RNA interference (RNAi) has shown immense potential for treating diseases by selectively silencing an abnormal/pathological pathway through the degradation of target messenger RNA (mRNA). However, exploitation of RNAi...
Tetragonal Zirconia Polycrystals stabilized with 3% mol. content of yttria (3Y-TZP) has excellent properties in terms of strength and fracture toughness. These properties are mostly imputable to the transformation tou...
Tetragonal Zirconia Polycrystals stabilized with 3% mol. content of yttria (3Y-TZP) has excellent properties in terms of strength and fracture toughness. These properties are mostly imputable to the transformation toughening mechanism, by which the doped metastable tetragonal phase of zirconia transforms to monoclinic under applied stress ahead of a crack. This phenomenon is accompanied by a volume expansion of 5%, and increases the resistance to crack growth, thus leading to higher toughness and strength. An important drawback of this material is represented by the Low Temperature Degradation (LTD or aging), which consists in the progressive tetragonal-to-monoclinic phase transformation by the influence of water. This work focuses on the improvement of 3Y-TZP aging behavior in order to develop a novel dental post, by means of the addition of ceria from the surface. This was achieved through the impregnation of the pre-sintered samples with a solution containing Cerium, followed by sintering. Various pre-sintering temperatures were studied in terms of microstructure, mechanical properties and aging resistance. The novel zirconia dental posts developed in this work are much more resistant to LTD as compared to the base material with no loss in mechanical properties.
The objective of this work is to evaluate the ability of Mn-Ti substituted barium-strontium hexaferrite to absorb high frequency electromagnetic wave. To accomplish this objective, Mn-Ti substituted barium strontium h...
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Three different kinds of siloxane-containing polybenzamide copolymers have been prepared: a series of siloxane-containing segmented copolymers; a siloxane-poly(benzamide) random copolymer; and a poly(benzamide) - poly...
Three different kinds of siloxane-containing polybenzamide copolymers have been prepared: a series of siloxane-containing segmented copolymers; a siloxane-poly(benzamide) random copolymer; and a poly(benzamide) - poly(dimethylsiloxane) block copolymer. The structures of these copolymers were confirmed using diffuse reflectance FTIR spectroscopy. Dilute solution viscometery showed them to be high polymers. The thermal stabilities of these copolymers were studied using thermal gravimetric analysis. Incorporation of siloxane units via a phenyl link was found to not affect the inherent thermal stability of the poly(benzamide) chain. The solution phase behavior of these copolymers in DMAC/LiCl was studied using an optical microscope fitted with cross-polars. The segmented copolymers and the block copolymer exhibited lyotropic behavior, which was influenced by the amount of siloxane and the overall molecular architecture. Solutions of the random copolymer were isotropic at all concentrations studied.
We show evidence of electrical and thermal conductivity percolation in polymer based carbon nanotube (CNT) composites, which follow power law variations with respect to the CNT concentrations in the matrix. The experi...
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Impression creep tests on a Sn-Pb eutectic alloy showed a hyperbolic sine stress dependence of impressing velocity and an activation energy of 55 kJ/mole which is independent of the punching stress. A finite element s...
Impression creep tests on a Sn-Pb eutectic alloy showed a hyperbolic sine stress dependence of impressing velocity and an activation energy of 55 kJ/mole which is independent of the punching stress. A finite element simulation showed that this phenomena could be explained by a constitutive law in which the creep rate is also a hyperbolic sine function of stress. This simulation also gives an impressing velocity which is proportional to the punch size for the same punching stress. Then by using lubrication theory, it is possible to relate this constitutive law to an interphase shearing mechanism in which the rate of interphase shear is a hyperbolic sine function of the shear stress. This theory gives a creep rate which depends inversely on the third power of grain size at low stresses.
The photoinduced dynamical reverse piezoelectric effect in epitaxial BiFeO3 thin films has been characterized by time-resolved hard X-ray diffraction measurements for ultrafast optical control of room temperature mult...
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