Titanium matrix composites (TMCs) have high specific strength and stiffness, and high-temperature TMCs can reduce weight by up to 50% when compared with monolithic super alloys while preserving equal stiffness and str...
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Titanium matrix composites (TMCs) have high specific strength and stiffness, and high-temperature TMCs can reduce weight by up to 50% when compared with monolithic super alloys while preserving equal stiffness and strength in jet engine systems for propulsion. The purpose of this work examines the use of mathematical models and learning approaches to optimize response such as porosity and control variables in synthesized hybrid titanium metal matrix composites (HTMMCs) reinforced by B4C-SiC-MoS2-ZrO2. To further understand the impacts of process factors on porosity reduction, the study employs methodologies such as the response surface methodology (RSM), integrated artificial neural networks (ANN), and genetic algorithm (GA). The findings indicate that these strategies have the potential to contribute to the industry. The optimal combination of 7.5wt.% SiC, 7.5wt.% B4C, 7.5wt.% ZrO2, 4wt.% MoS2, and 73.5wt.% Ti compositions was determined utilizing process factors such as milling period (6h), compaction pressure (50MPa), compact duration (50min), sintering temperature (1200°C), and sintering time (2h) as compared to pure Ti grade 5. The mechanical properties of the optimum combination of reinforcement weight percentage and process parameters resulted in a minimum porosity of 0.118%, density of 4.36gcm3, and micro-hardness of 63.4HRC boosted by 1.76%, and compressive strength of 2500MPa increased by 2.6%. In addition, these HTMMCs had a minimal wear rate of 0.176mm3/Nm and a corrosion resistance rate of 2.15×10-4mmpy. The investigation result analysis discovered that the RSM and combined ANN-GA models considerably enhanced the forecasting of multidimensional interaction difficulties in composite material production that were highly statistically connected, with R2 values of 0.9552 and 0.97984. The ANN-GA model provided a 95% confidence range for porosity predictions, which increased the production use of titanium-based particle composites. Furthermore, HMMCs can be u
Generating reduced-order,synthetic grain structure datasets that accurately represent the measured grain structure of a material is important for reducing the cost and increasing the accuracy of computational crystal ...
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Generating reduced-order,synthetic grain structure datasets that accurately represent the measured grain structure of a material is important for reducing the cost and increasing the accuracy of computational crystal plasticity *** study introduces a machine-learning-based approach,termed texture adaptive clustering and sampling(TACS),for generating representative Euler angle datasets that accurately mimic the crystallographic *** TACS approach employs K-means clustering and density-based sampling in a closed-loop iteration to create representative Euler angle ***-of-principle experiments were performed on rolled and recrystallized low-carbon *** of the TACS approach was extended to twenty-two datasets,varying lattice structures,and complex crystallographic textures,thereby encompassing a broad range of materials and crystal ***-Smirnov(K-S)test comparisons underscore the performance of the TACS approach over traditional electron backscatter diffraction EBSD dataset reduction techniques,with average K-S test scores nearing 0.9,indicating a high-fidelity representation of the original *** contrast,conventional methods display scores below 0.3,indicating less reliability of the structure *** independence of the TACS approach from material texture and its capability to autonomously generate datasets with predetermined data points demonstrates its unbiased potential in streamlining dataset preparation for crystallographic analysis.
Hybrid titanium metal matrix composites (HTMMCs) are advanced composite materials that can be tailored to a variety of applications. Because of their decreased fuel consumption and cost, they are popular in the transp...
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The simultaneous optimization of the bulk and surface characteristics of photoelectrodes is essential to maximize their photoelectrochemical(PEC)*** report a novel one-pot hydrothermal synthesis of textured and surfac...
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The simultaneous optimization of the bulk and surface characteristics of photoelectrodes is essential to maximize their photoelectrochemical(PEC)*** report a novel one-pot hydrothermal synthesis of textured and surface-reconstructed BiVO_(4)photoanodes(ts-BVO),achieving significant improvements in PEC water *** controlling precursor molarity and ethylene glycol(EG)addition,we developed a stepwise dual reaction(SDR)mechanism,which enables simultaneous bulk texture development and surface *** optimized CoBi/ts-BVO photoanode exhibited a photocurrent density of 4.3 mA∙cm^(−2)at 1.23 V *** hydrogen electrode(RHE)with a high Faradaic efficiency of 98%under one sun *** with nontextured BiVO_(4),the charge transport efficiency increased from 8%to 70%,whereas the surface charge transfer efficiency improved from 9%to 85%.These results underscore the critical role of both bulk and surface engineering in enhancing PEC *** findings offer a streamlined approach for improving the intrinsic properties of photoanodes in solar water splitting.
In recent years,sodium-ion capacitors have attracted attention due to their cost-effectiveness,high power density and similar manufacturing process to lithium-ion ***,the utilization of oxide electrodes in traditional...
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In recent years,sodium-ion capacitors have attracted attention due to their cost-effectiveness,high power density and similar manufacturing process to lithium-ion ***,the utilization of oxide electrodes in traditional sodium-ion capacitors restricts their further advancement due to the inherent low operating voltage and electrolyte consumption based on their energy storage *** address these challenges,we incorporated Zn,Cu,Ti,and other elements into Na_(0.67)Ni_(0.33)Mn_(0.67)O_(2) to synthesize P2-type Na_(0.7)Ni_(0.28)Mn_(0.6)Zn_(0.05)Cu_(0.02)Ti_(0.05)O_(2) with a modulated entropy and pillaring *** the synergistic interplay between the interlayer pillar and the entropy modulation within the layers,the material exhibits exceptional toughness,effectively shielding it from detrimental phase transitions at elevated voltage *** a result,the material showcases outstanding kinetic properties and long-term cycling stability across the voltage *** integrating these materials with hierarchical porous carbon nanospheres to form a"rocking chair"sodium-ion capacitor,the hybrid full device delivers a high energy density(171 Wh·kg^(-1))and high power density(5245 W·kg^(-1)),as well as outstanding cycling stability(77% capacity retention after 3000 cycles).This work provides an effective material development route to realize simultaneously high energy and power for next-generation sodium-ion capacitors.
Multicomponent rare earth phosphates hold immense potential as next-generation environmental barrier coatings(EBCs),offering enormous possibilities and flexibility by controlling and varying their components and fract...
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Multicomponent rare earth phosphates hold immense potential as next-generation environmental barrier coatings(EBCs),offering enormous possibilities and flexibility by controlling and varying their components and fractions to tailor their *** this work,the key material parameters(e.g.,ionic size and ionic size disorder)and the elements governing their thermal‒mechanical properties and resistance against calcium‒magnesium‒aluminosilicate(CMAS)corrosion were *** thermal conductivities of multicomponent rare-earth phosphates correlate well with cation size disorder,but no clear trend is identified for the coefficient of thermal expansion(CTE).Er-containing compositions display low CTEs and high fracture *** formation of a dense interfacial layer occurs for most CAMS corrosion-resistant compositions when tested at 1300°C,e.g.,(Lu_(0.2)Yb_(0.2)Er_(0.2)Y_(0.2)Gd_(0.2))PO_(4) and(Lu_(0.2)Yb_(0.2)Er_(0.2)Dy_(0.2)Gd_(0.2))PO_(4).These multicomponent phosphates also display the least recession upon molten CMAS attack at 1400°C without significant volumetric swelling,which is superior to their single-component counterparts and state-of-the-art EBCs based on rare-earth *** contrast,Sc-containing multicomponent phosphates display inferior performance against CMAS corrosion and penetration.A mechanistic understanding and understanding of the kinetics of the interfacial interaction at higher temperatures,as well as the key parameters governing their thermomechanical properties and CMAS corrosion,are valuable for designing data-driven materials of multicomponent phosphates for EBC applications.
Nickel-rich layered oxides are attractive cathode for lithium-ion batteries(LIBs)because of the high energy density and low *** critical problem is capacity fading caused by the highly reactive metastable phases under...
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Nickel-rich layered oxides are attractive cathode for lithium-ion batteries(LIBs)because of the high energy density and low *** critical problem is capacity fading caused by the highly reactive metastable phases under voltages of higher than 4.15 ***,we find that facile Ar/H2 plasma treating could produce oxygen vacancies that will readily transform into homogeneous spinel layer(~6 nm)on the LiNi_(0.8)CO_(0.1)Mn_(0.1)O_(2)(NCM811)surface after a few cycles of lithiation/delithiation *** to the structural matching between spinel and layered structure,the diffusion of Li ions could remain fast upon ***,the spinel layer is electrochemically inert,which guarantees surface stabilization and inhibits the detrimental phase transition from H2 to H3 at high *** the protection of the homogeneous spinel layer,the NCM_(811) electrode shows superior capacity retention of 91.2% after 200 cycles at the current density of 100 mA·g^(−1).This work proposes a novel strategy of surface reconstruction to stabilize nickel-rich layered oxide materials for LIBs.
Automobiles are the inevitable mode of ***,increasing fuel prices and carbon dioxide emissions are posing a serious threat to automobile users and the ***,the development of new lightweight materials has been a key ar...
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Automobiles are the inevitable mode of ***,increasing fuel prices and carbon dioxide emissions are posing a serious threat to automobile users and the ***,the development of new lightweight materials has been a key area of ***-based commercial alloys(AZ and ZK series alloys)are the lightest among all structural ***,there is still a question about the replacement of Aluminum-based alloys due to HCP crystal *** this connection,Mg-Al-Ca-Mn(AXM)Mg alloy can be a choice as an alternative to the existing Mg-based commercial alloys for structural *** contains(Al,Mg)_(2)Ca,Al_(2)Ca,Mg_(2)Ca,and Al_(8)Mn_(5)as the secondary phases,contributing to the microstructural refinement and property ***,the formation of those precipitates depends on the amount of Al,Ca,and Mn,especially,the Ca/Al *** addition,the secondary processes influence the grain refinement and property enhancement of texture ***,this review article focuses on elaborating on the significance of the Ca/Al ratio for the precipitate formation,secondary process,and texture *** co-segregation behavior of other micro-alloying elements like Cerium,Lanthanum,and Zinc in AXM Mg alloy systems has also been discussed for property enhancement.
The Subsea Shuttle Tanker (SST) was presented by the authors as an innovative and cost-effective solution in several research works. This new approach offers a viable alternative to subsea pipelines and shuttle tanker...
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With the increasing use of micro-manufactured devices and the demand for low-cost fabrication techniques, this study presents a simple and scalable surface polishing method for laser etched acrylic using WELD-ON 4 acr...
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