Emerging industrial systems and solutions are such that the inherent complexity of the system, coupled with highly dynamic conditions, demand operators to perceive and judge abnormal situations, predict multiple scena...
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The present paper discusses the effects of geometric parameters on mixed convective heat transfer and fluid flow in a lid-driven square enclosure fitted with an internal elliptical cylinder. The side walls of the encl...
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Currently, the main materials for the manufacture of sliding bearings are cast bronze and powder bronze, where the main alloying element is tin, the graphite content in these alloys is from 2 to 4%. At the same time, ...
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Reproducible wafer-scale growth of two-dimensional(2D)materials using the Chemical Vapor Deposition(CVD)process with precise control over their properties is challenging due to a lack of understanding of the growth me...
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Reproducible wafer-scale growth of two-dimensional(2D)materials using the Chemical Vapor Deposition(CVD)process with precise control over their properties is challenging due to a lack of understanding of the growth mechanisms spanning over several length scales and sensitivity of the synthesis to subtle changes in growth conditions.A multiscale computational framework coupling Computational Fluid Dynamics(CFD),Phase-Field(PF),and reactive Molecular Dynamics(MD)was developed–called the CPM model–and experimentally *** between theoretical predictions and thorough experimental measurements for a Metal-Organic CVD(MOCVD)-grown WSe_(2)model material revealed the full power of this computational ***-area uniform 2D materials are synthesized via MOCVD,guided by computational *** developed computational framework provides the foundation for guiding the synthesis of wafer-scale 2D materials with precise control over the coverage,morphology,and properties,a critical capability for fabricating electronic,optoelectronic,and quantum computing devices.
Control of the formation and stability of reverted austenite is critical in achieving a favorable combination of strength,ductility,and toughness in high-strength *** this work,the effects of Cu precipitation on the a...
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Control of the formation and stability of reverted austenite is critical in achieving a favorable combination of strength,ductility,and toughness in high-strength *** this work,the effects of Cu precipitation on the austenite reversion and mechanical properties of maraging stainless steels were investigated by atom probe tomography,transmission electron microscopy,and mechanical *** results indicate that Cu accelerates the austenite reversion kinetics in two manners:first,Cu,as an austenite stabilizer,increases the equilibrium austenite fraction and hence enhances the chemical driving force for the austenite formation,and second,Cu-rich nanoprecipitates promote the austenite reversion by serving as heterogeneous nucleation sites and providing Ni-enriched chemical conditions through interfacial *** addition,the Cu precipitation hardening compensates the strength drop induced by the formation of soft reverted *** tensile deformation,the metastable reverted austenite transforms to martensite,which substantially improves the ductility and toughness through a transformation-induced plasticity(TRIP)*** Cu-added maraging stainless steel exhibits a superior combination of a yield strength of~1.3 GPa,an elongation of~15%,and an impact toughness of~58 J.
Solid solutions of Na_(0.5) Bi_(0.5) TiO_(3)(NBT)and BiNi_(0.5) Ti_(0.5) O_(3)(BNiT)were prepared by a solid-state reaction route,and their electrical properties investigated by a combination of impedance spectroscopy...
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Solid solutions of Na_(0.5) Bi_(0.5) TiO_(3)(NBT)and BiNi_(0.5) Ti_(0.5) O_(3)(BNiT)were prepared by a solid-state reaction route,and their electrical properties investigated by a combination of impedance spectroscopy and electromotive force measurements to explore the possibility of developing mixed ionic-electronic conductors based on *** analysis showed that BNiT has a large solid solution limit in NBT(60 mol%based on X-ray diffraction),and the room temperature crystal structure changes from rhombohedral to pseudo-cubic with increasing BNiT *** diffraction revealed the coexistence of rhombohedral and tetragonal phases when the BNiT content≥40 mol%.Electrically,incorporation of BNiT induces p-type electronic conduction into NBT by hopping of holes between Ni^(2+)(Ni_(Ni)^(x))and Ni^(3+)(Ni·Ni),and therefore changes the electrical conduction mechanism systematically from predominant oxide-ion conduction to mixed ionic-electronic conduction and then to predominant p-type electronic *** total conductivity of the solid solutions showed a“V-shape”variation with increasing BNiT *** mechanisms for the phase evolution and the conductivity-composition relationships are *** high levels of ionic and electronic conductivity simultaneously in NBT by introducing elements with variable oxidation states remains challenging due to the competition between an enhanced electronic component and a suppressed ionic *** levels of BNiT incorporation are,however,beneficial to reducing the dielectric loss of NBT for dielectric applications.
The exploration of heterostructures composed of two-dimensional(2D)transition metal dichalcogenide(TMDc)materials has garnered significant research attention due to the distinctive properties of each individual compon...
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The exploration of heterostructures composed of two-dimensional(2D)transition metal dichalcogenide(TMDc)materials has garnered significant research attention due to the distinctive properties of each individual component and their phase-dependent unique *** the plasma-enhanced chemical vapor deposition(PECVD)method,we analyze the fabrication of heterostructures consisting of two phases of molybdenum disulfide(MoS_(2))in four different *** initial hydrogen evolution reaction(HER)polarization curve indicates that the activity of the heterostructure MoS_(2)is consistent with that of the underlying MoS_(2),rather than the surface activity of the upper MoS_(2).This behavior can be attributed to the presence of Schottky barriers,which include contact resistance,which significantly hampers the efficient charge transfer at junctions between the two different phases of MoS_(2)layers and is mediated by van der Waals ***,the energy barrier at the junction dissipates upon reaching a certain electrochemical potential,indicating surface activation from the top phase of MoS_(2)in the ***,the 1T/2H MoS_(2)heterostructure demonstrates enhanced electrochemical stability compared to its metastable 1T-MoS_(2).This fundamental understanding paves the way for the creation of phase-controllable heterostructures through an experimentally viable PECVD,offering significant promise for a wide range of applications.
Since the very first patent on poly(3,4-ethylenedioxythiophene) (PEDOT) that was filed in 1988, this polymer has been widely utilized and has achieved great success owing to its high electrical conductivity and excell...
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Future innovation of optoelectronic industrial applications for energy saving devices such as self-powered sensors and photodetectors have gained much research attention. Here, for the first time, two-dimensional (2D)...
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The positive photoplastic effect (PPE) and photoinduced stiffening are the reversible increases of the flow stress and the elastic modulus of a material upon irradiation with light. Several material groups, including ...
The positive photoplastic effect (PPE) and photoinduced stiffening are the reversible increases of the flow stress and the elastic modulus of a material upon irradiation with light. Several material groups, including the II-VI compounds and alkali halides show some form of these effects. The dependence of mechanical properties on light illumination has not been reported for methylammonium lead iodide (CH3NH3PbI3 or MAPbI3) perovskites. In this study a positive PPE and photoinduced stiffening were found in MAPbI3 thin film perovskites. Thin films of 500 nm thickness were synthesized and then polished. The chemical formation of MAPbI3 was verified by x-ray diffraction. Atomic force microscopy and scanning electron microscopy were used to characterize the surface topography. Nanoindentation experiments were performed to investigate the elastic and plastic properties in darkness and under illumination. The elastic modulus and hardness were found to increase by 53% and 67% respectively when the perovskite was illuminated.
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