A comparative study on the performance of gas atomized(GA)and rotating-disk atomized(RDA)aluminum alloy powders produced on industrial scale for laser directed energy deposition(L-DED)process was carried *** powder ch...
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A comparative study on the performance of gas atomized(GA)and rotating-disk atomized(RDA)aluminum alloy powders produced on industrial scale for laser directed energy deposition(L-DED)process was carried *** powder characteristics,the printing process window,and the quality,microstructure,and mechanical properties of printed parts were taken into account for comparison and *** results demonstrate that the RDA powder is superior to the GA powder in terms of sphericity,surface quality,internal defects,flowability,and apparent density,together with a larger printing process window during the L-DED parts ***,the resultant parts from the RDA powder have higher dimensional accuracy,lower internal defects,more uniform and finer microstructure,and more favorable mechanical properties than those from the GA powder.
Alloying has been proposed to circumvent scaling relations between the adsorption energies thus allowing for the complete optimization of multistep *** the fidelity of scaling rules on high-entropy alloy(HEA)surfaces ...
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Alloying has been proposed to circumvent scaling relations between the adsorption energies thus allowing for the complete optimization of multistep *** the fidelity of scaling rules on high-entropy alloy(HEA)surfaces is assessed focusing on hydrogen-containing molecules,^(*)AH_(x) for A=C and N(x=0,1,2,3),A=S(x=0,1,2)and A=O(x=0,1).Using an adsorbate-and site-specific deep learning model to rapidly compute the adsorption energies on CoMoFeNiCu HEA surfaces,the energies of ^(*)AH_(x) and ^(*)A are shown to be linearly correlated if ^(*)A and ^(*)AH_(x) have identical adsorption site ***,a local linear dependence emerges between the configuration-averaged adsorption energies irrespective of the site *** these correlations represent a weaker form of the scaling relationships,they are sufficient to prohibit the optimization of multistep *** underpinning of this behavior is twofold(1)the nearsightedness principle and(2)the narrow distribution of the adsorption energies around the mean-field *** the nearsightedness is general for all electronic systems,the second criterion applies in HEAs with relatively strong reactive *** present findings strongly suggest that alloys may not generally enable the breaking of scaling relationships.
Solute gradients next to an interface drive a diffusioosmotic flow, the origin of which lies in the intermolecular interactions between the solute and the interface. These flows on the surface of colloids introduce an...
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Solute gradients next to an interface drive a diffusioosmotic flow, the origin of which lies in the intermolecular interactions between the solute and the interface. These flows on the surface of colloids introduce an effective slip velocity, driving their diffusiophoretic migration. In confined environments, the interplay between diffusiophoresis and diffusioosmosis governs the motion of colloids. Previous studies have indeed demonstrated the quantitative modulation of phoretic migration by the osmotic flows. Here, we show that diffusioosmotic flows can lead to qualitatively distinct outcomes, reversing the direction of colloidal focusing expected from diffusiophoresis alone. Using microfluidic experiments in a T-junction, numerical simulations, and theoretical modeling, we explain our observations to be due to an interplay between diffusiophoretic migration of colloids toward the walls and their entrainment in a diffusioosmotic vortex. We show this focusing to be persistent for a range of salt types, salt gradients, and flow rates, and establish a criterion for its emergence. Our work sheds light on how boundaries modulate the solute-mediated transport of colloids in confined environments and how the colloidal trajectories can be utilized to infer the surface properties.
Low erosion high-energy propellant is one of the research directions to extend the weapon's life and improve the weapon's *** this study,energetic propellants containing different corrosion in-hibitors were de...
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Low erosion high-energy propellant is one of the research directions to extend the weapon's life and improve the weapon's *** this study,energetic propellants containing different corrosion in-hibitors were designed and *** bomb tests and semi-confined bomb experiments were used to investigate the burning and erosion properties of the *** mechanism of erosion-reducing of titanium dioxide(titania,TiO2),talc,and octaphenylsilsesquioxane(OPS)on the propellant was com-paratively *** results show that OPS has the lowest burning rate and the longest burning time,and a minimized loss of fire force,with the best effect of explosion heat *** erosion reduction efficiency of OPS is twice that of TiO2 and *** mechanism analysis shows that the decomposition and heat absorption of OPS can effectively reduce the thermal erosion effect and carbon erosion,and the gas produced can reduce the loss of chamber pressure and form a uniformly distributed nano-SiO2 protective *** solid-state high-efficiency organosilicon erosion inhibitor is an important guide for designing high-energy low-erosion gun propellants.
Natural fiber reinforced polymer composites are being used globally in every field of engineering and technology to develop structural and non-structural components. These composites are being extensively used in auto...
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Many-body interactions between polymer-grafted nanoparticles(NPs)play a key role in promoting their assembly into low-dimensional structures within polymer melts,even when the particles are spherical and isotropically...
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Many-body interactions between polymer-grafted nanoparticles(NPs)play a key role in promoting their assembly into low-dimensional structures within polymer melts,even when the particles are spherical and isotropically ***,capturing such interactions in simulations of NP assembly is very challenging because explicit modeling of the polymer grafts and melt chains is highly computationally expensive,even using coarse-grained ***,we develop a many-body potential for describing the effective interactions between spherical polymer-grafted NPs in a polymer matrix through a machine-learning *** approach involves using permutationally invariant polynomials to fit two-and three-body interactions derived from the potential of mean force *** potential developed here reduces the computational cost by several orders of magnitude,thereby,allowing us to explore assembly behavior over large length and time *** show that the potential not only reproduces previously known assembled phases such as 1D strings and 2D hexagonal sheets,which generally cannot be achieved using isotropic two-body potentials,but can also help discover interesting phases such as networks,clusters,and *** demonstrate how each of these assembly morphologies intrinsically arises from a competition between two-and three-body *** approach for deriving many-body effective potentials can be readily extended to other colloidal systems,enabling researchers to make accurate predictions of their behavior and dissect the role of individual interaction energy terms of the overall potential in the observed behavior.
Advances in precision coatings are critical in enhancing the functionality of porous materials and the performance of three-dimensionally (3-D) micro-architected devices in applications ranging from molecular sorption...
The flow-induced motion(FIM)of an elastically mounted square-section cylinder is experimentally investigated over a wide range of Reynolds numbers(1.5×10^(4)<Re<7.0×10^(4)).A 14 mlong towing tank water...
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The flow-induced motion(FIM)of an elastically mounted square-section cylinder is experimentally investigated over a wide range of Reynolds numbers(1.5×10^(4)
Magnesium alloys containing biocompatible components show tremendous promise for applications as temporary biomedical devices. However, to ensure their safe use as biodegradeable implants, it is essential to control t...
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Magnesium alloys containing biocompatible components show tremendous promise for applications as temporary biomedical devices. However, to ensure their safe use as biodegradeable implants, it is essential to control their corrosion rates. In concentrated Mg alloys, a microgalvanic coupling between the α-Mg matrix and secondary precipitates exists which results in increased corrosion rate. To address this challenge, we engineered the microstructure of a biodegradable Mg-Zn-RE-Zr alloy by friction stir processing (FSP), improving its corrosion resistance and mechanical properties simultaneously. The FS processed alloy with refined grains and broken and uniformly distributed secondary precipitates showed a relatively uniform corrosion morphology accompanied with the formation of a stable passive layer on the alloy surface. In vivo corrosion evaluation of the processed alloy in a small animal model showed that the material was well-tolerated with no signs of inflammation or harmful by-products. Remarkably, the processed alloy supported bone until it healed till eight weeks with a low in vivo corrosion rate of 0.7 mm/year. Moreover, we analyzed blood and histology of the critical organs such as liver and kidney, which showed normal functionality and consistent ion and enzyme levels, throughout the 12- week study period. These results demonstrate that the processed Mg-Zn-RE-Zr alloy offers promising potential for osseointegration in bone tissue healing while also exhibiting controlled biodegradability due to its engineered microstructure. The results from the present study will have profound benefit for bone fracture management, particularly in pediatric and elderly patients.
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