Excessive emission of carbon dioxide(CO_(2))has posed an imminent threat to human's environment and global *** achieve a sustainable future,solid oxide electrolysis cell(SOEC),which can efficiently combine CO_(2)re...
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Excessive emission of carbon dioxide(CO_(2))has posed an imminent threat to human's environment and global *** achieve a sustainable future,solid oxide electrolysis cell(SOEC),which can efficiently combine CO_(2)reduction reaction(CO_(2)RR)and renewable energy storage,has become increasingly attractive owing to its unique ***,symmetrical SOEC(SSOEC)has been considered as one of the most versatile cell configurations due to its simplified process,high compatibility,and low ***,the electrode material requirements become very demanding since efficient catalytic-activities are required for both CO_(2)RR and oxygen evolution reaction(OER).Herein,we demonstrate a novel high-entropy perovskite type symmetrical electrode Pr_(0.5)Ba_(0.5)Mn_(0.2)Fe_(0.2)Co_(0.2)Ni_(0.2)Cu_(0.2)O_(3-δ)(HE-PBM)for SSOEC.B-site doping of transition metals such as Mn,Fe,Co,Ni,and Cu in HE-PBM anode has been found to strongly accelerate the OER in the ***,the presence of in-situ formed Fe–Co–Ni–Cu quaternary alloy nanocatalysts from HE-PBM cathode under reducing atmosphere has resulted in superior catalytic-activity towards CO_(2)*** faster kinetics are also reflected by the significantly low polarization resistance of 0.289Ω⋅cm^(-2)and high electrolysis current density of 1.21 A⋅cm^(-2)for CO_(2)RR at 2.0 V and 800℃.The excellent electrochemical performance and stability demonstrate that the highentropy perovskite material is a promising electrode material in SSOEC for efficient and durable CO_(2)RR.
Recently,a disruptive idea was reported about the discovery of a new type of battery named Liquid Displacement Battery(LDB)comprising liquid metal electrodes and molten salt *** cell featured a novel concept of a poro...
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Recently,a disruptive idea was reported about the discovery of a new type of battery named Liquid Displacement Battery(LDB)comprising liquid metal electrodes and molten salt *** cell featured a novel concept of a porous electronically conductive faradaic membrane instead of the traditional ion-selective ceramic *** are attractive for stationary storage applications but need mitigation against *** the instant battery chemistry,Li|LiCl-PbCl_(2)|Pb,reducing the diffusion coefficient of lead ions can be a way forward and a solution can be the addition of Pb O to the *** latter acts as a supplementary barrier and complements the function of the faradaic *** remedial actions improved the cell’s coulombic efficiency from 92%to 97%without affecting the voltage *** addition,the limiting current density of a 500 m Ah cell increased from 575 to 831 m A cm;and the limiting power from 2.53 to 3.66 ***,the effect of Pb O on the impedance and polarization of the cell was also studied.
The development of environmentally friendly ceramics for electrostatic energy storage has drawn growing interest due to the wide application in high power and/or pulsed power electronic ***,it is difficult to simultan...
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The development of environmentally friendly ceramics for electrostatic energy storage has drawn growing interest due to the wide application in high power and/or pulsed power electronic ***,it is difficult to simultaneously achieve ultrahigh recoverable energy storage density(W rec>8 J/cm^(3))and high efficiency(η>80%),which restricts their application in the miniaturized,light weight and easy integrated electronic ***,the novel NaNbO_(3)-(Bi_(0.8)Sr_(0.2))(Fe_(0.9) Nb_(0.1))O_(3) relaxor antiferro-electric ceramics,which integrates the merits of antiferroelectrics and relaxors,are demonstrated to exhibit stabilized antiferroelectric phase and enhanced dielectric relaxor *** particular impor-tance is that the 0.88NN-0.12BSFN ceramic achieves giant electric breakdown strength E_(b)=98.3 kV/mm,ultrahigh W _(rec)=16.5 J/cm^(3) and high h=83.3%,as well as excellent frequency,cycling and thermal reliability *** comprehensive energy storage performance of NN-BSFN not only out-performs state-of-the-art dielectric ceramics by comparison,but also displays outstanding potential for next-generation energy storage capacitors.
Supply chain risk management involves an effort to establish collaboration among partners to develop a shared risk management process to deal with risks and uncertainties resulting from logistic activities and distrib...
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ISBN:
(纸本)9798350323153
Supply chain risk management involves an effort to establish collaboration among partners to develop a shared risk management process to deal with risks and uncertainties resulting from logistic activities and distribution of resources. Risk management in healthcare supply chains involves the identification of the risk of quality and information failure in delivering healthcare services. In recent times, the challenges of healthcare supply chains include the management of risks along with maintenance of the ecological balance of natural environments. Thus, mitigating the impact of supply chain disruptions and healthcare waste is a crucial need. The implementation of circular economy (CE) in healthcare supply chains can result in eliminating waste using eco-friendly materials, optimization of resource yields, and circulation of products at their highest value. The purpose of this study is to minimize the risk impact if the supply of the critical product is delayed or unavailable when needed and using sustainable approach with CE implementation to mitigate the risks. To fulfil the research objectives, the risk analysis, evaluation, assessment, and mitigation, as well as the CE strategy for establishing sustainable supply chains, are demonstrated. A qualitative case study is being undertaken at the primary care level, an upstream healthcare service provider. Primary care is crucial for health-care delivery. The risk matrix was built by considering the mean time to arrival for the critical product. Data was gathered through interviews with practitioners such as doctors, operational employees, and logistic department managers. This research used Failure Mode Effect and Critical Analysis (FMECA) to prioritize risks and minimize the risk of failure within healthcare supply chains. The results show that the highest Risk Priority Number (RPN) is associated with delays or shortages of critical products such as latex gloves, often due to import delays. To address this issue in
Wetting, indicating the ability of a liquid to spread out over solid surfaces,is of vital importance in addressing the scientific issues related to energy and environment technologies. The study of wetting encompasses...
Wetting, indicating the ability of a liquid to spread out over solid surfaces,is of vital importance in addressing the scientific issues related to energy and environment technologies. The study of wetting encompasses the academic disciplines of surface chemistry, nanotechnology, materialsscience and energy *** past several decades have witnessed significant progress in achieving desirable wetting performance with water,
Wetting mechanism of molten 2N(99 %)-, 5N(99.999 %)-purity aluminum and Al-12.6 %Si alloy on silicon nitride (Si3N4) substrate was investigated by conducting high-temperature wettability tests with a sessile drop meth...
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High/medium entropy alloys(H/MEAs)are generally possible to exhibit chemical short-range order(SRO).However,the complex role of SRO on mechanical properties from nano-scale to meso-scale is still challenging so ***,we...
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High/medium entropy alloys(H/MEAs)are generally possible to exhibit chemical short-range order(SRO).However,the complex role of SRO on mechanical properties from nano-scale to meso-scale is still challenging so ***,we study the strengthening mechanism and deformation behavior in a model body-centered-cubic HfNbTa MEA by using atomic-scale molecular dynamics,micro-scale dislocation dynamics,and meso-scale crystal plasticity finite *** SRO inhibits dislocation nucleation at the atomic scale,improving the flow *** SRO-induced ultrastrong local stress fluctuation greatly improves the micro-scale dislocation-based strength by the significant dislocation forest ***,the Ta-rich locally ordered structure leads to an obvious heterogeneous strain and stress partitioning,which forms a strong strain gradient in the adjacent grain interiors and contributes to the strong back-stress-induced strain hardening.
In this research, electroplastic test with and without stress relaxation is utilized to decouple the rate-dependent component of stress drop. The stress relaxation exhausts the effect of rate-dependent component by di...
In this research, electroplastic test with and without stress relaxation is utilized to decouple the rate-dependent component of stress drop. The stress relaxation exhausts the effect of rate-dependent component by dislocation overcoming the short-range obstacle. The net contribution due to electric current after stress relaxation is rate-independent or athermal. No additional assumptions are included to derive the athermal component. The methodology is successfully demonstrated through electric-assisted deformation tests using AA1050 alloy samples.
Although landfills damage the environment due to over-exploitation of land resources, several countries still depend on this waste management strategy. To reduce this dependency, several countries have begun to increa...
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In this study, we present a method to enhance the sensitivity of fluorinated EUV resists by leveraging the rapid coupling reaction between electrophilic carbon radicals and electron-rich alkenes. To validate the impac...
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