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Design of FeSiBPCu soft magnetic alloys with good amorphous forming ability and ultra-wide crystallization window

Journal of materials science & Technology 2023年第16期147卷 124-131页

作者： Xingdu Fan Tao Zhang Weiming Yang Junhua Luan Zengbao Jiao Hui Li Jiangsu Key Laboratory for Advanced Metallic Materials School of Materials Science and EngineeringSoutheast UniversityNanjing 211189China Institute of Massive Amorphous Metal Science China University of Mining and TechnologyXuzhou 221116China Center for Advanced Structural Materials Department of Mechanical and Biomedical EngineeringCollege of Science and EngineeringCity University of Hong KongKowloonHong KongChina Department of Mechanical Engineering The Hong Kong Polytechnic UniversityHong KongChina School of Materials Science and Engineering Shanghai UniversityShanghai 200444China

The Fe_(81.3)Si_(4)B_(13–x)PxCu_(1.7) soft magnetic alloys with high Cu and proper P elements addition were synthesized with the aim of ensuring the amorphous forming ability(AFA)while expanding the crystallization window(CW).It is found that the atomic ratio of P/Cu of∼3 is advantageous for AFA whereas a small amount of P addition promotes the precipitation ofα-Fe grains and excessive P addition induces surface crystallization behavior of the present *** Cu concentration can expand the annealing temperature(Ta)window whereas proper P addition effectively expands the annealing time(ta)*** Fe_(81.3)Si_(4)B_(13-x)PxCu_(1.7) soft magnetic alloy was successfully synthesized with a large Ta window of up to 130°C and ta window of 90 min,which is a breakthrough for nanocrystalline alloys with high saturation *** analysis reveals that the ultra-wide CW is related to the unique nucleation mechanism,that is,theα-Fe grains are precipitated attaching to the Cu or CuP clusters and enveloping the Cu clusters,resulting in the high number density ofα-Fe *** ultra-wide CW promises the potential material in flexibly choosing the annealing process according to the performance.

关键词： Nanocrystalline alloys Amorphous forming ability Crystallization window Soft magnetic properties

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Advances in doping strategies for sodium transition metal oxides cathodes:A review

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Frontiers in Energy 2024年第2期18卷 141-159页

作者： Zhijing ZHANG Haoze ZHANG Yaopeng WU Wei YAN Jiujun ZHANG Yun ZHENG Lanting QIAN Department of Chemical Engineering Waterloo Institute of NanotechnologyUniversity of WaterlooWaterloo ON N2L 3G1Canada School of Mechanical and Automotive Engineering South China University of TechnologyGuangzhou 510640China Institute of New Energy Materials Science and Engineering School of Materials Science and EngineeringFuzhou UniversityFuzhou 350108China

The electrochemistry of cathode materials for sodium-ion batteries differs significantly from lithium-ion batteries and offers distinct ***,the progress of commercializing sodium-ion batteries is currently impeded by the inherent inefficiencies exhibited by these cathode materials,which include insufficient conductivity,slow kinetics,and substantial volume changes throughout the process of intercalation and deintercalation ***,numerous methodologies have been utilized to tackle these challenges,encompassing structural modulation,surface modification,and elemental *** paper aims to highlight fundamental principles and strategies for the development of sodium transition metal oxide ***,it emphasizes the role of various elemental doping techniques in initiating anionic redox reactions,improving cathode stability,and enhancing the operational voltage of these cathodes,aiming to provide readers with novel perspectives on the design of sodium metal oxide cathodes through the doping approach,as well as address the current obstacles that can be overcome/alleviated through these dopant strategies.

关键词： sodium-ion batteries transition metal cathode doping strategy

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Development Trends and Challenges of Additive Manufacturing Metamaterials

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工程（英文） 2025年第1期44卷 2-6页

作者： Bo Song Shaoji Zhang Lei Zhang Yusheng Shi State Key Laboratory of Materials Processing and Die & Mold Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China State Key Laboratory of Materials Processing and Die & Mold Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China Department of Mechanical Engineering City University of Hong KongHong Kong 999077China

*** To design novel architectures with unique properties that sur-pass those of natural matter,scientists have developed diverse structures/materials by incorporating artificial structures of periodic/aperiodic nano-,micro-,and macro-scale,so called *** metamaterials have special properties such as a negative refractive index[1]and negative Poisson's ratio[2],which are important for acoustic,thermal,electromag-netic,mechanical,and other *** offer a high degree of design freedom in terms of the material composition and struc-tural ***,these unique properties require the structure to have an exact geometric structure or *** changes in structural dimensions or alignment orientation can dramatically affect performance[3].The evolution of metamate-rials has rendered conventional production methods inadequate for high-precision needs.

关键词： metamaterials development additive challenges manufacturing trends

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Investigation of microstructural and mechanical characteristics of Al-ZrO2 composites fabricated by stir casting

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Interactions 2024年第1期245卷 1-11页

作者： Maurya, R. Kumar, V. Gautam, S. Bharti, S. Mallika, S. Department of Materials Science and Engineering NIT Hamirpur HP Hamirpur177005 India Department of Mechanical Engineering Graphic Era Deemed to be University UK Dehradun248002 India

This study investigates optimizing the mechanical characteristics of aluminium-based metal matrix composites (MMCs) using ex-stir casting technique. Al8011 alloy, though versatile, has limitations in strength, hardness, and dimensional stability. To address this, zirconia (ZrO2) was incorporated, with an average particle size of 0.25 μm and variable weight% (0.5%, 1%, and 1.5%) to enhance mechanical properties. Tensile, and hardness tests, along with SEM and XRD analyses, were conducted. The outcome reveals a significant improvement in mechanical properties with increasing zirconia content. XRD study shows the presence of ZrO2 particles, while SEM confirms and shows the distribution of reinforced particles. This work offers insights for tailoring MMC properties through controlled zirconia reinforcement, with implications for industries requiring augmented strength and wear resistance. © The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024.

关键词： Tensile strength

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Recycling of Magnesium Alloy Using the Gravity-Driven Multiple-Effect Thermal System (G-METS)

Recycling of Magnesium Alloy Using the Gravity-Driven Multip...

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Magnesium Technology Symposium held at the TMS Annual Meeting and Exhibition, 2024

作者： Mc Arthur Sehar, Daniel Telgerafchi, Armaghan Ehsani Iurkovskyi, Artem Opoku, Emmanuel Powell, Adam Materials Science and Engineering Program Department of Mechanical Engineering Worcester Polytechnic Institute WorcesterMA United States Department of Mechanical Engineering Worcester Polytechnic Institute WorcesterMA United States

ISBN: (纸本)9783031502392

MagnesiumMagnesium metal has been significantly used in commercial applications from automobiles to aluminum alloys to defense weaponry. The surge in structural usage of magnesium over the past years has been due to high strength and excellent stiffness-to-weight ratio. RecyclingRecycling magnesium scrap is a crucial aspect of the sustainability of the economy and environmental welfare. G-METS is an advanced distillationDistillation system used in the conversion of low-grade magnesium scrap into high-purityHigh-purity magnesium metal. This multiple-effect system uses the weight of magnesiumMagnesium as a compressor, to build pressure differences between each effect of the condenser-evaporator, modifying boiling points, and enabling transfer of vaporization enthalpy. This system is exceptionally efficient compared to the energy-intensive conventional distillationDistillation technique. This study compares experiments and models of one- and two-effect distillers. © The Minerals, Metals & materials Society 2024.

关键词： Magnesium alloys

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Acoustofluidic scanning fluorescence nanoscopy with a large field of view

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Microsystems & Nanoengineering 2024年第3期10卷 159-167页

作者： Geonsoo Jin Neil Upreti Joseph Rich Jianping Xia Chenglong Zhao Tony Jun Huang Thomas Lord Department of Mechanical Engineering and Materials Science Duke UniversityDurhamNC 27708USA Department of Biomedical Engineering Duke UniversityDurhamNC 27708USA The MITRE Corporation McLeanVA 22102USA

Large-field nanoscale fluorescence imaging is invaluable for many applications,such as imaging subcellular structures,visualizing protein interactions,and high-resolution tissue ***,conventional fluorescence microscopy requires a trade-off between resolution and field of view due to the nature of the optics used to form the *** overcome this barrier,we developed an acoustofluidic scanning fluorescence nanoscope that simultaneously achieves superior resolution,a large field of view,and strong fluorescent *** acoustofluidic scanning fluorescence nanoscope utilizes the superresolution capabilities of microspheres that are controlled by a programmable acoustofluidic device for rapid fluorescence enhancement and *** acoustofluidic scanning fluorescence nanoscope resolves structures that cannot be resolved with conventional fluorescence microscopes with the same objective lens and enhances the fluorescent signal by a factor of~5 without altering the field of view of the *** improved resolution realized with enhanced fluorescent signals and the large field of view achieved via acoustofluidic scanning fluorescence nanoscopy provides a powerful tool for versatile nanoscale fluorescence imaging for researchers in the fields of medicine,biology,biophysics,and biomedical engineering.

关键词： field resolution utilize

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Hierarchically porous 3D Y-branched carbon tube grids for high-performance filter capacitors

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science China(Technological sciences) 2025年第4期68卷 49-58页

作者： Gan CHEN Fangming HAN Guowen MENG Bingqing WEI Key Laboratory of Materials Physics and Anhui Key Laboratory of Nanomaterials and NanotechnologyInstitute of Solid State PhysicsHFIPSChinese Academy of SciencesHefei 230031China Department of Materials Science and Engineering University of Science and Technology of ChinaHefei 230026China Department of Mechanical Engineering University of DelawareNewark DE 19716USA

The rapid development of sustainable green energy,which often generates fluctuating electrical signals,has driven the demand for high-performance filter capacitors in alternating/direct current *** bulky aluminum electrolytic capacitors with electric double-layer capacitors(EDLCs)holds promise for electronics ***,EDLCs face a trade-off between charge storage ability and ion/electron transport ***,we demonstrate three-dimensional Y-branched carbon tube(3D-YCT)grids with a hierarchically porous structure as electrodes for line-filtering *** branching patterns and positions within the 3D-YCT are precisely tailored through the nanochannels inside anodic aluminum oxide *** integrated 3D Y-branched CT arrays provide unobstructed pathways for fast frequency response and extensive surfaces for high *** resulting 3D-YCT-based EDLC achieves a desirable specific areal capacitance(C_(A))of 3.6 mF cm^(-2)with a phase angle of-80°at 120 Hz,outperforming most reported line-filtering EDLCs and demonstrating excellent line-filtering *** findings offer valuable insights for constructing miniaturized filter capacitors.

关键词： hierarchically porous structures three-dimensional Y-branched carbon tube grids fast frequency response electric double-layer capacitors AC line-filtering

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Microfluidic QCM enables ultrahigh Q-factor:a new paradigm for in-liquid gravimetric sensing

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Microsystems & Nanoengineering 2024年第4期10卷 377-389页

作者： Yicheng Zhao Zehra Parlak Wenjun Yu Daniel French Wilkins Aquino Stefan Zauscher Thomas Lord Department of Mechanical Engineering and Materials Science Duke UniversityDurhamNCUSA Qatch Technologies LLC.DurhamNCUSA Department of Civil and Environmental Engineering Duke UniversityDurhamNCUSA

Acoustic gravimetric biosensors attract attention due to their simplicity,robustness,and low ***,a prevailing challenge in these sensors is dissipation which manifests in a low quality factor(Q-factor),which limits their sensitivity and *** mitigate dissipation of acoustic sensors in liquid environments we introduce an innovative approach in which we combine microfluidic channels with gravimetric *** implement this novel paradigm we chose the quartz crystal microbalance(QCM)as our model system,owing to its wide applicability in biosensing and the relevance of its operating principles to other types of acoustic *** postulate that the crucial determinant for enhancing performance lies in the ratio between the width of the microfluidic channels and the wavelength of the pressure wave generated by the oscillating channel side walls driven by the *** hypothesis is supported by finite element analysis(FEA)and dimensional studies,which revealed two key factors that affect device performance:(1)the ratio of the channel width to the pressure wavelength(W=λp)and(2)the ratio of the channel height to the shear evanescent wavelength(H=λs).To validate our hypothesis,we fabricated a microfluidic QCM(μ-QCM)and demonstrated a remarkable 10-fold improvement in its dissipation when compared to conventional *** novel microfluidic approach offers several additional advantages,such as direct data interpretation,reduced volume requirement for sample liquids,and simplified temperature control,augmenting the sensor’s overall *** fostering increased sensitivity,accuracy,and ease of operation,our novel paradigm unlocks new possibilities for advancing gravimetric technologies,potentially for biosensing applications.

关键词： QCM enable hypothesis

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Additive manufacturing of Cu-AI-Mn shape memory alloy with enhanced superelasticity

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Rare Metals 2023年第12期42卷 4234-4245页

作者： Meng-Wei Wu Zhuo-Fan Hu Bing-Bing Yang Ying Tao Rui-Ping Liu Chun-Mei Ma Lei Zhang Department of Materials Science and Engineering China University of Mining&Technology(Beijing)Beijing 100083China School of Materials Science and Engineering University of Science and Technology BeijingBeijing 100083China Institute for Advanced Materials and Technology University of Science and Technology BeijingBeijing 100083China Department of Mechanical Engineering University of Alaska FairbanksFairbanks 99775-5905USA

The Cu-based shape memory alloy(SMA)with highly oriented columnar crystals is an ideal candidate for the commercial application,especially the ones obtained through rapid cooling via additive manufacturing *** this work,Cu_(71)Al_(18)Mn_(11)(at%)shape memory alloy with strong<001>texture columnar grains was successfully prepared by selective laser melting(SLM).An L27(313)orthogonal array was designed to systematically investigate the effects of laser power,scanning speed,scanning spacing,layer thickness and their interactions on the forming quality of Cu_(71)Al_(18)Mn_(11)***_(71)Al_(18)Mn_(11)alloys with density of 7.3204 g·cm^(-3)and relative density of 99.18%were successfully prepared when the laser power,scanning speed,scanning distance and layer thickness were 240 W,1000 mm·s^(-1),0.11 mm and 25μm,the transformation onset temperature(Ms),martensite phase transformation termination temperature(Mf),austenite phase transformation onset temperature(AS)and austenite phase transformation termination temperature(Af)are-21.84,-26.04,-15.75 and-12.36℃,*** compression strength and fracture strain along the building direction(BD)were significantly superior to the scanning direction(SD),while the superelasticity of compression along the SD reached 2.50%,which was better than that of2.32%along *** mechanical property and superelasticity anisotropy due to the formation of columnar grains and texture were *** study shows that SLM is a proposed method for the preparation of Cu-Al-Mn SMAs with high superelasticity,which provides a new strategy for enhancing the shape memory alloy superelasticity.

关键词： Shape memory alloy(SMA) Selective laser melting(SLM) Columnar grains Superelasticity properties

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Ultrasound-Enabled Adaptive Protocol for Fast Charging of Lithium-Ion Batteries

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Journal of Electrochemical Energy Conversion and Storage 2025年第3期22卷 031012页

作者： Im, Ganghyeok Lu, Wei Popa, Bogdan Ioan Epureanu, Bogdan I. Department of Mechanical Engineering University of Michigan Ann ArborMI48109 United States Department of Materials Science and Engineering University of Michigan Ann ArborMI48109 United States

This paper introduces an ultrasound-assisted multistage constant current (UA-MSCC) charging protocol to enhance the charging performance of lithium-ion batteries. In this approach, ultrasound is applied during the final portion of each MSCC charging phase. Experimental results demonstrate that ultrasound decreases the internal resistance of pouch cells by up to 7%, leading to significant increase in charging capacity during each MSCC stage. The overall charging time is reduced by 26% compared to the conventional constant current-constant voltage (CCCV) protocol. The performance improvement delivered by this ultrasound-assisted charging approach is especially large when the battery is charged at low temperatures and to a partial capacity. Notably, the application of ultrasound improves the coulombic efficiency to levels comparable to that at the room temperature when charging in cold environments (0 °C). This approach can be applied to commercial batteries to immediately improve their charging performance, and can be seamlessly integrated into battery management systems. Unlike approaches that necessitate electrode material modifications or electrolyte additives, which require a long development time, this UA-MSCC charging protocol offers a practical and easily applicable solution for improving the battery charging performance. © 2024 by ASME.

关键词： State of charge

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