.-R Kumar, Nitish Salunkhe, Rahul Wu, Kevin C.-W. Chakraborty, Biswarup Dutta, Saikat Electrochemical Energy & Sensor Research Laboratory Amity Institute of Click Chemistry Research & Studies Amity University Noida India Department of Chemistry Indian Institute of Technology Delhi Hauz Khas New Delhi110016 India Chemical Information Sciences Laboratory Department of Chemistry Pondicherry University Kalapet Pondicherry605014 India Department of Chemical Engineering National Taiwan University No. 1 Sec. 4 Roosevelt Road Taipei10617 Taiwan Molecular Science and Technology Program Taiwan International Graduate Program Academia Sinica Taiwan Materials Research Laboratory Department of Physics Indian Institute of Technology Jammu Jammu India Department of Chemical Engineering and Materials Science Yuan Ze University Taoyuan Chung-Li Taiwan Department of Chemical Engineering Chung Yuan Christian University No. 200 Zhongbei Rd. Zhongli Dist. Taoyuan City320 Taiwan

We developed a molybdenum (Mo)-doped cobalt (Co)-heterostructure embedded on a phosphorous (P) and nitrogen (N) dual-doped porous carbon which exhibits an intrinsic electronic transport channel of Co to Mo and P. The P,Mo,O−Co/PNC/NF (NF=Nickel foam) electrode offers 335 mV overpotential at 10 mA cm−2 in OER as compared with PMA-ZIF67-NC/NF and ZIF67-NC/NF electrode with an overpotential of 357 and 373 mV respectively. Linear sweep voltammetry (LSV) of overall water splitting (OWS) supports that the current density gradually increased at a cell potential of 1.6 V with a maximum of 40 mA with a corresponding cell potential of 1.79 V at a current density of 10 mA cm−2. Density functional theory (DFT) calculations for water adsorption on optimized [111] surface of Co, CoMo, and CoMoP2 with adsorbed H2O and corresponding lattice determine the electron density difference of [111] surface with adsorbed H2O for Eads (eV) 4.23 corresponds to adsorption energy for CoMoP2. XANE-EXAFS spectroscopy of P,Mo,O−Co/PNC at Co K edge and Mo K edge suggests the presence of higher valence of both Cox+ and Mox+ without metallic Co and Mo and Co−P and Mo−P bonds as major structural units due to phosphidation as determined by R-space FT-EXAFS spectra. © 2024 Wiley-VCH GmbH.

关键词： Cobalt

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Thermal, Morphological and Structural Characterization Of Cyperus Malaccensis And Graphene Oxide Acting As a Coupling Agent for Future Reinforcement Applications

SSRN

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SSRN 2023年

作者： de Mendonça Neuba, Lucas Junio, Raí Felipe Pereira Souza, Andressa Teixeira Chaves, Yago Soares Palmeira, Alexandre Alvarenga Tavares, Sheron Lazarus, Benjamin Pereira, Artur Camposo Monteiro, Sergio Neves Military Institute of Engineering - IME Department of Materials Science Praça General Tibúrcio 80 Praia Vermelha Urca RJ Rio de Janeiro22290-270 Brazil Department of Mechanical Engineering University of Rio de Janeiro State Rod. Pres. Dutra Km 298 Polo Industrial Rj Resende27537-000 Brazil Materials Science and Engineering Program University of California 9500 Gilman Drive La Jolla San DiegoCA United States Military Institute of Engineering Brazil

Natural lignocellulosic fibers (NLFs) are currently receiving exponential concern from researchers on employing them as an engineering material. Particularly, they are being applied as a reinforcement for conventional and biodegradable polymer matrices. Due to the fact that NLFs are a renewable resource, environmentally friendly and require less energy for processing. However, they present drawbacks related to their compatibility with the polymer matrix, caused by the difference in the hydrophilic nature of NLFs and the hydrophobic for polymers. Graphene oxide (GO) is becoming extremely interesting when applied as a coupling agent between the fiber-matrix interface. On account of the amphiphilic nature of the nanomaterial. Therefore, the present work focus on the investigation of the seven- islands sedge (Cyperus malaccensis) coated with GO in 0.1% of the weight of the fiber. Thus, make a comparison with the untreated sedge fibers in terms of their thermal behavior, morphological aspect and structural characterization. Based on the TGA/DTG curves, it was possible to verify that the coating has attained better thermal stability properties. While the DSC thermal curves revealed endothermic and exothermic peaks related to the fiber microstructures. The FTIR spectrum validated the presence of bans associated with the GO structure. XRD affirmed an increase in the crystallite size which improves the interface adhesion. At last, SEM images unveiled the effective GO coating on the surface of the natural fiber. © 2023, The Authors. All rights reserved.

关键词： Fibers

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Snake-Scale Stimulated Robust Biomimetic Composite Triboelectric Layer for Energy Harvesting and Smart Health Monitoring

SSRN

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SSRN 2023年

作者： Lin, Zong-Hong Huang, Ming-Zheng Parashar, Parag Chen, An-Rong Shi, Shih-Chen Tseng, Yao-Hsuan Lim, Kee Chin Yeh, Hsuan-Yu Pal, Arnab Institute of Biomedical Engineering National Tsing Hua University Hsinchu30013 Taiwan Department of Biomedical Engineering National Taiwan University Taipei10617 Taiwan Department of Chemical Engineering National Taiwan University Taipei10617 Taiwan Department of Materials Science and Engineering National Tsing Hua University Hsinchu30013 Taiwan Department of Mechanical Engineering National Cheng Kung University Tainan70101 Taiwan International Intercollegiate Ph.D. Program National Tsing Hua University Hsinchu30013 Taiwan

Extreme frictional wear of triboelectric layers severely hinders long-term sustainability of triboelectric nanogenerators (TENGs) for efficient ambient energy harvesting. The state-of-the-art solutions necessitate sophisticated structural designs and complex packaging constraints, impeding the feasibility of TENGs for practical applications. Herein, inspired by the structures and compositions of snake scales, a biomimetic composite (BC) film is fabricated as a wear-resistant triboelectric contact layer. The successful formation of disulfide bond-facilitated cross-linkage of cysteine proteins in the keratin-based BC film promotes excellent mechanical resilience and durability, thereby solving the material abrasion challenges associated with solid-solid triboelectric layers. The BC film, with toothed microstructure, exhibits improved charge transfer, low friction, and consistent long-term stable outputs compared to commercial films. Furthermore, a self-powered BC film-based TENG is integrated into a bicycle for biomechanical energy harvesting, lightening warning signals for safer night ride with stable 300 V electrical output for at least 6 hours. Moreover, a smart health monitoring system is further proposed by embedding TENG-based sensors into the bicycle saddle, accurately capturing the rider’s pelvic-saddle interactions on varying terrain slopes. By leveraging the unique biomechanical information, machine learning-assisted user identification and terrain slope data classifications are achieved with high accuracies, laying a foundation for futuristic smart healthcare applications. This work provides a strategy to reduce material abrasion by exploiting the unique characteristics of a biomimetic material, facilitating a basis for efficient environmental energy harvesting and smart sensing. © 2023, The Authors. All rights reserved.

关键词： Nanogenerators

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Room-temperature multiple ligands-tailored SnO_(2) quantum dots endow in situ dual-interface binding for upscaling efficient perovskite photovoltaics with high V_(OC)

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Light(science & Applications) 2021年第12期10卷 2467-2481页

作者： Zhiwei Ren Kuan Liu Hanlin Hu Xuyun Guo Yajun Gao Patrick W.K.Fong Qiong Liang Hua Tang Jiaming Huang Hengkai Zhang Minchao Qin Li Cui Hrisheekesh Thachoth Chandran Dong Shen Ming-Fai Lo Annie Ng Charles Surya Minhua Shao Chun-Sing Lee Xinhui Lu Frédéric Laquai Ye Zhu Gang Li Department of Electronic and Information Engineering Research Institute for Smart Energy(RISE)Guangdong-Hong Kong-Macao(GHM)Joint Laboratory for Photonic-Thermal-Electrical Energy Materials and DevicesThe Hong Kong Polytechnic UniversityHung HomKowloonHong KongChina Department of Electrical and Computer Engineering Nazarbayev UniversityNur-SultanKazakhstan The Hong Kong Polytechnic University Shenzhen Research Institute Shenzhen 518057China Hoffmann Institute of Advanced Materials Shenzhen Polytechnic7098 Liuxian BoulevardShenzhen 518055China Department of Applied Physics The Hong Kong Polytechnic UniversityHung HomKowloonHong KongChina Department of Chemical and Biological Engineering The Hong Kong University of Science and TechnologyClear Water BayKowloonHong KongChina King Abdullah University of Science and Technology(KAUST) KAUST Solar Center(KSC)Physical Sciences and Engineering Division(PSE)Material Science and Engineering Program(MSE)Thuwal 23955-6900Kingdom of Saudi Arabia Department of Physics The Chinese University of Hong KongShatin 999077 Hong KongChina Center of Super-Diamond and Advanced Films(COSDAF) Department of ChemistryCity University of Hong KongHong KongChina

The benchmark tin oxide(SnO_(2))electron transporting layers(ETLs)have enabled remarkable progress in planar perovskite solar cell(PSCs).However,the energy loss is still a challenge due to the lack of“hidden interface”*** report a novel ligand-tailored ultrafine SnO_(2) quantum dots(QDs)via a facile rapid room temperature ***,the ligand-tailored SnO_(2) QDs ETL with multi-functional terminal groups in situ refines the buried interfaces with both the perovskite and transparent electrode via enhanced interface binding and perovskite *** novel ETLs induce synergistic effects of physical and chemical interfacial modulation and preferred perovskite crystallization-directing,delivering reduced interface defects,suppressed non-radiative recombination and elongated charge carrier *** conversion efficiency(PCE)of 23.02%(0.04 cm^(2))and 21.6%(0.98 cm^(2),V_(OC) loss:0.336 V)have been achieved for the blade-coated PSCs(1.54 eV E_(g))with our new ETLs,representing a record for SnO_(2) based blade-coated ***,a substantially enhanced PCE(V_(OC))from 20.4%(1.15 V)to 22.8%(1.24 V,90 mV higher V_(OC),0.04 cm^(2) device)in the blade-coated 1.61 eV PSCs system,via replacing the benchmark commercial colloidal SnO_(2) with our new ETLs.

关键词： perovskite interface quantum

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Detection of COVID-19 infection based on electronic nose technique: preliminary study

Detection of COVID-19 infection based on electronic nose tec...

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2022 International Electrical engineering Congress, iEECON 2022

作者： Phukkaphan, Natnaree Eamsa-Ard, Tanthip Aunsa-Ard, Wandee Khunarak, Chayanin Nitivanichsakul, Tuleeya Roongpuvapaht, Boonsam Kerdcharoen, Teerakiat Mahidol University Materials Science and Engineering Program Faculty of Science Bangkok Thailand Chakri Naruebodindra Medical Institute Faculty of Medicine Ramathibodi Hospital Mahidol University Samut Prakan Thailand Department of Otolaryngology Head and Neck Surgery Ramathibodi Hospital Faculty of Medicine Mahidol University Bangkok Thailand Department of Physics Faculty of Science Mahidol University Bangkok Thailand Research Network of NANOTEC Mahidol University National Nanotechnology Center Thailand

ISBN: (纸本)9781665402064

The coronavirus COVID-19 pandemic have reached almost every country in the world and caused a global health crisis. It is necessary to detect COVID-19 with fast and accurate diagnosis method in order to prevent the rapid spread of Covid-19. This paper presents a preliminary study of using electronic nose (e-nose) technology for detection of COVD-19 infection. In this experiment, the human exhaled breaths of healthy volunteers, asymptomatic and symptomatic COVID-19 patients were collected with commercial face masks for 5 minutes followed by the measurement with an e-nose machine in a closed system. The COVID-19 positivity was confirmed by RT-PCR method. According to the experiment, the odor intensity of human exhaled breath can be described with the total sensing response value. The exhaled breath of COVID-19 infected patients show higher odor intensity than the healthy volunteers (control). The Principal Component Analysis (PCA) shows the classification of three data groups;healthy volunteers, COVID-19 infected patients and unclassified people. For the unclassified cases, the medical record has shown that these people have been subjected either to some respiratory diseases or just recovered from COVID-19 infection. From these preliminary results, e-nose technology and its measurement proto-cols can be considered as a viable tool for COVID-19 rapid detection. © 2022 IEEE.

关键词： COVID-19

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Synthesis and Characterization of Two-dimensional Cs2AgInCl6 Nanoplates as Building Blocks for Functional Surfaces

arXiv

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arXiv 2025年

作者： Khalfin, Sasha Veber, Noam Shaek, Saar Shamaev, Betty Levy, Shai Dror, Shaked Kauffmann, Yaron Khristosov, Maria Koifman Bekenstein, Yehonadav Department of Materials Science and Engineering Technion Israel Institute of Technology Haifa3200003 Israel The Solid-state institute Technion – Israel Institute of Technology Haifa3200003 Israel The Nancy and Stephen Grand Technion Energy Program Technion Israel Institute of Technology Haifa32000 Israel

breaking crystal symmetry is essential for engineering emissive double perovskite metal halides. The goal is to overcome their inherently indirect and disallowed optical transitions. Here we introduce a synthesis for silver - Cs2AgInCl6 two-dimensional hybrid nanoplate products that break the symmetry in two ways, their shape and their heterointerfaces. A comparative study between Cs2AgInCl6 nanocubes and nanoplates is presented to emphasize the difference in optical properties. A modified colloidal synthesis for Cs2AgInCl6 yields high-quality nanoplates with small lateral dimensions very different from the symmetric cubes. Each nanoplate is decorated with metallic silver nanoparticles, with diameters on the scale of the thickness of the perovskite nanoplate, forming significant heterointerfaces that further break symmetry. The Cs2AgInCl6 two-dimensional nanoplates also demonstrate facile transformation into larger crystalline nanosheets once deposited on substrates. We thus highlight those nanoplates as potential building blocks for assemblies of functional surfaces. © 2025, CC BY-NC-ND.

关键词： Perovskite

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Reducing Effective System Dimensionality with Long-Range Collective Dipole-Dipole Interactions

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Physical Review Letters 2024年第17期132卷 173803-173803页

作者： Ashwin K. Boddeti Yi Wang Xitlali G. Juarez Alexandra Boltasseva Teri W. Odom Vladimir Shalaev Hadiseh Alaeian Zubin Jacob Elmore Family School of Electrical and Computer Engineering Purdue University West Lafayette Indiana 47907 USA Birck Nanotechnology Center Purdue University West Lafayette Indiana 47907 USA Graduate Program in Applied Physics Northwestern University Evanston Illinois 60208 USA Department of Materials Science and Engineering Northwestern University Evanston Illinois 60208 USA Department of Chemistry Northwestern University Evanston Illinois 60208 USA School of Physics and Astronomy Purdue University West Lafayette Indiana 47907 USA

Dimensionality plays a crucial role in long-range dipole-dipole interactions (DDIs). We demonstrate that a resonant nanophotonic structure modifies the apparent dimensionality in an interacting ensemble of emitters, as revealed by population decay dynamics. Our measurements on a dense ensemble of interacting quantum emitters in a resonant nanophotonic structure with long-range DDIs reveal an effective dimensionality reduction to d¯=2.20(12), despite the emitters being distributed in 3D. This contrasts with the homogeneous environment, where the apparent dimension is d¯=3.00. Our work presents a promising avenue to manipulate dimensionality in an ensemble of interacting emitters.

关键词： Light-matter interaction Long-range interactions Metamaterials Optics & lasers Photonics Plasmonics Quantum optics

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Plasma Surface Treatment of Cocr and Nicr Alloys for Dental Applications: A Comparative Study of Tin Thin Film Plasma Deposition Techniques

SSRN

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SSRN 2024年

作者： Balica, Naasson Matheus Pereira Almeida, Larissa Solano Rossino, Luciana Sgarbi Pupim, Denise Monção, Renan Matos Costa, Thércio Henrique de Carvalho Santos, Rafaela Luiz Pereira Sousa, Rômulo Ribeiro Magalhães Nunes, Lívio César Cunha Federal University of Piauí Technology Center Graduate Program in Materials Science and Engineering Avenida Universitária s/n Ininga PI Teresina Brazil Federal University of São Carlos Graduate Program in Materials Science SP Sorocaba Brazil University of São Paulo Ribeirão Preto School of Dentistry Avenida do Café SP Ribeirão Preto Brazil Federal University of Rio Grande do Norte Technology Center Department of Mechanical Engineering University Campus Natal RN Lagoa Nova Brazil

Cobalt-chromium and nickel-chromium metal alloys have been widely used as biomaterials in the dental field due to their excellent physical-mechanical properties and biocompatibility, as well as the low cost of the material. However, in unfavorable environments, such as the oral cavity, these dental prostheses composed of these alloys can suffer alterations in their structure where they can undergo rapid changes with the surface corrosion process, which can vary with pH and temperature, typically related to changes in the patient's diet. The aim of this work is to carry out a comparative study between the cathodic cage (CC) and hollow cathode (HC) methods, in which a plasma deposition treatment of titanium nitride (TiN) thin films was carried out on CoCr and NiCr samples, in order to subsequently evaluate their surface characteristics and tribological properties in relation to each method. The samples were characterized using X-ray diffractometry (XRD), scanning electron microscopy (SEM/EDS) and micro abrasive wear tests on each sample from the three groups of alloys mentioned. It was observed that the TiN films provided greater resistance to the wear mechanism of all the samples, where through the characterizations, it can be inferred that the two types of treatments carried out on the samples are suitable for dental applications. © 2024, The Authors. All rights reserved.

关键词： Chromium alloys

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Mid-IR Gain of Tensile Germanium Waveguide Lasers with SiNx Stress Liners

Mid-IR Gain of Tensile Germanium Waveguide Lasers with SiNx ...

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2021 IEEE Photonics Society Summer Topicals Meeting Series, SUM 2021

作者： Reza, Md Shamim Gulyas, Istvan Wistey, Mark A. Materials Science Engineering and Commercialization Program Texas State University San MarcosTX78666 United States Department of Physics Texas State University San MarcosTX78666 United States

ISBN: (纸本)9781665416009

We used ab-initio and finite element strain modeling to explain high threshold current densities in reported tensile Ge lasers. Anisotropic strains improve carrier confinement but reduces optical confinement, and intervalence band absorption still dominates. Strain anisotropy increases Jth compared with simple slab models. © 2021 IEEE.

关键词： Germanium

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Enhancing Zinc Electrode Stability Through Pre-Desolvation and Accelerated Charge Transfer Via a Polyimide Interface

SSRN

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SSRN 2023年

作者： Lai, Chi-Yu Liao, Yin-Song Ku, Hao-Yu Jao, Wen-Yang Gull, Sanna Chen, Han-Yi Chou, Jyh-Pin Hu, Chi-Chang Department of Chemical Engineering National Tsing Hua University Hsinchu300044 Taiwan Tsing Hua Interdisciplinary Program National Tsing Hua University Hsinchu300044 Taiwan Department of Materials Science and Engineering National Tsing Hua University Hsinchu300044 Taiwan Department of Physics National Changhua University of Education Changhua50074 Taiwan

Aqueous zinc-based energy storage devices possess superior safety, cost-effectiveness, and high energy density;however, dendritic growth and side reactions on the zinc electrode curtail their widespread applications. In this study, we mitigate these issues by introducing a polyimide (PI) nanofabric interfacial layer onto the zinc substrate. Simulations reveal that the PI nanofabric promotes a pre-desolvation process, effectively desolvating hydrated zinc ions from Zn(H2O)62+ to Zn(H2O)42+ before approaching zinc surface. The exposed zinc ion in Zn(H2O)42+ provides an accelerated charge transfer process and reduces the activation energy for zinc deposition from 40 to 21 kJ mol−1. The PI nanofabric also acts as a protective barrier, reducing water molecule interactions and side reactions at the electrode. The PI-Zn symmetric cell exhibits remarkable cycling stability over 1200 h, maintaining a dendrite-free morphology and minimal byproduct formation. Moreover, the cell exhibits high stability and low voltage hysteresis even under high current densities (20 mA cm−2, 10 mAh cm−2) thanks to the three-dimensional porous structure of PI nanofabric. When integrated into full cells, the PI-Zn||AC hybrid zinc-ion capacitor and PI-Zn||MnVOH@SWCNT zinc-ion battery achieve impressive lifespans of 15000 and 600 cycles with outstanding capacitance retention. This approach paves a novel avenue for high-performance zinc metal electrodes. © 2023, The Authors. All rights reserved.

关键词： Charge transfer

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