As an n-type semiconductor, In_(2)O_(3)is considered a promising photocatalyst for producing amino acids using biomass derivatives as precursors. However, similar to other intrinsic semiconductors, In_(2)O_(3)suffers ...
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As an n-type semiconductor, In_(2)O_(3)is considered a promising photocatalyst for producing amino acids using biomass derivatives as precursors. However, similar to other intrinsic semiconductors, In_(2)O_(3)suffers from poor charge dynamics. Herein, we show the synthesis of Mo-doped In_(2)O_(3)(Mo-In_(2)O_(3)) with a porous rod-shaped structure through a onestep solvothermal reaction followed by calcination. Under visible-light irradiation, Mo-In_(2)O_(3)achieves a high conversion rate of 81% for the reaction that transforms lactic acid into alanine with a selectivity of 91%. Spectroscopic techniques and density functional theory calculations reveal that Mo doping introduces defect states slightly below the conduction band of In_(2)O_(3), which improves the separation of photogenerated electron-hole pairs. In addition, Mo atoms on the surface form extra adsorption and reaction centers that greatly enhance the reaction rate. This work provides insights into the development of transition metal-doped semiconductor photocatalysts to produce amino acids.
This study aims to present simple conversion expressions of strains–stresses and the energy density for beams and plates subjected to high-frequency random forces using the radiative energy transfer method (RETM). Eu...
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This study aims to present simple conversion expressions of strains–stresses and the energy density for beams and plates subjected to high-frequency random forces using the radiative energy transfer method (RETM). Euler–Bernoulli beam theory and Kirchhoff plate theory are introduced to describe the deflections of beam and plate. The conversion expressions of strains–stresses and energy density for a single propagation wave are quickly established by dispersion relations. For multi-cylindrical wave fields, the strains–stresses are superimposed by the wave fields generated by the actual source in the domain and the wave fields reflected by the fictitious sources at boundaries according to Huygens’ superposition principle. The conversion expressions of strains–stresses and energy density in the energy finite element method (EFEM), which supposes that the superposition of plane waves forms the wave field, are also derived. Numerical examples indicate that in damping-frequency space, the conversion expressions obtained by RETM have a wider application region than those obtained by EFEM and can be applied to a low-frequency band than the corresponding energy algorithm itself.
The recent observation of the compact star XTE J1814-338 with a mass of (Equation presented) and a radius of (Equation presented), together with the HESS J1731-347, which has a mass of (Equation presented) and a radiu...
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We present a robust integral method to estimate the daily mean per-person ventilation rate Qpp based on carbon dioxide (CO2) concentration measurements in operational spaces, and limited other data. The method makes n...
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Cross-flow turbine power is a net sum of power generation from rotating blades and power loss from rotating support structures. While the aggregate forces and torques at the turbine level are important for end use, th...
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We explore the relationship between a machine-learned structural quantity (softness) and excess entropy in simulations of supercooled liquids. Excess entropy is known to scale well the dynamical properties of liquids,...
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For many decades, experimental solid mechanics has played a crucial role in characterizing and understanding the mechanical properties of natural and novel materials. Recent advances in machine learning (ML) provide n...
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The rigid-plastic assumption has greatly simplified the theoretical analysis of dynamic plastic response of *** this framework,a common tool is the modal technique using approximate independent yield criteria,which le...
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The rigid-plastic assumption has greatly simplified the theoretical analysis of dynamic plastic response of *** this framework,a common tool is the modal technique using approximate independent yield criteria,which leads to upper-and lower-bound solutions,but usually with poor *** this paper,by utilizing the membrane factor method(MFM),the large-deflection dynamic plastic response of square plates subjected to exponentially decaying pulse loading is analyzed by taking both the transient response phase and the exact yield criterion into *** on the combination of saturation analysis(SA)and MFM,the complete solutions and regressive formulae of saturated deflection and saturated impulse are *** the dynamic behavior of plates under rectangular pulse loading serves as a benchmark of pulse-equivalent techniques,the large plastic deformation of square plates under short-duration rectangular pulse is also analyzed in ***,by comparing the SA results of pulse-loaded square plates with different boundary conditions,it is found that the saturated deflection and saturated impulse of the fully clamped and simply supported square plates both increase linearly with the pulse amplitude,and the slopes are approximately the same,so the conversion between the SA quantities of plates with different boundary conditions can be easily achieved.
Exploiting the growth rate dependency of intermetallic compounds (IMCs) on the substrate composition, the possibility of controlling porosity during transient liquid phase (TLP) bonding via a composition gradient is i...
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