self-oscillating polymer gel has become a distinguished class of smart soft materials. Here we fabricated and demonstrated a self-oscillating structural gel network with the incorporation of the Belousov-Zhabotinsky (...
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self-oscillating polymer gel has become a distinguished class of smart soft materials. Here we fabricated and demonstrated a self-oscillating structural gel network with the incorporation of the Belousov-Zhabotinsky (BZ) reaction. The structural polymer gel oscillates at a macroscopic level with remarkably faster kinetics compared to a normal gel of similar chemical compositions. The structural polymer gel also displays larger oscillating amplitude compared to the normal gel because of the increased diffusion of fluids surrounding the gel particles. This type of structural polymer gels can be harnessed to provide novel and feasible applications in a wide variety of fields, such as drug delivery, nanopatterning, chemical and biosensing, and photonic crystals.
Ferromagnetic Ising systems with competing interactions are considered in the presence of a random field. We find that in three space dimensions the ferromagnetic phase is disordered by a random field which is conside...
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Ferromagnetic Ising systems with competing interactions are considered in the presence of a random field. We find that in three space dimensions the ferromagnetic phase is disordered by a random field which is considerably smaller than the typical interaction strength between the spins. This is the result of a novel disordering mechanism triggered by an underlying spin-glass phase. Calculations for the specific case of the long-range dipolar LiHoxY1−xF4 compound suggest that the above mechanism is responsible for the peculiar dependence of the critical temperature on the strength of the random field and the broadening of the susceptibility peaks as temperature is decreased, as found in recent experiments by Silevitch et al.. [Nature (London) 448, 567 (2007)]. Our results thus emphasize the need to go beyond the standard Imry-Ma argument when studying general random-field systems.
This paper presents the design and fabrication of a highly-miniaturized system for continuous glucose monitoring which holds great promise for patients inflicted with diabetes mellitus. To achieve the realization of a...
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ISBN:
(纸本)9781479903313
This paper presents the design and fabrication of a highly-miniaturized system for continuous glucose monitoring which holds great promise for patients inflicted with diabetes mellitus. To achieve the realization of a truly implantable system, a variety of issues such as robust electrochemical sensor design, miniaturization of the electronic components and counteracting biofouling and negative tissue response need to be addressed. In this report, we present a highly-miniaturized transcutaneous continuous glucose monitoring system which holistically addresses the aforementioned tribulations associated with implantable devices. Specifically, a high performance amperometric electrochemical glucose sensor is integrated with custom designed complementary metal-oxide-semiconductor electronics. The fabricated electrochemical sensor is Clark-based, and employs stratification of five functional layers to achieve a linear response within the physiological range of glucose concentration (2–22 mM). Furthermore, the sensor is encased with a thick polyvinyl alcohol (PVA) hydrogel containing poly(lactic-co-glycolic acid) (PLGA) microspheres which provides continuous, localized delivery of dexamethasone utilized to combat inflammation and fibrosis. Such miniature size (0.665 mm 2 ) and low power operation (140 μW) of the electronic system render it ideal for continuous glucose monitoring devices and other metabolic sensing systems.
Electrical resistivity measurements as a function of temperature between 1 and 300 K were performed at various pressures up to 3 GPa on the superconducting layered compounds LnO0.5F0.5BiS2 (Ln = La, Ce). At atmospheri...
Electrical resistivity measurements as a function of temperature between 1 and 300 K were performed at various pressures up to 3 GPa on the superconducting layered compounds LnO0.5F0.5BiS2 (Ln = La, Ce). At atmospheric pressure, LaO0.5F0.5BiS2 and CeO0.5F0.5BiS2 have superconducting critical temperatures Tc of 3.3 and 2.3 K, respectively. For both compounds, the superconducting critical temperature Tc initially increases, reaches a maximum value of 10.1 K for LaO0.5F0.5BiS2 and 6.7 K for CeO0.5F0.5BiS2, and then gradually decreases with increasing pressure. Both samples also exhibit transient behavior in the region between the lower Tc phase near atmospheric pressure and the higher Tc phase at higher pressures. This region is characterized by a broadening of the superconducting transition, in which Tc and the transition width ΔTc are reversible with increasing and decreasing pressure. There is also an appreciable pressure-induced and hysteretic suppression of semiconducting behavior up to the pressure at which the maximum value of Tc is found. At pressures above the value at which the maximum in Tc occurs, there is a gradual decrease of Tc and further suppression of the semiconducting behavior with pressure, both of which are reversible.
We examine the general problem of light transport initiated by oblique illumination of a turbid medium with a collimated beam. This situation has direct relevance to the analysis of cloudy atmospheres, terrestrial sur...
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We examine the general problem of light transport initiated by oblique illumination of a turbid medium with a collimated beam. This situation has direct relevance to the analysis of cloudy atmospheres, terrestrial surfaces, soft condensed matter, and biological tissues. We introduce a solution approach to the equation of radiative transfer that governs this problem, and develop a comprehensive spherical harmonics expansion method utilizing Fourier decomposition (SHEFN). The SHEFN approach enables the solution of problems lacking azimuthal symmetry and provides both the spatial and directional dependence of the radiance. We also introduce the method of sequential-order smoothing that enables the calculation of accurate solutions from the results of two sequential low-order approximations. We apply the SHEFN approach to determine the spatial and angular dependence of both internal and boundary radiances from strongly and weakly scattering turbid media. These solutions are validated using more costly Monte Carlo simulations and reveal important insights regarding the evolution of the radiant field generated by oblique collimated beams spanning ballistic and diffusely scattering regimes.
This article was originally published online on 29 September 2014 with an error in the journal title of Ref. 36. The corrected reference appears below:
This article was originally published online on 29 September 2014 with an error in the journal title of Ref. 36. The corrected reference appears below:
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