Hemp is becoming one of the high-value economic crops in Thailand and many countries, in which it is cultivated for specific industrial applications, such as seeds, fibers, and medicinal products. After production pro...
Hemp is becoming one of the high-value economic crops in Thailand and many countries, in which it is cultivated for specific industrial applications, such as seeds, fibers, and medicinal products. After production processing, hemp hurds or residues obtained were approximately 2/3 w/w of starting raw material. They may be used as a renewable material or fuel via thermo-chemical conversion. Therefore, the objective of this work was to investigate thermo-chemical degradation and kinetic behaviors of hemp residues using thermogravimetry with non-isothermal conditions of 10-50 °C/min heating rates under an inert environment. From the results, it was found that hemp residues appeared to have three zones of thermal decomposition. With devolatilization, the residues were highly decomposed at temperatures between 200 and 400 °C for about 60% w/w of mass loss. By Flynn-Wall-Ozawa (FWO), Kissinger-Akahira-Sunose (KAS), and Kissinger free-model methods, the kinetic parameters were evaluated. The activation energies for the FWO and KAS were found to be an inverse function of conversion fractions, varying from 250 to 370 kJ/mol with the average values of 265.5 and 291.5 kJ/mol, respectively. While, for Kissinger, the activation energy was a constant of 282.3 kJ/mol.
Human activity recognition (HAR) is essential for effective Human-Robot Collaboration (HRC), enabling robots to interpret and respond to human actions. This study evaluates the ability of a vision-based tactile sensor...
详细信息
Surgical instrument segmentation in robot-assisted surgery (RAS) - especially that using learning-based models - relies on the assumption that training and testing videos are sampled from the same domain. However, it ...
详细信息
Strain-controlled isotropic compression gives rise to jammed packings of repulsive, frictionless disks with either positive or negative global shear moduli. We carry out computational studies to understand the contrib...
详细信息
This paper summarizes the experimental investigation of influence of process parameters on surface quality and dimensional accuracy of slots milled in titanium alloy TC4. Samples were milled using a 10 mm HXT coated m...
This paper summarizes the experimental investigation of influence of process parameters on surface quality and dimensional accuracy of slots milled in titanium alloy TC4. Samples were milled using a 10 mm HXT coated monolith end mill for HSM milling of superalloys and titanium alloys. Process parameters, such as rotational speed, feed rate, and depth of cut were selected based on the Taguchi L9 method. After machining samples were measured, including surface quality parameters such as roughness, waviness and dimensional deviations. Measurement results indicate that within inspected parameter range rotational speed to feed ratio has a greater influence on surface quality than the depth of cut while having less influence on dimensional accuracy.
Experimental data on the compressive strength σmax versus strain rate Ε eng for metallic glasses undergoing uniaxial compression shows significantly different behavior for different alloys. For some metallic glasse...
详细信息
Two-dimensional (2D) materials offer significant potential for applications in energy-harvesting devices, batteries, sensors, and transistors. However, their intrinsic brittleness makes them prone to mechanical failur...
详细信息
Two-dimensional (2D) materials offer significant potential for applications in energy-harvesting devices, batteries, sensors, and transistors. However, their intrinsic brittleness makes them prone to mechanical failure, limiting their practical use. In this work, we perform in situ transmission electron microscopy (TEM) fracture tests on monolayer MoSe 2 and uncover an extrinsic toughening effect induced by an ultrathin adsorbed polystyrene adlayer. This adlayer substantially enhances the fracture resistance of the 2D flakes. Through a combination of molecular dynamics simulations and finite element analysis, we elucidate the molecular mechanism behind this toughening effect. It arises from the active crack-bridging behavior of entangled polymer chains and the formation of a fracture process zone that stabilizes crack propagation and increases the energy required for crack extension. The proposed toughening mechanism offers a pathway to improving the mechanical reliability of 2D material-based devices by mitigating the risk of sudden failure.
Many researchers have identified robotics as a potential solution to the aging population faced by many developed and developing countries. If so, how should we address the cognitive acceptance and ambient control of ...
详细信息
The objective of this study was to develop and characterize an osteoimmunomodulatory diopside-based glass-ceramic nanoparticle synthesized using a sol-gel synthesis method. Hydroxyapatite nanoparticles were utilized a...
详细信息
The objective of this study was to develop and characterize an osteoimmunomodulatory diopside-based glass-ceramic nanoparticle synthesized using a sol-gel synthesis method. Hydroxyapatite nanoparticles were utilized as a gold standard control. X-ray diffraction, transmission electron microscopy, scanning electron microscopy equipped with energy dispersive spectroscopy, dynamic light scattering, and zeta-potential analysis were performed to characterize the crystalline phase, morphology, microstructure, composition, hydrodynamic size distribution, and surface charge, respectively. Weight loss, pH, and ion release were measured after immersion of glass-ceramic nanoparticles in simulated body fluid to evaluate the nanoparticle’s biodegradation, showing ranges of Ca 2+ , Mg 2+ , and Si 4+ ion release previously found to be osteogenic and angiogenic. Cytocompatibility with human bone-marrow-derived mesenchymal stem cells and murine RAW264.7 macrophages was studied using metabolic activity (MTT) and live/dead fluorescent assays, demonstrating dose-dependent cytotoxicity in RAW264.7 cells and excellent biocompatibility with mesenchymal stem cells. The effect of the nanoparticles on M1/M2 macrophage polarization potential was evaluated through ELISA and phase-contrast image analysis. Our glass-ceramic nanoparticle promoted greater M2-associated anti-inflammatory IL-1ra cytokine release than M1-associated pro-inflammatory TNF-α release compared to hydroxyapatite nanoparticles, though significant morphological changes were not observed. These results indicate that our glass-ceramic nanoparticle is a promising osteoimmunomodulatory biomaterial for bone regenerative applications.
暂无评论