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Concurrent hetero-/homo-geneous electrocatalysts to bi-phasically mediate sulfur species for lithium-sulfur batteries

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Journal of Energy Chemistry 2024年第6期93卷 663-668,I0016页

作者： Rui-Bo LingHu Jin-Xiu Chen Jin-Hao Zhang Bo-Quan Li Qing-Shan Fu Gulnur Kalimuldina Geng-Zhi Sun Yunhu Han Long Kong Xi’an Institute of Flexible Electronics(IFE) Northwestern Polytechnical UniversityXi’an 710129ShaanxiChina Institute of Advanced Materials Nanjing Tech UniversityNanjing 211816JiangsuChina Advanced Research Institute of Multidisciplinary Science Beijing Institute of TechnologyBeijing 100081China Department of Mechanical and Aerospace Engineering School of Engineering and Digital SciencesNazarbayev UniversityKabanbay Batyr Ave.53Astana 010000Kazakhstan

Expediting redox kinetics of sulfur species on conductive scaffolds with limited charge accessible surface is considered as an imperative approach to realize energy-dense and power-intensive lithium-sulfur(Li-S)*** this work,the concept of concurrent hetero-/homo-geneous electrocatalysts is proposed to simultaneously mediate liquid-solid conversion of lithium polysulfides(LiPSs)and solid lithium disulfide/sulfide(Li_(2)S_(2)/Li_(2)S)propagation,the latter of which suffers from sluggish reduction kinetics due to buried conductive scaffold surface by extensive deposition of Li_(2)S_(2)/Li_(2)*** selected model material to verify this concept is a two-in-one catalyst:carbon nanotube(CNT)scaffold supported iron-cobalt(Fe-Co)alloy nanoparticles and partially carbonized selenium(C-Se)*** Fe-Co alloy serves as a heterogeneous electrocatalyst to seed Li_(2)S_(2)/Li_(2)S through sulphifilic active sites,while the C-Se sustainably releases soluble lithium polyselenides and functions as a homogeneous electrocatalyst to propagate Li_(2)S_(2)/Li_(2)S via solution *** bi-phasic mediation of the sulfur species benefits reduction kinetics of LiPS conversion,especially for the massive Li_(2)S_(2)/Li_(2)S growth scenario by affording an additional solution directed route in case of conductive surface being largely *** strategy endows the Li-S batteries with improved cycling stability(836 mA h g^(-1)after 180 cycles),rate capability(547 mA h g^(-1)at 4 C)and high sulfur loading superiority(2.96 mA h cm^(-2)at 2.4 mg cm^(-2)).This work hopes to enlighten the employment of bi-phasic electrocatalysts to dictate liquid-solid transformation of intermediates for conversion chemistry batteries.

关键词： Lithium-sulfur batteries Electrocatalysis Lithium polysulfides Sulfur cathode Energy density

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Thermodynamic investigation of compounds in the MnO-V2O5 system and their applications

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Ceramics International 2025年第17期51卷 23751-23759页

作者： Li, Zhuoyang Zhang, Yang Pei, Guishang Jiao, Mengjiao Lv, Xuewei Chongqing Key Laboratory of Vanadium-Titanium Metallurgy and Advanced Materials Chongqing University No. 174 Shazheng Street Shapingba District Chongqing400044 China College of Materials Science and Engineering Chongqing University No. 174 Shazheng Street Shapingba District Chongqing400044 China Department of Materials Science and Engineering Seoul National University 1 Gwanak-ro Gwanak-gu Seoul08826 Korea Republic of The State Key Laboratory of Mechanical Transmissions Chongqing University No. 174 Shazheng Street Shapingba District Chongqing400044 China

MnV2O6 and Mn2V2O7 are essential compounds in the manganese salt roasting process for extracting vanadium and serve as excellent battery materials. Determining their thermodynamic properties is of significant theoretical and practical importance. In this study, MnV2O6 and Mn2V2O7 were synthesized through solid-state synthesis under a nitrogen atmosphere, and their crystal structures were analyzed using X-ray powder diffraction. The heat capacity of MnV2O6 and Mn2V2O7 were measured using relaxation calorimetry over the temperature range of 2–300 K. The entropy at 298.15 K, including magnetic contributions, was calculated as 178.99 ± 5.35 J K-1·mol-1 for MnV2O6 and Mn2V2O7 for 258.93 ± 6.47 J K-1·mol-1. The standard molar enthalpies of formation were determined using high-temperature solution calorimetry in a molten lead borate solvent, yielding -1997.09 ± 23.97 for MnV2O6 and -2427.71 ± 29.12 kJ mol-1 for Mn2V2O7 from their element references. Based on these reliable experimental data, other thermodynamic properties, including enthalpy changes, entropy, and Gibbs free energy, were calculated. Finally, thermodynamic simulations were conducted to analyze phase evolution during the manganese salt roasting process and to evaluate the water solubility of MnV2O6 and Mn2V2O7. © 2025 Elsevier Ltd and Techna Group S.r.l.

关键词： Enthalpy

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Use of Circular Economy Goals in Product Development: A Case Study from a Water-Proof Shoe Cover

Use of Circular Economy Goals in Product Development: A Case...

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2023 IEEE International Conference on Industrial engineering and engineering Management, IEEM 2023

作者： Ratnayake, R.M. Oshadha B. Ratnayake, R. M. Chandima British International School of Stavanger Stavanger4032 Norway University of Stavanger Department of Mechanical and Structural Engineering and Materials Science Stavanger Norway

ISBN: (纸本)9798350323153

This study explores the applications of circular economy principles at the product development phase to enable circular product development. In the climates where light rains are common in comparison to heavy downpours, it is impractical to use of a pair of rainboots since they are difficult to maneuver in and are not compact. To address this issue, a waterproof shoe-cover concepts and product were developed combining circular economy goals and product development process. This manuscript demonstrates how a cost-efficient and environmentally friendly shoe-cover product was developed. It also demonstrates how circular economy concepts were vital for ensuring cheap material cost and to create an eco-friendly shoe cover. The product development process paved an organized path to create a successful product. The findings of this case study reveal how to repurpose an existing product at the maturity of its performance by the application of circular economy principles and the product development process, to develop a new real-life product in a systematic way. The findings of this study enable enhancing circular entrepreneurships and self-sustained business ecosystems in different regions. © 2023 IEEE.

关键词： Circular economy concept generation product development shoe-cover

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SiO2-reinforced Poly (methyl methacrylate): Tribology Performance as Service Life Sensor

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Sensors and materials 2023年第8-2期35卷 2845-2854页

作者： Shi, Shih-Chen Zeng, Xin-Xing Chen, Tao-Hsing Wang, Chih-Chia Lin, Yue-Feng Department of Mechanical Engineering National Cheng Kung University No. 1 University Road Tainan City70101 Taiwan Department of Mechanical Engineering National Kaohsiung University of Science and Technology No. 415 Jiangong Rd. Sanmin Dist. Kaohsiung City807618 Taiwan Department of Chemical and Materials Engineering Chung Cheng Institute of Technology National Defense University No. 75 Shiyuan Road Taoyuan335009 Taiwan System Engineering and Technology Program National Yang Ming Chiao Tung University No. 1001 University Road Hsinchu300093 Taiwan Department of Mechanical Engineering National Chin-Yi University of Technology No. 57 Sec. 2 Zhongshan Rd. Taiping Dist. Taichung411030 Taiwan

Poly (methyl methacrylate) (PMMA), which is suitable for use in the human body owing to its biocompatibility, is commonly used in medical applications such as bone nails, bone cement, and dentures. However, owing to its hard and brittle nature, PMMA can cause damage when it is subjected to excessive stress and can also cause severe wear. In this study, three different sizes of silica particles were used as reinforcing additives to enhance the wear resistance of PMMA composites. A pin-on-disk wear test was conducted to record the coefficient of friction and wear volume, and the wear volume was measured using a 3D laser scanning microscope. In the wear test, the transfer film of micron and submicron particles produced a plowing effect, resulting in wide grooved wear scars and a higher wear rate than the raw material. The nanoparticle transfer film reduced direct material wear, the wear scars were fine and flat, and the wear rate was decreased, reducing the wear of SiO2-reinforced PMMA composites by 40%. The experimental results revealed that the wear volume is proportional to the wear time. In addition, the observed area of the transfer film on the wear counterpart can be used as a service life sensor of the coating material. © MYU K.K.

关键词： Tribology

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Recently deepened insights regarding Mg corrosion and advanced engineering applications of Mg alloys

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Journal of Magnesium and Alloys 2023年第11期11卷 3948-3991页

作者： Guang-Ling Song Andrej Atrens Department of Ocean Science and Engineering Southern University of Science and Technology1088 Xueyuan BoulevardShenzhen 518055China The University of Queensland School of Mechanical and Mining EngineeringCentre for Advanced Materials Processing and Manufacturing(AMPAM)St LuciaQld 4072 Australia State Key Laboratory of Physical Chemistry of Solid Surfaces Xiamen University422 S.Siming RdXiamen 361005China

This review summarizes recent insights into the Mg corrosion mechanism, clarifies many critical controversial points regarding the Mg corrosion behaviour, and updates some efforts made to extend the industrial application of Mg alloys. Based on the new understandings gained so far, future research directions are also suggested in the review. This review has the following logic. The first section "1. Scope"is a consolidation of the new understandings or developments regarding the Mg corrosion mechanism and the new applications for Mg alloys. It also highlights some key points for the review. The second section "2. Widely accepted knowledge" briefly summarizes the general understanding of Mg corrosion gained so far, which acts as the foundation for the following sections. The third section "3. Recently deepened insights" mainly briefs on some new insights into Mg corrosion phenomena based on recent findings. Different interpretations on the corrosion behaviours are comprehensively discussed in the fourth section "4. Controversial points" and the conclusions are drawn in the subsection"4.5 Clarified points". Apart from the fundamental understandings, various efforts in the application of Mg alloys are presented in the fifth section "5. New applications". Following the research tendency as indicated in the review, prioritized research areas are suggested in "*** directions". The review is concluded with "7. Concluding remarks" at last.

关键词： Mg Corrosion Hydrogen Anode Intelligentization

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Polarization-directed nanophotonic routers based on twodimensional inorganic molecular crystals

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InfoMat 2024年第8期6卷 111-118页

作者： Jiacheng Yao Xin Feng Tingting Zhang Fangqi Chen Zhenglong Zhang Hairong Zheng Tianyou Zhai Tao Ding Key Laboratory of Artificial Micro/Nano Structure of Ministry of Education School of Physics and TechnologyWuhan UniversityWuhanthe People's Republic of China State Key Laboratory of Materials Processing and Die&Mould Technology and School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhanthe People's Republic of China Department of Mechanical Engineering The University of Texas at DallasRichardsonTexasUSA School of Physics and Information Technology Shaanxi Normal UniversityXi'anthe People's Republic of China

Photonic and plasmonic hybrid nanostructures are the key solution for integratednanophotonic circuits with ultracompact size but relative low loss. However,the poor tunability and modulability of conventional waveguides makesthem cumbersome for optical multiplexing. Here we make use of twodimensionalmolecular crystal, α-Sb_(2)O_(3) as a dielectric waveguide via totalinternal reflection, which shows polarization-sensitive modulation of the propagatingbeams due to its large polarization mode dispersion. Both experimentsand simulations are performed to verify such concept. These Sb_(2)O_(3) nanoflakescan be coupled with plasmonic nanowires to form nanophotonic beam splittersand routers which can be easily modulated by changing the polarization of theincidence. It thus provides a robust, exploitable and tunable platform for onchipnanophotonics.

关键词： nanoflakes plasmonics polarization Sb_(2)O_(3) waveguides

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Fabrication and photoluminescence characteristics of novel red-emitting Ba_(2)LuNbO_(6):Eu^(3+)double-perovskite phosphors on near UV WLEDs

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Journal of Rare Earths 2022年第8期40卷 1173-1180页

作者： Haihong Guo Ting Wang Bitao Liu Wei Gao Liang Xiu Zhenen Cui Hao Zhang Qianrui Ma Shaoqing Wang Ziyang Li Longchao Guo Guilong Yan Siufung Yu Xue Yu Xuhui Xu Jianbei Qiu College of Materials and Chemistry&Chemical Engineering Chengdu University of TechnologyChengdu 610059China The Department of Applied Physics The Hong Kong Polytechnic UniversityHong Kong 999077China Research Institute for New Materials Technology Chongqing University of Arts and SciencesChongqing 402160China College of Materials Science and Engineering Kunming University of Science and TechnologyKunming 650093China School of Mechanical Engineering Chengdu UniversityChengdu 610059China

Red emitting phosphors play a significant role in accelerating the improvement of illumination quality for white light emitting diodes(WLEDs).In this work,by using solid-state reaction method,an efficient novel Ba_(2)LuNbO_(6):Eu^(3+)phosphor with double-perovskite structure was successfully ***,a series of Ba_(2)LuNbO_(6):Eu^(3+)red phosphors can be efficiently pumped by the near-ultraviolet(UV)light and then present high-brightness at orange emission(598 nm,~5D_(0)→~7 F_(1))and red emission(610 nm,~5D_(0)→~7 F_(2)).The ratio values of 610 to 598 nm in Ba_(2)LuNbO_(6):Eu^(3+)phosphors exceed 1 when the content of Eu^(3+)is larger than 0.4 mol,because the occupation of Eu^(3+)ions is changed from Lu^(3+)ions with symmetric sites to Ba^(2+)ions with asymmetric ***,the optimized concentration of Eu^(3+)at the~5D_(0)→~7 F_(2)transitions is obtained when x=1,indicating that there is non-concentration quenching in Ba_(2)LuNbO_(6):Eu^(3+)***,the CIE chromaticity coordinates of Ba_(2)LuNbO_(6):Eu^(3+)was calculated to be(0.587,0.361),the color purity was calculated to be 72.26%and internal quenching efficiency(IQE)was measured to be 67%.Finally,the thermal stability of Ba_(2)LuNbO_(6):Eu^(3+)phosphors was also *** work demonstrates that the novel double-perovskite red-emitting Ba_(2)LuNbO_(6):Eu^(3+)phosphors are prospective red emitting elements for WLEDs applications.

关键词： Ba_(2)LuNbO_(6):Eu^(3+) phosphors Non-concentration quenching Double-perovskite Red emitting Rare earths

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ITO纳米晶-植物纤维复合材料的电阻式压力传感器

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science China materials 2023年第10期66卷 3922-3930页

作者：夏亿劼黄鹏举林心铭吴鲁超李珂高晨溟钟高余 School of Mechanical Engineering University of Shanghai for Science and TechnologyShanghai 200093China Department of Materials Science Fudan UniversityShanghai 200433China

可穿戴电子设备因其在机器人触觉、人机交互和脉搏测试等领域具有潜在应用而引起广泛关注.作为一种可穿戴电子设备,柔性压力传感器应该是环保的,而且制造成本低.基于纤维素纸的压力传感器由于其优良的特性,如轻质、无毒或低毒、可降解... 详细信息

可穿戴电子设备因其在机器人触觉、人机交互和脉搏测试等领域具有潜在应用而引起广泛关注.作为一种可穿戴电子设备,柔性压力传感器应该是环保的,而且制造成本低.基于纤维素纸的压力传感器由于其优良的特性,如轻质、无毒或低毒、可降解性和柔韧性,而引起了人们的关注.在此,我们报道了一种基于铟锡氧化物(ITO)纳米晶体和植物纤维复合材料的电阻式触觉传感器.该压力传感器具有宽的检测范围(0-100 kPa)、高灵敏度(464.88 kPa^(-1))、快速的响应时间(6.93 ms)和恢复时间(7.18 ms)以及良好的加载/卸载稳定性.我们还展示了该压力传感器用于脉搏测试、呼吸监测、语音识别等各种人体运动检测.结果表明,ITO纳米晶-植物纤维复合材料压力传感器在智能可穿戴电子产品中显示出巨大应用潜力.

关键词： pressure sensors piezoresistance nanocrystalline composite

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Design and Feasibility Test of In-House Indirect Perfusion Bioreactor for 3-D Cell Culture 15

Design and Feasibility Test of In-House Indirect Perfusion B...

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15th Biomedical engineering International Conference, BMEiCON 2023

作者： Suwannaphan, T. Tharasanit, T. Wongpakham, T. Pimpin, A. Chessadangkul, K. King Mongkut's University of Technology North Bangkok Department of Mechanical Engineering Technology Bangkok Thailand Faculty of Veterinary Science Chulalongkorn University Department of Obstetrics Gynaecology and Reproduction Bangkok Thailand Chulalongkorn University Faculty of Engineering Department of Mechanical Engineering Bangkok Thailand Chulalongkorn University Biomedical Engineering Program Faculty of Engineering Bangkok Thailand

ISBN: (纸本)9798350345247

Selection of bioreactor system depends on many factors such as type of products, process of culture, and product density. No standard for development methodology is available nowadays. This work demonstrated the development of multi mini-chamber indirect perfusion bioreactor to support 3-D cell culture. The systems consisted of scaffolds, cell/scaffold retainers, culture tanks with a single peristaltic pump. Flow simulation was conducted to investigate the effects of flow rate and inlets/outlets' position on the distribution of shear stresses on the cell/scaffold cassettes installed inside the bioreactor. The prototype with 4 culture tanks connected in series was tested for long period operation. Lastly, preliminary experiments to culture and differentiate pig muscle stem cells were conducted. The results showed that muscle cells were successfully differentiated both on glass slides and aloe vera scaffolds inside the developed bioreactor. © 2023 IEEE.

关键词： Flow simulation

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Multi-function adsorbent-photocatalyst MXene-TiO_(2) composites for removal of enrofloxacin antibiotic from water

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Journal of Environmental sciences 2023年第2期124卷 414-428页

作者： Siwanat Sukidpaneenid Chamorn Chawengkijwanich Chonlada Pokhum Toshihiro Isobe Pakorn Opaprakasit Paiboon Sreearunothai TAIST-Tokyo Tech Program Sirindhorn International Institute of TechnologyThammasat UniversityPathum Thani 12121Thailand National Nanotechnology Center National Science and Technology Development AgencyPathum Thani 12120Thailand Department of Materials Science and Engineering School of Materials and Chemical TechnologyTokyo Institute of TechnologyTokyo 152-8550Japan School of Bio-Chemical Engineering and Technology Sirindhorn International Institute of TechnologyThammasat UniversityPathum Thani 12121Thailand

MXenes,a new family of two-dimensional transition metal carbides or nitrides,have attracted tremendous attention for various applications due to their unique properties such as good electrical conductivity,hydrophilicity,and ion *** this work,Ti_(3)C_(2) MXene,or MX,is converted to MX-TiO_(2) composites using a simple and rapid microwave hydrothermal treatment in HCl/NaCl mixture solution that induces formation of fine TiO_(2) particles on the MX parent structure and imparts photocatalytic activity to the resulting MX-TiO_(2) *** composites were used for enrofloxacin(ENR),a frequently found contaminating antibiotic,removal from *** relative amount of the MX and TiO_(2) can be controlled by controlling the hydrothermal temperature resulting in composites with tunable adsorption/photocatalytic *** addition was found to play important role as composites synthesized without NaCl could not adsorb enrofloxacin *** NaCl into the hydrothermal treatment causes sodium ions to be simultaneously intercalated into the composite structure,improving ENR adsorption greatly from 1 to 6 mg ENR/g *** also slows down the MX to TiO2 conversion leading to a smaller and more uniform distribution of TiO_(2) particles on the ***-TiO_(2)/NaCl composites,which have sodium intercalated in their structures,showed both higher ENR adsorption and photocatalytic activity than composites without NaCl despite the latter having higher TiO2 *** ENR on the composites can be efficiently degraded by free radicals generated from the photoexcited TiO2 particles,leading to high photocatalytic degradation *** demonstrates the synergetic effect between adsorption and photocatalytic degradation of the synthesized compounds.

关键词： MXene-TiO_(2)composites Ti3C2 Ion-exchange Photocatalytic degradation Enrofloxacin Antibiotics removal

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